• Title/Summary/Keyword: Ammonia-nitrogen

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Effect of Water Chemistry Factors on Flow Accelerated Corrosion : pH, DO, Hydrazine (유동가속부식에 영향을 미치는 수화학 인자 : pH, 용존산소, 하이드라진)

  • Lee, Eun Hee;Kim, Kyung Mo;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • v.12 no.6
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    • pp.280-287
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    • 2013
  • Flow accelerated corrosion(FAC) of the carbon steel piping in pressurized water reactors(PWRs) has been major issue in nuclear industry. Severe accident at Surry Unit 2 in 1986 initiated the worldwide interest in this area. Major parameters influencing FAC are material composition, microstructure, water chemistry, and hydrodynamics. Qualitative behaviors of FAC have been well understood but quantitative data about FAC have not been published for proprietary reason. In order to minimize the FAC in PWRs, the optimal method is to control water chemistry factors. Chemistry factors influencing FAC such as pH, corrosion potential, and hydrazine contents were reviewed in this paper. FAC rate decreased with pH up to 10 because magnetite solubility decreased with pH. Corrosion potential is generally controlled dissolved oxygen (DO) and hydrazine in secondary water. DO increased corrosion potential. FAC rate decreased with DO by stabilizing magnetite at low DO concentration or by formation of hematite at high DO concentration. Even though hydrazine is generally used to remove DO, hydrazine itself thermally decomposed to ammonia, nitrogen, and hydrogen raising pH. Hydrazine could react with iron and increased FAC rate. Effect of hydrazine on FAC is rather complex and should be careful in FAC analysis. FAC could be managed by adequate combination of pH, corrosion potential, and hydrazine.

Moisture Effect on Fermentation Characteristics of Cup-Plant Silage

  • Han, K.J.;Albrecht, K.A.;Muck, R.E.;Kim, D.A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.5
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    • pp.636-640
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    • 2000
  • Cup-plant (Silphium perfoliatum L.) has potential to produce high biomass and highly digestible forage in the wetlands where other productive forages do not grow or produce well. However, high moisture content at harvest is a considerable disadvantage of cup-plant for the production of high quality silage. This study was conducted to determine the effect of moisture content on the characteristics of cup-plant silage. Harvested cup-plant was ensiled in farm scale plastic bag silos and laboratory silos. In the plastic bag silos, first growth (FG) and regrowth (RG) cup-plant was harvested, wilted and ensiled. Dry matter content of FG and RG was 280 g/kg and 320 g/kg after 48 hr of wilting. The silage made with FG had pH 5.3 and 5.63 g/kg DM of acetate as a major volatile fatty acid. The composition of lactate, butyrate and acetate production was 1.0: 0.9: 2.3. The pH of silage made with RG was 4.5 and lactate was a major fermentation end product (16.8 g/kg DM). In the laboratory silos, wilted and unwilted first growth cup-plant material was ensiled to compare the early fermentation end products at days 2, 4, 11, and 40. Wilting increased dry matter content by 42% in the harvested material. Wilted silage showed about one unit lower pH until day 11. The contents of ammonia nitrogen and acetate were higher in un wilted silage, while that of lactate was higher in wilted silage (p<0.05). Butyrate and propionate were not detected in the wilted silage until day 40. We conclude from the results that moisture control is essential for the production of high quality cup-plant silage and high pH of cup-plant silage is due to low concentrations of fermentation end products.

Influence of Sulfur on Fresh Cassava Foliage and Cassava Hay Incubated in Rumen Fluid of Beef Cattle

  • Promkot, C.;Wanapat, M.;Wachirapakorn, C.;Navanukraw, C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.9
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    • pp.1424-1432
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    • 2007
  • Two male, rumen fistulated crossbred Brahman-Thai native beef cattle (body weight = $400{\pm}50$ kg), fed on rice straw as a source of roughage, were used as rumen fluid sources. The treatments were $2{\times}3$ factorial arrangements; two roughages (fresh cassava foliage and cassava hay) and three sulfur levels (elemental sulfur) at 0.2 (control), 0.5 and 1% of DM, respectively. The experiment revealed that the rates (c) of gas production, ammonia-nitrogen concentration, true digestibility, total concentration or molar proportions of VFA and microbial biomass were not significantly different between cassava hay and fresh cassava foliage. However, all parameters for cassava hay were higher than for fresh cassava foliage. The supplementation of 0.5% sulfur to fresh cassava foliage resulted in a significant increase in the rate of gas production, true digestibility, total concentration of VFA, microbial biomass, rate of HCN disappearance, thiocyanate appearance and cyanide percentage conversion into thiocyanate. However, there were no effects of sulfur supplementation at 0.2, 0.5 and 1% to cassava hay. The finding suggests the utilization of cassava foliage for rumen microorganisms in terms of fermentation and HCN detoxification could be improved by sulfur supplementation of 0.5% of DM.

Interrelation between N and S Nutrition on Accumulation of Storage Protein in Soybean Seed

  • Paek, Nam-Chon;Richard Shibles
    • Plant Resources
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    • v.1 no.2
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    • pp.113-120
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    • 1998
  • Soybean is an important crop because its seed has very high protein relative to others. The quality of soy protein is limited by the concentration of the sulfur-containing amino acids in the amino acid profile. Among the supply of various forms of 0.4mM sulfur as S nutrition during seed fill. only 0.4mM L-methionine can inhibit ${\beta}$-subunit synthesis completely and produce the highest glycinin-containing seeds. Compared to 0.4mM sulfate control, seeds supplied by 0.4mM L-methionine have lower ${\alpha}$-, no ${\beta}$-subunit, and highly increased glycinin without altering total protein concentration. Supply of 0.2mM cystine (0.4mM S) did not affect the accumulative pattern of seed storage protein (SSP) subunits. In the supply of L-methionine, 0.2mM treatment showed higher glycinin in seeds but 0.05mM resulted in lower glycinin than tile sulfate control. The relative abundance of ${\alpha}^`$-subunit was not altered by any N or S nutrition. Under 5mM nitrogen, protein concentration was increased about 3-5% by substituting ammonia for nitrate during seed fill independent of nutrition. The increase resulted in the only increase of 7S protein, mainly ${\beta}$-subunit. Our data suggest that the regulatory system of SSP genes responds to the balance between N and S assimilates supplied from mother plant. and controls the di fferential synthesis of their subunits for the maximum protein accumulation in developing soybean seed.

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Ozone-Activated Carbon Treatment in Middle Keum River containing Ammonia-Nitrogen (암모니아성질소를 함유한 금강중류 하천수의 오존-활성탄처리)

  • Kim, Chung-Hwan;Jung, Sang-Gi;Kim, Hag-Seong
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.355-363
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    • 2002
  • A demonstration plant was carried out to investigate the removal efficiency of $NH_3-N$ and $KMnO_4$ consumption depending on the existence of pre-chlorination for the ozonation and activated carbon process in the S water treatment plant which is located at the middle of Keum River. The averge removal efficiency of $KMnO_4$ consumption for $O_3/GAC$ processes with pre-chlorination and $O_3/BAC$ processes without pre-chlorination were 48.6% and 50% respectively. It is similar to removal effect of $KMnO_4$ consumption for GAC and BAC process depending on the existence of pre-chlorination. Otherwise, the removal of THMFP for GAC and BAC process was 58% and 68% respectively. $NH_3-N$ was not almost removed by sand filter and ozonation, but the average removal efficiency in the BAC process was about 31%. Especially, $NH_3-N$ was not almost removed by $O_3/BAC$ processes at the low temperature (below $$10^{\circ}C$$) in the winter season, $O_3/BAC$ processes have the advantage of removal of organic substance when it is compared to pre -chlorination followed by $O_3/GAC$ processes. Pre-chlorination followed by $O_3/GAC$ processes were required to remove $NH_3-N$ in the winter season because the removal of $NH_3-N$ was almost ineffective by $O_3/BAC$ process.

Reduction Effect of Airborne Pollutants in Pig Building by Air Cleaner Operated with Plasma Ion (플라즈마 이온 방식의 공기정화기를 이용한 돈사내 공기오염물질 저감 효과)

  • Kim, Yoon-Shin;Kim, Ki-Youn;Cho, Man-Su;Ko, Moon-Suk;Ko, Han-Jong;Jung, Jin-Won;Oh, Mi-Seok;Youn, Baek;Kim, Jung-Ho
    • Journal of Environmental Health Sciences
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    • v.36 no.4
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    • pp.306-312
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    • 2010
  • This field study was performed to evaluate the efficiency of a plasma ion-operated air cleaner in temporal reduction of airborne pollutants emitted from a pig housing facility. In the case of gaseous pollutants, the plasma ion air cleaner was not effective in reducing levels of ammonia, hydrogen sulfide, nitrogen dioxide, or sulfur dioxide (p>0.05). In the case of particulate pollutants, however, the air cleaner was effective in reducing levels of particulate matter ($PM_{2.5}$ and $PM_1$) by 79(${\pm}6.1$) and 78(${\pm}3.0$)%, respectively. Unlike the case of these fine particle fractions, the reduction of total suspended particles (TSP) and $PM_{10}$ following treatment was almost negligible. In the case of biological pollutants, the mean reduction efficiencies for airborne bacteria and fungi were relatively low at 22(${\pm}6.6$) and 25(${\pm}8.7$)%, respectively. Taken together, these results indicate that in terms of air pollutants released from this pig housing facility, the plasma ion air cleaner was primarily effective in reducing levels of $PM_{2.5}$ and $PM_1$.

The Variation of Water Quality due to Sulice Gate Operation in Shiwha Lake (시화호의 배수갑문 운용에 따른 수질변화)

  • 김종구;김준우;조은일
    • Journal of Environmental Science International
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    • v.11 no.12
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    • pp.1205-1215
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    • 2002
  • To evaluate the change for water quality after the water gate operation in Shiwha lake, in situ survey were conducted on september in 2000 and January, march, jane in 2001. Chemical characteristics and eutrophication level was estimated from the survey data. The water quality of the Shihwa lake was greatly affected by pollutant load from rainfall, and formation of stratification in summer and winter was increased to effect on nutrient release from sediment. Especially, high concentration of chlorophyll-a was occurred in autumn, due to increased nutrient, high water temperature and low salinity after rainfall runoff. The mean concentration of DIN, DIP were 0.346mg/L, 0.0217mg/L in surface water and 0.826mg/L, 0.0415mg/L in bottom water, respectively, which were over III grade of seawater standard. Also high percentage of ammonia nitrogen to DIN in bottom water for autumn and winter was affected by released nutrient from sediment. Correlation analysis of chlorophyll-a versus TSS was shown that organic matter was affected by autochthonous organic matter stem from the algae, these factor showed reverse correlation about salinity. Closely correlations among to the water quality constituent in continuity survey was appeared. The results of eutrophication index estimation showed the high potentiality of red tide occurrence in Shiwha lake, particularity in summer or fall. Overall water quality was greatly improve to compared with measuring data during 1997~1998 at the beginning water gate operation, which reported by KORDI. Therefore, to improve of water quality in Shiwha lake, we need to establish of management plan about nutrient release from sediment, rainfall runoff, maximum of seawater exchange.

Effect of Cassoy-urea Pellet as a Protein Source in Concentrate on Ruminal Fementation and Digestibility in Cattle

  • Wanapat, Metha;Promkot, C.;Wanapat, S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.7
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    • pp.1004-1009
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    • 2006
  • Four male crossbred native beef cattle (average body weight of 427.7 kg) were randomly allocated to four types of cassoy-urea pellet as a source of protein in concentrate according to a $4{\times}4$ Latin square design to determine effect of diets on ruminal fermentation and nutrient digestibility. The four types of cassoy-urea pellets contained cassava hay, soybean meal, urea and binding agent at 79.2:19.8:0:1 (27.9% CP dry matter), 78.4:19.6:1:1 (30.4% CP), 77.6:19.4:2:1 (33.0% CP) and 99:0:0:1 (23.8% CP) for dietary treatments; 1, 2, 3 and 4, respectively. All four concentrate mixtures contained similar crude protein levels (11% CP) and were fed to animals in two equal parts (0.5% of body weight per day) while urea-treated rice straw (5% urea) was given ad libitum. The experiment revealed that dietary concentrate treatments had no effect on dry matter intake while digestibilities of neutral-detergent fiber and crude protein were higher (p<0.05) in cattle fed dietary treatments 1, 2 and 3 than in cattle fed dietary treatment 4. Ruminal ammonia-nitrogen ($NH_3$-N), was higher and acetic acid concentration (C2) and ratio of C2 to propionic acid (C3) were lower (p<0.05) in cattle fed dietary treatments 1, 2 and 3 than in those on treatment 4. It is concluded that use of cassoy-urea pellet as a protein source in concentrates for cattle resulted in improvement of digestibility, ruminal fermentation and rumen ecology. Further research using cassoy-urea pellet in feeding trials with milking cows and fattening beef should be undertaken.

Effects of Spent Mushroom Substrates Supplementation on Rumen Fermentation and Blood Metabolites in Hanwoo Steers

  • Oh, Young-Kyoon;Lee, Won-Man;Choi, Chang-Weon;Kim, Kyoung-Hoon;Hong, Seong-Koo;Lee, Sang-Cheol;Seol, Yong-Joo;Kwak, Wan-Sup;Choi, Nag-Jin
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.12
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    • pp.1608-1613
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    • 2010
  • This study was designed to investigate the effects of supplementation of spent mushroom substrates (SMS) on rumen fermentation and blood metabolites in Hanwoo steers. The experiment was conducted as a duplicated Latin square design with six Hanwoo steers ($600{\pm}47\;kg$), each permanently fitted with a ruminal cannula. There were three treatments; i) control (concentrates 4.8 kg +rice straw 1.2 kg/d), ii) Pleurotus eryngiia (PE) treatment (concentrates 4.8 kg+rice straw 0.73 kg+Pleurotus eryngiia 1.20 kg/d) and iii) Pleurotus osteratus (PO) treatment (concentrates 4.8 kg+rice straw 0.73 kg+Pleurotus osteratus 1.20 kg/d). There were no major effects of different dietary treatments on rumen parameters such as pH, ammonia-N, individual and total VFA production. Parameters of N utilization, including blood urea nitrogen (BUN), total protein and albumin levels, were not significantly different among the treatments, except for creatinine. Thus, the present results indicated that protein utilization was mostly unaffected by SMS treatments such as PE and PO, even though creatinine concentration was lower in PE compared with control and PO treatments (p<0.05). The present results indicate that Pleurotus eryngii and Pleurotus osteratus could be used as a forage source to replace 40% of rice straw without any negative effects on rumen fermentation and blood metabolites in Hanwoo steers.

Estimation of Ruminal Degradation and Intestinal Digestion of Tropical Protein Resources Using the Nylon Bag Technique and the Three-step In vitro Procedure in Dairy Cattle on Rice Straw Diets

  • Promkot, C.;Wanapat, Metha;Rowlinson, P.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.12
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    • pp.1849-1857
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    • 2007
  • The experiment was carried out using fistulated multiparous Holstein Friesian crossbred (75% Holstein Friesian and 25% Red Sindhi) dairy cows in their dry period fed on untreated rice straw to evaluate the nutritive value of local protein feed resources using the in sacco method and in vitro pepsin-pancreatin digestion. Experimental feeds were cottonseed meal (CSM); soybean meal (SBM); dried brewery's grains (DBG); palm kernel meal (PSM); cassava hay (CH); leucaena leaf meal (LLM). Each feedstuff was weighed into duplicate nylon bags and incubated in each of the two rumen fistulated cows for 0, 2, 4, 8, 16, 24, and 48 h. Rumen feed residues from bags of 16 h incubation were used for estimation of lower gut digestibility by the technique of in vitro pepsin-pancreatin digestion. Ruminal ammonia-nitrogen ($NH_3-N$) concentrations did not differ between treatments or time with a mean of 5.5 mg%. Effective degradability of DM of CSM, SBM, DBG, PSM, CH and LLM were 41.9, 56.1, 30.8, 47.0, 41.1 and 47.5%, respectively. Effective degradabilities of the CP in feedstuffs were 49.6, 59.2, 40.9, 33.5, 47.3 and 65.0% for the respective feedstuffs. The CP in vitro pepsin-pancreatin digestibility as ranked from the highest to the lowest were SBM, CSM, LLM, CH, DBG, PSM, respectively. The intestinal and total tract digestion of feedstuffs in the current study were relatively lower than that obtained from previous literature. The results of this study indicate that SBM and LLM were highly degradable in the rumen, while CH, CSM and DBG were less degradable and, hence resulted in higher rumen undegradable protein. Soybean meal and LLM could be used to improve rumen ecology whilst CH, CSM and DBG could be used as rumen by-pass protein for ruminant feeding in the tropics.