• 한국대기환경학회지
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• 제22권5호
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• pp.701-711
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• 2006

Sewage treatment plants located near to large cities emit extremely higher concentration of odorous materials. This study evaluated flux profiles of ammonia emitted from the water surface of sewage treatment plants using a dynamic flux chamber. Also, an ammonia overall mass transfer coefficient and a mass transfer model was developed in order to estimate fluxes of ammonia using environment parameters and the flux from the sewage treatment plants. The developed mass transfer model was evaluated through a fitness analysis. Comparison modeled flux applying empirical overall mass transfer coefficients of ammonia and measured ammonia flux show a high linearity with 0.977. The flux ratio of 1.282 demonstrated highly statistical fitness, also. Modeled flux using the mass transfer model was compared with measured flux. In result, it indicated that empirical overall mass transfer coefficients were similar to measured flux. The mass transfer model using the empirical overall mass transfer coefficient developed in this study was proved to be an easy and effective method to make accurate and precise predictions for ammonia flux discharged from sewage treatment plants.

• 설비공학논문집
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• 제11권3호
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• pp.414-421
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• 1999

Falling film rectification involves simultaneous heat and mass transfer between vapor and liquid interface. In the present work, the adiabatic rectification process of ammonia-water vapor on the vertical plate was investigated. The continuity, momentum, energy and diffusion equations for the solution film and vapor mixture were formulated in integral forms and solved numerically. The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer in each phases were investigated. The stripping of water in vapor mixture occurred new the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer in falling film.

• International Journal of Air-Conditioning and Refrigeration
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• 제8권2호
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• pp.69-79
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• 2000

Falling film rectification involves simultaneous heat and mass transfer between vapor and solution film. In the present work, the adiabatic rectification process of ammonia-water vapor by the falling solution film on the vertical plate was investigated. The continuity momentum, energy and diffusion equations for the solution film and the vapor mixture were formulated in integral forms and solved numerically, The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer coefficient in each phases were investigated. The stripping of water in vapor mixture occurred near the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer coefficient in falling film.

• 상하수도학회지
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• 제25권4호
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• pp.503-510
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• 2011

Ammonia in water which is toxic to human, its concentration is regulated below 0.5 mg/L in drinking water. Current study aimed to develop appropriate models for ammonia stripping using hollow fiber membrane contactor. Two different models were developed during the study. Model 1 was assumed only free ammonia ($NH_3$) transfer in stripping process, whereas the Model 2 was assumed with total ammonia ($NH_3+{NH_4}^+$) transfer. Ammonium chloride ($NH_4CI$), sodium hydroxide(NaOH) were used to make ammonia solution, which was concentration of 25 mg as N/L at a pH of 10.5. The experimental conditions were such that, the liquid flow was in tube-side in upward direction and t he gas flow was on shell-side in downward direction a t room temperature. The experimental and modeling results showed that marginal difference were observed at low gas flux. However the difference between the both models and experimental value were increased when the gas flux was increased. The study concludes that the Model 1 with free ammonia is more appropriate when both models were compared and useful in ammonia stripping process at low gas flux.

• 설비공학논문집
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• 제12권1호
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• pp.102-111
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• 2000

A numerical model which simulates the simultaneous heat and mass transfer within a vertical tube GAX absorber was developed. The ammonia vapor and the solution liquid are in counter-current flow, and the hydronic fluid flows counter to the solution liquid. The film thickness and the velocity distribution of the liquid film were obtained by matching the shear stress at the liquid-vapor interface. Two-dimensional diffusion and energy equations were solved in the liquid film to give the temperature and concentration, and a modified Colburn-Drew analysis was used for the vapor phase to determine the heat and mass fluxes at the liquid-vapor interface. The model was applied to a GAX absorber to investigate the absorption rates, temperature and concentration profiles, and mass flow rates of liquid and vapor phases. It was shown that the mass flux of water was negligible compared with that of ammonia except the region near the liquid inlet. Ammonia absorption rate increases rapidly near the liquid inlet and decrease slowly. Both the absorption rate of ammonia vapor and the desorption rate of water near the liquid inlet increase as the vapor mass flow rate increases, but the mass fluxes of the ammonia and the water near the liquid outlet decrease as the mass flow rate of the vapor increases.

• 설비공학논문집
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• 제16권1호
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• pp.16-25
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• 2004

The flow and heat/mass transfer in the falling-film of a heat exchanger can be influenced by the motion of the surrounding refrigerant vapor. In this study, the effect of the vapor flow direction on the absorption heat transfer has been investigated for a falling-film helical coil which is frequently used as the absorber of ammonia/water absorption refrigerators. The experiments were carried out for different solution concentration. The heat and mass transfer performance was measured for both parallel and counter-current flow. The effect of vapor flow on the heat and mass transfer is found to be increased with decreasing solution concentration. In the experiments with low solution concentration, whose vapor specific volume is great, the counter-current flow of vapor resulted in uneven distribution of falling-film and reduced the heat transfer performance of the absorber. The direction of the vapor flow hardly affected the thermal performance as the solution concentration became stronger since the specific volume of the ammonia/water vapor was much smaller than that of the water vapor.

• Bulletin of the Korean Chemical Society
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• 제31권7호
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• pp.1920-1926
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• 2010

Yoon et $al.^1$ presented an approximate mathmatical model to describe ammonia removal from an experimental batch reactor system with gaseous headspace. The development of the model was initially based on assuming instantaneous equilibrium between ammonia in the aqueous and gas phases. In the model, a "saturation factor, $\beta$" was defined as a constant and used to check whether the equilibrium assumption was appropriate. The authors used the trends established by the estimated $\beta$ values to conclude that the equilibrium assumption was not valid. The authors presented valuable experimental results obtained using a carefully designed system and the model used to analyze the results accounted for the following effects: speciation of ammonia between $NH_3$ and $NH^+_4$ as a function of pH; temperature dependence of the reactions constants; and air flow rate. In this article, an alternative model based on the exact solution of the governing mass-balance differential equations was developed and used to describe ammonia removal without relying on the use of the saturation factor. The modified model was also extended to mathematically describe the pH dependence of the ammonia removal rate, in addition to accounting for the speciation of ammonia, temperature dependence of reactions constants, and air flow rate. The modified model was used to extend the analysis of the original experimental data presented by Yoon et $al.^1$ and the results matched the theory in an excellent manner.

• 설비공학논문집
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• 제12권6호
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• pp.561-569
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• 2000

Single phase and condensation heat transfer characteristics of ammonia in a horizontal tube have been investigated experimentally The horizontal test section is composed of smooth SUS316 tube for refrigerant flow, surrounding annulus for water flow, and temperature and Pressure measuring sensors. For single phase test, subcooled ammonia mass flux was varied from 320 to 501 kg/mrs and temperature was varied from 18 to $47^{\circ}C$. For condensation test, mass flux and saturation temperature were varied from 86 to 128 kg/$m^2$s and 34 to $47^{\circ}C$, respectively. The equations of Gnielinski Soliman et al., Traviss et at., Cavallini and Zecchin, Shah, Chen et al., Tandon et al., and Chilli and Anand were compared with the experimental data. New correlations are proposed based on the experimental results and the absolute mean deviation of the experimental data becomes 1.0% for single phase test and 4.9% for condensation test.

• 설비공학논문집
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• 제25권2호
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• pp.101-108
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• 2013

This paper is presented an experimental study of flow boiling heat transfer characteristics of ammonia, and is focused on pressure gradient and heat transfer coefficient of the refrigerant flow inside horizontal small tube with inner diameter of 3.0 mm and length of 2000 mm. The direct heating method is applied for supplying heat to the refrigerant, where the test tube is uniformly heated by electric current. The local heat transfer coefficients were obtained over a heat flux range of 20 to $80kW/m^2$, a mass flux range of 50 to $500kg/m^2s$, a saturation temperature range of 0 to $10^{\circ}C$, and quality up to 1.0. The pressure drops increase with increasing mass flux and heat flux, and with decreasing saturation temperature. The heat transfer coefficients increase with increasing mass flux and saturation temperature in middle and high quality region. And the local heat transfer coefficient increase with increasing heat flux in low quality region. The heat transfer coefficient of the experimental result was compared with six existing heat transfer coefficient correlation. A new boiling heat transfer coefficient correlation based on the superposition model for ammonia in small tubes is developed average deviation of -0.17% and mean deviation of 10.85%.

• 설비공학논문집
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• 제11권4호
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• pp.431-439
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• 1999

A generator-GAX combined rectification system of an ammonia absorption heat pump was investigated to get the optimum design values. The mass and heat transfer phenomena of the rectification system were analysed. The number of column plates, equilibrium temperature of solution on each plate and flow rates of solution and vapor generated were predicted. The characteristics of mass and heat transfer of the generator-GAX combined rectification system, i.e. concentration difference of leaving solution and vapor on each column plate, were found to be mainly governed by the pressure of generator, reflex ratio and temperature difference of analyser coolant. The number of rectification column plates for each different pressure in generator was obtained. The optimum locations for installing the feeder from solution-cooled absorber and GAX desorber in generator were predicted. The improvement of COP was followed by the increase of the rectifier efficiency and the number of column plate, and the decrease of reflex ratio.