• Title/Summary/Keyword: Ammonia emissions

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Study on Priority Decision for Ship's Alternative Fuel Selection Using Fuzzy TOPSIS Method (퍼지 TOPSIS 기법을 이용한 선박 대체 연료 선정의 우선순위 결정에 관한 연구)

  • Jeonghak Lee;Juyeong Shin;Jaehoon Jee
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.30 no.1
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    • pp.135-145
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    • 2024
  • At the 80th session of the MEPC, the IMO presented an enhanced GHG reduction strategy. The strategy is more specific and robust than the initial strategy presented at the 72nd session. The IMO aims to achieve 'Net Zero' GHG emissions from international shipping by 2050. In this study, a risk assessment was conducted for representative green fuels, namely. LNG, hydrogen, methanol, and ammonia. The fuzzy method was used to resolve the subjective ambiguity of results from the survey of the experts, and the positive and negative ef ects of the fuzziness were derived through the TOPSIS method. Finally, the closeness coefficients of the considered alternative fuels were determined using the Vertex method. As a result, methanol, LNG, hydrogen, and ammonia were preferred. This study suggests that the proposed approach can be used as a collective decision-making tool for selecting alternative fuels.

A case study on monitoring the ambient ammonia concentration in paddy soil using a passive ammonia diffusive sampler (논 토양에서 암모니아 배출 특성 모니터링을 위한 수동식 암모니아 확산형 포집기 이용 사례 연구)

  • Kim, Min-Suk;Park, Minseok;Min, Hyun-Gi;Chae, Eunji;Hyun, Seunghun;Kim, Jeong-Gyu;Koo, Namin
    • Korean Journal of Environmental Biology
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    • v.39 no.1
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    • pp.100-107
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    • 2021
  • Along with an increase in the frequency of high-concentration fine particulate matter in Korea, interest and research on ammonia (NH3) are actively increasing. It is obvious that agriculture has contributed significantly to NH3 emissions. However, studies on the long-term effect of fertilizer use on the ambient NH3 concentration of agricultural land are insufficient. Therefore, in this study, NH3 concentration in the atmosphere of agricultural land was monitored for 11 months using a passive sampler. The average ambient NH3 concentration during the total study period was 2.02 ㎍ m-3 and it was found that the effect of fertilizer application on the ambient NH3 concentration was greatest in the month immediately following fertilizer application (highest ambient NH3 concentration as 11.36㎍ m-3). After that, it was expected that the NH3 volatilization was promoted by increases in summer temperature and the concentration in the atmosphere was expected to increase. However, high NH3 concentrations in the atmosphere were not observed due to strong rainfall that lasted for a long period. After that, the ambient NH3 concentration gradually decreased through autumn and winter. In summary, when studying the contribution of fertilizer to the rate of domestic NH3 emissions, it is necessary to look intensively for at least one month immediately after fertilizer application, and weather information such as precipitation and no-rain days should be considered in the field study.

Experimental Study on Characteristics of Ammonia Conversion Rate of Urea Aqueous Solution in 250℃ Exhaust Pipe (250℃ 이하 배기관에서 우레아 수용액의 암모니아 전환율 특성에 관한 실험적 연구)

  • Ku, Kun Woo;Park, Hong Min;Hong, Jung Goo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.2
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    • pp.177-182
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    • 2015
  • The NOx emissions from diesel engines and industrial boilers are a major cause of environmental pollution. The selective catalytic reduction of urea is an aftertreatment technology that is widely used for the reduction of NOx emissions. The objective of this study was to investigate the characteristics of the thermal decomposition of a urea aqueous solution using laboratory-scale experimental equipment under conditions similar to those of marine diesel engines. A 40 wt. urea aqueous solution was used in this study. It was found that the total conversion rate varied with the inflow gas conditions and flow rates of the urea aqueous solution. In addition, there were conversion rate differences between NH3 and HNCO. At inflow gas temperature conditions of $210^{\circ}C$ and $250^{\circ}C$, the $NH_3$ conversion rate was found to be higher than that of the HNCO, depending on the residence time.

Modeling and Simulation of Small and Medium-sized Ships for Fuel Reduction Rate Verification (연료 감소율 검증을 위한 중소형 선박의 모델링 및 시뮬레이션)

  • Kim, Sung-Dong;Kim, Nam-Ho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.6
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    • pp.914-921
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    • 2022
  • The International Maritime Organization (IMO) has set a goal of reducing ship's carbon dioxide emissions by 70% and greenhouse gas emissions by 50% by 2050 compared to 2008. Shipowners and shipyards are promoting various R&D activities such as LNG propulsion, ammonia propulsion, electric propulsion, CO2 capture, and shaft generators as a way to satisfy this problem. The dual shaft generator has the advantage that it can be directly applied to an existing ship through remodeling. In this paper, the total fuel reduction rate that can be obtained by applying the shaft generator to the existing ship was verified through simulation. For this purpose, the size of the medium-sized ship was defined, and the governor, diesel engine, propeller, torque switch, generator for shaft generator, propulsion motor for shaft generator, and ship model were modeled and simulated.

Effects of Different Dietary Acidifier Sources of Calcium and Phosphorus on Ammonia, Methane and Odorant Emission from Growing-finishing Pigs

  • Kim, I.B.;Ferke, P.R.;Powers, W.J.;Stein, H.H.;Van Kempe, T.A.T.G.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.8
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    • pp.1131-1138
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    • 2004
  • The objective of this study was to investigate the effects of different sources of Ca and P on urine and ileal digesta pH, and ammonia ($NH_{3}$), methane ($CH_{4}$), and odor emission. In experiment 1, eight pigs (commercial three-way cross; initial BW 67$\pm$3 kg) were arranged in a repeated 4$\times$4 Latin Square design. All pigs were equipped with a T-cannula in the distal ileum. Four corn-soybean meal based diets were formulated. Diet 1 was the control in which dicalcium phosphate (DCP) and limestone ($CaCO_{3}$) were used as the sources of inorganic P and Ca. In Diets 2 and 3, ${H_{3}}{PO_{4}}$, monocalcium phosphate (MCP), and $CaSO_{4}$replaced DCP and $CaCO_{3}$ as the inorganic sources of P and Ca. Diet 4 was similar to Diet 1 except that it was fortified with HCl to provide an acid load similar to that of diet 2. Urine and ileal digesta pH were determined in pigs fed each of these diets. In Exp. 1, urine pH decreased (p<0.05) in animals consuming diets containing ${H_{3}}{PO_{4}}$-$CaSO_{4}$ (5.85$\pm$0.38) and MCP-$CaSO_{4}$(5.73$\pm$0.30) compared with the DCP-$CaCO_{3}$ diet (6.89$\pm$0.24). In the pigs consuming ${H_{3}}{PO_{4}}$-$CaSO_{4}$, ileal digesta pH decreased compared with the control (5.52$\pm$0.28 vs. 6.66$\pm$0.17; p<0.05). Based on the results of Exp. 1, a total of four trials were performed in environmental chambers for determining how $NH_{3}$, $NH_{4}$, and odor were affected by the different dietary Ca and P sources (Exp. 2). In Exp. 2, pigs fed the ${H_{3}}{PO_{4}}$-$CaSO_{4}$ diet had decreased (30%) $NH_{3}$ emissions compared with the control (p<0.05). Also, a combination of MCP-$CaCO_{3}$-$CaCl_{12}$ decreased $NH_{3}$ emission by 15% (p<0.05). Emission of $CH_{4}$ was decreased only with the ${H_{3}}{PO_{4}}$-$CaSO_{4}$ diet with 14% (p<0.05). Odorant emission of phenolics and volatile fatty acids increased roughly three-fold with the DCP-$CaSO_{4}$ diet but was not affected by other test diets. In conclusion, acidogenic Ca and P sources in swine diets can decrease the urinary pH and reduce $NH_{3}$ and $CH_{4}$ emission from swine facilities.

Dynamics of Air Temperature, Velocity and Ammonia Emissions in Enclosed and Conventional Pig Housing Systems

  • Song, J.I.;Park, K.H.;Jeon, J.H.;Choi, H.L.;Barroga, A.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.3
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    • pp.433-442
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    • 2013
  • This study aimed to compare the dynamics of air temperature and velocity under two different ventilation and housing systems during summer and winter in Korea. The $NH_3$ concentration of both housing systems was also investigated in relation to the pig's growth. The ventilation systems used were; negative pressure type for the enclosed pig house (EPH) and natural airflow for the conventional pig house (CPH). Against a highly fluctuating outdoor temperature, the EPH was able to maintain a stable temperature at 24.8 to $29.1^{\circ}C$ during summer and 17.9 to $23.1^{\circ}C$ during winter whilst the CPH had a wider temperature variance during summer at 24.7 to $32.3^{\circ}C$. However, the temperature fluctuation of the CPH during winter was almost the same with that of EPH at 14.5 to $18.2^{\circ}C$. The NH3 levels in the CPH ranged from 9.31 to 16.9 mg/L during summer and 5.1 to 19.7 mg/L during winter whilst that of the EPH pig house was 7.9 to 16.1 mg/L and 3.7 to 9.6 mg/L during summer and winter, respectively. These values were less than the critical ammonia level for pigs with the EPH maintaining a lower level than the CPH in both winter and summer. The air velocity at pig nose level in the EPH during summer was 0.23 m/s, enough to provide comfort because of the unique design of the inlet feature. However, no air movement was observed in almost all the lower portions of the CPH during winter because of the absence of an inlet feature. There was a significant improvement in weight gain and feed intake of pigs reared in the EPH compared to the CPH (p<0.05). These findings proved that despite the difference in the housing systems, a stable indoor temperature was necessary to minimize the impact of an avoidable and highly fluctuating outdoor temperature. The EPH consistently maintained an effective indoor airspeed irrespective of season; however the CPH had defective and stagnant air at pig nose level during winter. Characteristics of airflow direction and pattern were consistent relative to housing system during both summer and winter but not of airspeed. The ideal air velocity measurement favored the EPH and therefore can be appropriate for the Korean environment. Further emphasis on its cost effectiveness will be the subject of future investigations.

Sales Energy Promotion Efficiency and Policy Utilization Plan for Energy Facilities

  • KWON, Lee-Seung;LEE, Woo-Sik;KWON, Woo-Taeg
    • Journal of Distribution Science
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    • v.18 no.9
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    • pp.67-75
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    • 2020
  • Purpose: The purpose of this study is to enhance sales promotion efficiency for using solid refuse fuel facilities. Renewable energy technology using Solid Refuse Fuel (SRF) is an economic efficiency technology that recovers waste by burning various wastes. A survey on the pollutants discharged from the solid fuels facilities was investigated so that the SRF facilities could be expanded, distributed and reflected in the policy. Research design, data, and methodology: In this study, 9 business sites using SRF and Bio-SRF as main raw materials were investigated for 2 years. The characteristics of target business sites such as the type of fuel used, combustion method, combustion temperature, daily fuel consumption and environmental prevention facilities were studied. Results: The average pollution & ammonia concentration of Bio-SRF facilities was found to be 88.15% higher than that of SRF facilities. But the average acetaldehyde concentration of SRF facilities was found to be 88.15% higher than that of Bio-SRF facilities. Conclusions: The main issue is how much electric power generation using combustible materials affects air pollution. The waste recycling law provides the standard value according to the fuel property, but there is a considerable gap with the mixed fuel. Therefore, for efficient utilization of facilities using solid fuel products, additional research is needed to improve the distribution structure of exhaust pollutants is needed.

Design of a Combustion Chamber for Studying the Combustion Characteristics of Counterflow Flames at Elevated Pressure (압력변화에 따른 대향류 화염 연소특성 연구를 위한 가압 연소실 설계)

  • AHN, YEONG JONG;KU, JAE WON;CHOI, SUN;KOO, JAYE;KWON, OH CHAE
    • Journal of Hydrogen and New Energy
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    • v.28 no.3
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    • pp.315-321
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    • 2017
  • A combustion chamber is designed and fabricated for studying the combustion characteristics of counterflow flames at elevated pressure and establishing the fundamental combustion database of counterflow flames. The combustion chamber design aims to allow the maximum operating pressure of 11 bar and be able to conduct flame visualization and the measurements of flame extinction limits, flame temperature and combustion emissions at elevated pressure. Preliminary tests for counterflow nonpremixed $CH_4-NH_3-N_2$/air flames at 1-3 bar have been conducted, and the results confirm the proper operation of the designed chamber.

Nuclear power utilization as a future alternative energy on icebreakers

  • M. Bayraktar;M. Pamik
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.580-586
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    • 2023
  • Diversified fuel types such as methanol, hydrogen, liquefied natural gas, ammonia, biofuels, have been come to fore in consideration of the limitations, regulations, environmental perception and efficient use of resources on maritime sector. NE is described as a substantial alternative energy source on the marine vessels in the sense of de-carbonization and fuel efficiency activities carried out by IMO. Although NPVs have been constructed for the merchant, navy and supply fields over the years, their numbers are few and working ranges are quite limited. NE generation techniques, reactor types, safety and security issues in case of any leakage or radiation pollution are analyzed and comparisons are performed between fossil-based fueled and NP based on icebreakers. The comparison are conducted on the basis of dimensions, resistances and operational competences by the VIKOR. NP icebreakers operated in recent years occupy a notable position in the ranking, although fossil fueled ones are most prevalent. Consequently, refueling period and emissions are the principal benefits of NPVs. Nevertheless, the use of such systems on marine vessels especially for merchant ships may come to the fore when all concerns in terms of safety, security and society are resolved since the slightest mistake can have irreversible consequences.

Acidification of pig slurry effects on ammonia and nitrous oxide emissions, nitrate leaching, and perennial ryegrass regrowth as estimated by 15N-urea flux

  • Park, Sang Hyun;Lee, Bok Rye;Jung, Kwang Hwa;Kim, Tae Hwan
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.3
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    • pp.457-466
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    • 2018
  • Objective: The present study aimed to assess the nitrogen (N) use efficiency of acidified pig slurry for regrowth yield and its environmental impacts on perennial ryegrass swards. Methods: The pH of digested pig slurry was adjusted to 5.0 or 7.0 by the addition of sulfuric acid and untreated as a control. The pig slurry urea of each treatment was labeled with $^{15}N$ urea and applied at a rate of 200 kg N/ha immediately after cutting. Soil and herbage samples were collected at 7, 14, and 56 d of regrowth. The flux of pig slurry-N to regrowth yield and soil N mineralization were analyzed, and N losses via $NH_3$, $N_2O$ emission and $NO_3{^-}$ leaching were also estimated. Results: The pH level of the applied slurry did not have a significant effect on herbage yield or N content of herbage at the end of regrowth, whereas the amount of N derived from pig slurry urea (NdfSU) was higher in both herbage and soils in pH-controlled plots. The $NH_4{^+}-N$ content and the amount of N derived from slurry urea into soil $NH_4{^+}$ fraction ($NdfSU-NH_4{^+}$) was significantly higher in in the pH 5 plot, whereas $NO_3{^-}$ and $NdfSU-NO_3{^-}$ were lower than in control plots over the entire regrowth period. Nitrification of $NH_4{^+}-N$ was delayed in soil amended with acidified slurry. Compared to non-pH-controlled pig slurry (i.e. control plots), application of acidified slurry reduced $NH_3$ emissions by 78.1%, $N_2O$ emissions by 78.9% and $NO_3{^-}$ leaching by 17.81% over the course of the experiment. Conclusion: Our results suggest that pig slurry acidification may represent an effective means of minimizing hazardous environmental impacts without depressing regrowth yield.