• 제목/요약/키워드: Ammonia Gas

검색결과 717건 처리시간 0.028초

암모니아수의 농도별 간이 영향평가 방법 연구 (A Study on the Simplified Estimating Method of Off-site Consequence Analysis for Aqueous Ammonia)

  • 정유경;허화진;유병태;윤이;윤준헌;마병철
    • 한국가스학회지
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    • 제20권2호
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    • pp.49-57
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    • 2016
  • 암모니아 수용액은 탈질, 의류의 얼룩제거 등 생활전반에 광범위하게 사용되면서 누출사고도 빈번하게 발생하고 있다. 여기에서는 누출사고 시 비상대응에 필요한 영향범위를 비교적 정확하면서 신속하게 계산할 수 있는 간이 산정표와 산정식을 개발하였다. ALOHA 프로그램을 이용하여 일반적으로 유통되는 암모니아 수용액의 농도(10 % ~ 30 %)에 따른 영향거리를 액면의 크기($1m^2{\sim}500m^2$)별로 산정하여 제시하였다. 또한, 농도와 액면의 크기가 영향거리에 미치는 상관관계를 분석하여 해당 값에서 영향거리를 쉽게 계산할 수 있는 산정식을 개발하였다.

Effects of Yucca Extract and (or) Far Infrared Emitted Materials Supplementation on the Growth Performance, Serum Characteristics and Ammonia Production of Growing and Finishing Pigs

  • Hong, J.W.;Kim, I.H.;Moon, T.H.;Kwon, O.S.;Lee, S.H.;Kim, Y.G.
    • Asian-Australasian Journal of Animal Sciences
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    • 제14권9호
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    • pp.1299-1303
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    • 2001
  • For the Exp. 1, a total of fifty four crossbred [(Duroc Yorkshire)${\times}$Landrace] pigs ($77.67{\pm}1.42kg$ average initial BW) were used in a 41-d growth assay to determine the effects of yucca extract supplementation on growth performance, nutrient digestibility and serum characteristics of finishing pigs. Dietary treatments included 1) Control (basal diet), 2) YE60 (basal diet+60 ppm yucca extract), 3) YE120 (basal diet+120 ppm yucca extract). Average daily gain was not improved by yucca extract supplementation during the whole experimental perid (d 0 to 41). Pigs fed control diet showed the best average daily gain. Pigs fed control and YE120 diets tended to increase average daily feed intake compared with pigs fed YE60 diet (quadratic effect, p<0.0001). Gain/feed with control treatment was significantly better than the YE groups (linear effect, p<0.071). However, there was no significant difference among levels of yucca extract (p>0.10). Apparent digestibility of dry matter in pigs fed yucca extract were greater than for pigs fed control diets (linear effect, p<0.017). Pigs fed YE120 tended to have higher digestibility of nitrogen than pigs fed the control diets (linear effect, p<0.019). There were no significant differences in Total-, HDL- and LDL-cholesterol concentrations of serum, and the blood urea nitrogen (BUN) concentrations in serum was not influenced by the yucca extract supplementation (p>0.10). For the Exp. 2, fifteen [(Duroc${\times}$Yorkshire)${\times}$Landrace] pigs ($25.00{\pm}0.50kg$ average initial BW) were used in a 30-d metabolism experiment to determine the effects of yucca extract supplementation on fecal ammonia gas production. Treatments were : 1) Control (basal diet); 2) YE (basal diet+150 ppm yucca extract); 3) BD (basal diet+100 ppm Bio-Dr; yucca extract+far infrared emitted materials). Fecal ammonia gas production differences between d 0 and d 30 were significantly reduced (p<0.05) by feeding BD compared to control and YE. Also, when pigs were fed the diet with YE tended to be decreased ammonia gas production compared to pigs fed the control diet without significant differences (p>0.05). There were no differences for DM and N digestibility among pigs fed the treatment diets. In conclusion, yucca and (or) far infrared radiological materials can be used to make environment-friendly diets for growing-finishing pigs without negative effects on growth performance and nutrient digestibility.

$MoO_3$를 첨가한 ZnO 박막 센서의 암모니아 가스 검지 특성 (Ammonia Gas Sensing Characteristics of ZnO Based Thin Film Sensor Doped with $MoO_3$)

  • 김성우;최우창;최혁환;이명교;권태하
    • 센서학회지
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    • 제8권1호
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    • pp.24-31
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    • 1999
  • 감도가 우수하고 동작온도가 낮으며 반응속도가 빠른 암모니아 가스 센서를 제작하기 위해 ZnO에 촉매불순물 $MoO_3$의 첨가비와 박막 성장분위기 가스를 변화시키면서 RF 마그네트론 스펏터링 방법으로 박막을 성장하였다. 전기적 안정성을 향상시키기 위해 성장된 박막들을 aging 하여 센서를 제작한 후 암모니아 가스의 검지 특성을 조사하였다. 촉매불순물을 첨가하거나 산소분위기에서 성장된 박막의 경우 감도가 향상되었으며, 이는 표면 캐리어 농도와 전자이동도의 증가를 나타냈다. ZnO에 $MoO_3$를 무게비로 0.875 wt.% 첨가한 박막으로 제작한 센서가 160 ppm의 암모니아 가스 농도와 $300^{\circ}C$의 동작온도에서 70정도의 최대감도를 보였다. 산소분위기에서 $330^{\circ}C$로 72시간 동안 aging한 박막으로 만든 센서는 감도가 57정도로 감소하였으나, 센서의 동작온도가 $250^{\circ}C$로 낮아졌고, 선형성이 좋았으며 더 안정된 특성을 나타냈다.

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Hep G2 세포와 rat 간세포에서 Metronidazole에 의한 암모니아 독성 감소 (Metronidazole Reduced Ammonia Toxicity in Human Hep G2 cell and Rat Hepatocytes)

  • 김보애;김현정;김유영
    • KSBB Journal
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    • 제23권5호
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    • pp.381-386
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    • 2008
  • 본 연구에서는 암모니아에 의해 손상된 사람의 간세포주 Hep G2 cell과 rat의 hepatocyte에 대하여 metronidazole이 간 세포 손상을 억제하는 효과가 있음을 밝혔다. Metronidazole은 암모니아에 의한 세포 생존율 감소, 배지내의 암모니아 수준 및 지질과산화 증가 및 항산화 효소 발현 감소 그리고 세포 내 DNA 손상과 세포사멸을 억제하였다. 따라서 metronidazole은 암모니아로부터 기인하는 세포손상을 감소시켜 간세포 기능을 보호함으로써 간 기능의 저하로 발생한 과암모니아혈증에 효과적인 치료제로서의 가능성을 시사한다.

효소 고정화막의 응용에 대한 총설 (Zeolite Based Membrane for Removal of Ammonium: A Review)

  • 이주엽;라즈쿠마 파텔
    • 멤브레인
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    • 제32권3호
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    • pp.173-180
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    • 2022
  • 음용수 속 암모니아의 존재는 인간의 건강에 매우 해롭다. 농작물에서의 비료 사용, 산업 폐수, 화석 연료의 연소와 같은 활동으로 인해 가용성 암모니아는 지하수를 오염시킨다. 물에 존재하는 암모니아 농도가 낮더라도 해양생물 등의 수생환경을 훼손한다. 막 기술은 암모니아를 물로부터 효과적으로 제거하기 위한 매우 중요한 과정이다. 평평한 시트 막, 막 접촉기, 그리고 막 증류법은 암모니아를 제거하여 물을 정화하는 데 사용되는 방법들 중 하나이다. 막 접촉기는 막 증류법과는 달리 상변화 없이 액체와 가스 간의 또는 액체와 액체간의 질량 전달을 통해 암모니아를 제거하는 효율적인 공정이다. 다만 이 방법은 pH가 매우 높아 암모니아 제거에 비용이 많이 든다. 제올라이트는 우수한 이온 교환 능력을 가지고 있는데, 이는 암모니아와의 상호작용을 향상시켜 폐수로부터 흡착하는 능력을 향상시킨다. 제올라이트를 함유한 혼합 매트릭스 막은 암모니아 흡착 및 폐수로부터의 분리 효율을 향상시킨다. 이 리뷰에서는 위에서 소개된 내용이 자세히 논의될 것이다.

양계장에서 입식 및 출하작업시 분진과 가스상 물질의 노출 측정 조사 (Exposure to Dust and Organic Gas during Chicken Entrance and Shipment Tasks in Poultry Farms)

  • 김경란;김효철;이경숙;채혜선
    • 한국산업보건학회지
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    • 제24권4호
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    • pp.471-477
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    • 2014
  • Objectives: This study was conducted to evaluate area exposure of airborne dust and organic gas during entrance and shipment of chicken in poultry farms Methods: Total dust was measured with NIOSH method 0500. The volume of distributed dust and organic gas(Ammonia, TVOC, Hydrogen Sulfide) were measured using direct reading instrument. Results: The range of concentrations of total dust in area sample was $0.07{\sim}4.91mg/m^3$ during the entrance of chicks and $4.37{\sim}9.4mg/m^3$ during shipment respectively. Concentration of ammonia reached approximately 9 ppm during shipment. There was a difference of concentration of total dust in the area sample between shipment and entrance tasks. Conclusions: It was found that the development of a special intervention program by type of task should be considered for reducing respiratory health effects among poultry farmers.

석탄회의 축사 깔짚 이용기술 (Technique for Using Fly Ash as a Bedding Materials at Livestock House)

  • 고영두;김재황;김두환;고병두;이수칠;이종찬;김삼철
    • 한국축산시설환경학회지
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    • 제5권1호
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    • pp.37-44
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    • 1999
  • This study was carried out to improve utilization of substitute fly-ash in bedding material of animal waste treatments. The amount used of fly-ash used in a pigpen or beef stall was 50% lower than that of existing bedding material of animal waste treatments. From the results, substitution effect of fly-ash put over the floor of the stable became much better. Effects of processed fly ash as a spread straw decreased ammonia(NH3) and Hydrogensulfide (H2S) gas at beef stall, but there was no benefit of replacement terms. Effect of processed fly ash as a spread straw increased 4∼5 times replacement terms more than control NH3 and H2S gas was decreased. A lot of maggots and porasites were grown at sawdust pig farm, but fly ash inhibited to grow maggots and paraeters. In conclusion, as substituting fly-ash for 5% sawdust(DM basis) in making animal waste into a compost with fly ash, we can reduce the sawdust purchasing costs and produce the high quality of a compost, especially a pollutant as NH3 and H2S gas, etc. from the process of biodegradation, and as substituting fly-ash(1,540 won per ton ; can be extended the replacement period of spreading straw approximatively 4∼5 times) for sawdusts(111,000 won per ton) will increase a real income in livestock house.

Nitrogen source로 ammonia를 사용해 GSMBE로 성장된 GaN 박막 특성 (Growth of GaN on sapphire substrate by GSMBE(gas source molecular beam epitaxy) using ammonia as nitrogen source)

  • 조해종;한교용;서영석
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2004년도 하계종합학술대회 논문집(2)
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    • pp.501-504
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    • 2004
  • High quality GaN layer was obtained on 0001 sapphire substrate using ammonia($NH_3$) as a nitrogen source by gas source molecular beam epitaxy. As a result, RHEED is used to investigate the relaxation processes which take place during the growth of GaN. In-situ RHEED(reflection high electron energy diffraction) appeared streaky-like pattern. The full Width at half maximum of the x-ray diffraction(FWHM) rocking curve measured from plane of GaN has exhibited as narrow as 8arcmin and surface roughness was 7.83nm. Photoluminescence measurement of GaN was investigated at room temperature, where the intensity of the band edge emission is much stronger than that of deep level emission. The GaN epitaxy layer according to various growth condition was investigated.

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나노 은 입자 세정법을 이용한 무기 악취물질의 제거 (Removal of Inorganic Odorous Compounds by Scrubbing Techniques using Silver Nano-particles)

  • 신승규;;송지현
    • 한국대기환경학회지
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    • 제24권6호
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    • pp.674-681
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    • 2008
  • Silver as a metal catalyst has been used to remove odorous compounds. In this study, silver particles in nano sizes ($5{\sim}30nm$) were prepared on the surface of $NaHCO_3$, the supporting material, using a sputtering method. The silver nano-particles were dispersed by dissolving $Ag-NaHCO_3$ into water, and the dispersed silver nano-particles in the aqueous phase was applied to remove inorganic odor compounds, $NH_3$ and ${H_2}O$, in a scrubbing reactor. Since ammonia has high solubility, it was removed from the gas phase even by spraying water in the scrubber. However, the concentration of nitrate (${NO_3}^-$) ion increased only in the silver nano-particle solution, implying that the silver nano-particles oxidized ammonia. Hydrogen sulfide in the gas phase was rapidly removed by the silver nano-particles, and the concentration of sulfate (${SO_4}^{2-}$) ion increased with time due to the oxidation reaction by silver. As a result, the silver nano-particles in the aqueous solution can be successfully applied to remove odorous compounds without adding additional energy sources and producing any harmful byproducts.