• Title/Summary/Keyword: Ammonia/water solution

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Study on Coagulant Application for Calcium Ammonium Nitrate Extraction of Denitrification Scrubber Waste Cleaning Solution (탈질 스크러버 폐 세정액에 포함된 질안석회 추출을 위한 응집제 적용 연구)

  • Lee, Hyun Suk;Song, Woon Ho
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.2
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    • pp.289-295
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    • 2017
  • The International Maritime Organization (IMO) in accordance with the regulations with respect to the combustion gases, such as NOx, SOx generated by the marine engine. The combustion gases must be equipped with a device to reduce emissions from all ships passing through the Baltic SECAs. In Korea, the International Maritime Organization (IMO) and the development of a device for NOx, SOx reduction. Scrubber is used in the ammonia water and the Urea solution in the waste water. The waste water containing ammonium nitrate and ammonium sulfate, react of the NOx and SOx gas. In this study, the recovery of by-product, which contains the waste water was used as an organic solvent extraction method of salting out. Ammonium nitrate and ammonium sulfate, the recovery process. A qualitative analysis of the collected by-product FT-IR analysis. Through the elemental analysis and SEM-EDS, characteristic evaluation was performed with an impurity.

Synthesis of Size Controlled Spherical Silica Nanoparticles via Sol-Gel Process within Hydrophilic Solvent

  • Kim, Tae Gyun;An, Gye Seok;Han, Jin Soon;Hur, Jae Uk;Park, Bong Geun;Choi, Sung-Churl
    • Journal of the Korean Ceramic Society
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    • v.54 no.1
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    • pp.49-54
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    • 2017
  • In this study, based on hydrolysis and condensation via $St{\ddot{o}}ber$ process of sol-gel method, synthesis of mono-dispersed silica nanoparticles was carried out with hydrophilic solvent. This operation was expected to be a more simplified process than that with organic solvent. Based on the sol-gel method, which involves simply controlling the particle size, the particle size of the synthesized silica specimens were ranged from 30 to 300 nm by controlling the composition of tetraethylorthosilicate (TEOS), DI water and ammonia solution, and by varying the stirring speeds while maintaining a fixed amount of ethanol. Increasing the content of DI water and decreasing the content of ammonia caused the particle size to decrease, while controlling the stirring speed at a high level of RPMs enabled a decrease of the particle size. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) were utilized to investigate the success factors for synthesizing process; Field emission scanning electron microscopy (FE-SEM) was used to study the effects of the size and morphology of the synthesized particles. To analyze the dispersion properties, zeta potential and particle size distribution (PSD) analyses were utilized.

The Characteristics of Cooling Performance on 7RT Ammonia Absorption System (7RT급 암모니아 흡수식 냉온수기의 냉방성능 특성)

  • Lee, Ho-Saeng;Jin, Byoung-Ju;Yoon, Jung-In;Hwang, Jun-Hyeon;Jin, Slm-Won;Kyung, Ick-Soo;Erickson, Donald C
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.8
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    • pp.433-438
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    • 2009
  • Experimental results for performance characteristics of small $NH_3$ absorption chiller/ heater are presented. The apparatus consists of 7RT water-cooled absorption system, solution pump, boiler, cooling tower and peripheral devices. The effect of experimental parameters, such as refrigerant mass flow rate, solution mass flow rate and cooling water temperature have been investigated in view of the system performance. The capacity of each heat exchanger increased as refrigerant mass flow rate increased in cooling mode. Also, a cooling capacity increased as a strong solution mass flow rate increased. The cooling and heating COP show 0.5, 1.5 regardless of refrigerant mass flow rate, respectively. The results focus on the evaluation for performance characteristics of system with respect to variation of refrigerant mass flow rate under standard design conditions.

Preparation and Properties of Modified Polyethylenes: 1. Preparation and Properties of Dispersions in Water (변성 폴리에틸렌의 제조 및 물성 : 1. 제조 및 수분산 특성)

  • Lee, Jae Heung;Lee, Sang-Hun
    • Journal of Adhesion and Interface
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    • v.3 no.3
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    • pp.7-14
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    • 2002
  • Modified polyethylenes with polar side groups of -COOK, $-CONH_2$, and -COOH were prepared at a dispersion state in water by reacting poly(ethylene-co-methylacrylate) (PEMA) with aqueous solution of KOH and ammonia. Types and their contents of side groups were investigated by infrared spectroscopy, elemental analysis and atomic absorption analysis. Solution viscosity and surface tension were also measured as a function of solid contents. Stability and transparency of the dispersions were greatly affected by the content of COOK in the side groups. The stable dispersion could be prepared at a composition of COOK of 20 mole% at least. The transparency was increased with increasing the COOK contents, but decreased with increasing the amide content at a constant composition of COOK. Solution viscosities increased abruptly at a lower solid content when the COOK contents were increased, implying higher entanglement between the chains in dispersions with higher content of hydrophilic COOK group. The dispersions of higher COOK content revealed lower surface tension values.

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An experimental study on the mixing of evaporating liquid spray with duct flow (덕트 유동에서 증발을 수반하는 액상 스프레이의 혼합 특성에 대한 실험적 연구)

  • Kim, Young-Bong;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.93-96
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    • 2005
  • High temperature furnace such as Steam power plant and incinerator contribute considerable part of NOx generation and face urgent demand of De-NOx system. Reducing agents are necessary to use De-NOx system. In this study mixing caused by direct injection of reducing agent solution spray into flue gas duct was measured. Carbonated water was used as tracer and simulated agent because ammonia as a reducing agent is not proper to experiment. Mixing and evaporation must occur simultaneously and quickly enough to achieve desirable efficiency. To achieve that, the angle of attack of static mixer and the location is simulated and $CO_2$ concentration is measured.

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The Studies on the Constituents of Baek-bu-ja, Aconiti koreani Rhizoma (백부자 Aconiti koreani Rhizoma의 성분연구)

  • Han, Dae-Suk;Kim, Jung-Yun
    • Korean Journal of Pharmacognosy
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    • v.2 no.1
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    • pp.39-40
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    • 1971
  • An alkaloidal component was extracted from the root of Aconitum koreanum R. $R_{AYMOND}$ of the commercial origin. Crude extract was obtained in ca. 2% yield out of dried root with ether-methanol (10:1). White amorphous compound was precipitated out from the HCl solution upon the addition of ammonia water, and crude base was obtained by extraction of its mother liquid with chloroform. This crude base was purified by the alumina-column chromatographic method. A pure alkaloidal component(500mg) was yielded from its crude base. Its pure base comes as needle crystals melting at $250{\sim}252^{\circ}C$ (decomp.), $[\alpha]^{20}_D$ D+9.82 (methanol) and Anal. calcd. for $C_{19}H_{27}O_{8}N$.

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Recovery of Nickel from Spent Petroleum Catalyst by Hydrometallurgical Process (습식제련공정에 의한 석유화학 폐촉매로부터 니켈의 회수)

  • Kim, Jong-Hwa;Song, Ju-Yeong;Yang, Seok-Jin;Jeon, Sung-Gyun
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.273-281
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    • 2010
  • Nickel recovery method was studied by the wet process from the catalyst used in hydrogenation process. Nickel content in waste catalyst was about 16%. At the waste catalyst leaching system by the alkaline solution, selective leaching of nickel was possible by amine complex formation reaction from ammonia water and ammonium chloride mixed leachate. The best leaching condition of nickel from mixed leachate was acquired at the condition of pH 8. LIX65N as chelating solvent extractant was used to recover nickel from alkaline leachate. The purity of recovered nickel was higher than 99.5%, and the whole quantity of nickel was recovered from amine complex.

Changes in the Nutrient Components Associated with the Growth of Lettuce in Circulating Hydroponics (순환식 양액재배에서 상추의 성장에 따른 양액성분의 변화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.24 no.8
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    • pp.1075-1084
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    • 2015
  • This study was conducted to investigated the changes in the nutrient components ($NO_3{^-}-N$, $NH_4{^+}-N$, $PO_4{^{3-}}P$, $K^+$, $Ca^{2+}$, and $Mg^{2+}$) and environmental parameters (electrical conductivity, total dissolved solids and pH) on the leaf lettuce (Lactuca sativa L.) grown with hydroponics. Recirculating hydroponic cultivation system was consisted of planting port, LED lamp, water tank, and circulating pump for hydroponic. Nutrient solution was used in the standard solution for Japan vegetables experimental station and commercial hydroponic. The result showed that electrical conductivity (EC), total dissolved solids (TDS) and pH, depending on the growth of lettuce decreased continuously. With the growth of the lettuce, nitrate nitrogen, ammonia nitrogen, phosphate phosphorus were required for periodic replacement. The number of pH compensation due to the growth of lettuce are the most high. The concentration of $Ca^{2+}$ and $Mg^{2+}$ during the lettuce growth showed no significant change. However, $K^+$ concentration increased due to the replacement with nitrogen and phosphorus. Electric conductivity and total dissolved solids with total nutrient concentration showed the linear relationship and the correlation coefficient $R^2$ were 0.8601 and the 0.827, respectively.

Surface Properties and interfacial Potential Distribution of Surface Treated-Alumina (표면처리한 알루미나의 표면물성과 계면전위분포)

  • 홍영호;함영민
    • Journal of the Korean Ceramic Society
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    • v.33 no.7
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    • pp.823-831
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    • 1996
  • Due to the intrinsic low surface activation of ${\gamma}$-alumina it has been used limitely in practice. Accordingly forward enhancing its utility ${\gamma}$-alumina surface was treated with slfuricf aicd nitric acid and chloric acid respec-tively. Subsequently the effects of surface activity on the surface electrical characteristics were investigated. The ${\gamma}$-alumina was prepared by the precipitation of aluminium nitrate [Al(NO3)3.9H2O] using ammonia water as a precipitator and it was chemically treated with such acids mentioned above. The surface and morphology of the acid-treated ${\gamma}$-alumina were analysed by XRD, BET and the surface activities were measured by the amine titration methods. The interfacial properties of the ${\gamma}$-alumina dispersed in electrolyte solution were esti-mated by the surface charge density measured using potentiometric tiration. Based on the relation between surface charge density and the acid amount the following results were drawn for the surface and interfacial electrical properties ; Acidic properties of surface-treated alumina increase with anion load on alumina surface. P. Z. C decreases with acid amount on alumina surface. The surface charge densities were apart from electrolyte ionic strength. The acidity of ${\gamma}$-alumina is linearly dependent on the P. Z,.C when the ${\gamma}$-alumina was dispersed in aqueous electrolyte solution.

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THE EFFECTS OF UREA NITROGEN ON THE METABOLISM OF PLANTS (II) The response of some nitrogen components of barley to urea and other nitrogen in water culture.

  • Kim, . Joon Ho
    • Journal of Plant Biology
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    • v.5 no.2
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    • pp.6-12
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    • 1962
  • For the comparison with the previous paper (4) the present report deals with the absorption and metabolism of urea and other nitrogen ions in barley seedling absorbed through root. 1. The amount of nitrate in barley treated with urea reach it peak on the 8th day. NO3 on the 4th, NH4 on the 6th or 8th, respectively. 2. The ammonia content in urea group reaches its peak on the 6th day but other groups on the 4th day. The present data in the urea group show to shorten 4 days compared with that of the previous paper(4). 3. the content of total amide from the present data aare gradully increased on all of the groups during this experiment. These are agreement with the result of the previous paper (4). 4. the alcohol solution nitrogen in the urea gorup shows the similar tendency to the NaNO3 group but reaches it peak 2 days later than in the (NH4)2SO4 group. 5. The content of total nitrogen in the urea series has the lowest amount at the beginning while the richest from the 4th day after. These would be explained on that the absorption of urea is delayed and the PH in the urea solution does not change, so called "physiological neutrality". The author should like express his sincere thanks to Prof. M.J.Lee of Seoul National University for his valuable advices.e advices.

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