• Title/Summary/Keyword: Ambient gas temperature

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A Study on Physical Properties of BP

  • Hong, Kuen-Kee;Lee, Young-Won;Im, Jong-Hyun;Kim, Chul-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.88-90
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    • 2005
  • Boron Phosphide films were deposited on (111) Si substrate at 650 $^{\circ}C$, by the reaction of $B_2H_6$ with $PH_3$ using APCVD. $N_2$ was carried out as carrier gas. The optimal gas rates were 20 m$\ell$/min for $B_2H_6$, 60 m$\ell$/min for $PH_3$ and 1 $\ell$/min for $N_2$. After as grown the films were insitu annealed for 1hour in N$_2$ ambient at $550^{\circ}C$ and measured. The measurement of AFM shows that the RMS is $29.626{\AA}$ for the reaction temperature at 650$^{\circ}C$. The measurement of XRD shows that the films have the orientation of (101). Also, the measurement of AES is shown that the films have $B_{13}P_2$ stoichiometry.

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Spray Behavior Characteristics of Injector Used for HC-DeNOx Catalyst System in the Transparent Exhaust Manifold (모사 배기관 내 HC-DeNOx 촉매용 인젝터의 분무 거동 특성)

  • Lee, Dong-Hoon;Oh, Jung-Mo;Jeong, Hae-Young;Lee, Ki-Hyung;Yeo, Kwon-Gu
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.4
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    • pp.54-60
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    • 2007
  • A new method that optimizes a control of hydrocarbon (HC) addition to diesel exhaust gas for HC type DeNOx catalyst system has been developed. These catalysts are called as the HC-DeNOx catalyst in this paper. The system using HC-DeNOx catalyst requires a resonable quantity of hydrocarbons addition in the inlet gas of the catalyst, because the HC concentration in a diesel engine is so low that the HC is not sufficient for NOx conversion. Generally ambient temperature in the exhaust manifold is $250{\sim}350^{\circ}C$, so spray behavior in this case is different from that of any other condions. This research shows spray behavior of injected hydrocarbons in the transparent exhaust manifold.

Oxygen-Deficient Perovskite, (CaLa) (MgMn)O5.43 Prepared Under Oxygen Gas Pressure of 1 Bar (산소 1기압하에서 합성된 산소결함 Perovskite(CaLa)(MgMn)O$_{5.43}$의 물리화학적 특성연구)

  • 최진호;홍승태;김승준
    • Journal of the Korean Ceramic Society
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    • v.28 no.8
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    • pp.603-610
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    • 1991
  • An oxygen deficient perovskite (CaLa)(MgMn)O5.43, with the cubic unit cell parameter of 3.826$\AA$, was prepared 115$0^{\circ}C$ for 10 hrs under the ambient oxygen gas pressure. The average oxidation state of manganese was determined to be 3.86 by the iodometric titration, so that the perovskite could be formulated as (CaLa) ({{{{ { MgMn}`_{ chi } ^{II } }}{{{{ { Mn}`_{ y} ^{III } }}{{{{ { Mn}`_{1- chi -y } ^{IV } }})O5.43 (2x+y=0.14). From X-ray photoelectron spectroscopy, the manganese ions in the lattice are mostly tetravalent, but two paramagnetic configurations were observed in the EPR spectrum: One sharp isotropic signal with hyperfines (ΔH 50 G, g=1.997$\pm$0.002 and │A│=82(4)$\times$10-4 cm-1) and a broad isotropic one (ΔH 1600 G, g=1.994$\pm$0.002), those which correspond respectively to Mn(II) and Mn(IV) ions. According to the magnetic susceptibility measurement, it follows the Curie-Weiss law from 20 K up to room temperature with $\mu$eff=5.23 $\mu$B, which is relatively larger than spin-only value({{{{ { mu }`_{eff} ^{s.o } }}=4.04 $\mu$B) due to the effect of weak ferromagnetic coupling. Such a result is in accord with a theory of semicovalence exchange.

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Emission and heat recovery characteristics of heat recovery and combustor-type CO2 generator for greenhouses (온실용 축열 연소기형 이산화탄소 발생기의 배기 및 열회수 특성)

  • Choi, Byungchul;Lee, Jung-Hyun
    • Journal of Power System Engineering
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    • v.18 no.4
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    • pp.52-59
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    • 2014
  • The purpose of this study is to evaluate the performance of after-treatment equipment and thermal storage devices for a heat recovery and combustor-type $CO_2$ generator fuelled a kerosene. To reduce the levels of harmful exhaust gases produced by a $CO_2$ generator, a catalyzed particulate filter(CPF) has been selected as an after-treatment device, by considering back pressure and exhaust gas temperature. The CO conversions of the catalyzed SiC filter(full plugging) were 92%, and the concentration of PM(particulate matter) was near ambient. A thermal recovery device was used to recover 13% of the heat energy from the exhaust gas through heat exchangers installed on the exhaust line of the $CO_2$ generator. 69% of the moisture within the exhaust gases was removed by condensing water, in order to minimize excessive humidity within the greenhouse.

DeNOx by SCR (Selective Catalytic Reduction) Using LPG as a Reductant (LPG-SCR에 의한 질소산화물 제거)

  • Kim, Moon-Chan
    • Applied Chemistry for Engineering
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    • v.23 no.6
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    • pp.588-593
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    • 2012
  • In this study, selective catalytic reduction (SCR) reaction was performed using liqufied petroleum gas (LPG) as a reductant for removing NOx. The catalysts were manufactured with different amounts of Cu and Fe supported on HZSM-5 in order to remove NOx. The NOx conversion ratio was studied with changing the temperature and the catalyst amount. The catalysts were manufactured by calcination with flowing the ambient air at $500^{\circ}C$ for three hours. Cupper of 1~4 wt% and iron of 0.5~2 wt% were supported on HZSM-5 of which Si/Al ratio were 80. According to the reaction results, the catalyst which Cu of 3 wt% supported on HZSM-5 showed the highest conversion rate. XRD, XPS, and TPR analysis were also performed for the characterization of catalysts.

DESIGN AND APPLICATION OF A SINGLE-BEAM GAMMA DENSITOMETER FOR VOID FRACTION MEASUREMENT IN A SMALL DIAMETER STAINLESS STEEL PIPE IN A CRITICAL FLOW CONDITION

  • Park, Hyun-Sik;Chung, Chang-Hwan
    • Nuclear Engineering and Technology
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    • v.39 no.4
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    • pp.349-358
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    • 2007
  • A single-beam gamma densitometer is utilized to measure the average void fraction in a small diameter stainless steel pipe under critical flow conditions. A typical design of a single-beam gamma densitometer is composed of a sealed gammaray source, a collimator, a scintillation detector, and a data acquisition system that includes an amplifier and a single channel analyzer. It is operated in the count mode and can be calibrated with a test pipe and various types of phantoms made of polyethylene. A good average void fraction is obtained for a small diameter pipe with various flow regimes of the core, annular, stratified, and bubbly flows. Several factors influencing the performance of the gamma densitometer are examined, including the distance between the source and the detector, the measuring time, and the ambient temperature. The void fraction is measured during an adiabatic downward two-phase critical flow in a vertical pipe. The test pipe has an inner diameter of 10.9 mm and a thickness of 3.2 mm. The average void fraction was reasonably measured for a two-phase critical flow in the presence of nitrogen gas.

Application of CFD model for passive autocatalytic recombiners to formulate an empirical correlation for integral containment analysis

  • Vikram Shukla;Bhuvaneshwar Gera;Sunil Ganju;Salil Varma;N.K. Maheshwari;P.K. Guchhait;S. Sengupta
    • Nuclear Engineering and Technology
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    • v.54 no.11
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    • pp.4159-4169
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    • 2022
  • Hydrogen mitigation using Passive Autocatalytic Recombiners (PARs) has been widely accepted methodology inside reactor containment of accident struck Nuclear Power Plants. They reduce hydrogen concentration inside reactor containment by recombining it with oxygen from containment air on catalyst surfaces at ambient temperatures. Exothermic heat of reaction drives the product steam upwards, establishing natural convection around PAR, thus invoking homogenisation inside containment. CFD models resolving individual catalyst plate channels of PAR provide good insight about temperature and hydrogen recombination. But very thin catalyst plates compared to large dimensions of the enclosures involved result in intensive calculations. Hence, empirical correlations specific to PARs being modelled are often used in integral containment studies. In this work, an experimentally validated CFD model of PAR has been employed for developing an empirical correlation for Indian PAR. For this purpose, detailed parametric study involving different gas mixture variables at PAR inlet has been performed. For each case, respective values of gas mixture variables at recombiner outlet have been tabulated. The obtained data matrix has then been processed using regression analysis to obtain a set of correlations between inlet and outlet variables. The empirical correlation thus developed, can be easily plugged into commercially available CFD software.

SPRAY CHARACTERISTICS OF DIRECTLY INJECTED LPG

  • Lee, S.W.;Y. Daisho
    • International Journal of Automotive Technology
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    • v.5 no.4
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    • pp.239-245
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    • 2004
  • It has been recognized that alternative fuels such as Liquid Petroleum Gas (LPG) show less polluting combustion characteristics than diesel fuel. Furthermore, engine performance is expected to be nearly equal to that of the diesel engine if direct-injection stratified-charge combustion of the LPG can be adopted in the spark-ignition engine. However, spray characteristics of LPG are quite different from those of diesel fuel. understanding the spray characteristics of LPG and evaporating processes are very important for developing efficient and low emission LPG engines optimized in fuel injection control and combustion processes. In this study, the LPG spray characteristics and evaporating processes were investigated using the Schlieren and Mie scattering optical system and single-hole injectors in a constant volume chamber. The results show that the mixture moves along the impingement wall that reproduced the piston bowl and reaches in ignition spark plug. LPG spray receives more influence of ambient pressure and temperature significantly than that of n-dodecane spray.

Characteristics of a-Si:H Films for Contact-type Linear Image Sensor (밀착형 선형 영상감지소자를 위한 a-Si:H막의 특성)

  • 오상광;박욱동;김기완
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.28A no.11
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    • pp.894-901
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    • 1991
  • Contact-type linear image sensors have been fabricated by means of RF glow discharge decomposition method of silane and hydrogen mixtures. The dependences of the electrical and optical properties of these sensor on thickness, RF power, substrate temperature and ambient gas pressure have been investigated. the ITO/i-a-Si:H/Al structure film shows photosensitivity of 0.85 and photocurrent to dark current ratio ($I_{ph}/I_{d}$) of 150 at 5V bias voltage under 200${\mu}W/cm^[2}$ red light intensity. Under 200${\mu}W/cm^[2}$ green light intensity, the ratio is 100. In order to investigate photocarrier transport mechanism and to obtain ${\mu}{\gamma}$ product we have measured the I-V characteristics of these sensors favricated with several different deposition parameters under various light sources. The linear inage sensor for document reading has been operated under reverse bias condition with green light source, resulting in ${\mu}{\gamma}$ product of about 1.5$[\times}10^{-9}cm^{2}$/V.

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Disintegration Mechanism of Ammonium Nitrate Droplets by Melt Spray (용융 분무에 의한 질산암모늄 액적의 분열 메카니즘)

  • Ahn, Jin-Hwan;Kim, Jae-Kyeong;Kim, Jun-Hyung;Koo, Kee-Kahb
    • Journal of the Korea Institute of Military Science and Technology
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    • v.12 no.2
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    • pp.206-212
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    • 2009
  • The pressurized spray system with nitrogen gas was designed to fabricate the spherical AN(ammonium nitrate) particles. When AN melt was sprayed from a nozzle with equivalent diameter of 0.28mm into an ambient dry air, the ligament breakup mechanism of the molten AN was found to be responsible for the droplet formation(or disintegration) of AN melt. In the experimental range of spray temperature with $170{\sim}200^{\circ}C$ and atomization pressure with $0.1{\sim}0.4MPa$, the spherical AN particles with mean diameter of $130{\sim}250{\mu}m$ were obtained.