• Bulletin of the Korean Chemical Society
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• v.23 no.3
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• pp.488-496
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• 2002

SPME techniques have proven to be very useful tools in the analysis of wide VOCs in the air. In this study, we estimated VOCs in ambient and workplace air using a Tedlar ba /SPME/GC/MS system. The calibration curve was set to be linear over the range of 1-30 ppbv. The detection limits ranged from 10 pptv to 0.93 ppbv for all VOCs. Reproducibility of TO-14 target gas mixtures by SPME/GC/MS averaged at 8.8 R.S.D (%). Air toxic VOCs (hazardous air pollutants, HAPs) containing a total of forty halohydrocarbons, aromatics, and haloaro-matic carbons could be analyzed with significant accuracy, detection limit and linearity at low ppbv level. Only reactive VOCs with low molecular weight, such as chloromethane, vinylchloride, ethylchloride and 1,2-dichloro-ethane, yielded relatively poor results using this technique. In ambient air samples, ten VOCs were identified and quantified after external calibration. VOC concentration in ambient and workplace air ranged from 0.04 to 1.85 ppbv. The overall process was successfully applied to identify and quantify VOCs in ambient/workplace air.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.7 no.1
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• pp.71-85
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• 1997

The purpose of this study was to evaluate concentrations of organic solvent mixtures in air of rotogravure printing workplaces. Qualitative and quantitative analysis of organic solvents contained in the gravure inks used at rotogravure factories had been done. The results obtained were as follows: 1. The gravure inks mainly consist of toluene, methyl ethyl ketone(MEK), and ethyl acetate(EA), and traces of isopropyl alcohol(IPA), xylene, 2-butanol, cyclohexane, cellosolve etc were also contained in them. 2. Thinner used as a diluent consist of toluene, MEK, and EA. 3. Geometric mean concentration of toluene in ambient air were 23.81 ppm at gravure printing of packing material, 42.10 ppm at gravure printing of wallpaper, 16.95 ppm at gravure printing of plastic bottle for beverage and 4.31 ppm at gravure printing of plywood printing or floor covering. Concentrations of toluene in ambient air showed statistically significant difference between types of printing. 4. Concentrations of MEK in ambient air were 12.43 ppm at gravure printing of packing material, 5.47 ppm at gravure printing of wallpaper, 16.78 ppm at gravure printing of plastic bottle for beverage and 16.44 ppm at gravure printing of plywood printing or floor covering. MEK concentrations in ambient air showed no significant difference. 5. Conentrations of EA were 14.30 ppm at gravure printing of packing material, 1.92 ppm at gravure printing of wallpaper and 21.12 ppm at gravure printing of plywood printing or floor covering. EA concentrations in ambient air shown significant difference. 6. Percentage of the workplaces where the ambient air concentration of organic solvent mixtures exceeded the Korean Permissble Exposure Level(KPEL) amounted to 18.03%. 7. Toluene concentrations in ambient air of rotogravure printing workplaces ranged from 0.69 to 156.02 ppm and urinary hippuric acid excretion ranged from 0.10 to $1.32g/{\ell}$.

• Journal of Korean Society for Atmospheric Environment
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• v.11 no.4
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• pp.339-349
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• 1995

The purpose on this study is to optimize the chromatographic determination method of trace aldehydes in ambient air. Carbonyl compounds in urban air were trapped at $C_{18}$ DNPH-coated cartridges, and generated hydrazone derivatives were separated by HPLC and detected by UV-vis spectroscopic detector at 360nm. Formaldehyde and acetaldehyde compounds could be isolated from urban(Seoul) air with more than 95% collection efficiency. The analytical detection limits for formaldehyde and acetaldehyde are 0.06pp $b_{v}$, 0.08pp $b_{v}$ for 108 L air samples, respectively. The precision of this method are 3 .sim. 4%(RSD) for mutiple injection of hydrazone standards. Separation of seven dinitrophenylhydrazones could be achieved in appoximately 20 minutes operation time using $C_{18}$ column with apprepriate eluent. The method was applied to the analysis of aldehydes and ketone in Seoul ambient air. The 24-h ambient levels of formaldehyde, acetaldehyde reached up to 6 .sim. 14 and 3 .sim. 8ppbv, respectively. The daily average concentration ratio were 0.60 for acetaldehyde/formaldehyde.yde.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.9
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• pp.825-834
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• 2000

A heat exchanger analysis is performed to investigate the heating characteristics of cryogenic nitrogen by ambient air for the purpose of cryogenic automotive propulsion. The heat exchanger is a concentric triple-passage for supercritical nitrogen, and the radial fins are attached on the outermost tube for the crossflow of ambient air. The temperature distribution is calculated for the nitrogen along the passage, including the real gas properties of nitrogen, the fluid convections and the conductions through the tube walls and the fins. Since the wall temperature of the outer (ambient side) tube is very low in most cases, a heavy frost can be formed on the surface, affecting the heat exchange performance. By the method of the similarity between the heat and the mass transfer of moist air, the frost growth and the time-dependent effectiveness of the heat exchanger are calculated for various operating conditions. It is concluded that the frost formation can augment the heating of nitrogen during the initial period because of the latent heat, then gradually degrades the heat exchange because of the increased thermal resistance. Practical design issues are discussed for the flow rate of nitrogen, the velocity and humidity of ambient air, and the sizes of the fin.

• The Korean Journal of Ceramics
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• v.4 no.1
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• pp.28-32
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• 1998

This paper reports on photoluminescence (PL), luminescence decay curves, and compositional analysis of porous silicon(PS) which is aged under air ambient by Fourier transform infrared vibrational spectroscopy (FTIR) and by Auger electron spectroscopy (AES). Porous silicos which has been aged under air ambient yields two PL band structures, i.e. blue/violet PL and red PL. The evolution of a blue/violet band is pronounced, especially for thin PS film which is prepared in dilute HF solution. The blue/violet PL band has been observed initially to increrase rapidly with aging, then saturated with further atmospheric aging. The ambient air aged PS exhibits a fast decay time of sub-nanosecond at room temperature and shows appreciably faster decay time than that at 20K. Atmospheric aging of this thin blue/violet luminescing PS yield non-stoichiometric oxide judging from the vibrational spectra of Si-O and AES analysis.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.33 no.8
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• pp.9-17
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• 2004

차세대의 공조시스템을 논의하는 데 있어서 잊어서는 안 되는 키워드 중의 하나가 “Task/Ambient Air-Conditioning System”이 있다. 이것은 기존의 실내온열환경을 균일하게 조절한다는 개념에서, 거주역(Task-zone)에 대해서는 고품질의 환경을, Ambient-zone에 대해서는 다소 완화된 환경을 제고하고자 하는 생각으로, 퍼스널 공조와 같은 고도화된 공조시스템에서 자연환기의 이용에 이르기까지 폭넓은 범위에 미치고 있다. (중략)

• Korean Journal Plant Pathology
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• v.14 no.6
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• pp.720-724
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• 1998

Open-top field chamber study was carried out to investigate effect of ambient ozone level on the yield of rice cultivar 'Dongjin' in Kwangyang area located in the vicinity of the industrial complex of Yechon petrolium refinery and chemical works or Kwangyang Iron and Steel works during the summer of 1997. mean ozone concentration of ambient air during daytime (9:00∼17:00) was revealed to exceed over 40 ppb which is defined to be a critical level causing plant injury and yield reduction in Europe. Yield component analysis showed that there was no significant difference in rice yield between ambient air and charcoal-filtered air. The results suggest that the ambient ozone levels during the exposure period had no effect on yield reduction of rice cultivar 'Dongjin' and it is likely that the cultivar is tolerant to ambient ozone levels.

• Journal of Environmental Science International
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• v.13 no.6
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• pp.519-525
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• 2004

Air pollution from the Daegu industrial complex (Die) in Korea has been a common nuisance and cause of complaints for nearby residents. The current study measured the indoor and outdoor levels of six VOC (benzene, toluene, ethylbenzene, and three isomeric xylenes) at two residential areas with a different proximity to the ODIC, plus the ambient levels at two industrial areas within the boundary of the DDIC. The QA/QC program included the range of correlation coefficient (0.94-0.99) for calibration curves, within the permissible range. Toluene was the most abundant VOC in the ambient air both in residential and industrial areas. Both indoor and outdoor air concentrations of all target VOC except benzene were higher in residential area near the DIC compared to that further away from the DIC. Moreover, the ambient air concentrations of all target VOC except benzene for two industrial sites (A and B) were significantly higher than the outdoor or indoor air concentrations in the two residential areas. The findings further suggested that VOC ambient levels measured in a residential area near the DIC be used as a potential indicator of odor-causing unidentified air pollutants transported from the DIC. Moreover, it was found that the elevated ambient toluene levels outweighed the indoor sources with respect to the environmental exposure of residents nearby the DIC. However, in the residential area further away from the DIC, the toluene indoor sources outweighed the outdoor sources.

• Journal of Biosystems Engineering
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• v.24 no.4
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• pp.343-350
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• 1999

The ambient air is commonly used as low-temperature heat source for heat pump operation. However, the coefficient of performance(COP) of the air to water heat pump is decreased with the ambient air temperature drop. In this study to solve this problem, the AVACTHE(Automatic Variable Area Capillary Type Heat Exchanger) with 3 levels of heat exchange area(0, 1,495.4, 1,794.5$\textrm{cm}^2$)was installed in the refrigerant circuit of the heat pump. The AVACTHE effect on the performance of heat pump was tested with the ambient air temperature variation. The COP improvement of the heat pump could be achieved by the AVACTHE installation when below -5$^{\circ}C$ of the ambient air temperature.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 1999.12a
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• pp.211-218
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• 1999

The ambient air is commonly used as low-temperature heat sources for heat pump operation. However, the coefficient of performance (COP) of the air -water heat pump is decreased with the ambient air temperature drop. In this study to solve this problem , the AVACTHE(Automatic Variable Area Capillary Type Heat Exchanger) with 3 levels of heat exchange area(0, 1495.4, 1794.5$\textrm{cm}^2$) was installed in the refrigerant circuit of the heat pump. The AVACTHE effect on the performance of heat pump was tested with the ambient air temperature variation. The high level COP of the heat pump could be achieved by the AVACTHE installation when below -5$^{\circ}C$ of the ambient air temperature.