• Title/Summary/Keyword: Amber

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Color Enhancement of the Type II and Type I aB Brown Diamonds into Colorless by HPHT Process (고온고압법에 의한 Type II, Type I aB 갈색 다이아몬드의 색향상)

  • Song, Jeong-Ho;Song, Oh-Sung
    • Journal of the Korean Ceramic Society
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    • v.49 no.3
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    • pp.221-225
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    • 2012
  • It is possible to enhance the color of the natural diamond with a high pressure high temperature(HPHT) process. We employed a pyrophyllite tube cell and cubic press apparatus for HPHT treatment on the brown colored Type II (5.6 GPa/ $1700^{\circ}C$/ 52 min), and Type I aB(5.6 GPa/ $1650^{\circ}C$/ 30 min) diamond samples. We investigated the microstructure, Types, fluorescence, properties of the diamonds with an optical microscopy, FT-IR, photoluminescence(PL) spectroscopy, Diamond-View, and micro-Raman spectroscopy. Two tinted brown diamonds changed into colorless just after the HPHT process. Optical microscopy showed that no crack and significant inclusion evolution occurred during the HPHT process except the small graphite spot appeared in Type I aB sample. FTIR spectrum confirmed that no Type, amber center, and platelet defect change with the HPHT treatment. Diamond-View could not distinguish the HPHT treated diamonds from the naturals. PL spectroscopy showed that N3 and H3 color centers remained even after HPHT process. Consequently, we successfully changed the color of diamonds into colorless by 5.6 GPa HPHT process.

Dentinogenesis imperfecta type II: A case report with 17 years of follow-up

  • Gama, Francisco Jose Reis;Correa, Isabella Sousa;Valerio, Claudia Scigliano;Ferreira, Emanuelle de Fatima;Manzi, Flavio Ricardo
    • Imaging Science in Dentistry
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    • v.47 no.2
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    • pp.129-133
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    • 2017
  • Dentinogenesis imperfecta is a dominant autosomal hereditary disorder of dentin formation that affects the deciduous and permanent teeth. Its etiology is characterized by inadequate cell differentiation during odontogenesis. The clinical characteristics of dentinogenesis imperfecta are discolored teeth with a translucency that varies from gray to brown or amber. Radiographically, the teeth exhibit pulp obliteration, thin and short roots, bell-shaped crowns, and periapical bone rarefaction. The aim of this report was to present a case of dentinogenesis imperfecta type II that was followed up over a 17-year period. This report also presents scanning electron microscopy images of the enamel and dentin, showing that both were altered in the affected teeth. The disease characteristics and the treatments that were administered are reported in this study to guide dentists with respect to the need for early diagnosis and adequate follow-up to avoid major sequelae.

Expansion Properties of Mortar Using Waste Glass and Industrial By-Products

  • Park, Seung-Bum;Lee, Bong-Chun
    • International Journal of Concrete Structures and Materials
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    • v.18 no.2E
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    • pp.125-132
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    • 2006
  • Waste glass has been increasingly used in industrial applications. One shortcoming in the utilization of waste glass for concrete production is that it can cause the concrete to be weakened and cracked due to its expansion by alkali-silica reaction(ASR). This study analyzed the ASR expansion and strength properties of concrete in terms of waste glass color(amber and emerald-green), and industrial by-products(ground granulated blast-furnace slag, fly ash). Specifically, the role of industrial by-products content in reducing the ASR expansion caused by waste glass was analyzed in detail. In addition, the feasibility of using ground glass for its pozzolanic property was also analyzed. The research result revealed that the pessimum size for waste glass was $2.5{\sim}1.2mm$ regardless of the color of waste glass. Moreover, it was found that the smaller the waste glass is than the size of $2.5{\sim}1.2mm$, the less expansion of ASR was. Additionally, the use of waste glass in combination with industrial by-products had an effect of reducing the expansion and strength loss caused by ASR between the alkali in the cement paste and the silica in the waste glass. Finally, ground glass less than 0.075 mm was deemed to be applicable as a pozzolanic material.

AKARI ALL-SKY BRIGHT SOURCE CATALOGUE: FAR-INFRARED LUMINOUS QUASARS AND THE OPTICAL FAR-INFRARED CORRELATION

  • Sedgwick, Chris;Serjeant, Stephen;Pearson, Chris;Yamamura, I.;Makiuti, S.;Ikeda, N.;Fukuda, Y.;Oyabu, S.;Koga, T.;Amber, S.;White, Glenn J.
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.305-307
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    • 2017
  • We have identified 22 quasars in the AKARI far-infrared all-sky Bright Source Catalogue, using a matching radius of < 10", and excluding matches which are close to foreground extended sources or cirrus. We have confirmed a relation between quasar optical luminosity and far-infrared luminosity which was found in an earlier study. In addition, we have found that the 11 sources which are at redshift z > 1 are magnified with respect to the predicted far-infrared luminosity, and consider this may be due to gravitational lensing. If confirmed, this would provide a new way to identify lenses; if not, we may have identified an interesting new population of extreme starbursting quasars.

Effects of generalized-Born implicit solvent models in NMR structure refinement

  • Jee, Jun-Goo
    • Journal of the Korean Magnetic Resonance Society
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    • v.17 no.1
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    • pp.11-18
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    • 2013
  • Rapid advances of computational power and method have made it practical to apply the time-consuming calculations with all-atom force fields and sophisticated potential energies into refining NMR structure. Added to the all-atom force field, generalized-Born implicit solvent model (GBIS) contributes substantially to improving the qualities of the resulting NMR structures. GBIS approximates the effects that explicit solvents bring about even with fairly reduced computational times. Although GBIS is employed in the final stage of NMR structure calculation with experimental restraints, the effects by GBIS on structures have been reported notable. However, the detailed effect is little studied in a quantitative way. In this study, we report GBIS refinements of ubiquitin and GB1 structures by six GBIS models of AMBER package with experimental distance and backbone torsion angle restraints. Of GBIS models tested, the calculations with igb=7 option generated the closest structures to those determined by X-ray both in ubiquitin and GB1 from the viewpoints of root-mean-square deviations. Those with igb=5 yielded the second best results. Our data suggest that the degrees of improvements vary under different GBIS models and the proper selection of GBIS model can lead to better results.

Use of Conformational Space Annealing in Molecular Docking

  • Lee, Kyoung-Rim;Czaplewski, Cezary;Kim, Seung-Yeon;Lee, Joo-Young
    • Proceedings of the Korean Society for Bioinformatics Conference
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    • 2004.11a
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    • pp.221-233
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    • 2004
  • Molecular docking falls into the general category of global optimization problems since its main purpose is to find the most stable complex consisting of a receptor and its ligand. Conformational space annealing (CSA), a powerful global optimization method, is incorporated with the Tinker molecular modeling package to perform molecular docking simulations of six receptor-ligand complexes (3PTB, 1ULB, 2CPP, 1STP, 3CPA and 1PPH) from the Protein Data Bank. In parallel, Monte Carlo with minimization (MCM) method is also incorporated into the Tinker package for comparison. The energy function, consisting of electrostatic interactions, van der Waals interactions and torsional energy terms, is calculated using the AMBER94 all-atom empirical force field. Rigid docking simulations for all six complexes and flexible docking simulations for three complexes (1STP, 3CPA and 1PPH) are carried out using the CSA and the MCM methods. The simulation results show that the docking procedures using the CSA method generally find the most stable complexes as well as the native -like complexes more efficiently and accurately than those using the MCM, demonstrating that CSA is a promising search method for molecular docking problems.

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Musical Identity Online: A "Netnographic" Perspective of Online Communities

  • Strubel, Jessica;Pookulangara, Sanjukta;Murray, Amber
    • International Journal of Costume and Fashion
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    • v.13 no.2
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    • pp.15-29
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    • 2013
  • Today's technology enables consumers to trade millions of dollars, conduct online banking, access entertainment, and do countless other activities at the click of a button. Online social networks (OSN) have become a cultural phenomenon that allows for individualistic consumerism. Consumers are increasingly utilizing OSN to share ideas, build communities, and contact fellow consumers who are similar to themselves. The relevance of online communities to the music is immense especially because musicians are now using social media to build global audiences. Not only is information about music and performance disseminated online, but musical commodities are sold and traded online. Online music communities allow consumers to elect and create new identities online through the purchase of subcultural commodities. Given the growing economic importance of online music communities it is important to get a holistic view of subcultural communities online. This study utilized content analysis of online music community websites using the Netnography methodology as developed by Kozinet for data collection to analyze consumers' purchasing and consumption behavior of subcultural commodities online as related to the formation of subcultural identities. Findings showed that subcultural items are predominantly purchased online, especially digital music, and there is a need for more custom craft items. The authors presented a new conceptual taxonomy of online subcultural consumer classifications based on online behavior patterns.

Zoogeographic Analysis on the Subfamily Tryphoninae (Hymenoptera:Ichneumonidae) (뭉툭맵시벌아과(벌목:맵시벌과)의 동물지리학적 분석)

  • 차진열;이종욱;권용정
    • Korean journal of applied entomology
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    • v.38 no.1
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    • pp.1-10
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    • 1999
  • According to zoogeographic analysis, distribution types of Korean species of the subfamily Tryphoninae are as follows; Holarctic species (9.6%), Transpalearctic (38.4%), Transpalearctic-Oriental (8.2%), Eastern Palearctic (Trans-Far East Asia)-Oriental (4.1 %), Eastern Palearctic (17.8%) and Endemic (21.9%). Because of large numbers of palearctic and endemic species, we believe that the Korean Tryphoninae may have originated from northern hemisphere. The oldest fossil species of the Tryphoninae are the Catachoru rninor Townes and Urotryphon pusillus Townes in Creataceous amber from the peninsula Taimyr, Siberia. The world-wide distribution of the Tryphoninae appears to coincide with the continental movement.

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Expression of a Carboxy-Terminal Deletion Mutant of Recombinant Tadpole H-Chain Ferritin in Escherichia coli

  • Lee, Mi-Young;Kim, Young-Taek;Kim, Kyung-Suk
    • BMB Reports
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    • v.29 no.5
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    • pp.411-416
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    • 1996
  • In order to study the role of the protein shell in both iron uptake and iron core formation of ferritin, we constructed a deletion mutant of the ferritin gene and expressed the mutant gene in Escherichia coli, This mutant was obtained by introducing an amber mutation at position Pro-157 and a deletion of the 19 amino acid residues at the carboxy-terminus of the recombinant tadpole H-chain ferritin. The deleted amino acids correspond to E-helix forming the hydrophobic channel in the protein. E. coli harboring the plasmid pTHP157, which contains the deleted gene, was grown at $23^{\circ}C$ in the presence of 0.1 mM IPTG, and the induced protein appeared to be partly soluble. Nondenaturing polyacrylamide gel electrophoresis showed that the expressed mutant H-chains coassemble into holoprotein, suggesting that E-helix is not necessary for assembly of the subunits as reported for human H-chain ferritin. Its ability in iron core formation was proven in an Fe staining gel, the result disagreeing with the observation that the hydrophobic channel is necessary for iron core formation in human H-chain ferritin.

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Editing of Genomic TNFSF9 by CRISPR-Cas9 Can Be Followed by Re-Editing of Its Transcript

  • Lee, Hyeon-Woo
    • Molecules and Cells
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    • v.41 no.10
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    • pp.917-922
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    • 2018
  • The CRISPR-Cas system is a well-established RNA-guided DNA editing technique widely used to modify genomic DNA sequences. I used the CRISPR-Cas9 system to change the second and third nucleotides of the triplet $T{\underline{CT}}$ of human TNSFSF9 in HepG2 cells to $T{\underline{AG}}$ to create an amber stop codon. The $T{\underline{CT}}$ triplet is the codon for Ser at the $172^{nd}$ position of TNSFSF9. The two substituted nucleotides, AG, were confirmed by DNA sequencing of the PCR product followed by PCR amplification of the genomic TNFSF9 gene. Interestingly, sequencing of the cDNA of transcripts of the edited TNFSF9 gene revealed that the $T{\underline{AG}}$ had been re-edited to the wild type triplet $T{\underline{CT}}$, and 1 or 2 bases just before the triplet had been deleted. These observations indicate that CRISPR-Cas9-mediated editing of bases in target genomic DNA can be followed by spontaneous re-editing (correcting) of the bases during transcription.