• 한국산업정보학회논문지
• /
• 제22권5호
• /
• pp.31-37
• /
• 2017

본 논문에서는 자동화 계측 시스템 설계를 통하여 액상황산알루미늄 제조 공정을 개선하였다. 액상황산알루미늄 제조과정은 대용량의 무게를 사용하며 제품의 품질이 생산과정에서 투입되는 원료의 비율에 높게 의존하기 때문에 정밀한 중량 분석이 매우 중요하다. 자동화설계를 위하여 대용량의 무게를 정밀하게 측정할 수 있는 로드셀 센서와 자동화 공정에서 가장 많이 활용되는 PLC 기술을 적용하였다. 자동화 시스템을 사용하기 전에 생산된 황산알루미늄에 포함된 산화알루미늄의 함량은 8.023% ~ 8.250%의 변화가 나타났으나 자동화 시스템 적용 이후에는 8.09% ~ 8.109% 로 변화폭이 크게 감소하였다. 그 결과 계량오차에 의한 품질 불량률을 감소시킬 수 있었으며 물과 재이용수의 부정확한 투입으로 인한 반응제품의 역류 현상과 같은 안전사고를 감소시킬 수 있었다.

• 한국표면공학회지
• /
• 제37권1호
• /
• pp.13-21
• /
• 2004

The deposition rate, the current efficiency and surface morphology of trivalent Cr deposits were investigated according to additives in sulfate bath and current density. The deposition rate of the Cr deposits plated from the formic acid complexed bath was noticeably higher than that of the glycine complexed bath. The current efficiency of the deposition from formic acid bath was higher than that of the glycine bath and increased with current density in the range of 20-50 A/d$\m^2$. The current efficiency of the deposition from the formic acid bath with boric acid buffer was higher than that of the bath with aluminum sulfate or boric acid-aluminum sulfate buffers. The nodular crystallite size of the Cr deposits increased with current density and the uniform and crack-free growth of the deposits for the aluminum sulfate was observed compared to the other buffers.

• 한국세라믹학회:학술대회논문집
• /
• 한국세라믹학회 2003년도 춘계총회 및 연구발표회 초록집
• /
• pp.215.1-215
• /
• 2003

• 원예과학기술지
• /
• 제17권6호
• /
• pp.758-760
• /
• 1999

몇가지 전처리제와 절화장미에 효과적인 보존용액으로 알려진 HQS+sucrose+ethionine 혼합액을 병행 처리하여 절화수명과 품질을 비교함으로써 절화장미의 관상가치를 향상시키고자 본 실험을 수행하였다. 절화수명은 증류수에 보존시에는 전처리 효과가 없었으며, HQS+sucrose+ethionine 용액에 보존하였을 때에는 aluminum sulfate 혼합액과 NaOCl 전처리에서 수명이 연장되었다. 흡수량은 증류수에 보존한 처리구에서 높은 경향을 보여 생체중과 반대의 결과를 나타냈다. 생체중은 STS+sucrose 전처리를 제외하고는 HQS+sucrose+ethionine 혼합액에 보존시 증류수보다 증가하였다. 꽃목굽음은 HQS+sucrose+ethionine 용액에 보존했을 때에는 모든 전처리에서 증류수보다 지연되는 경향을 보였으며 특히 aluminum sulfate 혼합액 전처리에서는 수명 종료시까지 꽃목굽음 현상이 거의 나타나지 않았다. 화경과 꽃잎의 건물중은 STS+sucrose 전처리를 제외하고는 처리간 차이가 없었으며, 보존용액에 있어서는 HQS 혼합액이 증류수보다 증가하는 경향을 보였다. 화색은 L값과 a값은 처리간 차이가 없었 으나 b값은 증류수에 보존한 처리구에서 최초의 값에 비해 낮게 나타났다.

• 한국환경과학회지
• /
• 제31권1호
• /
• pp.1-8
• /
• 2022

In this study, solid-liquid separation conditions for coagulation and sedimentation experiments using inorganic coagulant (aluminum sulfate and Poly-Aluminum Chloride (PAC)) were optimized with brine wastewater discharged by the epoxy-resin process. When the turbidity and suspended solid (SS) concentration in raw wastewater were 74 NTU and 4.1 mg/L, respectively, their values decreased the lowest in a coagulant dosage of 135.0 - 270.0 mg Al³⁺/L. The epoxy resin was re-dispersed in the upper part of wastewater treated above 405.0 mg Al³⁺/L. The removal efficiencies of turbidity and SS via dosing with aluminum sulfate and PAC were evaluated at initial turbidity and SS of 74 - 630 NTU and 4.1 - 38.5 mg/L, respectively. They increased most in the range from 135.0 - 270.0 mg Al³⁺/L. The solid-liquid separation condition was quantitatively compared to the correlation of SS removal efficiency between the coagulant dosage and SS concentration based on the concentration of aluminum ions. The empirical formula, R = be^aD, shows the relationship between SS removal efficiency (R) and coagulant dosage (D) at 38.5 mg/L; it produced high correlation coefficients (r²) of 0.9871 for aluminum sulfate and 0.9751 for PAC.

• Journal of the Korean Wood Science and Technology
• /
• 제16권1호
• /
• pp.3-8
• /
• 1988

This study was carried out to examine the effect of pretreatment of veneer with aluminum sulfate solution for the manufacture of the kapur plywood on the reduction of urea resin spread. The results were as follows: 1. Specific gravities of plywoods made of the kapur veneers ranged from 0.83 to 0.84 and their moisture contents based on air dry weight showed from 10.6% to 11.4%. These met the Korean Industrial Standards. 2. In the case of dry shear strength for the 3rd class plywood, 40% reduction- spread met K S as well as normal urea resin spread. pH of the aluminum sulfate solution gave better result at pH 4.5 and pH 6 than at pH 3. For the manufacture of the 2nd class plywood, hot and cold water-wet shear strength show the best results at the following conditions; such as 20% reduction spread, pH 4.5 of aluminum sulfate solution and all veneer treatment.

• 한국세라믹학회지
• /
• 제26권1호
• /
• pp.81-90
• /
• 1989

High purity alumina and amorphous silica were prepared from Ha-dong kaolin by means of appliance of sulfuric acid. The effect of sulfuric acid concentration, reaction temperature and reaction time on the formation of aluminum sulfate was investigated. The precipitation conditions ofaluminum sulfate from the sulfuric acid solution with ethanol and ammonium hydroxide were deteremined. In the optimum condition, the conversion of aluminum oxide in kaolin to aluminum oxide powder was 85.0 percent. Alumina powder was prepared by calcination of the precipitates, and its purity was 99.0 percent.

• 상하수도학회지
• /
• 제18권3호
• /
• pp.331-336
• /
• 2004

The correlation between polymeric aluminum species of coagulant and its coagulation efficiency was investigated using several commercial polymeric Al(III) inorganic coagulants (Poly Aluminum Hydroxy Chloro Sulfate 2020 (PAHCS2020), Poly Aluminum Hydroxy Chloro Sulfate 2500 (PAHCS2500) which was introduced in Korean water treatment plants. The poly aluminum chloride (PAC), Poly Aluminum Hydroxide Chloride Silicate (PACS)) and the aluminum salts ($AlCl_3$, Alum ($Al_2(SO_4)_3$)) were used for the purpose of comparison. The comparison of the coagulation efficiency of each coagulant was made by turbidity removal through the standard jar testing procedure and the determination of the hydrolytic Al(III) species was made by the ferron method which can differentiate the monomeric aluminum species from the polymeric aluminum species. Overall, PAHCS2020 and PAHCS2500 showed the better performance in turbidity removal than the aluminum salts. The performance of coagulation was even better without adjustment of pH during the coagulation experiment. The positive correlation between polymeric aluminum species of coagulant and coagulation efficiency was found.

• 한국세라믹학회지
• /
• 제27권6호
• /
• pp.747-754
• /
• 1990

Aluminum hydrate gels were prepared from the mixtures of bauxite and ammonium sulfate by wet acid process. Optimum conditions for obtaining the maximum yield( 99%) of aluminum hydrates from the same amount of bauxite were confirmed as follows ; 1. Mixing ratio ; addition of 25mole% of ammonium sulfate to 1mole of bauxite. 2. Calcination ; heated at 350℃ for 1hr. 3. Extraction ; leached at 95℃ in 1% H2SO4 for 90min. 4. pH of precipitating solution; slight below 7.0. Amorphous aluminum hydrates were precipitated at the pH lower than 8.5, but the precipitates crystallized to bayerite at the pH was 10. Mean diameter of α-Al2O3 powders which were obtained by calcining the aluminum hydrates was below 0.2㎛, and EDS analysis revealed than SiO2 was it's primary impurity.

• 한국환경과학회지
• /
• 제8권6호
• /
• pp.711-716
• /
• 1999

This research explored the feasibility of preparing and utilizing a prefonned polymeric solution of Al(III) for coagulation in water treatment. Slow base(NaOH) injection into supersaturated aluminum chloride and aluminum sulfate solutions did produce high yields of Al polymers useful to water treatment applications. The method of characterization analysis was based on timed spectrophotometer with ferron as a color developing reagent. The hydrolytic Al species were divided into $monomeric(Al_a),\;polymeric(Al_b),\;and\;precipitate(Al_c)$ from the difference in reaction kinetics. The analysis of PACl's characteristics showed that the quantity of polymeric Al produced at value of$ r(OH_{added}/AI)=2.2$ was $83\%$ of the total aluminum in solution, as showing maximum contents and precipitated Al was dramatically increased when r was increased above 2.35. In addition, the characteristics of polyaluminum sulfate (PAS) showed that polymeric Al contained at r = 0.75 was $18\%$ of the total aluminum in solution. The synthesized PACI and PAS were stable during storing period, as indicating negligible aging effect. The effect of sulfate ion on PACI was dependent on the concentration of sulfate ion. That is, polymeric species decrease and precipitate species increase as sulfate ion concentration increased. It can be concluded that the sulfate cause the formation of $Al(OH)_{3(S)}$ at low pH. However, The effect of calcium ion was negligible for distribution of Al species.