• 제목/요약/키워드: Aluminum sulfate

검색결과 212건 처리시간 0.021초

Mg-Al 복합 황산염 수화물의 열분해 속도 (Kinetics of the Thermal Decomposition of Mg-Al Sulfate Hydrate)

  • 박홍채;오기동
    • 한국세라믹학회지
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    • 제24권5호
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    • pp.417-422
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    • 1987
  • Kinetic studies were made on the thermal decomposition of hydrated magnesium aluminum double sulfate by a nonisothermal TG method. Thermal analyses of the dehydration of tricosahydrate showed that the reaction proceeded via decahydrate to the anhydrous MgAl2(SO4)4 in the range 50$^{\circ}$to 400$^{\circ}C$. Decomposition of MgAl2(SO4)4 occurred as the two-step between 650$^{\circ}$ and 970$^{\circ}C$. Dehydration of MgAl2(SO4)4$.$23H2O and a 2D diffusion controlled with an activation energy of 16.6kcal/mole, respectively. MgAl2(SO4)4 fitted the contracting volume model with an activation energy of 10.5kcal/mole, and MgSO4 fitted a contracting area model with an activation of 4.5kcal/mole.

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천연염료를 이용한 한지염색에 관한 연구(II) -양파껍질을 중심으로- (Studies on the Dyeing of Hanji by Natural Dye-stuffs(II) -With a focus on the Onion-peelings-)

  • 전철
    • 펄프종이기술
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    • 제35권1호
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    • pp.48-53
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    • 2003
  • The objective of this study was to find in what color Korean handmade paper(Hanji) is dyed when it is dyed with a pigment extracted from waste onion peelings using different kinds of mordant, and how the paper is discolored and variety of strength under the condition of accelerated aging test. The results of this experiment are as follows. 1. Korean handmade paper was dyed in different colors according to the kinds of mordant. Mainly it was dyed in orange-brown, and sometimes in gold or khaki. 2. Korean handmade paper dyed was not discolored much, which suggests that the pigment is strong under the condition of aging. 3. As for durability, Korean handmade paper dyed in gold was strongest. Korean handmade paper, to which aluminum sulfate, iron sulfate or sodium dichromate was applied as mordant, had poor durability. Thus, these were not suitable as mordant.

칡 뿌리에서 분리한 B-amylase의 효소학적 특성 (Enzymatic Properties of $\beta$-amylase Isolated from Arrowroot)

  • 윤상혁;심우만
    • 한국식품영양학회지
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    • 제9권1호
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    • pp.85-91
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    • 1996
  • B-amylase(EC 3.2.1.2) was isolated from the root of arrowroot(Peuria thunbergiana Bentham) with distilled water and then fractionated with ammonium sulfate. Crude extract was partially purified by ion exchange chromatography and gel filtration. The enzymatic properties of partially purified $\beta$-amylase were as follows, the enzyme was fractionated with ammonium sulfate between 0.2 and 0.4 saturation, and showed the typical reaction properties of B-amylase producing only maltose from starch. Optinum pH and temperature were pH 6.5, $50^{\circ}C$ respectively. The activity of the enzyme had proportional relations with enzyme protein concentration below 4mg, and had Michaelis constant of 66.7mg% for soluble starch. The enzyme was inhibited by some metal louts such as silver, cadmium, mercury, aluminum, iron and copper.

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동물성 섬유에 대한 Lac추출물의 염색성(II) -매염방법과 매염제 종류의 효과- (Dyeabilites of Lac extract onto the silk and wool fabrics(II) -Effects of mordanting methods and various mordants-)

  • 김호정;박문영;이문철
    • 한국의류학회지
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    • 제27권9_10호
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    • pp.1134-1143
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    • 2003
  • The purpose of this study is to investigate surface color change and effects of mordants on the K/S values of silk and wool fabrics dyed with Lac extract, according to the mordanting methods and conditions such as temperature, concentration and time of the mordanting bath. The results were as follow; 1 K/S values of the silk and wool fabrics according to the temperature of the mordanting bath were shown a slight decline beyond 40$^{\circ}C$. 2. Surface color of the silk changed from red to reddish purple and that of the wool showed red tone when mordanted with Aluminum postassium sulfate, Copper acetate and Copper (II) sulfate regardless of the mordanting conditions. 3. The light and dry cleaning fastness of silk and wool fabrics dyed with Lac extract according to the mordanting methods were very good.

히드로탈시트의 최적 합성조건 (Optimal Conditions for Hydrotalcite Synthesis)

  • 신화우;박형민;안세민
    • 약학회지
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    • 제43권6호
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    • pp.689-695
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    • 1999
  • Hydrotalcite was prepared by reacting with sodium carbonate, magnesium oxide and aluminum sulfate solutions in this study. The optimum synthesis conditions based on the yield of the product were established by applying Box-Wilson experimental design. It was found that the optimum synthesis conditions of hydrotalcite were as follows; reacting temperature : 48~63$^{\circ}C$, concentration of reactant solution : about 20%, molar concentration ratio of two reactants [MgO]/[Al. sulfate] ; 7.35~8.1, temperature of washing water : 34.4~37.4$^{\circ}C$, drying temperature : 74~81.5$^{\circ}C$. The physicochemical properties of hydrotalcite as medicine were studied by use of chemical analysis, D.S.C. thermogram, bulk volume test and acid consuming capacity measurements.

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치자를 이용한 한지의 염색성 (Dyeing properties of Gardenia on Han Jee)

  • 김애순
    • 한국의류학회지
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    • 제25권8호
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    • pp.1493-1499
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    • 2001
  • This paper investigated the dyeabiltiy and surface color of Han Jee dyed with Gardenia extract after mordanted with mordants under the various dyeing conditions. The results obtained were as follows 1) λmax of the dyeing Han Jee dyed with Gardenia appeared at 660 and 710nm. 2)K/s value of dyeing Han Jee was increased when dyeing condition, temperature, time was higher. 3) Surface color of Han Jee with mordants changed differently according to the mordants used : 3.2Y by Aluminum acetate, 2.0GY by Copper sulfate, 9.5YR by Iron sulfate. 3.4Y by Tin chloride, and 4.5Y by non-mordanting.

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재생지 폐수의 최적 응집조건 결정에 관한 연구 (Studies on the Determination of Optimal Flocculation Condition in Wastewater of Recycled Paper)

  • 이성호;임택준;조준형
    • 펄프종이기술
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    • 제33권3호
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    • pp.44-51
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    • 2001
  • Sedimentation characteristics such as SS, $BOD_5$, COD removal efficiency of waste water in the toilet paper mill using milk carton were examined. Optimum dosage of coagulant, rapid mixing time and slow mixing time were determined by turbidity, SS, COD, $BOD_5$ and then equation for treatment efficiency was suggested. Mechanical strength of floc was determined by turbidity. For the coagulant, polyacrylamide (PAM) is more efficient for removing pollution than the aluminium sulfate. Effective mixing ratios of PAM and aluminum sulfate to remove pollution are 70:30 and 30:70. The lowest turbidity was showed when rapid mixing at 300 rpm after coagulant injection was applied. That which indicates the highest point of flocs mechanical strength.

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쑥을 이용한 천연염색에 관한 연구 (The Study on Natural Dyeing with Artemisia)

  • 임명은;유혜자;이혜자
    • 한국의류학회지
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    • 제21권5호
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    • pp.911-921
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    • 1997
  • Recently the interest in natural dyeing has been increased because of the color clarity, natural grace and reactionism in fashion. Indigo dyeing, safflower dyeing and Gal-ott in Cheju-Do become generally known, so the study about the natural dyeing is continued with national intrust and support. In this study, 1 used artemisia for various dyeing tests because we can get it easily. 1 tested the dyeability in wool as well as cotton and silk with wormwood in natural dyeing material. I also dyed nylon with the same material for the comparison of the molecular structure. The mercerization and the chitosan treatment were done in cotton to improve the low dyeability in the natural dyeing. The result of this study are as follows; We have to dye repeatedly to get deep color in natural dyeing, and mordant treatment brought good result in color difference and dyeing fastness. 1. Compared with silk, wool and nylon, the dyeability of cotton was the worse. The color difference of cotton was 18.81 without mordants , and 24.05 with mordant. The dyeability of cotton was much increased by mordants such as potassiumdichromate, copper sulfate, iron sulfate and salt water. The color of cotton was turned into yellow-green in potassium dichromate and yellow-green with deep green in copper sulfate. The mercerization and the chitosan treatment of cotton made the improvement in color, dyeability, laundering fastness, abrasion fastness. 2. The color difference of silk was 3 times as high as cotton. It showed the similar degree with the chitosan treated-cotton. That is to say, silk had good dyeability because it contains amino group and carboxyl group. The dyebility of silk was increased by a mordant such as iron sulfate, potassium dichromate and salt water, Drycleaning fastness showed 5 grade, abrasion-fastness was high over 4~5 grade and sunlight fastness showed 1 grade in all case. 3. The color difference of wool was the best among four fabrics because of 18 kinds of amino acids. It is considered that the sulfate of wool has the polarity and help metal- mordants get the better dyeability such as potassium dichromate, iron sulfate, copper sulfate, and aluminum chloride. The color was reddish-green in potassium dichromate, yellow.greenin iron sulfate and copper sulfate, and yellow in the rest mordants. Drycleaning fastness of wool showed over 4~5 grade, abrasion fastness 5 grade. Sunlight-fastness 1 grade. 4. The dyeability of nylon was almost same because of the similar molecular structure with silk. The clarity of color was poor. The color was yellow-green in copper sulfate and yellow in the rest mordants. Laundering fastness and abrasion-fastness of nylon was good. Sunlight- fastness represented 1 grade.

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골판지 재활용 공정수의 혐기성 분해에 따른 유해 기체의 생성과 부식 (Generation of Hazardous Gas and Corrosion Originated from Anaerobic Digestion of Process Water in OCC Recycling Mill)

  • 박대식;류정용;송봉근;서영범;성용주
    • 펄프종이기술
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    • 제37권3호
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    • pp.59-65
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    • 2005
  • There are accumulations of remained chemical additives and contaminants in the process water of semi-closed linerboard mill. High temperature of the process water aggravates the anaerobic digestion of contaminated process water and causes the generation of hazardous gases, which are from the biological reaction of varied additives and contaminants. The hydrogen sulfide in the gases easily combine with moisture in the air, and become sulfuric acid, which causes corrosion of paper machinery. This hydrogen sulfide is from the reduction of sulfate ions in the process water, and the sulfate ions are mostly from the alum. We changed the alum to PAC (Poly Aluminum Chloride). The results were preventing generation of hydrogen sulfide, and equivalent sizing effect by the use of PAC.

복합응집제를 이용한 염색가공 폐수의 처리 (Treatment of Dye-Processing Wastewater with Complex Chemical Coagulants)

  • 서명포;김병소
    • 한국산업융합학회 논문집
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    • 제9권2호
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    • pp.111-116
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    • 2006
  • This study provides the optimal conditions treating with the coagulation process and the other chemical treatment processes for dyeing wastewater, especially various dyeing complex wastewater. The results are shown as follows: 1. Optimum reaction condition of pH for ferrous sulfate was the range of 9 to 12. And when 3,000ppm(mg/l) of ferrous sulfate was dosed, the maximum $COD_{Mn}$ removal rate was approximately 40%. 2. In case of ferrous chloride and Bittern as coagulants, optimum pH range was 10 to 11. And maximum $COD_{Mn}$ removal rate was approximately 46% to 50% for dose of 2,000ppm(mg/l) to 6,000 ppm. 3. It is confirmed that the activated sludge process following coagulation precipitation method provides better treatment efficiency than the coagulation precipitation method following the activated sludge process. 4. The purpose of this study was to produce CGF (Cyanoguanidineformaldehyde resin) by organic compounds. 5. The complex coagulation agent by this study is the most economical coagulant with Alum(aluminum sulfate) and the removal efficiency is approximately 54% with 1,000ppm(mg/l) of pH range 6 to 7.

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