• Title/Summary/Keyword: Alumino-borosilicate

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Fabrication and Optical Characterization of Highly Dy3+-ion-incorporated Alumino-borosilicate Glasses for Magneto-optical Applications at 1550 nm (1550 nm 자기광학 응용을 위한 고농도 Dy3+ 이온이 함유된 알루미노보로실리케이트 유리의 제조 및 자기광학 특성 분석)

  • Kadathala Linganna;Yong-Tak Ryu;Young-Ouk Park;Bong-Ahn Yu;Bok Hyeon Kim
    • Korean Journal of Optics and Photonics
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    • v.35 no.3
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    • pp.115-120
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    • 2024
  • Magneto-optical (MO) materials have attracted much attention, since they can be utilized for various optical applications, such as magnetic field sensors, optical current sensors, optical isolators, and optical circulators. In this study, alumino-borosilicate (ABS) glasses with high concentrations of Dy3+ ions were fabricated by a conventional melt-quenching technique, and the dependence of their thermal, optical, and magneto-optical properties on Dy3+ ion concentration was investigated. The MO property of the glasses was investigated by measurement of Faraday rotation at 1550 nm. The Faraday rotation angle increased linearly with the increase of Dy3+ ion concentration in the glasses. A very high Verdet constant of -6.86 rad/(T·m) was obtained for glass with a Dy3+ ion concentration of 30 mol%. In addition, the ABS-Dy glasses showed good thermal stability of greater than 128 ℃ against crystallization, and high optical transmission of 70% in the visible to near-infrared windows of 480-720, 1390-1560, and 1800-2400 nm. Due to the high Verdet constant and good thermal stability, the ABS-Dy glasses in this study could be candidate optical materials for MO device applications at 1550 nm.

Preparation of Borosilicate Foamed Glass Body with Sound Absorption Characteristics by the Recycling Waste Liquid Crystal Display Glass (폐 LCD 유리를 이용한 흡음특성을 갖는 붕규산유리발포체 제조)

  • Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.612-619
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    • 2016
  • In this research, an alumino-borosilicate foamed glass with sound absorption property was prepared using the waste borosilicate glass obtained from the recycling process of waste liquid crystal display (LCD) panel. A 100 g of pulverized waste borosilicate glass with the particle size of under 325 mesh, was mixed with 0.3 g (wt/wt) of graphite, each 1.5 g (wt/wt) of $Na_2CO_3$, $Na_2SO_4$ and $CaCO_3$ as a foaming agent, and 6.0 g (wt/wt) of $H_3BO_3$ and 3.0 g (wt/wt) of $Al_2O_3$ as a pore control agent. Following mixture was under the foaming process for 20 minutes at a foaming temperature of $950^{\circ}C$. The result yielded the foaming agent with 45% of the opened porosity and 0.5-0.7 of the sound absorbing coefficient. This alumino-borosilicate foamed glass with the sound absorption property showed excellent physical and mechanical properties such as density of $0.21g/cm^3$, bending strength of $55N/cm^2$ and compression strength of $298N/cm^2$ which can be ideally used as sound absorption materials with heat-resisting and chemical-resisting property.

Low k Materials for High Frequency High Integration Modules

  • Na, Yoon-Soo;Lim, Tae-Young;Kim, Jin-Ho;Shin, Hyo-Soon;Hwang, Jong-Hee;Cho, Yong-Soo
    • Journal of the Korean Ceramic Society
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    • v.46 no.4
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    • pp.413-418
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    • 2009
  • Glass systems based on Ca, Sr, Ba, and Zn modified alumino-boro silicates were investigated in order to improve the dielectric and mechanical properties of a typical LTCC (low temperature co-fired ceramic) which was developed for high frequency highly-integrated modules. The glass was prepared by a typical melting procedure and then mixed with cordierite fillers to fabricate glass/ceramic composite-type LTCC materials. The amount of cordierite filler was fixed at 50 volumetric%. For an optimal glass composition of 7.5% CaO, 7.5% BaO, 5% ZnO, 10% $Al_2O_3$, 30% $B_2O_3$, and 40% $SiO_2$ in mole ratio, the resultant LTCC composite showed a dielectric constant of 5.8 and a dielectric loss ($tan{\delta}$) of 0.0009 after firing at $900^{\circ}C$. An average bending strength of 160MPa was obtained for the optimal composition.

Preparation and Nonlinear Optical Properties of CuCl-doped Nonlinear Optical Glasses : II. Nonlinear Optical Properties (CuCl 미립자가 분산된 비선형 광학유리의 제조와 비선형 광특성: II. 비선형 광특성)

  • 윤영권;한원택;이민영
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.429-435
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    • 1997
  • The third order nonlinear optical susceptibilities, {{{{ chi }}(3), of the CuCl doped alumino-borosilicate glasses were measured by the two beam configuration DFWM method and the absorption saturation method, and the measured {{{{ chi }}(3) values were about 10-8 esu in both methods. The response time was estimated to be about 105ps from the time decay curve of the luminescence spectra obtained by time-correlated single-photon counting (TCSPC) method.

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Preparation and Nonlinear Optical Properties of CuCl-doped Nonlinear Optical Glasses : III. Bimodal Distribution of CuCl Nanocrystals and Temperature Dependent Optical Absorption Spectra (CuCl 미립자가 분산된 비선형 광학유리의 제조와 비선형 광특성: III. CuCl 반도체 미립자의 Bimodal 분포 특성과 온도에 따른 광흡수도)

  • 윤영권;한원택
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.436-442
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    • 1997
  • The bimodal distribution of CuCl nano-crystals precipitated in alumino-borosilicate glass matrix (30SiO2-45B2O3-7.5Al2O3-7.5Na2O-7.5CaO-2.5GeO2(mole %)) was investigated by TEM and the temperature dependent optical spectroscopy. Two types of CuCl particles with different size were observed by TEM and it was confirmed by the splitting of Z3 absorption peak at low temperature and the occurrence of deflection point in the optical spectra with temperature.

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Preparation and Nonlinear Optical Properties of CuCl-doped Nonlinear Optical Glasses: I. Preparation, Microstructure, and Optical properties (CuCl 미립자가 분산된 비선형 광학유리의 제조와 비선형 광특성: I. 제조와 미세조직 및 광특성)

  • 윤영권;한원택
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.420-428
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    • 1997
  • Alumino-borosilicate glasses containing nano-sized CuCl crystals for nonlinear optical application were prepared by the melting and precipitation process, and structural and optical properties were investigated by using XRD, TEM, SAXS, and optical spectroscopy. the average radius of the precipitated CuCl particles was about 2 nm. The blue shift of Z3 resonance peak with decreasing the precipitated CuCl particles size was found and the radius increased with decreasing the glass transition temperature of the matrix glass and with increasing the temperature and duration time of the precipitation heat treatment.

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Low Temperature Sintering and Microwave Properties in (Mg0.93Ca0.07)TiO3 Ceramics ((Mg0.93Ca0.07)TiO3 세라믹스의 저온소결과 마이크로파 유전특성)

  • Shin, Dong-Soon;Choi, Young-Jin;Park, Jae-Gwan;Park, Jae-Hwan;Nahm, Sahn
    • Journal of the Korean Ceramic Society
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    • v.39 no.6
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    • pp.598-603
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    • 2002
  • The effects of alumine borosilicate glass composition on the densification and the microwave properties of (M $g_{0.93}$C $a_{0.07}$)Ti $O_3$ ceramics were studied. As the amount of glass increase, the density of ceramics increases and grain growth enhances. When 20 ~30 wt% of glass added, it was densified to over 95% of (M $g_{0.93}$C $a_{0.07}$)Ti $O_3$ theoretical density. (M $g_{0.93}$C $a_{0.07}$)Ti $O_3$ ceramic sintered at 95$0^{\circ}C$ exhibits dielectric constants of 15~16, quality factor of 8000 and temperature coefficient of resonant frequency of -45 ppm/$^{\circ}C$ by adding 20 wt% alumine borosilicate glass.