• 한국전기전자재료학회논문지
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• 제17권3호
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• pp.353-359
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• 2004

In this study. porcelain insulator samples which have a different alumina composition were manufactured in order to test electrical and mechanical properties and make an analysis of the propagation phenomena of micro cracks on porcelain body. From XRD quantitative analysis the crystalline phases were different with alumina composition, sample C and D which have about l7wt％ Corundum phase without the Cristobalite phase shows better electrical and mechanical properties than sample A and B which have the Cristobalite phase. In dielectrics test on porcelain samples with below l7wt％ alumina composition, it was found that the amount of glass phase(SiO$_2$) have an main effect to decrease the dielectric loss(tan$\delta$), and the dielectric breakdown voltage of aluminous porcelain insulators was largely affected by its relative density. As a micro tracks analysis, HRB were measured, then the intensity of HRB increased with the amount of alumina composition. On the other hand, the propagation behaviors of cracks was fairly influenced by the distribution of pores.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 춘계학술대회 논문집 유기절연재료 방전 플라즈마연구회
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• pp.85-88
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• 2003

In this study, porcelain insulator samples which have a different alumina composition were manufactured in order to test electrical and mechanical properties and make an analysis of the propagation phenomena of micro cracks on porcelain body. From XRD quantitative analysis the crystalline phases were different with alumina composition, sample C and D which have about 17wt% Corundum phase without the Cristobalite phase shows better electrical and mechanical properties than sample A and 8 which have the Cristobalite phase. In dielectrics test on porcelain samples with below 17wt% alumina composition, it was found that the amount of glass phase$(SiO_2)$have an main effect to decrease the dielectric loss$(tan{\delta})$, and the dielectric breakdown voltage of aluminous porcelain insulators was largely affected by its relative density. As a micro cracks analysis, HRS were measured, then the intensity of HRS increased with the amount of alumina composition. On the other hand, the propagation behaviors of cracks was fairly influenced by the distribution of pores.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 추계학술대회 논문집 전기설비전문위원
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• pp.261-262
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• 2008

Damaged glass insulator that is utilized the high-speed railroad in domestic try to find the cause. This paper is investigated on the characteristics of alumina cement as the binder of class insulator. The components of glass insulator ore stub(tin), rod(tin), shed(tempered glass), and alumina cement. If composition of alumina cement is not unified, crack of alumina cement generated. As these results, cracked marks of cement is appeared and composition of alumina cement is not unified. Therefore, it is estimated that main element of long-term degradation is a alumina cement.

• The Korean Journal of Ceramics
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• 제4권4호
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• pp.363-367
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• 1998

Alumina/mica and spinel/mica composites were fabricated by sintering of compacts containing 20 mass% fluoromica ($KMg_3AlSi_3O-{10}F_2$) glass and alumina or spinel. In both composites, mica precipitated as plate-like crystals at temperatures lower than $1300^{\circ}C$ and melted at $1300^{\circ}C$ to $1400^{\circ}C$. In alumina/mica composites, alumina and glass reacted to produce spinel, and the densification progressed by the solution-precipitation of alumina. Consequently, the glass composition changed and the mica did not precipitate at temperatures higher than $1400^{\circ}C$. However, mica precipitated after a reheating process. In spinel/mica composites, the glass composition did not change. After the mica phase melted, it recrystallized during slow cooling. The relative density reached the maximum at $1500^{\circ}C$ for alumina/mica and at $1300^{\circ}C$ spinel/mica composites, and decreased at further high temperatures.

• The Korean Journal of Ceramics
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• 제6권1호
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• pp.78-82
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• 2000

Although alumina aggregates have been used as refractory aggregates due to the improved mechanical properties of refractories as a result of the low contraction of alumina aggregates, the aggregates have a difficulty in fabrication due to its low sinterability. Two types of alumina aggregates and a fused alumina aggregate containing transient liquid forming additives are prepared to investigate the sintering characteristics of aggregates. $Al_2O_3$rich composition in the $Al_2O_3$-MgO-$SiO_2$(-$TiO_2$) system is chosen for the transient liquid phase sintering and the final recrystallized bonding phase between grains inside the fused alumina aggregates is found to be a needle-like mullite phase. The flexural strength of alumina bars, reaction-bonded using the paste having a composition of $Al_2O_3$-MgO-$SiO_2$-$TiO_2$, is about 78 MPa, which is one half value of that of pure alumina.

• 한국세라믹학회지
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• 제36권10호
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• pp.1123-1131
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• 1999

Alumina-glass composites which are considered as the material of the choice for all dental crown was prepared by aqeous-based tape casting and sintering for 2h at 1120$^{\circ}C$ followed by glass infiltration for 2h at 1100$^{\circ}C$ Biaxial strength and fracture toughness of the composites were evaluated to determine the optimum composition of the tape as a function of the amount of constituent such as alumina binder and plasticizer. The strength and the fracture toughness of the alumina tape increased with increasing the contents of alumina and binder. These observations are consistent with in fluence of the constituents on mean alumuna particle distance in tapes suggesting that high strength of the glass infiltrated alumina composites is related to toughening by crack bowing. The biaxial strength and the fracture toughness of the composite containing the optimum constituent composition were 523 MPa and 3.3 MPa$.$1/2 respectively.

• 한국세라믹학회지
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• 제42권1호
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• pp.1-6
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• 2005

In aqueous alumina tape casting, the effects of altering the composition of the suspensions, the binders and the casting thickness were studied. The rheological behavior of the suspensions and the defects of the dried tapes were examined and the relationships between them are discussed. The changes in the defect regions reported in the previous paper were related with the rheological properties with variations of the binder, the composition and the casting thickness. The shear thinning factor increased with the organic content and the solid content (the decrease of water content). The apparent viscosity increased with the shear thinning factor. The relation between the shear thinning factor and the log apparent viscosity was similar for all binder types. In the relation between the defect free region and the rheological properties, the defect free region became narrower with increasing casting thickness. The defect free region is independent of binder type. Therefore, the thicker tape is more difficult to produce in aqueous alumina tape casting. Knowledge of the rheological properties of the suspensions could help Predict the defect type and the possibility of defect free dried tapes.

• 한국재료학회지
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• 제11권12호
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• pp.1086-1090
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• 2001

Composition effects on microstructure and metallizing properties of the alumina sintered body were evaluated to develop the metallized alumina tubes having superior properties for electronic devices. SEM observation revealed that resultant micrographs and fractographs were varied with composition chance of additives and $SiO_2$-rich specimens showed better microstructural characteristics with uniform distribution of fine and round particles than other CaO-rich or MgO-rich ones. The resultant interfacial microstructure of the $SiO_2$-rich metallized alumina tubes also showed good metallizing properties with no defects between layers and uniform thickness of metallizing layer.

• 한국표면공학회지
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• 제33권4호
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• pp.261-265
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• 2000

Geometrically and chemically well defined Pt/alumina model catalysts have been prepared. To this end, we fabricated electrochemically alumina supports in which pores of constant size, length and shape were regularly distributed over a wide area of the surface. Platinum particles were dispersed on the pore surfaces via organometallic chemical vapor deposition technique using (trimethyl) methylcyclopentadienylplatinum (IV) as a precursor. The chemical composition of the alumina plane surfaces was examined by Auger electron spectroscopy and the adsorption characteristics of the platinum particles were studied by thermal desorption spectroscopy. A variety of industrial catalytic problems are now open for further investigation utilizing the Pt/alumina model catalysts.

• Journal of Welding and Joining
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• 제14권6호
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• pp.93-100
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• 1996

Effect of a flux composition on weld metal toughness in submerged arc welding with 60kgf/$\textrm{mm}^2$ grade C-Mo type wires was investigated and interpreted in terms of weld metal microstructure and hardenability. Flux workability was also studied by characterizing a weld bead profile. Compared to other weld metals, .weld metal used alumina basic flux with nickel showed lowest oxygen content, highest hardenability and the most acicular ferrite. The highest impact toughness of that weld metal, however, was attributed to the tough matrix due to the nickel rather than to the larger amount of acicular ferrite. Manganese silicate flux had better workability than alumina basic flux, showing broader welding conditions resulting in a depth-to-width ratio of 0.5. The composition of oxides in the weld metal was dependent on the flux composition, showing MnO-SiO$_2$-TiO in manganese silicate flux and MnO-SiO$_2$-Al$_2$O$_3$-TiO in alumina basic flux. MnO-SiO$_2$composition in both oxides was similar to a tephroite.