• 마이크로전자및패키징학회지
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• 제6권1호
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• pp.11-21
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• 1999

For microelectronic packaging application, the crystallizable glass powder in CaO-$A1_2O_3-SiO_2-B_2O_3$system was mixed with various amounts of alumina inclusions (\approx 4 $\mu \textrm{m}$), and its sintering behavior, crystallization behavior, and dielectric constant were examined in terms of vol% of alumina and the reaction between the alumina and the glass. Sintering of the CASB glass powder alone at $900^{\circ}C$ resulted in full densification (99.5%). Sintering of alumina-filled composite at $900^{\circ}C$ also resulted in a substantial denslfication higher than 97% of theoretical density, In this case, the maximum volume percent of alumina should be less than 40%. XRD analysis revealed that there was a partial dissolution of alumina into the glass. This alumina dissolution, however, did not show the particle growth and shape accommodation. Therefore, the sintering of both the pure glans and the alumina-filled composite was mainly achieved by the viscous flow and the redistribution of the glass. Alumina dissolution accelerated the crystallization initiation time at $1000^{\circ}C$ and hindered the densification of the glass. Dielectric constants of both the alumina-filled glass and the glass-ceramic composites were increased with increasing alumina content and followed rule of mixture. In case of the glass-ceramic matrix composites showed relatively lower dielectric constant than the glass matrix composite. Furthermore, as alumina content increased, crystallization behavior of the glass was changed due to the reaction between the glass and the alumina. As alumina reacted with the glass matrix, the major crystallized phase was shifted from wollastonite to gehlenite. In this system, alumina dissolution strongly depended on the particle size: When the particle size of alumina was increased to 15 $\mu\textrm{m}$, no sign of dissolution was observed and the major crystallized phase was wollastonite.

• 한국분말재료학회지
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• 제16권6호
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• pp.431-437
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• 2009

Various inorganic fillers improve the thermal conductivity and physical properties of organic products. Alumina has been used a representative filler in the heat radiation sheet for the heat radiation of electric device. The high filling rate of alumina increases the thermal conductivity and properties of products. We successfully developed the spherical alumina by flame fusion process using the oxygen burner with LPG fuel. In the high temperature flame (2500$\sim$3000$^{\circ}C$) of oxygen burner, sprayed powders were melting and then rotated by carrier gas. This surface melting and rotation process made spherical alumina. Especially effects of chemical composition and particle size of stating materials on the melting behavior of starting materials in the flame and spheroidization ratio were investigated. As a result, spheroidization ratio of boehmite and aluminum hydroxide with endothermic reaction of dehydration process was lower than that of the sintered alumina without dehydration reaction.

• 한국세라믹학회지
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• 제39권2호
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• pp.164-170
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• 2002

Acrylate 수계 결합제를 사용한 알루미나 테이프 캐스팅용 슬러리의 완전분산을 위한 최적의 분산제와 분산제량을 결정하기 위해 침강실험, 분말 함유량 실험, 점도 및 zeta 전위 측정을 행하였다. 알루미나 슬러리의 완전분산은 분산제를 polycarboxylic acid로 했을 때 얻어졌으며, 최적의 첨가량은 알루미나 100에 대하여 0.23∼0.24g 이었다. 분말에 대한 분산제량이 증가할수록 분산은 잘 이루어졌으나, 일정량 이상이 첨가되면 분산제가 용매 안에 과잉으로 존재하여 분산을 저해하는 요인으로 작용하였다. 테이프 캐스팅용 슬러리는 100g의 알루미나 분말에 0.2g의 polycarboxylic acid를 첨가하였을 때 분산 및 테이프 특성이 가장 우수하였고, 이 때 혼합한 결합제는 acrylate였고, 가소제는 Benzoflex를 사용하였다. 이 때 슬러리 최적 점도는 약 570 cps였고, 테이프 내 알루미나 량은 57 vol%이었다.

• 한국세라믹학회지
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• 제48권2호
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• pp.168-172
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• 2011

Alumina powder was added in a general porcelain (Backja) with clay, feldspar and quartz contents to promote the mullite ($3Al_2O_3{\cdot}2SiO_2$) generation in the porcelain. Low melting materials ($B_2O_3(450^{\circ}C)$, $MnO_3(940^{\circ}C)$, CuO($1080^{\circ}C$)) were doped at ~3 wt% to modify the sinterability of porcelain with a high alumina contents and promote the mullite generation. Green body was made by slip casting method with blended slurry and then, they were fired at $1280^{\circ}C$ for 1hr by a $2^{\circ}C/min$. Densifications of samples with high alumina contents (20~30 wt%) were impeded. As the doping contents of low melting materilas increased, the sinterability of samples was improved. The shrinkage rate and bulk density of samples were improved by doping with low melting materials. Mullite phase increased with increasing the low melting contents in the phase analyses. This means lots of alumina and quartz were transformed into mullite phase by low melting contents doping. In the results, high bending strength of samples with high alumina contents was accomplished by improving the densification and mullite generation in the porcelain.

• 한국세라믹학회지
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• 제32권2호
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• pp.217-226
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• 1995

Alumina powders were dispersed using crosslinkable organic molecules by electrosteric stabilization and then consolidated by crosslinking of organic molecules. The effect of processing variables such as the physicochemical properties of both solvent media and organic molecules, the proportions of mixed organic media, etc. were studied. FT-IR was used todeduce the mechanism of organic molecules adsorption on the alumina particle surfaces. The adsorption characteristics and the electrokinetic behavior of alumina suspensions were correlated with the stability of particle in alumina suspension using rheological measurements. The green body of alumina consolidated by the chemical crosslinking of the adsorbed organic molecules after the alumina suspension had been stabilized was tough enough for green machining and the sintered alumina fabricated by this proposed process also showed a high bending strength and a homogeneous microstructure.

• 한국세라믹학회지
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• 제33권5호
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• pp.547-555
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• 1996

Porous alumina ceramics were fabricated by pseudo-boehmite phydosol-gel process within/without commercial $\alpha$-alumina particles average 1 and 40 micron respectively. The pore characteristics of fired specimens were studied by the measurement of bulk density total porosity thyermal analysis pore volume pore distribution BET area XRD and SEM. with increasing of firing temperature pore volume and BET surface area were decreased and the average pore size was increased to approximately 146$\AA$ upto 80$0^{\circ}C$ by de-watering of [OH] and formation of $\alpha$-alumina. The fired relative density of the alumina-dispersed specimen with average 1 micron particle was increased with the amounts of dispersed particle by bimodal packing theory which is compared to the ones of specimen including of average 40 micron particle. It was confirmed that the percola-tion threshold in porous ceramics with coarser particle (40 micron) has formed between the transformed-alumina from hydrogel and dispersed-alumina of above 50 vol% particle and the total porosity was increased at the threshold point above.

• 한국세라믹학회지
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• 제40권7호
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• pp.632-636
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• 2003

To prepare the alumina cement free vibrated alumina castable, $\rho$-alumina is employed as a binder material, and nano-sized clay is added to enhance the curing strength and give thixotropic behavior. The rheological behavior of matrix of castable is controlled by investigating the influences of ultrafines, $\rho$-alumina, and nano-sized clay on the viscosity of matrix. The microsilica and ultrafine alumina were added 3 wt% and 4 wt%, respectively to the matrix, which showed that the viscosities tends to be lowest values. The rheological property of the matrix is well established by adding $\rho$-alumina as 8 wt% and clay as 4 wt%. The thixotropic behavior of the $\rho$-alumina bonded castable was appeared by introducing nano-sized clay into the matrix and adjusting the pH near to the PZC of the clay suspension.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 일렉트렛트 및 응용기술
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• pp.103-107
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• 2002

Ethyl silicate was used as organic binder for alumina refractories. In the present work only 15% of the water required for complete hydrolysis of ethyl silicate was initially added. The balance was provided from the atmosphere under controlled conditions of temperature and rh. The purpose of detailing the possible binder problem areas is more to indicate that the binder can have an effect on ceramic operations.

• 한국세라믹학회지
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• 제45권7호
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• pp.405-410
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• 2008

Ceramics are widely used as plasma resistant materials in semiconductor industries. However, the plasma erosion resistance has not been properly evaluated in terms of microstructural changes during the exposure to plasma. In this study, microstructure developments of $Al_2O_3$ were investigated under the fluorine plasma conditions. In polycrystalline alumina, uniform erosion throughout the specimen as well as spatially distributed local erosion were observed. Local erosion was much more severe in lower purity alumina. In contrast to the polycrystalline alumina, only uniform erosion was observed in single crystalline sapphire. These specimens, however, had practically the same erosion depth, which results in the incorrectly similar plasma resistance. This implies that the plasma erosion resistance of ceramics should be evaluated in terms of the microstructural changes, as well as the conventionally accepted erosion depth.

• 한국세라믹학회지
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• 제43권12호
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• pp.859-864
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• 2006

For the pressure compaction process of the ceramic powder, the green density is very different with both the ceramic body shape and the processing conditions. The density difference cause non-uniform shrinkages and deformations, and make cracks in the sintered ceramics. In this paper, Material properties of the alumina powder mixed with binder and the friction coefficient between the powder and the tool set were determined through the simple compaction experiments: Also the powder flow characteristics were simulated and the green density was analyzed during the powder compaction process with Finite Element Method (FEM). The results show that the density distributions of the green body were improved at the optimized processing condition and both the possibility of the farming crack generation and rho deformation of the sintered Alumina body were reduced.