• 한국세라믹학회지
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• 제16권1호
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• pp.13-20
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• 1979

High purity alumina has been extracted form low grade Korean alunite. Alunite ore was treated by 15% $NH_4OH$ solution, followed by 10% $H_2SO_4$ leaching and metallic impurities such as Fe and Ti were removed by solvent extraction method. Alumina prepared by the extraction process was 99.9% in purity. Hot Petroleum Drying Method has been employed for the preparation of uniformly fine alumina powder, using chemical reagent aluminum sulfate and ammonium aluminum sulfate extrated from Korea alunite. The sinterability of alumina powder prepared by Hot Petroleum Drying Method was shown to be improved in comparison with the one treated by other methods such as ball milling method, but dry pressing was difficult due to the agglomeration of calcined powder. The best slip of alumina powder prepared by Hot Petroleum Drying Method contained a lower soild content than the one treated by other methods. The alumina body formed by soild and drain casting with the former alumina powder showed a higher sintered density.

• 대한기계학회논문집
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• 제18권12호
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• pp.3404-3412
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• 1994

The present study was undertaken to investigate the dry wear process and wear mechanism of the alumina ceramics in the purity variation which are used for the mechanical seal, roll, liner and dies. The wear test was carried out under different experimental condition using the wear testing device and in which the annular surface rubbed on dry sliding condition various sliding speed, contact pressure and sliding distance. In case of alumina purity 95%, there was speed range which wear loss increased rapidly owing to enlargement of heat impact force and temperature rise of wear surface. According as the alumina purity increased, wear loss decreased but alumina purity 85% with much void and defect had the most wear loss than any other alumina purity. The friction coefficient of sliding initial stage of wear curves has a large value but according to increase of sliding distance, it decreased owing to drop of the shear strength of wear surfaces.

• 한국세라믹학회지
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• 제31권6호
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• pp.678-684
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• 1994

The surface of alumina is capable of acquiring a change when it is in an aqueous solution. This surface change will have a strong influence on the surrounding ions, particularly those of opposite change known as the counter ions. A site-binding model of the {{{{ gamma }}-alumina/KCl(aq) interface was used to calculated theoretical surface ionization constants and P.Z.C.(Point of zero change) of {{{{ gamma }}-alumina. This paper was carried out to investigate the effect of calcination temperature on the acidic and electrical properties of pure {{{{ gamma }}-alumina prepared by the precipitation method from the Al(NO3)3.9H2O and NH4OH. From the experimental data it was shown that {{{{ gamma }}-alumina have a mainly Br nsted acid site. However, the acidity of {{{{ gamma }}-alumina decreased with increasing calcination temperature at strength Ho +9.3. The surface charge density of {{{{ gamma }}-alumina was increased with electrolyte ionic strength and calcination temperature.

• 한국전기전자재료학회논문지
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• 제29권10호
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• pp.613-619
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• 2016

The aim of this study is to improve of dielectric properties using epoxy/nano alumina composites with adding glycerol diglycidyl ether (GDE:1,2 g). This paper deals with the effects of dielectric properties(${\epsilon}^{\prime}_r$ and $tan{\delta}$) for epoxy/nano alumina contents (1,3 phr) and GDE addition (1,2 g)composites. 5 kinds specimen were prepared with containing epoxy resins, epoxy nano alumina composites. Average particle size of nano used were 30 nm. The nano alumina used were gamma phase particles of spherical shape. The suppression of epoxy chain motion by addition of nano alumina+GDE decreased dielectric loss and relative permittivity magnitude.

• The Korean Journal of Ceramics
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• 제4권4호
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• pp.292-296
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• 1998

In wet powder processing of alumina, a number of organic molecules such as dispersant and binder are used to produce the flow behavior and properties requisite for shape forming. In this study, interparticle forces of alumina particles suspended in aqueous media were controlled by suspension pH, poly (methacrylic acid) (PMAA, used as dispersant) and poly (vinyl alcohol) (PVA, used as binder). The combined adsorption isotherms of the dispersant and binder additives on alumina were determined by total organic carbon analyzer, while the adsorption of dispersant was differentiated from binder in the mixed additive system by ultraviolet spectroscopy. The electrokinetic behavior of alumina suspensions were then correlated with the adsorption characteristics of dispersant and binder onto alumina particles. It was found that the isoelectric ($pH_{iep}$) of alumina shifted from pH 8.9${\pm}$0.1 to acidic pH as PMAA concentration increased, while PVA adsorption did not affect the $pH_{iep}$ but caused a decrease in the near surface potential.

• 한국세라믹학회지
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• 제36권7호
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• pp.718-724
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• 1999

Densification and grain growth behavior of bimodal size distributed alumina powder mixtures were investigated as a function of amount of coarse alumina powder. The specimens which contained coarse alumina powder for 60to 80wt% showed the highest green density. The amount of shrinkage of sintered specimen lineraly decreased with the increase of coarse alumina powder up to the content that showed the highest green density and then further addition of coarse alumina powder led to drastic decrease of shrinkage of specimen. Especially crack-like void were concurrently revealed in the sintered body with addition of coarse alumina powder above 60wt% When the sintering temperature increased up to 1650$^{\circ}C$ the amount of shrinkage of specimen linearly decreased and the grain growth were also retarded with increase of coarse lauminia powder.

• 한국세라믹학회지
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• 제35권12호
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• pp.1308-1315
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• 1998

Effects of particle size of alumina on densification behavior during liquid-phase sintering of alumina-talc system were investigated with emphasis on particle rearrangement process. In the case of using coarse alu-mina powder densiication of specimens was rapidly accelerated after formation of liquid phase due to easy particle rearrangement process with addition of talc and increase of sintering temperature. On the contrary when fine alumina powder was used premature densification of alumina matrix region formed before for-mation of liquid phase rigid skeleton structure and then it seemed to inhibit rearrangement process during crease of sintering temperature. As results the densification of specimens using coarse alumina powder was higher than that of the case of using fine one.

• 대한기계학회논문집
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• 제14권3호
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• pp.547-553
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• 1990

본 연구에서는 알루미나 세라믹(Al$_{2}$O$_{3}$)재료와 순수구리를 티타늄 용자재로써 접합한 브레이징 접합물내의 냉각후 잔류응력을 유한요소법으로 사용하여 해석하였다.

• 한국세라믹학회지
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• 제35권6호
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• pp.610-618
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• 1998

Alumina were added to ceria based ceramic powders upto 9.7 vol% and composite powders were sprayed by plasma spraying process in order to improve the mechanical properties such as hardness fracture tough-ness and thermal shock resistance. The ceria based coating sprayed without alumina has the typical colum-nar and lamellar structure. Alumina addition has lowered the amount of columnar and lamellar sturcture Added alumina was segreagated in the grain boundary and grain of ceria based crystal accompanied with pore. The maximum value of density and the minimum value of porosity were observed at the sprayed coating with 4.8 vol% alumina. The hardness fracture toughness and thermal shock resistance were increased with alumina addition. The improvement of mechanical properties of plasma sparyed ceria based coatings result-ed from the disapperance of the columnar and lamellar sturcture by addition of alumina.

• 한국세라믹학회지
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• 제31권1호
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• pp.1-10
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• 1994

Monodispersed alumina and Mg-doped alumina fine particles were prepared by controlled hydrolysis of alkoxides. Aluminium alkoxide and magnesium alkoxide were dissolved into complex solvent which was composed of hydrophobic n-octanol and hydrophilic acetonitrile. Hydroxypropyl cellulose(HPC) was used as a dispersant for the alumina particles. The size of these prepared powders was approximately 0.3 ${\mu}{\textrm}{m}$. In the case of sintering above 100$0^{\circ}C$, most of these prepared powders were transformed to $\alpha$-alumina. The relative density of the sintered body of these prepared powders at 1$600^{\circ}C$ was 98%. The sintered body of the Mg-doped alumina powder had more uniform grain size than that of the undoped alumina podwer.