• Korean Chemical Engineering Research
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• v.56 no.5
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• pp.655-662
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• 2018

To respond effectively to climate change following the launch of the new climate system, the government is seeking to expand the use of distributed power resources. Among them, the district heating system centered on Combined Heat and Power (CHP) is accepted as the most realistic alternative. On the other hand, the government recently announced the change of energy paradigm focusing on eco-friendly power generation from the base power generation through $8^{th}$ Basic Plan for Long-term Electricity Supply and Demand(BPE). In this study, we analyzed the quantitative effects of profit and loss on the CHP operating business by changing patterns of the heat production, caused by the change of energy paradigm. To do this, the power market long-term simulation was carried out according to the $7^{th}$ and $8^{th}$ BPE respectively, using the commercialized power market integrated analysis program. In addition, the CHP operating model is organized to calculate the power and heat production level for each CHP operation mode by utilizing the operating performance of 830MW class CHP in Seoul metropolitan area. Based on this, the operation optimization is performed for realizing the maximum operating profit and loss during the life-cycle of CHP through the commercialized integrated energy optimization program. As a result, it can be seen that the change of the energy paradigm of the government increased the level of the ordered power supply by Korean Power Exchange(KPX), decreased the cost of the heat production, and increased the operating contribution margin by 90.9 billion won for the 30 years.

• YAKHAK HOEJI
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• v.52 no.6
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• pp.419-425
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• 2008

A qualitative and quantitative analytical method was developed for detection of methamphetamine (MA) and its main metabolite amphetamine (AM) in oral fluid. Oral fluids of eleven drug abusers were provided by Police, specimens were collected by stimulation with a cotton swab treated with 20 mg of citric acid ($Salivette^{(R)}$; Sarstedt, USA). As the preliminary test, oral fluid samples were screened for amphetamines by Fluorescence Polarization Immunoassay (TDxFLx, Abbott Co.). Extraction for MA was performed using solid-phase extraction (SPE) by $RapidTrace^{TM}$ (Zymark, USA) with mixed mode cation exchange cartridge, CLEAN $SCREEN^{(R)}$ (130 mg/3 ml, UCT) after dilution with phosphate buffer. Samples were evaporated and derivatized by pentafluoropropionic acid anhydride (PFPA). Quantitation of MA and AM was performed by gas chromatography-mass spectrometry (GC-MS) using selective ion monitoring (SIM), the quantitation ions were m/z 204 (MA), 208 (MA-$D_5$), 190 (AM) and 194 (AM-$D_5$). The selectivity, linearity of calibration, limit of detection (LOD) and quantification (LOQ) within- and between day precision, accuracy and recoveries were examined as parts of the method validation. All oral fluid samples gave positive results to immunoassay for MA (cut-off level, 50 ng/ml as d-amphetamine). Concentrations of MA and AM by GC-MS in eleven samples were ranged 104.2${\sim}$4603.3 ng/ml and 32.4${\sim}$268.6 ng/ml, respectively. Extracted calibration curves of MA and AM were linear over the two concentration range of 1${\sim}$100 and 50${\sim}$1000 ng/ml with correlation coefficient of above 0.999. LOQ of MA and AM was 1 and 3 ng/ml, respectively. The intraand inter-day run precisions (CV) for MA and AM were less than 10%, and the accuracies (bias) for MA and AM were also less than 10% at the two different concentrations 5 and 100 ng/ml at low calibration range, 50 and 1000 ng/ml at high calibration range. The absolute recoveries of MA and AM at low and high calibration ranges were more than 82% and 75%, respectively. In this study the qualitative and quantitative analytical method of MA in oral fluid was established. Oral fluid testing may detect drug use in past hours because of its shorter detection window than urine, and be useful in post-accident situations. So oral fluids will be most useful for testing drug abuse in the driving under the influence of drug (DUID) as the alternative specimens of urine.

• Plant Journal
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• v.10 no.2
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• pp.38-47
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• 2014

Renewable Portfolio Standards was introduced into the system in Korea in 2012. Interest in the unutilized and renewable energy sources is increasing. and these being actively investigated. An organic rankine cycle has emerged as an alternative in order to take advantage of bio-gas engine heat of sewage treatment plants whose capacity is 1500 kW. The organic rankine cycle power system was simulated by a simulator which is a commercial program of power plant design and performance analysis. The biogas engine is operated by $460^{\circ}C$ and 2.7 kg/s flow rate in the sewage treatment plant. Working fluids(R-601a, R-123, R-245fa) are selected to use in ORC power system in this temperature range. It was the isopentane that is the best performance among three working fluids. It could be obtained net power of 163.1 kW and efficiency of 13.66% from isopentane in the simulation.

• Journal of Energy Engineering
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• v.25 no.2
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• pp.94-100
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• 2016

ESS(Energy Storage System) is an important source that keeps power supply stable and utilizes electricity efficiently. For example, ESS contributes to resolve power supply imbalance, stabilize new renewable energy output and regulate frequency. ESS is predicted to be expanded to 55.9GWh of installed capacity by 2023, which is 30 times more than that of 2014. To raise competitiveness of domestic ESS industry in this increasing world market, we have disseminated load-shift ESS for continuous power supply imbalance with FR ESS, and also necessity to secure domestic track record is required. However in case of FR ESS, utility of installing thermal power plant is generally generated within 5% range of rated capacity, so that scalability of domestic market is low without dramatic increase of thermal power plant. Necessity of load-shift ESS dissemination is also decreasing effected by surplus backup power securement policy, raising demand for new dissemination model. New dissemination model is promising for $CO_2$ reduction effect in spite of intermittent output. By stabilizing new renewable energy output in connection with new renewable energy, and regulating system input timing of new renewable energy generation rate, it is prospected model for 'post-2020' regime and energy industry. This research presents a policy alternatives of REC multiplier calculation method to induce investment after outlining PV-connected ESS charge/discharge mode to reduce GHG emission, This alternative is projected to utilize GHG emission reduction methodology for 'Post-2020' regime, big issue of new energy policy.

• Economic and Environmental Geology
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• v.47 no.6
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• pp.673-681
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• 2014

Recently, many countries in the world try to develop alternative energy sources, however, traditional hydrocarbon resources are still occupying most of the energy resources. Exploration demands for high technologies are increasing in the development of limited oil & gas resources field owing to the exhaustion of hydrocarbon resources for access area. Therefore, an effort for the development and the application of new technologies such as azimuth seismic survey, ocean-bottom seismic survey and marine controlled-source electromagnetic survey is necessary as well as an understanding of the existing technologies such as 2D/3D seismic survey. This dissertation is designed with the purpose of introducing marine hydrocarbon exploration technologies and analyzing their internalexternal researches, development and science information. In this study, we analised total 616 dissertations for the marine petroleum exploration released in the Sci-expanded DB of 'web of science' during the 2001~2014 periods.

• Korean Journal of Remote Sensing
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• v.31 no.6
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• pp.523-530
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• 2015

A Multiple Regression Method (MRM) is used for the first time with Ozone Monitoring Instrument (OMI) and Moderate Resolution Imaging Spectroradiometer (MODIS) data to estimate formaldehyde (HCHO) Vertical Column Density (VCD). For a 3.5-year period from January 2005 through July 2008, HCHO VCD estimation is investigated in cities over Asia in two categorized areas: (1) Major cities in Northeast Asia (Beijing, Seoul, and Tokyo), (2) Major cities in Southeast Asia (New Delhi, Dhaka, and Bangkok). In the Major cities in Northeast Asia, there are good agreements between HCHO estimated by the multiple linear regression method ($HCHO_{MRM}$) and HCHO measured by OMI ($HCHO_{OMI}$) (0.78 < $R^2$ < 0.82). However, in Major cities in Southeast Asia, there were poor agreements between $HCHO_{OMI}$ and $HCHO_{MRM}$ (0.24 < $R^2$ < 0.39). In addition, an unbiased assessment of the MRM performance using modeling and validation groups shows that the performance of the MRM based on separate modeling and validation groups is comparable to that using all the data for deriving Multiple Regression Equations (MREs). This study demonstrates that MRM can be an alternative tool for HCHO estimation in certain areas over Asia.

• Membrane Journal
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• v.25 no.6
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• pp.496-502
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• 2015

Facilitated transport is one of the possible solutions to simultaneously improve permeability and selectivity, which is challenging in conventional polymer-based membranes. Olefin/paraffin separation using facilitated transport membrane has received much attention as an alternative solution to the conventional distillation process. Herein, we report olefin separation composite membranes based on the polymer blends containing $AgBF_4/Al(NO_3)_3$ mixed salts. Free radical polymerization process was used to synthesize an amphiphilic graft copolymer of poly(dimethyl siloxane)-graft- poly(ethylene glycol) methyl ether methacrylate (PDMS-g-POEM). In addition, poly(ethylene oxide) (PEO) was introduced to the PDMS-g-POEM graft copolymer to form polymer blends with various ratios. The propylene/propane mixed-gas selectivity and permeance reached up to 5.6 and 10.05 GPU, respectively, when the PEO loading was 70 wt% in polymer blend. The improvement of olefin separation performance was attributed to the olefin facilitating silver ions as well as the highly permeable blend matrix. The stabilization of silver ions in the composite membrane was achieved through the introduction of $Al(NO_3)_3$ which suppressed the reduction of silver ions to silver particles.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.22 no.3
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• pp.200-208
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• 2012

Objectives: This study investigated the performance of three separate units of a portable photoionization detector (PID, ppb-RAE 3000) for measuring volatile organic compounds (VOCs) in a laboratory. Methods: A laboratory evaluation of the accuracy, precision, and inter-instrumental variance of three separate units of a portable PID (ppb-RAE 3000) was performed. The evaluation was based on the preparation of a test air sample of known toluene or ethylacetate concentration in a Tedlar$^{(R)}$ bag. The test air sample was monitored and data were logged consecutively by the three PIDs. A certified gas of 50 ppm toluene was also monitored during the test to ensure the reliability of the generated test air sample. Four different concentrations ranging from 0.1 to 2 TLV were used and a series of five measurements for each concentration level was performed. The accuracy was evaluated using National Institute for Occupational Safety and Health (NIOSH) criteria. Results: The results from the oldest ppb-RAE3000 unit among the three test units generally fell outside the NIOSH recommended accuracy criteria of ${\pm}25%$, whereas the other two units produced results which were acceptable at, or greater than, 25 ppm of toluene, or 0.5 TLV. These units also met the NIOSH criteria for some ethylacetate measurements but the results were not consistent. Conclusions: Considering the inconsistent performance of these ppb-RAE 3000 units, this device may not be appropriate for use as an alternative to the standard measurement methods. However, it can serve good survey instruments to identify exposure sources or concentration profiles. For all applications, the ppb-RAE 3000 should be used with frequent calibration checks, additional validation using a reference material, and careful maintenance.

• Economic and Environmental Geology
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• v.38 no.1
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• pp.1-22
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• 2005

Carbon dioxide ($CO_2$) is the greatest contributor among the major greenhouse gases covered by the Kyoto Protocol. Therefore, substantial efforts for the control and reduction of $CO_2$ emissions, including increased efficiency of fossil fuel energy usage, development of energy sources with lower carbon content, and increased reliability on alternative energy sources, are being performed worldwide. However, development and industrial application of $CO_2$ sequestration techniques are needed to meet the requirements of the Kyoto Protocol. Among the $CO_2$ sequestration methods developed, geological sequestration methods such as the storage in deep aquifers, deep coal seams and oil and gas reservoirs and the mineral carbonation is considered most favorable because of its stability and environmental effectiveness. In this review, geochemical concepts and technologic development of geologic sequestration technology, especially the storage in deep aquifers and the mineral carbonation, are discussed. The weakness and strengths for each of geologic sequestration methods, are also reviewed.

• Land and Housing Review
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• v.12 no.3
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• pp.109-119
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• 2021

Global warming caused by greenhouse gas emissions has rapidly increased abnormal climate events and geotechnical engineering hazards in terms of their size and frequency accordingly. Biopolymer-based soil treatment (BPST) in geotechnical engineering has been implemented in recent years as an alternative to reducing carbon footprint. Furthermore, thermo-gelating biopolymers, including agar gum, gellan gum, and xanthan gum, are known to strengthen soils noticeably. However, an explicitly detailed evaluation of the correlation between the factors, that have a significant influence on the strengthening behavior of BPST, has not been explored yet. In this study, machine learning regression analysis was performed using the UCS (unconfined compressive strength) data for BPST tested in the laboratory to evaluate the factors influencing the strengthening behavior of gellan gum-treated soil mixtures. General linear regression, Ridge, and Lasso were used as linear regression methods; the key factors influencing the behavior of BPST were determined by RMSE (root mean squared error) and regression coefficient values. The results of the analysis showed that the concentration of biopolymer and the content of clay have the most significant influence on the strength of BPST.