• Korean Journal of Materials Research
• /
• v.12 no.7
• /
• pp.550-554
• /
• 2002

The effect of Mn on cavitation erosion resistance and the sliding wear resistance of Fe-base hardfacing NewAlloy was investigated. Mn is known to decrease stacking fault energy and enhance the formation of $\varepsilon$-martensite. Cavitation erosion resistance for 50 hours and sliding wear resistance for 100 cycles were evaluated by weight loss. Fe-base hardfacing NewAlloy showed more excellent cavitation erosion resistance than Mn-added NewAlloys. $\Upsilon-\alpha$' phase transformation that can enhance erosion resistance by matrix hardening occurred in every specimens. But, only in Mn free Fe-base hardfacing NewAlloy, the hardened matrix could repress the propagation of cracks that was initialed at the matrix-carbides interfaces more effectively than Mn-added NewAlloy The Mn free Fe-base hardfacing NewAlloy showed better sliding wear resistance than Mn-added alloys. Mn-addition up to 5wt.% couldn't increase the sliding wear and cavitation erosion resistance of Fe-base hardfacing alloy because it didn't make $\Upsilon\to\varepsilon$ martensite phase transformation. Therefore, it is considered that the cavitation erosion and the sliding wear resistance can be improved due to $\Upsilon\to\varepsilon$ martensite phase transformation when Mn is added more than 5wt.% in Fe-base hardfacing alloys.

• Korean Journal of Materials Research
• /
• v.22 no.10
• /
• pp.499-503
• /
• 2012

The present study is intended to comparatively investigate the changes in microstructure and tensile properties at room and elevated temperatures in commercial AM50(Mg-5%Al-0.3%Mn) and 0.3 wt%CaO added ECO-AM50 alloys produced by permanent mould casting. The typical microstructure of AM50 alloy was distinctively characterized using two intermetallic compounds, ${\beta}(Mg_{17}Al_{12})$ and $Al_8Mn_5$, along with ${\alpha}$-(Mg) matrix in an as-cast state. The addition of a small amount of CaO played a role in reducing dendrite cell size and quantity of the ${\beta}$ phase in the AM50 alloy. It is interesting to note that the added CaO introduced a small amount of $Al_2Ca$ adjacent to the ${\beta}$ compounds, and that inhomogeneous enrichment of elemental Ca was observed within the ${\beta}$ phase. The ECO-AM50 alloy showed higher hardness and better YS and UTS at room temperature than did the AM50 alloy, which characteristics can be mainly ascribed to the finer-grained microstructure that originated from the CaO addition. At $175^{\circ}C$, higher levels of YS and UTS and higher elongation were obtained for the ECO-AM50 alloy, demonstrating that even 0.3 wt%CaO addition can be beneficial in promoting the heat resistance of the AM50 alloy. The combinational contributions of enhanced thermal stability of the Ca-containing ${\beta}$ phase and the introduction of a stable $Al_2Ca$ phase with high melting point are thought to be responsible for the improvement of the high temperature tensile properties in the ECO-AM50 alloy.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.23 no.3
• /
• pp.44-50
• /
• 2019

HNIW is a high energy material and has four crystalline phases, it is known that the thermal properties of the material depend on the crystal phase. In this sturdy, the viscosity, mechanical and burning properties of a solid propellant with nitrate ester polyester(NEPE) system with respect to the crystal phases of HNIW. According to the crystal phase of HNIW, the mechanical properties of the cured propellant did not change considerably, however differences were observed in the burning properties. Considering both a high density and stable burning properties, the optimum crystal phase of HNIW can be identified as the main factor influencing to the NEPE system propellant.

• Korean Journal of Metals and Materials
• /
• v.49 no.2
• /
• pp.93-103
• /
• 2011

Precipitation behavior of high-nitrogen duplex Fe-24Cr-7Mn-4Ni-4Mo-0.43N stainless steel aged at $850^{\circ}C$ was investigated using scanning transmission electron microscopy. Based on the analyses of selected area diffraction patterns, four kinds of precipitates (intermetallic sigma (${\sigma}$) and chi (${\chi}$), $Cr_2N$ and secondary austenite) were identified. At the ferrite/austenite phase boundary, the ${\sigma}$ phase and secondary austenite were formed via ${\alpha}{\rightarrow}{\gamma}+{\sigma}$ eutectoid reaction. The precipitation of $Cr_2N$ occurred at the austenite grain boundary as well as the interior of the ferrite. The intermetallic ${\chi}$ phase also formed within the ferrite and showed a cube-cube orientation relationship with the ferrite. Further aging produced a lamellar structure composed of $Cr_2N$ and austenite along the ferrite/austenite boundary and enhanced the precipitation of the ${\chi}$ phase. The crystallographic features of the precipitates were also examined in terms of the orientation relationship with the austenite or ferrite matrix.

• Transactions on Electrical and Electronic Materials
• /
• v.15 no.5
• /
• pp.284-289
• /
• 2014

The effects of additives (Nb, Bi and Cr) on the microstructure, varistor properties, and aging behavior of V/Mn/Co/ La/Dy co-doped zinc oxide ceramics were systematically investigated. An analysis of the microstructure showed that all of the ceramics that were modified with various additives were composed of zinc oxide grain as the main phase, and secondary phases such as $Zn_3(VO_4)_2$, $ZnV_2O_4$, and $DyVO_4$. The $Bi_2O_3$-modified samples exhibited the lowest density, the $Nb_2O_5$-modified sample exhibited the largest average grain size, and the $Cr_2O_3$-modified samples exhibited the highest breakdown field. All additives improved the non-ohmic coefficient (${\alpha}$) by either a small or a large margin, and in particular an $Nb_2O_5$ additive noticeably increased the non-ohmic coefficient to be as large as 36. The $Bi_2O_3$-modified samples exhibited the highest stability with variation rates for the breakdown field and for the non-ohmic coefficient (${\alpha}$) of -1.2% and -26.3%, respectively, after application of a DC accelerated aging stress of 0.85 EB/$85^{\circ}C$/24 h.

• Proceedings of the KIEE Conference
• /
• 1995.07c
• /
• pp.1190-1192
• /
• 1995

Poly(vinylidene fluoride)(PVDF) is one of the most studied polymers in the latest date. The interest in PVDF lies in its remarkable piezoelectric and pyroelectric properties. Also, PVDF has at least four known crystalline structures(; they are referred to as the ${\alpha},\;{\beta},\;{\gamma}\;and\;{\alpha}_p$ phase or forms II, I, III and $IV_p$). In this study, the manufactured PVDF thin film through vapor deposition method had form II(; the glass at $70^{\circ}C$). This thin film was investigated by x-ray diffraction(XRD), Fourier Transform Infrared(FT-IR) spectroscopy and Differential Thermal Analysis(DTA). XRD and FT-IR indicate crystallization forms from the glass at $70^{\circ}C$ into form II.

• Korean Journal of Optics and Photonics
• /
• v.11 no.6
• /
• pp.385-389
• /
• 2000

A phase-retardation function which was derived from Wigner distribution function (WDF) is used to increase a focal depth of a radially symmetric optical system. The WDF for one-dimensional signal is represented as a two-dimensional function of phasespace ($\chi,\zeta$), and a normalized irradiance is described as a form of the Strehl ratio (SR). The increase in the focal depth is accomplished by delivering a shearing tilt a that represents a characteristic of free space propagation with simple manipulation in the WDF space. In this paper we propose a method for evaluating the focal depth quantitatively by representing the phaseretardation function in terms of the focal depth term. In order to verify the validity of the proposed method, we compared the numerically analyzed result with that of J. Sochki's study. study.

• Preventive Nutrition and Food Science
• /
• v.14 no.4
• /
• pp.354-357
• /
• 2009

Three compounds, vanillic acid, p-hydroxylcinnamic acid, p-hydroxybenzaldehyde have been isolated from the ethylacetate extract of Sparganium stoloniferum Buch.-Ham roots using silica gel open column chromatography, preparative thin-layer chromatography (pTLC) and reverse phase high performance liquid chromatography. The structures of the compounds were established on the basis of IR, extensive 1D NMR, and MS analyses. The ethylacetate (EtOAc) extract, vanillic acid, and p-hydroxybenzaldehyde showed $\alpha$-glucosidase inhibition activity of 72.71%, 20.13%, and 30.42%, at the concentration of 10 ${\mu}g/mL$, respectively. The EtOAc extract exhibited strong antioxidant activity with an $IC_50$ value of 24.37 ${\mu}g/mL$ against DPPH radical scavenging activity, the vanillic acid, p-hydroxylcinnamic acid, and p-hydroxybenzaldehyde with an $IC_50$ value of 2.10 ${\mu}M$, 1.59 ${\mu}M$, and 2.72 ${\mu}M$ against DPPH, respectively.

• Natural Product Sciences
• /
• v.24 no.3
• /
• pp.213-218
• /
• 2018

Chemical investigation of the plant Tristemma hirtum P. Beauv (Melastomataceae) resulted to the isolation of a new flavonol glycoside named quercetin-7-O-${\alpha}$-D-arabinofuranoside (1), together with nine known compounds including 3'-hexadecanoyl-2'-(9aZ)-tetradecanoyl-glycerol 1'-O-[${\beta}$-D-galactopyranosyl-(1'' ${\rightarrow}$ 6'')-${\alpha}$-D-galactopyranoside] (2), arjunolic acid (3), ${\beta}$-sitosterol-3-O-${\beta}$-D-glucopyranoside (4), terminolic acid (5), quercetin (6), asiatic acid (7), maslinic acid (8), $1{\beta}$-O-galloylpedunculagin (9) and 6-hydroxyapigenin 7-O-${\beta}$-D-glucopyranoside (10) from the methanol extract using normal and reversed phase column chromatography. The structures of these compounds were determined by comprehensive interpretation of their spectral data mainly including 1D- 2D-NMR ($^1H-^1H$ COSY, HSQC, and HMBC) spectroscopic and ESI-TOF-MS mass spectrometric analysis.

• Journal of the Korean Society for Heat Treatment
• /
• v.12 no.1
• /
• pp.1-8
• /
• 1999

This study has investigated the effect of aging treatment on the microstructure and mechanical properties of Mg-6Al-xZn(x = 1.5, 2.5) alloys fabricated by the squeeze casting process. The microstructures of as-squeeze cast were composed of pro-eutectic ${\alpha}$, super saturated ${\alpha}$ and ${\beta}(Mg_{17}Al_{12})$ compound. Aged at both $200^{\circ}C$ and $240^{\circ}C$, Mg-6Al-xZn alloys showed the peak hardness due to the formation of ${\beta}(Mg_{17}Al_{12})$ precipitates. The discontinuous precipitates of the lamella type are predominant at $200^{\circ}C$ aging treatment, while the finely dispersed continuous precipitates were dominant at $240^{\circ}C$ aging treatment. Mg-6Al-xZn alloys fabricated by the squeeze casting process had the better combination of tensile strength and elongation compared to the conventionally cast alloys. As zinc contents increased, the tensile strength was increased by the solid solution strengthening effect of zinc.