• Title/Summary/Keyword: Alpha phase

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Li+ Extraction Reactions with Ion-exchange type Lithium Manganese Oxide and Their Electronic Structures (이온교환형 리튬망간산화물의 리튬이온 용출특성 및 전자상태)

  • Kim, Yang-Soo;Chung, Kang-Sup;Lee, Jae-Chun
    • Korean Journal of Materials Research
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    • v.12 no.11
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    • pp.860-864
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    • 2002
  • $Li^{+}$ extraction reactions with ion-exchange type lithium manganese oxide in an aqueous phase were examined using chemical and x-ray diffraction (XRD) analysis. In the process of extraction reaction, the lithium manganese oxide showed a topotactic extraction of $Li^{+ }$ in the aqueous phase mainly through an ion-exchange mechanism, and the $Li^{+}$ extracted samples indicated a high selectivity and a large capacity for $Li^{+}$ . The electronic structures and chemical bonding properties were also studied using a discrete variational (DV)-X$\alpha$ molecular orbital method with cluster model of (Li$Mn_{12}$ $O_{40}$ )$^{27-}$ for tetrahedral sites and ($Li_{7}$ Mn $O_{38}$ )$^{3}$ for octahedral site in $Li_{1.33}$ $Mn_{1.67}$ / $O_{4}$ respectively. Li in the manganese oxides is highly ionized in both sites, but the net charge of Li was greater for tetrahedral sites than octahedral. These calculations suggest that the tetrahedral sites have higher $Li^{+}$ $H^{+}$ exchangeability than the octahedral sites, and are preferable for the selective adsorption for L $i^{+}$ ions.s.

A preparation of hexacelsian powder by solution-polymerization route and its phase transformation behavior (Solution- polymerization 방법에 의한 hexacelsian 분말의 합성 및 상전이 공정에 의한 celsian 소결체의 제조)

  • Sang-Jin Lee;Young-Soo Yoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.428-436
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    • 1997
  • Hexacelsian ($BaO{\cdot}Al_2O_3{\cdot}2SiO_2$) powder was prepared by a solution-polymerization route employing PVA solution as a polymeric carrier. A fine amorphous-type hexacelsian powder with an average particle size of 0.8 $\mu \textrm{m}$ and a BET specific surface area of $63 \textrm{m}^2$/g was made by a ball-milling the powder precursor for 12 h after calcination at $800^{\circ}C$ for :1 h. A densified hexacelsian was obtained through sintering at $1550^{\circ}C$ for 2 h under an air atmosphere. The $\alpha\longleftrightarrow\beta$ and $\beta\longleftrightarrow\gamma$ displacive phase transformation in polycrystalline hexacelsia,n was examined by using dilatometry and differential scanning calorimtry. The reconstructive transformation between hexacelsian and celsian was obtained by annealing at $1600^{\circ}C$ for 72h. Volume contraction of 5.6% was accompanied by the reconstructive transformation.

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Transfer of Orally Administered Terpenes in Goat Milk and Cheese

  • Poulopoulou, I.;Zoidis, E.;Massouras, T.;Hadjigeorgiou, Ioannis
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.10
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    • pp.1411-1418
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    • 2012
  • The objective of the present study was to investigate the relationships between terpenes… intake and their presence in animal tissues (blood and milk) as well as in the final product (cheese). Eight dairy goats were divided in two balanced groups, representing control (C) and treatment (T) group. In T group oral administration of a mixture of terpenes (${\alpha}$-pinene, limonene and ${\beta}$-caryophyllene) was applied over a period of 18 d. Cheese was produced, from C and T groups separately, on three time points, twice during the period of terpenes… oral administration and once after the end of experiment. Terpenes were identified in blood by extraction using petroleum ether and in milk and cheese by the use of solid phase micro-extraction (SPME) method, followed by GC-MS analysis. Chemical properties of the milk and the produced cheeses were analyzed and found not differing between the two groups. Limonene and ${\alpha}$-pinene were found in all blood and milk samples of the T group after a lag-phase of 3 d, while ${\beta}$-caryophyllene was determined only in few milk samples. Moreover, none of the terpenes were traced in blood and milk of C animals. In cheese, terpenes' concentrations presented a more complicated pattern implying that terpenes may not be reliable feed tracers. We concluded that monoterpenes can be regarded as potential feed tracers for authentification of goat milk, but further research is required on factors affecting their transfer.

Spatio-Spectral Coherence Analysis of ERP signals for Attentional Visual Stimulus (시각 자극의 집중에 따른 뇌유발전위의 공간-주파수 상관 분석)

  • Lee, ByuckJin;Yoo, SunKook
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.10
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    • pp.217-228
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    • 2013
  • In this paper, the brain function in relation with human's visual attention was investigated by means of coherence and bicoherence methods. Throughout experimentation with attentional visual stimulus ERP (Event Related Potential) data and synthesized simulated data with different combinations of parameters, it is demonstrated that bicoherence and coherence can be useful to reveal the phase synchronies between different frequency bands at fixed scalp location, and between different scalp locations at fixed frequency band, respectively. Both methods are also affected by time interval from the onset, and the level of white noise added. The phase coupled relationships among ${\Theta}$, ${\delta}$, and ${\alpha}$ bands, and between frontal and central lobes were observed for attentional tasks, while those were little observable for inattentional tasks, which can show brain's functional spatio-spectral differences associated with human's attention.

CSE1L/CAS, a microtubule-associated protein, inhibits taxol (paclitaxel)-induced apoptosis but enhances cancer cell apoptosis induced by various chemotherapeutic drugs

  • Liao, Ching-Fong;Luo, Shue-Fen;Shen, Tzu-Yun;Lin, Chin-Huang;Chien, Jung-Tsun;Du, Shin-Yi;Jiang, Ming-Chung
    • BMB Reports
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    • v.41 no.3
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    • pp.210-216
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    • 2008
  • CSE1L/CAS, a microtubule-associated, cellular apoptosis susceptibility protein, is highly expressed in various cancers. Microtubules are the target of paclitaxel-induced apoptosis. We studied the effects of increased or reduced CAS expression on cancer cell apoptosis induced by chemotherapeutic drugs including paclitaxel. Our results showed that CAS overexpression enhanced apoptosis induced by doxorubicin, 5-fluorour-acil, cisplatin, and tamoxifen, but inhibited paclitaxel-induced apoptosis of cancer cells. Reductions in CAS produced opposite results. CAS overexpression enhanced p53 accumulation induced by doxorubicin, 5-fluorouracil, cisplatin, tamoxifen, and etoposide. CAS was associated with $\alpha$-tubulin and $\beta$-tubulin and enhanced the association between $\alpha$-tubulin and $\beta$-tubulin. Paclitaxel can induce G2/M phase cell cycle arrest and microtubule aster formation during apoptosis induction, but CAS overexpression reduced paclitaxel-induced G2/M phase cell cycle arrest and microtubule aster formation. Our results indicate that CAS may play an important role in regulating the cytotoxicities of chemotherapeutic drugs used in cancer chemotherapy against cancer cells.

Kinetic studies using a linear regression analysis for a sorption phenomenon of 17a-methyltestosterone by Salvinia cucullata in an active plant reactor

  • Adnan, Fahrizal;Thanasupsin, Sudtida Pliankarom
    • Environmental Engineering Research
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    • v.21 no.4
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    • pp.384-392
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    • 2016
  • The aim of this study was to investigate the removal efficiency of $17{\alpha}$-methyltestosterone (MT) from aqueous solution by Salvinia cucullata Roxb. ex Bory in an active plant-based reactor with a specific focus on linear regression analysis for the sorption phenomena of MT onto the plant roots. A high performance liquid chromatographic method using UV detection (245 nm) was used to analyse the samples. The batch experiments of the active plant reactor (APR) were established to investigate the ability of Salvinia cucullata to remove MT from the liquid phase. The results revealed that 40% and 60% removal of MT from the liquid phase was observed at 5 min. and at 4 h, respectively. Salvinia cucullata can effectively remove MT from the aqueous solution in APRs. Kinetic studies revealed that the sorption phenomena of MT by Salvinia is best described using a linearized pseudo - second order model. Based on the kinetic parameters, it is likely that during the first 4 h of the contact (t = 0 to t = 4 h) sorption is the major driving mechanism of the disappearance of MT from aqueous solutions. However, at higher MT concentrations, diffusivity of MT has a significant effect on the migration of MT from the bulk stream to the root surface. The isotherm analysis revealed that the sorption kinetics favourably followed pseudo second-order. The results of isotherm analysis have indicated that the sorption of MT onto the root surfaces of Salvinia cucullata was favourable and almost irreversible.

Mechanical, Electrical Properties and Manufacture of the $\beta$-SiC-$ZrB_2$ Electroconductive Ceramic Composites by Pressureless Sintering (무가압소결한 $\beta$-SiC-$ZrB_2$계 도전성 복합체의 제조 및 기계적, 전기적 특성)

  • Shin, Yong-Deok;Kwon, Ju-Sung
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.2
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    • pp.98-103
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    • 1999
  • The effect of $Al_2O_3$ additives to $\beta-SiC+39vol.%ZrB_2$ electroconductive ceramic composites by pressureless sintering on microstructural, mechanical and electrical properties were investigated. The $\beta-SiC+39vol.%ZrB_2$ ceramic composites were pressureless sintered by adding 4, 8, 12wt.% $Al_2O_3$ powder as a liquid forming additives at $1950^{\cire}C$ for 1h. Phase analysis of composites by XRD revealed mostly of $\alpha-SiC(6H), ZrB_2$ and weakly $\alpha-SiC(4H), \beta-SiC (15R)$ phase. The relative density of composites was lowered by gaseous products of the result of reaction between \beta-SiC and Al_2O_3$, therefore, porosity was increased with increasing $Al_2O_3$ contents, and showed the maximum value of 1.4197MPa.$m^{1/2}$ for composite with 4wt.% $Al_2O_3$ additives. The electrical resistivity of $\beta-SiC+39vol.%ZrB_2$ electroconductive ceramic composite was increased with increasing $Al_2O_3$ contents, and showed positive temperature coefficient resistance (PTCR) in the temperature range of $25^{\cire}C$ to $700^{\cire}C$.

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Effect of Porosity on the Fracture Toughness and Electrical Conductivity of Pressureless Sintered ${\beta}-SiC-ZrB_2$ Composites (무가압소결(無加壓燒結)한 ${\beta}-SiC-ZrB_2$ 복합체(複合體)의 파괴인성(破壞忍性)과 전기전도성(電氣傳導性)에 미치는 기공(氣孔)의 영향)

  • Shin, Yong-Deok;Kwon, Ju-Sung
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.847-849
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    • 1998
  • The effect of $Al_{2}O_{3}$ additives on the microstructure, mechanical and electrical properties of ${\beta}$-SiC+39vol.%$ZrB_2$ electroconductive ceramic composites by pressureless sintering were investigated. The ${\beta}$-SiC+39vol.%$ZrB_2$ ceramic composites were pressureless sintered by adding 4, 8, 12wt.% $Al_{2}O_{3}$ powder as a liquid forming additives at $1950^{\circ}C$ for 1h. Phase analysis of composites by XRD revealed mostly of $\alpha$-SiC(6H), $ZrB_2$ and weakly $\alpha$-SiC(4H), $\beta$-SiC(15R) phase. The relative density of composites was lowered by gaseous products of the result of reaction between $\beta$-SiC and $Al_{2}O_{3}$ therefore, porosity was increased with increased $Al_{2}O_{3}$ contents. The fracture toughness of composites was decreased with increased $Al_{2}O_{3}$ contents, and showed the maximum value of $1.4197MPa{\cdot}m^{1/2}$ for composite added with 4wt.% $Al_{2}O_{3}$ additives. The electrical resistivity of ${\beta}$-SiC+39vol.%$ZrB_2$ electroconductive ceramic composite was increased with increased $Al_{2}O_{3}$ contents, and showed positive temperature coefficient resistance (PTCR) in the temperature from $25^{\circ}C$ to $700^{\circ}C$.

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Preparation and Characterization of P-Type Thermoelectric $\beta-FeSi_2$ Containing Dispersed Si Phase(l)-Microstructural Evolution with Processing Conditions- (Si 분산 조직의 p형 $\beta-FeSi_2$ 열전재의 제조 및 특성(l)-제조 조건에 따른 미세조직의 변화-)

  • Min, Byeong-Gyu;Kim, Il-Ho;Lee, Dong-Hui
    • Korean Journal of Materials Research
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    • v.8 no.7
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    • pp.584-590
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    • 1998
  • The microstructures of finely distributed Si-phases in $\beta$-$FeSi_2$ thermoelectric matrix, were produced by heat-treating the melt-cast ingots of single $\alpha$-$Fe_2Si_5$ phase at 730~85$0^{\circ}C$ for 4~20 hours, or by resistance-hot-pressing the mechanically alloyed powders ordinarily consisting of $\varepsilon$-FeSi and Si phases at 760~85$0^{\circ}C$ for 10 minutes of composition. $(Fe_{0.98}Mn_{0.02})_xSi_2(x{\leq$}1) The size and interspacing of dispersed Si-phases were able to control within a range of 0.05~0.27$\mu\textrm{m}$ and 0.2~0.6$\mu\textrm{m}$ by variations of heat treatment temperature and sintering temperature as well as the composition. respectively. The dispersion of Si- phases was expected to be effective for the reduction of thermal conductivity responsible for the increment of thermoelectric figure of merit.

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Fault Diagnosis of Solar Power Inverter Using Characteristics of Trajectory Image of Current And Tree Model (전류 궤적 영상의 특징과 트리모델을 이용한 태양광 전력 인버터의 고장진단)

  • Hwang, Jae-Ho
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.47 no.4
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    • pp.102-108
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    • 2010
  • The photovoltaic system changes solar energy into DC by solar cell and this DC is inverted into AC which is used in general houses by inverter. Recently, the use of power of the photovoltaic system is increased. Therefore, the study of 3 phase solar system to transmit large power is very important. This paper proposes a method that finds simply faults and diagnoses the switch open faults of 3-phase pulse width modulation (PWM) inverter of grid-connected photovoltaic system. The proposed method in $\alpha\beta$ plane uses the patterns of trajectory image as the characteristic parameters and differenciates a normal state and open states of switches. Then, the result is made into tree. The tree is composed of 21 fault patterns and the parameters to classify faults are a shape, a trajectory area, a distributed angle, and a typical vector angle. The result shows that the proposed method diagnosed fault diagnoses, classified correctly them, and made a pattern tree by fault patterns.