• 한국분말재료학회지
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• 제12권1호
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• pp.36-42
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• 2005

Four different mechanical alloying(MA) processes were employed to fabricate very fine intermetallic compound $Al_3Zr$ particles dispersed Al composite materials(MMC) with Al-4at.%Zr composition. Phase transformations including phase stability during MA and heat treatment processes were investigated. Part of Zr atoms were dissolved into Al matrix and part of them reacted with hydrogen produced by decomposition of PCA(methanol) to form hydride $ZrH_2$ during first MA process. These $ZrH_2$ hydrides disappeared when alloy powders were heat treated at $500^{\circC}$. Stable $Al_3Zr$ dispersoids with $DO_23$ structure were formed by heat treating the mechanically alloyed powders at $400^{\circC}$. On the other hand, metastable $Al_3Zr$dispersoids with $L1_2$ structure were formed during first MA of powers with Al-25at.%Zr composition. These metastable $Al_3Zr$ dispersoids transformed to stable $Al_3Zr$ with $DO_23$ structure when heat treated above $450^{\circC}$.

• E2M - 전기 전자와 첨단 소재
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• 제7권4호
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• pp.312-316
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• 1994

In this study, ln$_{1-x}$ Ga$_{x}$P alloy crystal which has different compositions were grown by the temperature gradient solution(TGS) method, and the properties of deep levels were measured in the temperature range of 9OK-450K. We find the four deep levels of E$_{1}$, E$_{2}$(248meV), E$_{3}$(386meV) and E$_{4}$(618meV) in GaP, which has composition of Ga in In$_{1-x}$ Ga$_{x}$P is one, and the trap densities of E$_{3}$ and E4 levels were 7.5*10$^{14}$ cm$^{-3}$ and 9*10$^{14}$ cm$^{-3}$ , respectively. A broad deep level spectra was revealed in In$_{1-x}$ Ga$_{x}$P whose composition of Ga, x, were 0.56 and 0.83, and the activation energy and trap densities were about 430meV and 6*10$^{14}$ cm$^{-3}$ , respectively.ectively.

• Corrosion Science and Technology
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• 제2권2호
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• pp.59-67
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• 2003

Electrochemical potentiokinetic reactivation (EPR) tests are used to evaluate the degree of sensitization (DOS) of stainless steels and nickel base alloys. The validity of EPR test to detect DOS of these alloys, however, depends all the electrolyte composition employed. The existence of precipitates such as NbC, and TiC, etc. in the alloys also affects the reactivation behaviors of these alloys. In this investigation, the reactions involved during EPR processes are analyzed. In 0.5 M $H_2SO_4$+ 0.01 M KSCN electrolyte, a reactivation peak associated with the localized attack around NbC, different from that of intergranular corrosion, is observed for the solution annealed 347 SS. For solution annealed Alloy 600, matrix corrosion and localized attack around TiC with distinct anodic peaks appeared in the EPR curves are seen in the $H_2SO_4$+ KSCN electrolyte. With proper adjustment of elect rolyte composition, the contribution from intergranular corrosion, as a result of chromium carbide precipitation along the grain boundaries, can be distingui shed from the matrix and localized corrosion for the sensitized Alloy 600.

• 한국기계가공학회지
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• 제12권2호
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• pp.49-54
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• 2013

Recently welding of aluminum material is actively carried out to make lightweight in the fields of LNG vessels, aircraft, chemical plants, etc. To obtain high strength, hardness and elongation, elements such as manganese, zinc, silicon, etc should be added in aluminum alloy, which has been improved on the mechanical properties like precipitation hardening, age hardening, loosening, corrosion resistance acid resistance. Ar gas is used as a shielding gas of MIG welding for aluminum, also $N_2$, $O_2$, $CO_2$, $H_2$ etc can be added depending on the composition of the alloy. In this study, Ar + $O_2$, Ar, and He were used for welding, hardness, penetration status and changes in composition of penetrated parts were compared and analyzed. This made it possible to know the status and changes of the process in the penetrated parts depending on used gas throughout this study.

• 한국자기학회지
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• 제5권4호
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• pp.261-268
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• 1995

비대칭 자화 반전 효과의 원인을 조사하기 위하여 ${(Fe_{1-x}Co_{x})}_{75}Si_{10}B_{15}$계 비정질 자성 합금 리본을 부자장 중에서 열처리 온도 $380^{\circ}C$로 하여 16시간 동안 열처리한 후 합금 조성에 따른 자기 이력 곡선의 변화에 대하여 연구하였다. Fe나 Co만을 함유하고 있는 하금의 경우보다 이들 두 금속을 모두 함유하고 있는 비정질 합금 리본의 경우가 무자장 열처리에 의해서 자구벽내에 더 큰 유도 자기 이방성을 형성함으로써 보다 뚜렷한 비대칭 자화 반전 효과를 얻을 수 있었다. 또한 영자왜 조성에 가까운 비정질 합금의 경우에서 보다 뚜렷한 비대칭 자화 반전 효과를 얻을 수 있었는데, 두가지 금속 모두를 함유하는 특히 서로 비슷한 함량을 함유 하는 조성을 가질수록 뚜렷한 효과를 얻을 수 있다는 사실과 복합적으로 적용하였다.

• 한국세라믹학회지
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• 제37권7호
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• pp.632-637
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• 2000

Thermoelectric conversion properties of commercial Fe-Si2 and Fe-Si alloy ingots prepared by RF inductive furnace were investigated. As sintering temperature increased, density of the specimen increased and the phase transformation from metallic phases ($\varepsilon$-FeSi, ${\alpha}$-Fe2Si5) to semiconducting phase (${\beta}$-FeSi2) occurred more effectively. The FeSi phase was detected even after 100hrs of annealing treatment. For the Fesi1.95∼FeSi2.05 specimens prepared by RF inductive furnace, the thermoelectric property improved as the composition of the specimen approached to stoichiometric composition FeSi2. Electrical conductivity of the specimen increased with increasing temperatures showing typical semiconducting behavior. From the electrical conductivity measurements, activation energy in the intrinsic region (above about 700 K) was calculated to be approximately 0.46 eV. In spite of non-doping, the Seebeck coefficient for every specimen exhibited p-type conduction due to Si deficiency. Its maximum value was located at about 475 K, and then decreased abruptly with increasing temperatures. The power factor was governed by the Seebeck coefficient of the specimen more significantly than by electrical conductivity.

• 한국표면공학회지
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• 제43권2호
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• pp.64-72
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• 2010

CuSnZn electroplating was investigated as alternative to Ni plating. Evaluation of electrolyte and plating process was performed to control physical characteristics of the film, and to collect practical data for application. Hull-cell test was conducted for basic comparison of two commercialized products and developed product. Based on hull-cell test results, long term test of three electrolytes was performed. Various analysis on long term tested electrolyte and samples have been done. Reliable and practical data was collected using FE-SEM (FEI, Sirion), EDX (ThermoNoran SIX-200E), ICP Spectrometer (GBC Scientifi c, Integra XL), FIB (FEI, Nova600) for anlysis. Physical analysis and reliability test of the long term tested film were also carried out. Through this investigation plating time, plating speed, electrolyte composition, electrolyte metal consumption, hardness and corrosion resistance has been compared. This set of data is used to predict and control the chemical composition of the film and modify the physical characteristics of the CuSnZn alloy.

• 한국재료학회지
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• 제29권5호
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• pp.288-296
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• 2019

The passivation of AZ91D Mg alloys through plasma anodization depends on several process parameters, such as power mode and electrolyte composition. In this work, we study the dependence of the thickness, composition, pore formation, surface roughness, and corrosion resistance of formed films on the electrolyte temperature at which anodization is performed. The higher the electrolyte temperature, the lower is the surface roughness, the smaller is the oxide thickness, and the better is the corrosion resistance. More specifically, as the electrolyte temperature increases from 10 to $50^{\circ}C$, the surface roughness (Ra) decreases from 0.7 to $0.15{\mu}m$ and the corrosion resistance increases from 3.5 to 9 in terms of rating number in a salt spray test. The temperature increase from 10 to $50^{\circ}C$ also causes an increase in magnesium content in the film from 25 to 63 wt% and a decrease in oxygen from 66 to 21 wt%, indicating dehydration of the film.

• Structural Engineering and Mechanics
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• 제82권5호
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• pp.571-585
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• 2022

As a vital component of power grids, long-span transmission tower-line systems are vulnerable to wind load excitation due to their high flexibility and low structural damping. Therefore, it is essential to reduce wind-induced responses of tower-line coupling systems to ensure their safe and reliable operation. To this end, a shape memory alloy-bidirectional tuned mass damper (SMA-BTMD) is proposed in this study to reduce wind-induced vibrations of long-span transmission tower-line systems. A 1220 m Songhua River long-span transmission system is selected as the primary structure and modeled using ANSYS software. The vibration suppression performance of an optimized SMA-BTMD attached to the transmission tower is evaluated and compared with the effects of a conventional bidirectional tuned mass damper. Furthermore, the impacts of frequency ratios and SMA composition on the vibration reduction performance of the SMA-BTMD are evaluated. The results show that the SMA-BTMD provides superior vibration control of the long-span transmission tower-line system. In addition, changes in frequency ratios and SMA composition have a substantial impact on the vibration suppression effects of the SMA-BTMD. This research can provide a reference for the practical engineering application of the SMA-BTMD developed in this study.

• 열처리공학회지
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• 제36권2호
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• pp.69-76
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• 2023

In this study, we present a system for identifying equivalent grades of standardized wire rod steel based on alloy composition using machine learning techniques. The system comprises two models, one based on a supervised multi-class classification algorithm and the other based on unsupervised autoencoder algorithm. Our evaluation showed that the supervised model exhibited superior performance in terms of prediction stability and reliability of prediction results. This system provides a useful tool for non-experts seeking similar grades of steel based on alloy composition.