• Title/Summary/Keyword: All-solution-process

검색결과 726건 처리시간 0.033초

Bilirubin의 전기화학적 환원거동 (Electrochemical Reduction Behavior of Bilirubin)

  • 배준웅;이흥락;정미식;박태명
    • 대한화학회지
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    • 제35권4호
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    • pp.374-378
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    • 1991
  • pH 7.8의 인산 완충용액에서 Bilirubin의 전기화학적인 환원거동을 직류 폴라로그래피, 시차 펄스폴라로그래피, 순환 전압전류법 및 정전위 전기량법으로 조사하였다. 직류 폴라로그램에서 반파전위가 -1.32V와 -1.51V vs. Ag/AgCl인 2개의 환원파를 확인하였고, 각 환원파의 전류유형은 제1환원파는 확산지배적인 전류였으며 제2환원파는 반응성전류가 약간 포함된 확산전류였다. 그리고 각 환원단계는 모두 비가역적이었다. 또한 Bilirubin의 농도가 3.4 ${\times}$ 10$^{-4}$M 이하일 때 나타나는 전방파가 흡착에 의한 전류임을 확인하였다. 환원반응에 관여하는 전자수는 제1단계에서는 2개였으며, 제2단계에서는 1개였다.

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구매종속성을 고려한 주문충족률의 근사적 계산 (Approximate Calculation of Order Fill Rate under Purchase Dependence)

  • 박창규
    • 산업경영시스템학회지
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    • 제40권4호
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    • pp.137-146
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    • 2017
  • For the competitive business environment under purchase dependence, this paper proposes a new approximate calculation of order fill rate which is a probability of satisfying a customer order immediately using the existing inventory. Purchase dependence is different to demand dependence. Purchase dependence treats the purchase behavior of customers, while demand dependence considers demand correlation between items, between regions, or over time. Purchase dependence can be observed in such areas as marketing, manufacturing systems, and distribution systems. Traditional computational methods have a difficulty of the curse of dimensionality for the large cases, when deriving the stationary joint distribution which is utilized to calculate the order fill rate. In order to escape the curse of dimensionality and protect the solution from diverging for the large cases, we develop a greedy iterative search algorithm based on the Gauss-Seidel method. We show that the greedy iterative search algorithm is a dependable algorithm to derive the stationary joint distribution of on-hand inventories in the retailer system by conducting a comparison analysis of a greedy iterative search algorithm with the simulation. In addition, we present some managerial insights such as : (1) The upper bound of order fill rate can be calculated by the one-item pure system, while the lower bound can be provided by the pure system that consists of all items; (2) As the degree of purchase dependence declines while other conditions remain same, it is observed that the difference between the lower and upper bounds reduces, the order fill rate increases, and the order fill rate gets closer to the upper bound.

Repair of Pre-cracked Reinforced Concrete (RC) Beams with Openings Strengthened Using FRP Sheets Under Sustained Load

  • Osman, Bashir H.;Wu, Erjun;Ji, Bohai;Abdulhameed, Suhaib S.
    • International Journal of Concrete Structures and Materials
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    • 제11권1호
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    • pp.171-183
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    • 2017
  • Strengthening reinforced concrete (RC) beams with openings by using aramid fiber reinforcement polymers (AFRP) on the beams' surfaces offers a useful solution for upgrading concrete structures to carry heavy loads. This paper presents a repairing technique of the AFRP sheets that effectively strengthens RC beams, controls both the failure modes and the stress distribution around the beam chords and enhances the serviceability (deflection produced under working loads be sufficiently small and cracking be controlled) of pre-cracked RC beams with openings. To investigate the possible damage that was caused by the service load and to simulate the structure behavior in the site, a comprehensive experimental study was performed. Two unstrengthened control beams, four beams that were pre-cracked before the application of the AFRP sheets and one beam that was strengthened without pre-cracking were tested. Cracking was first induced, followed by repair using various orientations of AFRP sheets, and then the beams were tested to failure. This load was kept constant during the strengthening process. The results show that both the preexisting damage level and the FRP orientation have a significant effect on strengthening effectiveness and failure mode. All of the strengthened specimens exhibited higher capacities with capacity enhancements ranging from 21.8 to 66.4%, and the crack width reduced by 25.6-82.7% at failure load compared to the control beam. Finally, the authors present a comparison between the experimental results and the predictions using the ACI 440.2R-08 guidelines.

SBS 수목드라마에서 나타난 등장인물 관계분석 -그레마스 행위소 모델 중심으로- (A Analysis on the Relations among Characters shown in SBS Wednesday and Thursday Dramas -Focusing on the Greimas' Actantial Model-)

  • 임운주
    • 디지털융복합연구
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    • 제13권1호
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    • pp.481-486
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    • 2015
  • 이 연구는 SBS 수목드라마에서 나타난 등장인물의 행위들에서 만들어 내는 다양한 관계들이 어떻게 소통되고 있는지를 그레마스 행위소 모델을 통해 의미를 분석하고자 하였다. 주체와 대상의 관계에서 주체가 가지고 있는 결핍구조를 분석하여 이러한 관계에서 발생하는 문제들을 살펴본다면 서로 다른 장르에서 나타나는 드라마 속의 등장인물 관계를 종합적으로 분석할 수 있다. 이를 해석해보면 같은 사건에서 시작된 발신된 주체와 대상의 결핍 구조는 다르게 나타난 반면, 우연한 사건으로 인한 주체와 대상은 같은 결핍구조를 가지고 있었다. 주체와 발신자의 관계에서는 주체보다 나약하고 보호 받아야하는 불쌍한 인물들로 설정되었을 때는 극중 역할이 제한적이지만 발신자가 주체에게 적대자로써의 역할을 같이하는 구조에서는 주체보다 권위적이었다. 세 작품 속에서 나타난 반대자들은 결국 주체와 대상에게 또 다른 협력자들로 변절하며 사건 해결에 도움을 주며, 불행해지기보다는 한결 더 성숙해지는 경향이 있었다.

Microscopical and chemical surface characterization of CAD/CAM zircona abutments after different cleaning procedures. A qualitative analysis

  • Gehrke, Peter;Tabellion, Astrid;Fischer, Carsten
    • The Journal of Advanced Prosthodontics
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    • 제7권2호
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    • pp.151-159
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    • 2015
  • PURPOSE. To describe and characterize the surface topography and cleanliness of CAD/CAM manufactured zirconia abutments after steaming and ultrasonic cleaning. MATERIALS AND METHODS. A total of 12 ceramic CAD/CAM implant abutments of various manufacturers were produced and randomly divided into two groups of six samples each (control and test group). Four two-piece hybrid abutments and two one-piece abutments made of zirconium-dioxide were assessed per each group. In the control group, cleaning by steam was performed. The test group underwent an ultrasonic cleaning procedure with acetone, ethyl alcohol and antibacterial solution. Groups were subjected to scanning electron microscope (SEM) analysis and Energy-dispersive X-ray spectroscopy (EDX) to verify and characterize contaminant chemical characterization non- quantitatively. RESULTS. All zirconia CAD/CAM abutments in the present study displayed production-induced wear particles, debris as well as organic and inorganic contaminants. The abutments of the test group showed reduction of surface contamination after undergoing an ultrasonic cleaning procedure. However, an absolute removal of pollutants could not be achieved. CONCLUSION. The presence of debris on the transmucosal surface of CAD/CAM zirconia abutments of various manufacturers was confirmed. Within the limits of the study design, the results suggest that a defined ultrasonic cleaning process can be advantageously employed to reduce such debris, thus, supposedly enhancing soft tissue healing. Although the adverse long-term influence of abutment contamination on the biological stability of peri-implant tissues has been evidenced, a standardized and validated polishing and cleaning protocol still has to be implemented.

Recent Reseach in Simulation Optimization

  • 이영해
    • 한국시뮬레이션학회:학술대회논문집
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    • 한국시뮬레이션학회 1994년도 추계학술발표회 및 정기총회
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    • pp.1-2
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    • 1994
  • With the prevalence of computers in modern organizations, simulation is receiving more atention as an effectvie decision -making tool. Simualtion is a computer-based numerical technique which uses mathmatical and logical models to approximate the behaviror of a real-world system. However, iptimization of synamic stochastic systems often defy analytical and algorithmic soluions. Although a simulation approach is often free fo the liminting assumption s of mathematical modeling, cost and time consiceration s make simulation the henayst's last resort. Therefore, whenever possible, analytical and algorithmica solutions are favored over simulation. This paper discussed the issues and procedrues for using simulation as a tool for optimization of stochastic complex systems that are dmodeled by computer simulation . Its emphasis is mostly on issues that are speicific to simulation optimization instead of consentrating on the general optimizationand mathematical programming techniques . A simulation optimization problem is an optimization problem where the objective function. constraints, or both are response that can only be evauated by computer simulation. As such, these functions are only implicit functions of decision parameters of the system, and often stochastic in nature as well. Most of optimization techniqes can be classified as single or multiple-resoneses techniques . The optimization of single response functins has been researched extensively and consists of many techniques. In the single response category, these strategies are gradient based search techniques, stochastic approximate techniques, response surface techniques, and heuristic search techniques. In the multiple response categroy, there are basically five distinct strategies for treating the responses and finding the optimum solution. These strategies are graphica techniqes, direct search techniques, constrained optimization techniques, unconstrained optimization techniques, and goal programming techniques. The choice of theprocedreu to employ in simulation optimization depends on the analyst and the problem to be solved. For many practival and industrial optimization problems where some or all of the system components are stochastic, the objective functions cannot be represented analytically. Therefore, modeling by computersimulation is one of the most effective means of studying such complex systems. In this paper, after discussion of simulation optmization techniques, the applications of above techniques will be presented in the modeling process of many flexible manufacturing systems.

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사회적 약자보호를 위한 국가인권보호 활동의 발전방향 -경찰의 치안대책을 중심으로- (A study of the police legislative system for the disadvantaged)

  • 황현락
    • 융합보안논문지
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    • 제12권2호
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    • pp.71-86
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    • 2012
  • 21세기 지식정보화시대에서는 그 특성상 다원화되고 양극화가 급속히 진행되어 사회의 여러 계층과 지역간 빈부간의 격차가 심화되어가는 경향이 있다. 여기서 나타나는 다양한 사회갈등은 정부 어느 한 부처의 독자적인 노력과 활동만으로는 지역사회의 다양한 치안문제에 효율적으로 대응하기 불가능하다. 지방화 분권화 민주화 등 다양한 사회변화에 대처하기 위해 경찰행정에 대한 주민과 지역 사회의 광범위한 참여와 협력이 무엇보다 중요하다. 특히 사회적 약자를 충분히 지키고 보호할 수 있기 위해서는 경찰의 치안대책 뿐만아니라 중앙정부나 지방자치단체 그리고 관련기관에서도 여러 가지 대안이 종합적으로 고려되어야한다. 소고에서는 보편적 인권의 역사적인 발전과정을 간단하게 살펴보고, 경찰업무와 관련하여 사회적 약자의 개념을 모색하고, 평소 경찰의 직무수행 중 나타나는 사회적 약자의 인권침해 실태 분석하고 문제점을 찾아 그에 합당한 해결책을 행정법제의 개선을 통해 모색해보았다.

순환식 병류형 유채씨 건조 시뮬레이션 (Circulating Concurrent-flow Drying Simulation of Rapeseed)

  • 한재웅;금동혁;김웅;레안득;조성호;김훈
    • Journal of Biosystems Engineering
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    • 제35권6호
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    • pp.401-407
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    • 2010
  • In this study, computer simulations were conducted to assess the use of a circulating concurrent-flow dryer for rapeseed drying and to determined the effect of this drying method on the germination ratio of rapeseed after the drying process was complete. The simultaneous heat and mass transfer between air and rapeseed in a concurrent-flow dryer was examined by simulation. The drying simulation was based on several parameters with sequent time series. Equations concerning air psychrometrics, physical properties, thermal properties, equilibrium moisture content, thin layer drying of rapeseed, etc. were all combined to solve the simulation models. Based on energy and mass transfer in the concurrent-flow drying model, a simulation program for the circulating concurrent-flow rapeseed dryer was built along with a detailed description of the mathematical solution to the model. A pilot scale circulating concurrent-flow dryer(200 kg/batch) was used to verify the fitness of the simulation program. A comparison between the experimental data and the model predicted results was presented and discussed. The drying parameters and germination ratio were analyzed and the accuracy of the simulation program was evaluated. The simulation program proved to be reliable and was shown to be a convenient tool for predicting rapeseed drying and germination ratio of rapeseed in a concurrent-flow dryer.

위성의 Dual-Spin Turn 방법 분석 및 자세획득 (Investigation of Dual-Spin Turn and Attitude Acquisition of Satellite)

  • 서현호;이승우
    • 한국항공우주학회지
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    • 제34권2호
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    • pp.36-47
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    • 2006
  • 인공위성에서 자세획득을 위해 기동을 하거나 이상상태 발생으로 위성이 임무를 수행하지 못하여 결국에 위성을 잃어버리게 되는 Flat Spin 상태에서 자세를 복구하는 방안인 Dual Spin Turn의 원리에 대한 연구가 수행되었다. Dual Spin Turn 현상에서 중요한 모멘텀 전달 원리를 물리적으로 명확하게 설명하였다. 그리고 기존의 연구결과에서 많이 알려진 방법을 포함하여 일반적인 위성의 관성모멘트 조건과 모멘텀 휠의 회전 방향 등을 여러 가지로 변화시켜 보면서 타당성을 검증하였다. Dual Spin Turn 과정은 개루프 제어와 에너지 감쇄장치의 도입이라는 2단계 제어방법을 이용하여 여러 경우에 대해 시뮬레이션으로 분석해보았다. 또한 제어의 타당성을 입증하기 위해 2단계 제어 이후의 안정성에 대해 검증하였다. 그리고 Dual Spin Turn을 이용하여 Flat Spin Recovery를 수행하는 시나리오를 예제로 제시하였다.

잉크젯 프린팅을 이용한 초박막 투명 TiO2 코팅층 제조 (Preparation of Ultra-Thin Transparent TiO2 Coated Film by Ink-Jet Printing Method)

  • 윤초롱;오효진;이남희;;이원재;박경순;김선재
    • 한국표면공학회지
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    • 제40권4호
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    • pp.190-196
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    • 2007
  • Dye sensitized solar cells(DSSC) are the most promising future energy resource due to their high energy efficiency, low production cost, and simple manufacturing process. But one problem in DSSC is short life time compared to silicon solar cells. This problem occurred from photocatalytic degradation of dye material by nanometer sized $TiO_2$ particles. To prevent dye degradation as well as to increase its life time, the transparent coating film is needed for UV blocking. In this study, we synthesized nanometer sized $TiO_2$ particles in sols by increasing its internal pressure up to 200 bar in autoclave at $120^{\circ}C$ for 10 hrs. The synthesized $TiO_2$ sols were all formed with brookite phase and their particle size was several nm to 30 nm. Synthesized $TiO_2$ sols were coated on the backside of fluorine doped tin oxide(FTO) glass by ink jet printing method. With increasing coating thickness by repeated ink jet coating, the absorbance of UV region (under 400 nm) also increases reasonably. Decomposition test of titania powders dispersed in 0.1 mM amaranth solution covered with $TiO_2$ coating glass shows more stable dye properties under UV irradiation, compared to that with as-received FTO glass.