• Title/Summary/Keyword: All Solid State.

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Discussion on the Sealing Gap Behavior of Rocket Motor Connection with the Structural Design Parameters (추진기관 기밀체결부의 형상설계변수에 따른 기밀조립 갭의 영향평가)

  • Kim, Seong-eun;Ro, Young-hee;Hwang, Tae-kyung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.517-520
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    • 2017
  • In this paper, we represented the structural design parameter effect on the sealing gap behavior of solid rocket motor case and nozzle connection under penetrated pressure through the sealing path between insulation rubber and the ablative FRP bonded on the inside convergent wall of nozzle. It is important to keep the good sealing capacity during all the combustion time of SRM. To achieve the crucial role of sealing system of SRM, designers must consider design factors for stable sealing clearance gap as the nearly unchanged initial design state as possible for sufficient compression rate of O-ring under sealing gap pressure.

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Application of CR-39 Microfilm for Rapid Discrimination Between Alpha-Particle Sources

  • Dwaikat, Nidal;Al-Karmi, Anan M.
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.881-885
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    • 2017
  • This work presents a new technique for discriminating between alpha particles of different energy levels. In a first study, two groups of alpha particles emitted from radium-226 and americium-241 sources were successfully separated using a CR-39 microfilm of appropriate thickness. This thickness was adjusted by chemical etching before and after irradiation so that lower-energy particles were stopped within the detector, while higher-energy particles were revealed on the back side of the detector. The number of tracks on the front side of the microfilm represented all alpha particles incident on that side from the two sources. However, the number of tracks on the back side of the microfilm represented only the long-range alpha particles of higher energy that arrived at that side. Therefore, by subtracting the number of tracks on the back side from the number of tracks on the front side, one could easily determine the number of tracks for the short-range alpha particles of lower energy that remained embedded in the microfilm. Discrimination of the two energy levels is thus achieved in a simple, fast, and reliable process.

Fabrication and Characterization of Thin Film Supercapacitor using $WO_3$ ($WO_3$를 이용한 박막형 슈퍼캐패시터의 제작 및 특성 평가)

  • 신호철;신영화;임재홍;윤영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.575-578
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    • 2000
  • In this work, all solid-state thin film supercapacitor(TFSC) was fabricated using tungsten trioxide (WO$_3$) with a structure WO$_3$/LiPON/WO$_3$/Pt/TiO$_2$/Si (substrate). After TiO$_2$ was deposited on Si(100) wafer by d.c. reactive sputtering, the Pt current collector films were grown on TiO$_2$glue layer without breaking vacuum by d.c. sputtering. Fabrication conditions of WO$_3$ thin film were such that substrate temperature, working pressure, gas ratio of $O_2$/Ar and r.f. power were room temperature, 5 mTorr, 20% (O$_2$(8sccm)/Ar(32sccm)) and 200W, respectively. LiPON electrolyte film were grown on the WO$_3$ film using r.f. magnetron sputtering at room temperature. The XRD pattern of the as-deposited WO$_3$ thin film were shown no crystalline peak (amorphous). The SEM image of as-deposited WO$_3$ thin film showed that the surface is smooth and uniform. The capacitiy of as-fabricated TFSC was 0$\times$10$^{-2}$ F/$\textrm{cm}^2$-${\mu}{\textrm}{m}$.

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Preparation of Hard Magnetic $Sm_2Fe_{17}N_x$ Compound by Mechanical Alloying (기계적 합금화법에 의한 영구자석용 $Sm_2Fe_{17}N_x$ 화합물의 제조)

  • 이충효;김명근;석명진;김지순;윤석길;권영순
    • Journal of Powder Materials
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    • v.8 no.1
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    • pp.55-60
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    • 2001
  • Mechanical alloying technique was applied to prepare hard magnetic $Sm_2Fe_{17}N_x$ compound powders. Staring from pure Fe and Sm powders, the formation process of hard magnetic $Sm_2Fe_{17}N_x$ phase by mechanical alloying and subsequent solid state reaction was studied. As milled powders were found to consist of Sm-Fe amorphous and $\alpha$-Fe phases in all compositions of $Sm_xFe_{100-x}$(x = 11, 13, 15, 17). The effects of starting composition on the formation of $Sm_2Fe_{17}$ intermetallic compound was investigated by heat treatment of mechanically-alloyed powders. When Sm content was 15 at.%, heat-treated powders consisted of nearly $Sm_2Fe_{17}$ single phase. For preparation of hard magnetic $Sm_2Fe_{17}N_x$ powders, additional nitriding treatment was performed under $N_2$ gas flow at 45$0^{\circ}C$. The increase in the coercivity and remanence was proportional to the nitrogen content which increased drastically at first and then increased gradually as the nitriding time was extended to 3 hours.

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SYNTHESIS OF METASTABLE ALLOYS BY ION MIXING IN THE BINARY METAL SYSTEMS AND THEORETICAL MODELLING

  • Liu, B.X.;Zhang, Z.J.;Jin, O.;Pan, F.
    • Journal of the Korean Vacuum Society
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    • v.4 no.S2
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    • pp.148-155
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    • 1995
  • (1) The metastable crystalline(MX) phases formed by ion mixing are classified into 5 types, i.e. the super-saturated solid solutions and the enlarged HCP-I phases reported earlier, and the newly observed FCC-I phases in hcp-based alloys, The FCC-ll and HCP-ll phases in bcc-based alloys. The growth kinetics of the MX phases is discussed. (2) The interfacial free energy in the multilayered films was found to play an important role in ion beam mixing(IM) induced amorphization. By adding sufficient interfaces, amorphous alloys were obtained even in the systems with rather positive heat of formation. (3) Gibbs free energy diagrams of some representative systems were constructed, by calculating the free energy curves of all the competing phases. Steady-state thermal annealing was conducted and the results confirmed the relevance of the constructed diagrams, which were inturn employed to interpret the MX phase formation as well as the glass forming ability upon IM in the binary metal systems.

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Study of the Nonstoichiometry and Physical Properties of the$Nd_{1-x}Sr_xFeO_{3-y}$ System

  • Chul Hyun Yo;Hyung Rak Kim;Kwang Hyun Ryu;Kwon Sun Roh;Jin Ho Choy
    • Bulletin of the Korean Chemical Society
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    • v.15 no.8
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    • pp.636-640
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    • 1994
  • The nonstoichiometric perovskite solid solutions of the $Nd_{1-x}Sr_xFeO_{3-y}$ system for the compositions of x=0.00, 0.25, 0.50, 0.75, and 1.00 have been prepared at $1150^{\circ}C$ in the air pressure. The compound of x=0.00, NdFe$O_{3.0}$, contains only $Fe^{3+}$ ion in octahedral site and the others involves the mixed valence state between $Fe^{3+}$ and $Fe^{4+}$ ions. The mole ratio of $Fe^{4+}$ ion or the ${\tau}$-value increases steadily with the x-value and then is maximized at the compositionof x= 1.00. The nonstoichiometric chemical formulas of the system are formulated from the x, ${\tau}$ and y values. From the Mossbauer spectroscopy, the isomer shift of $Fe^{3+}$ ion decreases with the increasing x-value, which is induced by the electron transfer between the$Fe^{3+}$ and $Fe^{4+}$ ions. The transfer is made possible by the indirect interaction between $Fe^{3+}$ and$Fe^{4+}$ ions via the oxygen ion. The eg electrons of the$Fe^{3+}$ ions are delocalized over all the Fe ions. Due to the electron transfer, the activation energy of electrical conductivity is decrease with the increasing amount of $Fe^{4+}$ ion.

Synthesis of Lu3Al5O12:Ce3+ Nano Phosphor by Coprecipitation Method, and Their Optical Properties (공침법을 이용한 Lu3Al5O12:Ce3+ 나노 형광체 합성과 광학적 특성 분석)

  • Kang, Taewook;Kang, Hyeonwoo;Kim, Jongsu;Kim, Gwangchul
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.4
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    • pp.51-56
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    • 2019
  • LuAG:Ce(Lu3Al5O12:Ce3+) nano phosphor were synthesized by applying the coprecipitation method. It is used to increase the color rendering of phosphor ceramic plate for high power LEDs and laser lighting. Internal quantum efficiency and absorption of LuAG:Ce nano phosphor are 51.5 % and 64.4 %, respectively, which is higher than the previously studied nano phosphors. The maximum absorption wavelength of this phosphor is 450 nm blue light, and the emission wavelength is 510 nm. The emission wavelength shifted to longer wavelength when the concentration of Ce increased in the heat treatment of the reducing atmosphere. Thermal quenching of LuAG nano phosphor was 70 % at 200 ℃, it was explained by their significant quenching of all raman scattering modes, implying the restriction of electron-phonon couplings caused by their defects.

Improved Micropropagation of Root Chicory, Cichorium intybus L. var. sativus.

  • Lim, Jung-Dae;Yang, Deok-Chun;Lee, Hyeon-Yong;Kim, Jong-Dai;Lee, Jin-Ha;Sung, Eun-Soo;Yu, Chang-Yeon
    • Plant Resources
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    • v.7 no.1
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    • pp.60-64
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    • 2004
  • The establishment of an efficient protocol for plant regeneration and micropropagation from leaf explant cultures of Chicory, Cichorium intybus L. var. sativus. is reported. Callus formation rate appeared 100% from explant in all growth regulators, but calli formed in the prensence of naphthaleneacetic acid (NAA) were appeared very compact and non-embryogenic state. The regenerated shoots were obtained from leaf explant cultures on solid MS medium containing different concentrations of cytokinins and auxin. The highest number of shoots (5.7) per explant and shoot growth (2.8cm) was obtained on MS medium containing 0.1 mg BAP L$^{-1}$ and 0.1 mg NAA L$^{-1}$ . Indole acetic acid was the most suitable auxin for root formation among three auxins tested. 2,4-D had no effect on shoot and root formation.

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Effect of Nickel Addition on Sintering Behavior and Electrical Conductivity of BaCe0.35Zr0.5Y0.15O3-δ

  • An, Hyegsoon;Shin, Dongwook;Ji, Ho-Il
    • Journal of the Korean Ceramic Society
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    • v.56 no.1
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    • pp.91-97
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    • 2019
  • The effect of different Ni-containing additives on the sintering behavior and electric conductivity of the proton conducting electrolyte $BaCe_{0.35}Zr_{0.5}Y_{0.15}O_{3-{\delta}}$ (BCZY5) was investigated. Ni-doped, NiO-added, and $BaY_2NiO_5$(BYN)-added (all 4 mol%) BCZY5 samples were prepared by the solid state synthesis method and sintered at $1400^{\circ}C$ for 6 h. Among the three samples, the onset of densification was observed at the lowest temperature for NiO-added BCZY5, which is attributed to the formation of an intermediate phase at a low melting temperature. The BYN-added sample, where no consumption of the constitutional elements of the electrolyte was expected during sintering, exhibited the highest electrical conductivity whereas the doped sample had the lowest conductivity. The electrical conductivities at $500^{\circ}C$ under humid argon atmosphere were measured to be 2.0, 4.8, and $6.2mS{\cdot}cm^{-1}$ for Ni-doped and NiO- and BYN-added samples, respectively.

Diversity of freshwater red algae at Khao Luang National Park, southern Thailand

  • Chankaew, W.;Sakset, A.;Chankaew, S.;Ganesan, E.K.;Necchi, Orlando Jr.;West, John A.
    • ALGAE
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    • v.34 no.1
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    • pp.23-33
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    • 2019
  • Freshwater red algal diversity and the relationship with water conditions in 22 stream segments in the area around Khao Luang National Park, Nakhon Si Thammarat province, southern Thailand, were studied during a period of twelve months (May 2014 to April 2015). Sixteen species of freshwater red algae, belonging to eight genera (Audouinella, Balliopsis, Batrachospermum, Caloglossa, Compsopogon, Kumanoa, Sirodotia, and Thorea) were identified, which were all reported earlier for the country. Thorea clavata (Thoreaceae) was the most common species occurring in eight stream segments. Caloglossa beccarii sensu lato (Delesseriaceae) and Sirodotia huillensis Skuja (Batrachospermaceae) had the highest percent cover with up to 40% and 20% per stream segment, respectively. The water quality showed most sites to be unpolluted or ultra-oligotrophic to oligotrophic. Canonical Correspondence Analysis revealed some trends in occurrence of individual species with stream environmental variables: Batrachospermum sp.with strong current velocity; Kumanoa hirosei with high turbidity, total dissolved solid and alkalinity; Caloglossa beccarii with high conductivity; Kumanoa tabagatenensis with high ammonia-nitrogen and Thorea siamensis with high calcium and magnesium. In view of the scarce studies on the stream ecology of freshwater red algae in Philippines and neighbouring countries, it is expected that the data presented here would be helpful in more critical further studies in south-east Asia in general.