• Title/Summary/Keyword: All Solid State.

Search Result 390, Processing Time 0.023 seconds

Fabrication and Electrochemical Characterization of All Solid-State Thin Film Micro-Battery by in-situ Sputtering (In-situ 스퍼터링을 이용한 잔고상 박막 전지의 제작 및 전기화학적 특성 평가)

  • Jeon Eun Jeong;Yoon Young Soo;Nam Sang Cheol;Cho Won Il;Shin Young Wha
    • Journal of the Korean Electrochemical Society
    • /
    • v.3 no.2
    • /
    • pp.115-120
    • /
    • 2000
  • All solid-state thin film micro-batteries consisting of lithium metal anode, an amorphous LiPON electrolyte and cathode of vanadium oxide have been fabricated and characterized, which were fabricated with cell structure of $Li/LiPON/V_2O_5Pt$. The effect of various oxygen partial pressure on the electrochemical properties of vanadium oxide thin films formed by d.c. reactive sputtering deposition were investigated. The vanadium oxide thin film with deposition condition of $20\%\;O_2/Ar$ ratio showed good cycling behavior. In in-siか process, the LiPON electrolyte was deposited on the $V_2O_5$ films without breaking vacuum by r.f. magnetron sputtering at room temperature. After deposition of the amorphous LiPON, the Li metal films were grown by a thermal evaporator in a dry room. The charge-discharge cycle measurements as a function of current density and voltage variation revealed that the $Li/LiPON/V_2O_5$ thin film had excellent rechargeable properly when current density was $7{\mu}A/cm^2$. and cut-off voltage was between 3.6 and 2.7V In practical experiment, a stopwatch ran on this $Li/LiPON/V_2O_5$ thin film micro-battery. This result means that thin film micro-battery fabricated by in-siか process is a promising for power source for electronic devices.

Electrochemical performance of the flexible supercapacitor based on nanocarbon material/conductive polymer composite and all solid state electrolyte (탄소나노복합재료와 전고체 전해질 기반의 유연성 슈퍼커패시터의 전기화학적 특성 분석)

  • Kim, Chang Hyun;Kim, Yong Ryeol;Jeong, Hyeon Taek
    • Journal of the Korean Applied Science and Technology
    • /
    • v.36 no.1
    • /
    • pp.200-207
    • /
    • 2019
  • In this study, flexible supercapacitor based on the all solid state electrolyte with PVA (polyvinyl alcohol)-$H_3PO_4$, ionic liquid as a BMIMBF4 (1-buthyl-3-methylimidazolium tetrafluoroborate) and reduced graphene oxide/conductive polymer composite was fabricated and characterized electrochemical properties with function of its flexibility. In order to measure and compare that electrochemical performances (including cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge,after 0~100th bending test) of prepared flexible supercapacitor based on reduced graphene oxide/conducting polymer composite and all solid state electrolyte, we have conducted press machine with constant pressure ( 0.01/cm2) for $100^{th}$ bending test. As a result, specific capacitance of the flexible supercapacitor was 43.9 F/g which value decreased to 42.0 and 40.1 F/g after 50 and $100^{th}$ bending test, respectively. This result exhibited that decreased electrochemical property of the flexible supercapacitor effected on physical stress on the electrode after repeated bending test. In addition, we have measured that electrode surface morphology by SEM to prove its decreased electrochemical property of the flexible supercapacitor after prolonged bending test.

Synthesis and Properties of Poly(1,1-diethynyl-1-silacyclopent-3-enes and -1-silacyclobutane)

  • Kim, Eun-Joo;Park, Jung-Woo;Kim, Yong-Rok;Park, Young-Tae
    • Bulletin of the Korean Chemical Society
    • /
    • v.24 no.4
    • /
    • pp.484-488
    • /
    • 2003
  • Polycarbosilanes containing diacetylene and organosilacyclic groups, such as poly(1,1-diethynyl-1-silacyclopent-3-ene), poly(1,1-diethynyl-3-triethylsilyl-1-silacyclopent-3-ene), and poly(1,1-diethynyl-1- silacyclobutane), were synthesized by the Glaser oxidative coupling polymerization reactions of 1,1-diethynyl-1-silacyclopent-3-ene, 1,1-diethynyl-3-triethylsilyl-1-silacyclopent-3-ene, and 1,1-diethynyl-1-silacyclobutane, respectively. These materials are almost insoluble in usual organic solvents such as $CHCl_3$ and THF. The polymers were characterized by using several spectroscopic methods in solid state. FTIR spectra of all the polymeric materials show that the characteristic C≡C stretching frequencies appear at 2146-2170 $cm^{-1}$, in particular. The polymers in the solid state show that the strong maximum excitation peaks appear at 255-257 nm and the strong maximum fluorescence emission bands at 401-402 nm. About 71-87% of the initial polymer weights remain at 400 ℃ in nitrogen according to thermogravimetric analysis.

Garbage Collection Technique for Balanced Wear-out and Durability Enhancement with Solid State Drive on Storage Systems

  • Kim, Sungho;Kwak, Jong Wook
    • Journal of the Korea Society of Computer and Information
    • /
    • v.22 no.4
    • /
    • pp.25-32
    • /
    • 2017
  • Recently, the use of NAND flash memory is being increased as a secondary device to displace conventional magnetic disk. NAND flash memory, as one among non-volatile memories, has many advantages such as low power, high reliability, low access latency, and so on. However, NAND flash memory has disadvantages such as erase-before-write, unbalanced operation speed, and limited P/E cycles, unlike conventional magnetic disk. To solve these problems, NAND flash memory mainly adopted FTL (Flash Translation Layer). In particular, garbage collection technique in FTL tried to improve the system lifetime. However, previous garbage collection techniques have a sensitive property of the system lifetime according to write pattern. To solve this problem, we propose BSGC (Balanced Selection-based Garbage Collection) technique. BSGC efficiently selects a victim block using all intervals from the past information to the current information. In this work, SFL (Search First linked List), as the proposed block allocation policy, prolongs the system lifetime additionally. In our experiments, SFL and BSGC prolonged the system lifetime about 12.85% on average and reduced page migrations about 22.12% on average. Moreover, SFL and BSGC reduced the average response time of 16.88% on average.

Photoluminescence Properties of Red Phosphors Gd1-xVO4:Eux3+ Subjected to Eu3+ Concentration (Eu3+ 농도에 따른 적색 형광체 Gd1-xVO4:Eux3+의 형광 특성)

  • Cho, Shin-Ho;Cho, Seon-Woog
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.25 no.3
    • /
    • pp.193-197
    • /
    • 2012
  • $Gd_{1-x}VO_4:{Eu_x}^{3+}$ red phosphors were synthesized with changing the concentration of $Eu^{3+}$ ion by using a solid-state reaction method. The crystal structure, surface morphology, and photoluminescence and photoluminescence excitation properties of the red phosphors were measured by using X-ray diffractometer, field emission-scanning electron microscopy, and florescence spectrometer, respectively. The XRD results showed that the main peak of all the phosphor powders occurs at (200) plane. As for the photoluminescence properties, the maximum excitation spectrum occurred at 306 nm due to the charge transfer band from ${VO_4}^{3-}$ to $Eu^{3+}$ ions and the maximum emission spectrum was the red luminescence peaking at 619 nm when the concentration of $Eu^{3+}$ ion was 0.10 mol.

Synthesis and Emission Properties of CaMoO4:Tb3+ Green Phosphor Powders and Thin Films (CaMoO4:Tb3+ 녹색 형광체 분말과 박막의 제조와 발광 특성)

  • Jeon, Yongil;Cho, Shinho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.26 no.4
    • /
    • pp.264-270
    • /
    • 2013
  • $CaMoO_4:Tb^{3+}$ green phosphor powders and thin films were successfully prepared by using the solid-state reaction method and the radio-frequency magnetron sputtering technique, respectively. The crystalline structure of all phosphor powders with different $Tb^{3+}$ ion concentrations was found to be a tetragonal system with the maximum diffraction intensity at $28.58^{\circ}$, while that of the phosphor thin films, irrespective of the type of substrate, was amorphous. As for the phosphor powders, the grain particles showed the chain-like patterns with inhomogeneous size distribution, the excitation spectra were composed of a broad band peaked at 307 nm and two small narrow bands centered at 381 and 492 nm, and the highest green emission spectrum was observed at 0.01 mol of $Tb^{3+}$ ions. As for the phosphor thin films, the average transmittance exceeding 85% was measured in the 400~1,100 nm range and the optical band gap showed a significant dependence on the type of substrate.

Carbon Dioxide Sorption Properties and Sintering Behavior of Lithium Zirconate Prepared by Solid-State Reaction (고상반응에 의하여 제조된 Li2ZrO3의 이산화탄소 흡수 및 소결 특성)

  • Woo, Sang-Kuk;Lee, Shi-Woo;Yu, Ji-Haeng
    • Journal of the Korean Ceramic Society
    • /
    • v.43 no.5 s.288
    • /
    • pp.309-314
    • /
    • 2006
  • We synthesized lithium zirconate using solid-state reaction and analyzed thermal properties (TG/DTA) of starting materials and the synthesized one. When $Li_2ZrO_3$ powder was exposed to $CO_2$ environment at $500^{\circ}C$, 93% of the theoretical absorption weight was gained within 280 min with fairly high sorption rate. Almost all the absorbed $CO_2$ was generated by heating the sample to $800^{\circ}C$. We also investigated densification behavior of $Li_2ZrO_3$ under $CO_2$ environment. By sintering $Li_2ZrO_3$ at $760^{\circ}C$ using 2-step process, we obtained dense product, composed mainly of $Li_2ZrO_3\;and\;ZrO_2$, with relative density of 92%.

Design of Solid-State Transmitter and Receiver for Active Array Radar System (능동 배열 레이더 시스템 구현을 위한 반도체형 송수신기 설계)

  • Lee, Yu-Ri;Kim, Jong-Pil;Lee, Soo-Ho;Jeong, Myung-Deuk
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.21 no.12
    • /
    • pp.1335-1342
    • /
    • 2010
  • This paper presents design and measurement result of S-band, $\bigcirc$ kW solid-state transmitter and receiver for active array radar system. Transmitter characteristics show 63 dB gain, 200 usec pulse width(max.), 10 % duty(max.) and 63 dB pulse to pulse stability. Receiver characteristics show 23 dB gain and 3.2 dB noise figure. Receiving mode for pulse network analyzer is used for pulse to pulse stability measurement. Measurement results satisfies all specification.

Characteristics of $ZnGa_2O_4$ phosphor prepared by Precipitation method and Solid-state reaction method (침전법과 고상반응법으로 제조한 $ZnGa_2O_4$ 형광체의 특성)

  • Cha, Jae-Hyeok;Kim, Se-Jun;Kwak, Hyun-Ho;Choi, Hyung-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.06a
    • /
    • pp.383-384
    • /
    • 2007
  • The nano and micro-sized $ZnGa_2O_4$ phosphor were prepared by precipitation method and solid-state method. The luminescence, formation process and structure of phosphor powders were investigated by means of XRD, SEM and PL. The result of XRD analysis showed that $ZnGa_2O_4$ spinel structure was formed at as-prepared in the case of precipitation method. However, micro-sized phosphor was required high heating treatment to have a satisfactory spinel structure. The CL intensity of nano-sized phosphor was about 4-fold higher than that of micro-sized phosphor. The emission spectra of all $ZnGa_2O_4$ phosphor show a self activated blue emission band at around 420 nm in the wide range of 300~600 nm.

  • PDF

Electrical Properties of ZnxMn3-xO4 Ceramics for Application as IR Detectors

  • Kim, Kyeong-Min;Lee, Sung-Gap;Lee, Dong-Jin
    • Transactions on Electrical and Electronic Materials
    • /
    • v.17 no.4
    • /
    • pp.227-230
    • /
    • 2016
  • ZnxMn3-xO4 (0.95≤x≤1.20) specimens were prepared using a conventional solid state reaction method. All specimens were sintered in air at 1,200℃ for 12 h, cooled at a rate of 2℃/min to 800℃, and subsequently quenched to room temperature. We investigated the electrical properties of ZnxMn3-xO4 specimens with various amounts of ZnO for use as IR detectors. At a composition of x≥1.15, the ZnO phase precipitates beside the spinel structure. The electrical resistivity at room temperature, activation energy, responsivity, and detectivity of a Zn1.10Mn1.90O4 specimen are 653.2 kΩ-cm, 0.392 eV, 0.016 V/W, and 7.52×103 cmHz1/2/W, respectively.