• Title/Summary/Keyword: Alkaline treatment

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Effect of SCODMn and pH Adjustment on Physicochemical Characteristics in Liquid Fertilizer Production Process Using Swine Manure (SCODMn 농도 및 pH 조정이 양돈분뇨의 후숙발효과정에 미치는 이화학적 영향)

  • Hong, In-Gi;Kim, Soo-Ryang;Lee, Myung-Gyu
    • Journal of Animal Environmental Science
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    • v.18 no.sup
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    • pp.13-20
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    • 2012
  • This research investigated the effect of $SCOD_{Mn}$ concentrations and pH adjustment at the stage before land application, namely 2nd-aeration treatment stage of liquid fertilizer in the liquid fertilizer treatment process of swine manure on the physicochemical compositions of 2nd-aeration treated liquid fertilizer. The liquid fertilizer used in this research is the alkaline fermented liquid fertilizer of swine manure more than pH 9.0 through aeration treatment (Alkaline fermentation treatment group). About the alkaline liquid fertilizer, phosphate neutralization treatment was conducted with phosphoric acid and it was a phosphate neutralization treatment group. In 2nd-aeration treatment of liquid fertilizer for 30 days, each group was divided into alkaline treatment groups (T-1, T-2, and T-3) and phosphate neutralization treatment groups (T-4, T-5, and T-6) according to early $SCOD_{Mn}$ concentrations. The research results are as follows. 1. As for $SCOD_{Mn}$ reduction rate, the average 29.9% in alkaline treatment groups and the average 36.9% in phosphate neutralization treatment groups were shown and so the relatively high reduction rate was shown in phosphate neutralization treatment groups. 2. After finishing the experiment, the group of the lowest $SCOD_{Mn}$ concentrations was the phosphate neutralization treatment group, T-6 with the lowest inflow concentrations. In case the final goal level of 2nd-aeration treated liquid fertilizer is assumed as concentrations less than $SCOD_{Mn}$ 3,000 ppm, it would be desired that inflow concentrations of 2nd-aeration treatment groups are adjusted less than $SCOD_{Mn}$ 5,500 ppm. 3. As for the persistence rate of nitrogen, the average 29.3% in alkaline treatment groups and the average 38.9% in phosphate neutralization treatment groups were shown and so phosphate neutralization treatment groups showed the relatively low loss rate of nitrogen, meanwhile, in the case of T-P, phosphate neutralization treatment groups maintained high concentrations (average 1,473 ppm). 4. In the event of 2nd-aeration treatment of liquid fertilizer, "alkaline fermentation treatment" condition in 'low phosphate-low nitrogen' type and "phosphate neutralization treatment" condition in 'high phosphate-high nitrogen' type are expected to be favorable.

Alkaline Sizing of TMP with AKD (AKD에 의한 TMP의 중성사이징)

  • 김봉용
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.1
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    • pp.1-6
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    • 2002
  • Alkaline sizing characteristics of TMP (thermomechanical pulp) handsheets with AKD (alkylketene dimer) were studied under various conditions. The sizing degree of TMP handsheet was much lower than that of chemical pulp. Especially, the sized TMP handsheet dried at $20^{\circ}C$ showed no sizing features, but sizing degree of TMP handsheet was clearly Increased by heat treatment at $105^{\circ}C$. The sizing effect of TMP was also improved by addition of $CaCO_3$, but it was not affected by pH. Therefore, sizing effect of TMP with AKD can be improved to some extent by controlling stock condition and heat treatment of handsheet.

ALKALINE HYDROGEN PEROXIDE TREATED ASPEN AS A RUMINANT FEED

  • Myung, K.H.;Kennelly, J.J.;Chung, K.C.;Kim, Y.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.1 no.4
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    • pp.195-199
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    • 1988
  • Two experiments were conducted to evaluate the nutritive value of a diet containing 20% alkaline hydrogen peroxide(AHP) treated aspen sawdust for ruminants. In experiment 1, sheep fed treated aspen(treated) had higher (p < 0.05) average daily gain and improved feed/gain ratio compared to animals fed untreated aspen (untreated), Apparent NDF and ADF digestibilities of treated aspen were higher (p < 0.05) than for untreated material. A similar trend was observed for DM, organic matter and cellulose digestibilities coefficients. In experiment 2, the soluble and degradable DM and crude protein (CP) fractions tended to increase with AHP treatment. Treatment also increased (p<0.05) the degradation rate of the degradable fraction. Results of these experiment indicate that AHP treatment results in a substantial improvement in the extent of utilization of aspen sawdust by ruminants.

Study on Biochemical Constituents of Caprine Ovarian Follicular Fluid after Superovulation

  • Mishra, O.P.;Pandey, J.N.;Gawande, P.G.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.12
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    • pp.1711-1715
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    • 2003
  • The experiment was designed on 42 non pregnant Black Bengal goat. Out of which 18 were subjected to a superovulatory treatment comprising of eCG and hCG for embryo transfer study. The remaining 24 goats received no treatment and served as control for parameter studied as well as recipient for embryo transfer studies. Important biochemical constituents such as acid and alkaline phosphatase, total protein and cholesterol and inorganic phosphorus were estimated in the follicular fluid of control and treated group and the values were separately recorded for small medium and large size follicle. The results indicated a significant effect on acid phosphotase activity due to size of follicle. The value increased progressively from small to medium and from medium to large follicles. Alkaline phosphotase activity showed reverse trend. Alkaline phosphotase decreased progressively as size increased. The concentration of inorganic phosphorus did not reveal any significant difference between the control and treatment groups and also between the different size follicles. The concentration of protein decreased significantly from small to medium and from medium to large, although no difference was observed between the control and treatment groups. The concentration of Cholesterol in the follicular fluid indicated a significant increase from small to medium and to large follicle. Here also no difference was observed due to treatment. Similar in the composition of follicular fluid in the respect of above mentioned constituents indicated no of super ovulatory treatment on follicular fluid composition.

Effects of Commercial Nitrilase Hydrolysis on Acrylic Fabrics

  • Kim, Hye Rim;Seo, Hye Young
    • Fashion & Textile Research Journal
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    • v.18 no.6
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    • pp.889-896
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    • 2016
  • This study aims to evaluate the hydrolytic activity of a commercial nitrilase and optimize nitrilase treatment conditions to apply eco-friendly finishing on acrylic fabrics. To assess the possibility of hydrolyzing nitrile bonds in acrylic fabric using a commercial nitrilase, the amounts of hydrolysis products, ammonia and carboxylate ions, were measured. The treatment conditions were optimized via the amount of ammonia. The formation of carboxylate ions on the fabric surface was detected by X-ray photoelectron spectroscopy and wettability measurements. After nitrilase treatment, ammonia was detected in the treatment liquid; thus, nitrilase hydrolyzed the nitrile bonds in acrylic woven fabric. The largest amount of ammonia was released into the treatment liquid under the following conditions: pH 8.0, $40^{\circ}C$, and a treatment time of 5 h. The formation of carboxylate ions on the acrylic woven fabric surface by nitrilase hydrolysis was proven by the increased O1s content measuring of XPS analysis. From comparison of the results of nitrilase and alkaline hydrolysis, the white index and strength of the alkali-hydrolyzed acrylic fabric decreased, whereas those of the nitrilase-hydrolyzed samples were maintained. The nitrilase hydrolysis improved the sensitivity of acrylic fabrics to basic dye similarly to alkaline hydrolysis without the drawbacks of yellowing and decreased strength caused by alkaline hydrolysis.

Relationship between Sporulation and Synthesis of Alkaline Protease in Streptomyces sp. (방선균 일주에서 포자형성과 호알칼리성 단백질 분해효소의 생합성과의 관계성)

  • 정병철;신현승;이계준
    • Korean Journal of Microbiology
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    • v.26 no.4
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    • pp.355-361
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    • 1988
  • The aims of the present studies were to understand the physiolosical and genetic characters of Streptomyces sp. isolated from soil. It revealed that Streptomyces sp. SMF301 had very fast growth rate and produced extracellular protease and heavily sporulated on rich media. It also showed $\beta$-lactamase activity and pigment production. Nonsporulating mutants were isolated after NTG or acriflavin treatment and their characters were compared with the parent strain. It was found that the mutants obtained by acriflavin treatment and ghier characters were compared with the parent strain. It was found that the mutants obtained by acriflavin treatment lost the pigment formation and $\beta$-lactamase production. Protease actibity of the mutant was lowered and the pH optimum was changed toward neutral. It was found that the changes were resulted from the reduction of alkaline protease biosynthesis in the bald mutant. Therefore it is considered that sporulation, pigment formation, $\beta$-lactamase production, and alkaline protease production in Streptomyces sp. might be controlled with a closely related relationship.

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Alkaline Softening of $TiO_2$ Delustered Polyester Fabrics ($TiO_2$로 소광가공된 폴리에스테르 직물의 알칼리 유연가공에 관한 연구)

  • 이정순
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.1
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    • pp.157-169
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    • 1996
  • Polyester yarns and fabrics containing three levels of $TiO_2$ delusterant were hydrolyzed with NaOH and examined for physical and morphological changes. The mechanical propertis and hand values of alkaline hydrolyzed polyester fabrics were measured using KES-FB system. Also, the relationship between the morphology and the mechanical property of alkaline hydrolyzed polyester fabrics was analyzed. The results are as follows: 1. At an initial stage of alkaline treatment, the concentration of $TiO_2$ did not affect the weight loss of the treated yarns. But by increasing treatment time, the effect of the concentration of $TiO_2$ on the weight loss of the fiber became more pronounced. The weight loss were increased in the following order; fulldull> semidull> clear 2. The effect of hydrolysis on yarn tensile strength seems to be more related to the size of the pits on the fibers rather than the number of pits. 3. Axially oriented pits occurred along the hydroyzed, delustered fiber surfaces, while such pitting was absent on hydrolyzed fiber containing no $TiO_2$. The number of voids across the surface of a fiber increased with an increase in the amount of TiOa incorporated into the fibers. The size of the voids depended on the treatment time of hydrolysis rather than the concentration of TiOa. 4. The mechanical properties and hand values of polyester fabrics were changed by alkaline treatment but were identical regardless of the concentration of TiOa. While the mechanical properties of polyester fabrics depended on the structural change of the fibers and the yarns within the fabrics as the fiber diameter became progressively smaller rather than the size and number of pits.

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Sewage Sludge Treatment with Internal Recirculation and Diverse Pre-treatment Methods Using Combined Digestion Process (혼합 소화공정에서 내부반송과 다양한 전처리를 통한 하수 슬러지 처리)

  • Ha, Jeong Hyub;Choi, Suk Soon;Park, Jong Moon
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.613-619
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    • 2018
  • In this study, various influent sludge pre-treatment methods and the internal recirculation of thickened sludge from effluents using a liquid/solid separation unit were adopted to investigate their effects on the sludge digestion and methane production in a combined mesophilic anaerobic and thermophilic aerobic sludge digestion process. A lab-scale combined sludge digestion process was operated during 5 phases using different feed sludge pre-treatment strategies. In phase 1, the feed sludge was pre-treated with a thermal-alkaline method. In contrast, in phases 2, 3 and 4, the internal recirculation of thickened sludge from the effluent and thermal-alkaline, thermal, and alkaline pre-treatment (7 days) were applied to the combined process. In phase 5, the raw sludge without any pre-treatment was used to the combined process. With the feed sludge pre-treatment and internal recirculation, the experimental results indicated that the volatile suspended solid (VSS) removal was drastically increased from phases 1 to 4. Also, the methane production rate with the thermal-alkaline pre-treatment and internal recirculation was significantly improved, showing an increment to 285 mL/L/day in phase 2. Meanwhile, the VSS removal and methane production in phase 5 were greatly decreased when the raw sludge without any pre-treatment was applied to the combined process. Considering all together, it was concluded that the combined process with the thickened sludge recirculation and thermal-alkaline pre-treatment can be successfully employed for the highly efficient sewage sludge reduction and methane gas production.

The Investigation on Color Change of Dis-azo Acid Dye in Wool Dyeing (양모섬유의 염색시 디스아조계 산성염료의 변색현상 규명)

  • 김미경;김태경;윤석한;임용진
    • Textile Coloration and Finishing
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    • v.15 no.2
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    • pp.86-92
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    • 2003
  • It is already known that the color of wool fabric dyed with disazo acid dyes could be changed in dyeing process and this is accelerated under alkaline condition. Focus was given to figuring out the mechanism of this color change, through the LC-MS analysis. In this study, no color change was seen in wool fabrics dyed with C. I. Acid Blue 113 under weak acidic, neutral and weak alkaline conditions for 1hour. However, the wool fabrics dyed under weak alkaline condition for a long time over 3 hours fumed reddish orange. When the wool fabrics dyed under weak acidic, neutral and weak alkaline conditions were treated with $0.5g/L\;Na_2C0_3$ solution, all of them turned reddish orange. On the other hand, the color of silk fabrics dyed with C. I. Acid Blue 113 were not changed after the same alkaline treatment. Wool contains cystine and cysteine, whereas silk does not. Due to the reversible reduction/oxidation process of cystine and cysteine in wool dyeing, the C. I. Acid Blue 113 of the dis-azo type is decomposed by reduction and consequently turned them into the reddish orange mono-azo types dye.

Ultrasonic and Alkaline Pre-treatments of Waste Activated Sludge for Enhancing Anaerobic Digestion (혐기성 소화를 위한 폐활성슬러지의 초음파와 알칼리 전처리)

  • Park, In Geun;Son, Han Hyung;Lee, Chae Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.2
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    • pp.53-63
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    • 2018
  • The hydrolysis of organic solid waste, such as sludge, is the rate-limiting step of the anaerobic digestion. The longer rate-limiting step lead to decrease of treatment efficiency and increase hydraulic retention time and anaerobic digester. Therefore, the pre-treatment has been applied for accelerating the hydrolysis step. This study was investigated the effects of pre-treatment of waste activated sludge using ultrasonic and alkaline integrated treatment simultaneously. The results showed the cumulative methane production and the methane production rate increased while the lag phase decreased. Therefore ultrasonic and alkaline integrated pre-treatment of waste activated sludge resulted in acceleration of hydrolysis step in anaerobic digestion.