• Title/Summary/Keyword: Alkaline material

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A Study on the Application and Grouting Effects of Akali-Silicasol Grout Material from Field Test (현장시험을 통한 알칼리성 실리카졸 주입재의 적용성 및 주입효과에 대한 연구)

  • Kim, Younghun;Lee, Jinkyu;Yang, Hyungchil;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.8
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    • pp.5-13
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    • 2012
  • This research have investigated the application and the injection effect of the alkaline silicasol grouting materia (which is) recently developed. To compare the engineering characteristics of the alkaline silicasol which is formed with 3D-gel and the sodium silicate, it have studied the strength and environmental effects through the laboratory test, and field application was investigated with a review of the injection effect and waterproof through the field test. As a result of the laboratory test, unconfined compression strength of alkaline silicasol was 5 times more than sodium silicate. As a result of the leaching test, a total amount of the eluviated elements was very small, it considered the environment-friendly material. As a result of the field test, considerable reduction of the coefficient of permeability at the hydraulic layer was confirmed, and it could secure that the coefficient of permeability showed a lower than standard value of $10^{-5}cm/sec$.

A Study on DMT Synthesis Using Crude TPA Sludge Generated from PET Alkaline Waste Water as Raw Materials (PET 감량폐약으로부터 발생되는 crude TPA sludge를 원료로 한 DMT 합성에 관한 연구)

  • Cho, Hwan;Kim, Jong Bo;Jeong, Hee Cheon;Jeon, Byung Dae
    • Textile Coloration and Finishing
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    • v.7 no.2
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    • pp.9-16
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    • 1995
  • When alkaline waste water of PET fabric is treated with sulfuric acid, undegradable material, crude TPA sludge is generated, so that treatment has a serious problem. The result of DMT synthesis using crude TPA sludge generated from PET alkaline waste water were as follows: 1. When crude TPA generated from alkaline waste water is reactioned with methanol under catalyst of sulfuric acid, pure DMT can be obtained. 2. In DMT synthesis from crude TPA, addition of copper sulfate can increase yield, and increasing the amount of sulfuric acid can shorten reaction time.

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Crystal Structure and Photoluminescence of Domestic Natural Alkaline Feldspar (국산 천연알카리 장석의 결정구조와 Photoluminescence)

  • Choi, Jin-Ho;Cheon, Chae-Il;Kim, Jeong-Seog
    • Journal of the Korean Ceramic Society
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    • v.44 no.5 s.300
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    • pp.155-159
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    • 2007
  • Blue light-emitting phosphors having the excitation spectrum range of the medium-long ultraviolet ($280nm{\sim}400nm$) have been prepared by solid state reaction method. As a starting material the natural alkaline feldspar powder produced from the domestic mine field in Buyeo, Chungnam-do. The photoluminescence characteristics and crystal structures have been analyzed for the phosphor samples. The powder mixture of the natural alkaline feldspar and the rare-earth oxide was calcined at $800{\sim}1000^{\circ}C\;for\;3{\sim}4h$ in air. The calcined samples we fully ground at room temperature and then heat-treated in the mild reducing gas atmosphere of $5%H_2-95%N_2$ mixture at $1100{\sim}1150^{\circ}C\;for\;3{\sim}4h$. The natural alkaline feldspar material consists of the monoclinic orthoclase ($KAlSi_3O_8$) and the triclinic albite ($NaAlSi_3O_8$) phases. At the $0.5wt%Eu_2O_3$ addition the PL spectrum showed the maximum intensity and with further increase of $Eu_2O_3$ the PL intensity decreased. The albite phase disappeared in the $Eu_2O_3$ doped phosphors. The effect of the co-doped activator on the PL characteristics have been also discussed.

Study of Alkaline Peroxide Mechanical Pulp Made from Pinus densiflora (국내산 소나무로 제조된 APMP 특성 연구)

  • Lee, Ji-Young;Nam, Hyegeong;Kim, Chul-Hwan;Kwon, Sol;Park, Dong-Hun;Joo, Su-Yeon;Lee, Min-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.100-110
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    • 2016
  • Alkaline Peroxide Mechanical Pulping (APMP) of Pinus densiflora harvested from domestic mountains was explored. APMP contributes to various advantages including pulp quality, elimination of the need for a bleaching process, and energy savings. Sequential treatment of impregnation of bleaching chemicals and refining not only overcome the concern of alkaline darkening of wood chips during chemical impregnation, but it also brightens the chips to the desired brightness levels suitable for writing and printing papers. APMP pulping from Pinus densiflora was greatly influenced by the dosage levels of hydrogen peroxide and sodium hydroxide. Alkaline peroxide treatment was carried out by applying one of three levels of hydrogen peroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips) and one of three levels of sodium hydroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips). Other chemicals including a peroxide stabilizers and metal chelation were constantly added for all treatments. Chemical treatment with a liquor-to-wood ration of 9:1 was carried out in a laboratory digestor. Compared to BTMP, APMP pulping displayed outstanding characteristics including the less requirement of refining energy, the better improvement of tensile strength, the more reduction of shives, and the greater increase of pulp brightness. In particular, when 4.5% of hydrogen peroxide with impregnation during 90 minutes was used, the brightness of APMP reached 64.9% ISO. Even though bulk of APMP was decreased with the increase of sodium hydroxide, a better and improved balance could be achieved between optical and strength properties. The spent liquor obtained from the discharge of the impregnation process at the dosage level of 4.5% hydrogen peroxide exhibited an equal level of residual peroxide with BTMP. In conclusion, APMP pulping showed successful results with Pinus densiflora due to its better response to the development of optical and physical properties compared to TMP pulping.

A Study on the Variation of Anion Exchange Membrane of Hydrogen Generator of Alkaline Electrolysis (알칼리 수전해 수소제조의 이온 교환막 변화 분석)

  • Byun, Chang-Sub;Lim, Soo-Gon;Kim, Su-Kon;Shin, Hoon-Kyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.7
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    • pp.563-566
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    • 2013
  • We investigated the variation of anion exchange membrane of hydrogen generator of alkaline electrolysis. We detected the variation of elements and change of anion exchange membrane using EDS and FE-SEM. We detected two different sites of membrane because of different structure of membrane. $Sp_1$ shows that the distribution ratio of C, O, Al is 98% very higher than $Sp_2$ of 78%. Especially, the main elements of STS316 which is P, S, Fe, Ni were more detected at $Sp_2$ than $Sp_1$. We think that this result depends on the structure of membrane. This also affect the resistance, lifetime of membrane and decrease the efficiency of hydrogen production. We hope that this article is a foundation of developing of hydrogen production technology.

An Experimental Study on the Degradations of Material Properties of Vinylester/FRP Reinforcing Bars under Accelerated Alkaline Condition (급속 알칼리 환경하에서의 비닐에스터/FRP 보강근의 재료성능 저하 특성에 관한 실험적 연구)

  • Oh, Hongseob;Kim, Younghwan;Jang, Naksup
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.51-59
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    • 2019
  • There is increasingly more research focusing on the application of FRP reinforcing bars as an alternative material for steel reinforcing bars, but most such research look at short term behavior of FRP reinforced structures. In this study, the microscopic analysis and tensile behavior of Basalt and Glass FRP bars under freezing-thawing and alkaline conditions were experimentally evaluated. After 100 cycles of the freezing and thawing, the tensile strength and elastic modulus of FRP bars decreased by about 5%. In the case of microstructure of FRP bars during the initial 20 days, no significant damages of FRP bar sections were found under $20^{\circ}C$ alkaline solution; however, the specimens immersed in $60^{\circ}C$ alkaline solution were found to experience resin dissolution, fiber damage and the separation of the resin-fiber interface. In the alkaline environment, the strength decrease of about 10% occurred in the environment at $20^{\circ}C$ for 100 days, but the tensile strength of FRPs exposed for 500 days decreased by 50%. At temperature of $40^{\circ}C$ and $60^{\circ}C$, an abrupt decrease in the strength was observed at 50 and 100 days. Especially, the tensile strength decrease of Basalt fiber Reinforced Polymer bars showed more severe degradation due to the damage caused by dissolution of resin matrix and fiber swelling in alkaline solution. Therefore, in order to improve the long-term performance of the surface braided FRPr reinforcing bars, surface treatment is required to ensure alkali resistance.

THE EFFECT OF DENTURE CLEANSERS ON SOFT LINING MATERIALS (의치 세정제가 탄성 의치상 이장재에 미치는 효과에 관한 연구)

  • Jang, Bok-Sook;Kim, Chang-Whe;Kim, Yung-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.31 no.2
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    • pp.219-235
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    • 1993
  • To determine the compatibilities of soft liming materials with denture cleansers by measuring the flexibility and elasticity and investigating the surface changes, 4 self-curing acrylic resin soft lining materials and 1 heat-curing silicone soft lining material were evaluated. 3mm thick x 20mm diameter discs of soft lining materials were individually bonded to a hard acrylic resin base as per manufacturers’instructions. Using an Instron universal testing machine, a static stress of $2kg/cm^2$ was applied for 30secs., the strain in compression was measured, giving an indication of the material’s flexibility. Elastic recovery was measured at 10secs. After removal of stress. Surface changes were investigated with Stereomicroscope. Then the specimens were immersed in 4alkaline peroxide denture cleansers and water as control group, tests were carried out at 1 day, 2 days, 7 days, 14 days and 30 days. The results were as follows : 1. Alkaline peroxide denture cleansers caused considerable porosity on the surface of selfcuring acrylic resin soft lining materials, and the most affected by the cleansers were Viscogel, Coe-Soft, Coe-Comfort, Lynal, in that order. 2. There was significant difference in flexibility between each soft lining material except for Coe-Comfort and Visco-gel, and every soft lining material was significant difference in elasticity. Especially Molloplast-B and Lynal were less flexible and more elastic than other soft lining materials(p<0.05). 3. The denture cleansers increased the flexibility and elasticity of the soft lining materials compared with control group(p<0.05), and Denalan, Polident, Kleenite, Efferdent affected the soft lining materials in that order. 4. There was significant difference in flexibility between each denture cleanser except for Denalan and Polident(p<0.05). Though Denalan and Polident, Denalan and Kleenite did not show significant difference in elasticity, other denture cleansers showed significant difference among each other(p<0.05). 5. Clinically Coe-Comfort, Coe-Soft and Visco-gel were incompatible with alkaline peroxide denture cleansers, and Lynal would be used within only 2 weeks. But Molloplast-B was compatible with alkaline peroxide denture cleansers.

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Luminescence behaviour of rare earth doped alkaline earth aluminates synthesized by combustion method (연소법에 의한 rare earth doped doped alkaline earth aluminates 형광체의 발광특성)

  • Jung, Young-Ho;Park, Jin-Won;Park, Jo-Yong;Khatkar, S.P.;Taxak, V.B.;Myung, Kwang-Shik;Han, Sang-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.581-584
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    • 2002
  • A new method for the preparation of lanthanide ions activated strontium aluminates phosphor by combustion method has been proposed. Combustion method consist of the redox reactions between the respective metal nitrates and urea in a preheated funace at $500^{\circ}C$. The luminescence behavior of the phosphor was studied and compared with corresponding phosphor prepared by conventional method. Effect of $Mg^{2+}$ ion concentration in strontium aluminate phosphor was investigated and the maximum luminescence of about $100cd/m^2$ was obtained. This method gave better brightness and small size to the phosphor than made by conventional method.

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Analysis on Variation of Primary Elements of Stainless Steel Interacting with Alkali Solution (알칼리 전해액의 상호작용에 의한 Stainless Steel 주성분의 변화 분석)

  • Byun, Chang-Sub;Lim, Soo-Gon;Kim, Su-Kon;Choi, Ho-Sang;Shin, Hoon-Kyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.7
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    • pp.522-527
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    • 2013
  • In this paper, We studied the change of surface and variation of elements on both electrodes of hydrogen generator of alkaline electrolysis in use of FE-SEM and SIMS. We used the stainless steel 316(600 ${\mu}m$) as electrode in condition of 25%KOH, $60^{\circ}C$ Temperature. The results show that the intensity of elements (C, Si, P, S, Ti, Cr, Mn, Fe, Ni, Mo) of Positive Electrode are decreased as much as about $10^1{\sim}10^3 $than the original electrode. Thickness of Positive Electrode is decreased about 40 ${\mu}m$ after chemical reaction. The negative electrode, however, shows a slight variation in the intensity of elements (C, Si, P, Fe, Ni, Mn, Mo) but Change of thickness and surface' shape of electrode show nothing after chemical reaction. The change in thickness and variation of Stainless Steel 316 cause the lifetime of electrode to be shorted. We also observed hydrogen, oxygen, potassium in both electrodes. Especially, The potassium is increased in proportional with depth of positive electrode. this means the concentration of alkali solutions is changed. and so we have to supply alkaline solution to generator in order to produce same quantity of hydrogen gas continuously. we hope that this study gives a foundation to develop the electrode for hydrogen generator of alkaline electrolysis.