• 제목/요약/키워드: Alkaline condition

검색결과 456건 처리시간 0.024초

Mixed Office Wastepaper의 중성탈묵 (Neutral Deinking of Mixed Office Wastepaper)

  • 윤병태;오세균
    • 펄프종이기술
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    • 제31권2호
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    • pp.50-57
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    • 1999
  • This study was carried out to compare a conventional alkaline flotation deinking conditions with neutral deinking conditions with and without enzyme addition with respect to the ink removal efficiency and theflotation deinking filtrate quality such as chemical oxygen demand, cationic demand, suspended solids. Based on ink removal rate the neutral deinking condition without enzyme was better than the alkaline deinking condition, and the neutral deinking with enzyme addition turned out to be the best. The brightness of the deinked pulp was found to be the same trend as the ink removal rate. Flotation reject rate for the neutral deinking condition without enzyme was higher than that of the alkaline deinking condition, but that of the neutral deinking condition with enzyme was lower than that of the alkaline and the neutral deinking condition without enzyme. On the freeness of the deinked pulp, the neutral deinking condition with enzyme had the highest value and the alkaline deinking condition had the lowest value among the conditions tested. On the filtrate of the flotation stage, the cationic polymer demand of the neutral deinking condition with enzyme was much lower than the other conditions. Suspended solids and chemical exygen demand for the neutral flotation deinking filtrate was lower than those of the alkaline flotation deinking filtrate.

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아세테이트 직물의 NaOH 처리시 무기염 첨가에 따른 영향 (The Effect of Sodium Acetate in Alkaline Treatment of Acetate Fabrics)

  • 성종미;김혜림;송화순
    • 한국의류산업학회지
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    • 제7권1호
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    • pp.85-90
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    • 2005
  • The effect of sodium acetate to reduce the fiber damage and hardening of acetate fabrics during alkaline treatment is studied. The optimal condition is controlled concentration 2%, at $50^{\circ}C$ for 6 minutes and at $70^{\circ}C$ for 2 minutes through the result of weight loss, shrinkage and tensile strength. Alkaline treated acetate fabrics under optimal condition show softer than untreated acetate fabrics. Alkaline treatment with sodium acetate brings the reduction in hardening and shrinkage in internal fiber of acetate fabric. Also, alkaline treatment with sodium acetate improves the tensile strength of acetate fabrics compared with only alkaline treatment. The moisture regain of acetate fabrics is also improved by alkaline treatment under optimal condition.

Corrosive Wear of Alloy 690 Tubes in Alkaline Water

  • Hong, Seung Mo;Jang, Changheui;Kim, In Sup
    • Corrosion Science and Technology
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    • 제8권3호
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    • pp.126-131
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    • 2009
  • The interaction between wear and corrosion can significantly increase total material losses in water chemistry environment. The corrosive wear tests of a PWR steam generator tube material (Alloy 690) against the anti vibration bar material (409 SS) were performed at room temperature. The tests were performed in alkaline water chemistry conditions. NaOH solution was selected for test condition to investigate the corrosive wear effect of steam generator tube material in alkaline pH condition without other factors. The flow induced vibration can caused tube damage and the corrosion can be occurred by water chemistry. The test results showed that, in the alkaline solution at pH 13.9, the corrosion current density was increased about ten times than that in the distilled water. And wear rate at pH 13.9 was increased about ten times from that at neutral condition. However, the wear rate was decreased with time. The decrease would be attributed to the change in roughness of specimen or sub-layer of the worn surface with time. From microstructure observation, severe abrasive shape and several wear debris were found. From those results, it could infer that the oxide film on Alloy 690 changed to easily breakable one in the alkaline water, and then abrasion with corrosion became the main wear mechanism.

전처리 방법에 따른 하수슬러지 가용화 비교연구 (Comparison of Sewage Sludge Solubilization through Different Pretreatment Methods)

  • 권재현;김봉준;김민규;염익태;김형수
    • 상하수도학회지
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    • 제17권4호
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    • pp.567-573
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    • 2003
  • The pretreatment process was carried out to solubilize the sewage sludge for enhancing its biodegradability using alkaline treatment, ultrasonic treatment(15kHz), ozone treatment and different combination of these three methods: alkaline followed by ultrasonic as well as ozone, and ultrasonic followed by alkaline. The solubilization efficiency was evaluated based on the SCOD/TCOD ratio and VSS/TS ratio. In results, the proper condition of alkaline treatment was shown as 30meq/l of NaOH, pH 12 and 3hours of reaction time. Solubilization efficiency increased to 17% from initial 2% based on SCOD/TCOD ratio under this condition. In ultrasonic treatment, the higher ultrasonic power, the longer treatment time and the lower sludge volume resulted in higher solubilization respectively. There was a rapid increase in solubilization efficiency after 20 minute, then it was measured as 32% of SCOD/TCOD ratio in 1 hour at a ultrasonic power of 1,300W with 1/sludge. Solubilization efficiencies in combined treatment using alkaline and ultrasonic were 47-53% higher than single treatment at a sonicated time of 1 hour. Ozone treatment followed by alkaline treatment also represented the enhanced solubilization compared to ozone treatment. Therefore, ultrasonic or ozone treatment assisted by alkaline could achieve the short treatment time as well as high solubilizetion efficiency.

닭발의 침지조건이 닭발 젤라틴에 미치는 영향 (Effect of Soaking Condition on the Physicochemical Properties of Chicken Feet Gelatin)

  • 장은경;임주연;김광옥
    • 한국식품과학회지
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    • 제34권3호
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    • pp.425-430
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    • 2002
  • 본 연구에서는 축산 부산물인 닭발을 산과 알칼리에 각각 침지하여 제조한 젤라틴의 이화학적 특성을 조사하였다. 침지조건에 따른 아미노산 함량은 큰 차이가 없었으나 상업적으로 판매되는 돈피나 소가죽 젤라틴과는 그 조성이 달랐다. 이는 원료의 특성과 제조공정의 차이에서 기인하는 것으로 사료된다. 젤라틴의 수율과 젤라틴 겔의 경도는 산성 조건에서 24시간 침지한 경우에, 알칼리 조건에서 1주 침지한 경우에 가장 높다고 평가되었다. 점도와 투명도는 침지기간이 증가함에 따라 산성 조건에서는 증가한 반면 알칼리 조건에서는 감소하였다. 색도는 산처리 닭발 젤라틴 겔이 알칼리처리 젤라팅 겔에 비해 L값은 높고, a값과 b값이 낮아 미관상 더 바람직하다. 이화학적 특성이 우수한 산처리 24시간 침지 시료와 알칼리 처리 1주 침지 시료의 분자량 분포를 Gel permeation chromatography로 살펴본 결과, 두 시료 모두 12개의 획분으로 구성되었다. 가장 많이 발견되는 분자량은 669 kD으로 알칼리 처리 시료가 산처리 시료에 비해 두 배나 많았으며, 300 kD 이하는 산처리 시료가 알칼리 처리군에 비해 현저히 많아 산처리 시료가 알칼리 처리군에 비해 상대적으로 저분자화 되어있었다.

홍모기(Culex pipiens pallens)의 난성숙 과정 중 alkaline phosphase의 활성 (Activity of Alkaline Phosphatase from the Mosquito, Culex pipiens pallens)

  • 이영수;이승훈;박영민;성기창
    • 한국동물학회지
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    • 제36권3호
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    • pp.425-432
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    • 1993
  • Culex pipiens pallens에 존재하는 Alkaline phosphatase의 연구를 위한 적정 분석조건과 우화 후, 시간 경과에 따른 Alkaline phosphatase 활성 경향에 대해서 연구하였다. C. pipiens에 존재하는 Alkaline phosphatase의 활성은 우화 직후부터 지속적으로 감소하다가, 흡혈 자극에 의해서 급격하게 증가한다. 흡혈 후 30시간이 경과했을 때, 최대의 활성도를 보이고 감소하나, 흡혈 48시간 이후에는 다시 증가하여 지속적으로 유지됨을 알 수 있다. 기관별 분석에서 첫번째 활성 증가는 중장에서 일어나고, 두번째 활성 증가는 난소에서 일어남을 알 수 있다. 그리고 흡혈 후 30시간된 성체에서는 5개의 동위효소 밴드가 보이는데, 난소에서 ALP-1와 ALP-2가 나타나고, 가슴에서는 ALP-3, ALP-4와 ALP-5가 보인다. 지방체에서는 ALP-4와 ALP-5가, 중장에서는 ALP-3, ALP-4와 ALP-5가 나타남을 알 수 있다. 그리고 흡혈 후 72시간된 성체에서, ALP-1, ALP-2가 동일하게 존재함을 알 수 있다.

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Bacillus속 AP-5 균주의 고온성 알카리 배양에 따른 Alkaline Pretense의 생성 및 성질 (Production and Properties of Alkaline Pretense from Bacillus sp. Strain in Thermophilic and Alkaline Condition)

  • 이광배
    • 환경위생공학
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    • 제5권2호
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    • pp.103-110
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    • 1990
  • For production of thermophilic and alkaline protease, Bacillus sp. strain AP-5 was isolated from a compost. The production of the protease was reached at maximum for 4 days at $55^{\circ}$ in standing culture. Chitin and Cellulose as carbon source, and Skim Milk as nitrogen source were favorable for the production of the enzyme. Optimal temperature and optimal pH of the enzyme was $55^{\circ}$ and 11, respectively. Metal ion didn't effect on the enzyme activity, the protease was very stable at heat treatment of 30 min at $55^{\circ}$.

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다른 전해질분위기에서 수소주입시킨 TRIP강의 SP시험 (Small Punch Test of TRIP Steel Charged with Hydrogen under Different Electrolyte Condition)

  • 김광식;유광현;박재우;강계명
    • 한국가스학회지
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    • 제19권1호
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    • pp.64-70
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    • 2015
  • TRIP강의 수소에 의한 취성화정도를 확인하기 위하여 산성과 알칼리성 전해질 분위기 하에서 전류밀도와 주입시간을 달리하여 수소를 강제주입시킨 후 sp시험으로 평가하고자 하였다. SP시험결과 산성 전해질 분위기가 알칼리성 전해질 분위기에 비해 수소 취성화가 더욱 민감하게 반응하는 것으로 조사되었다. 또한 산성 전해질은 주입시간과 전류밀도가 수소취성화에 영향을 미치는 인자로 확인되었으며, 알칼리성 전해질은 주입시간이 전류 밀도보다 수소 취성화를 촉진하는 요소로 조사되었다.

Comparing Bioavailability of Cadmium and Arsenic in Agricultural Soil Under Varied pH Condition

  • Oh, Se Jin;Kim, Sung Chul;Ok, Yong Sik;Oh, Seung Min;Lee, Bup Yeol;Lee, Sang Hwan;Yang, Jae E.
    • 한국토양비료학회지
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    • 제48권1호
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    • pp.57-63
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    • 2015
  • Bioavailability of cadmium (Cd) and arsenic (As) can be different depending on soil pH. For this reason, main purpose of this research was to compare bioavailability of Cd and As in agricultural field under varied soil pH and different extractants. Bioavailable fraction of Cd and As in soil was extracted with $CaCl_2$, $NaNO_3$, DTPA, EDTA, and low molecular weight organic acids (LMWOAs). Soil samples and cultivated crops were collected at the range of soil pH 4.5-8.5 and correlation analysis was conducted between bioavailable fraction of Cd and As in soil and total concentration of Cd and As in crops. Results showed that concentration of Cd and As in acidic soil was ranged $0.002-0.462mg\;kg^{-1}$ and $0.041-4.903mg\;kg^{-1}$ respectively. In alkaline condition, concentration of Cd and As were ranged $0.006-0.351mg\;kg^{-1}$ and $0.039-2.807mg\;kg^{-1}$ respectively. Comparing bioavailable fraction of Cd and As in acidic and alkaline soil condition, higher concentration was measured in acidic condition. Similarly, higher average concentration of Cd and Asin crops was observed in acidic condition (0.398 and $0.751mg\;kg^{-1}$ respectively) than alkaline condition (0.248 and $0.264mg\;kg^{-1}$). Among different extractants, LMWOAs method showed higher correlation ($r^2=0.545$) for Cd in acidic condition indicating that LMWOAs method could be applied for evaluating bioavailability of Cd in acidic soil. However, no high correlation was observed for As in both acidic and alkaline condition. Overall, bioavailable fraction of Cd and As can be higher in acidic condition of soil than alkaline condition resulting higher uptake of Cd and As from soil to crops. Therefore, efficient best management practice (BMPs) for Cd and As in acidic soil should be conducted for minimizing uptake of Cd and As into crops.

양모섬유의 염색시 디스아조계 산성염료의 변색현상 규명 (The Investigation on Color Change of Dis-azo Acid Dye in Wool Dyeing)

  • 김미경;김태경;윤석한;임용진
    • 한국염색가공학회지
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    • 제15권2호
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    • pp.86-92
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    • 2003
  • It is already known that the color of wool fabric dyed with disazo acid dyes could be changed in dyeing process and this is accelerated under alkaline condition. Focus was given to figuring out the mechanism of this color change, through the LC-MS analysis. In this study, no color change was seen in wool fabrics dyed with C. I. Acid Blue 113 under weak acidic, neutral and weak alkaline conditions for 1hour. However, the wool fabrics dyed under weak alkaline condition for a long time over 3 hours fumed reddish orange. When the wool fabrics dyed under weak acidic, neutral and weak alkaline conditions were treated with $0.5g/L\;Na_2C0_3$ solution, all of them turned reddish orange. On the other hand, the color of silk fabrics dyed with C. I. Acid Blue 113 were not changed after the same alkaline treatment. Wool contains cystine and cysteine, whereas silk does not. Due to the reversible reduction/oxidation process of cystine and cysteine in wool dyeing, the C. I. Acid Blue 113 of the dis-azo type is decomposed by reduction and consequently turned them into the reddish orange mono-azo types dye.