• Title/Summary/Keyword: Alkaline condition

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Neutral Deinking of Mixed Office Wastepaper (Mixed Office Wastepaper의 중성탈묵)

  • 윤병태;오세균
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.2
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    • pp.50-57
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    • 1999
  • This study was carried out to compare a conventional alkaline flotation deinking conditions with neutral deinking conditions with and without enzyme addition with respect to the ink removal efficiency and theflotation deinking filtrate quality such as chemical oxygen demand, cationic demand, suspended solids. Based on ink removal rate the neutral deinking condition without enzyme was better than the alkaline deinking condition, and the neutral deinking with enzyme addition turned out to be the best. The brightness of the deinked pulp was found to be the same trend as the ink removal rate. Flotation reject rate for the neutral deinking condition without enzyme was higher than that of the alkaline deinking condition, but that of the neutral deinking condition with enzyme was lower than that of the alkaline and the neutral deinking condition without enzyme. On the freeness of the deinked pulp, the neutral deinking condition with enzyme had the highest value and the alkaline deinking condition had the lowest value among the conditions tested. On the filtrate of the flotation stage, the cationic polymer demand of the neutral deinking condition with enzyme was much lower than the other conditions. Suspended solids and chemical exygen demand for the neutral flotation deinking filtrate was lower than those of the alkaline flotation deinking filtrate.

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The Effect of Sodium Acetate in Alkaline Treatment of Acetate Fabrics (아세테이트 직물의 NaOH 처리시 무기염 첨가에 따른 영향)

  • Sung, Jong-Mi;Kim, Hye-Rim;Song, Wha-Soon
    • Fashion & Textile Research Journal
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    • v.7 no.1
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    • pp.85-90
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    • 2005
  • The effect of sodium acetate to reduce the fiber damage and hardening of acetate fabrics during alkaline treatment is studied. The optimal condition is controlled concentration 2%, at $50^{\circ}C$ for 6 minutes and at $70^{\circ}C$ for 2 minutes through the result of weight loss, shrinkage and tensile strength. Alkaline treated acetate fabrics under optimal condition show softer than untreated acetate fabrics. Alkaline treatment with sodium acetate brings the reduction in hardening and shrinkage in internal fiber of acetate fabric. Also, alkaline treatment with sodium acetate improves the tensile strength of acetate fabrics compared with only alkaline treatment. The moisture regain of acetate fabrics is also improved by alkaline treatment under optimal condition.

Corrosive Wear of Alloy 690 Tubes in Alkaline Water

  • Hong, Seung Mo;Jang, Changheui;Kim, In Sup
    • Corrosion Science and Technology
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    • v.8 no.3
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    • pp.126-131
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    • 2009
  • The interaction between wear and corrosion can significantly increase total material losses in water chemistry environment. The corrosive wear tests of a PWR steam generator tube material (Alloy 690) against the anti vibration bar material (409 SS) were performed at room temperature. The tests were performed in alkaline water chemistry conditions. NaOH solution was selected for test condition to investigate the corrosive wear effect of steam generator tube material in alkaline pH condition without other factors. The flow induced vibration can caused tube damage and the corrosion can be occurred by water chemistry. The test results showed that, in the alkaline solution at pH 13.9, the corrosion current density was increased about ten times than that in the distilled water. And wear rate at pH 13.9 was increased about ten times from that at neutral condition. However, the wear rate was decreased with time. The decrease would be attributed to the change in roughness of specimen or sub-layer of the worn surface with time. From microstructure observation, severe abrasive shape and several wear debris were found. From those results, it could infer that the oxide film on Alloy 690 changed to easily breakable one in the alkaline water, and then abrasion with corrosion became the main wear mechanism.

Comparison of Sewage Sludge Solubilization through Different Pretreatment Methods (전처리 방법에 따른 하수슬러지 가용화 비교연구)

  • Kwon, Jae-Hyun;Kim, Bong-Jun;Kim, Min-Kyu;Yeom, Ick-Tae;Kim, Hyung-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.17 no.4
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    • pp.567-573
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    • 2003
  • The pretreatment process was carried out to solubilize the sewage sludge for enhancing its biodegradability using alkaline treatment, ultrasonic treatment(15kHz), ozone treatment and different combination of these three methods: alkaline followed by ultrasonic as well as ozone, and ultrasonic followed by alkaline. The solubilization efficiency was evaluated based on the SCOD/TCOD ratio and VSS/TS ratio. In results, the proper condition of alkaline treatment was shown as 30meq/l of NaOH, pH 12 and 3hours of reaction time. Solubilization efficiency increased to 17% from initial 2% based on SCOD/TCOD ratio under this condition. In ultrasonic treatment, the higher ultrasonic power, the longer treatment time and the lower sludge volume resulted in higher solubilization respectively. There was a rapid increase in solubilization efficiency after 20 minute, then it was measured as 32% of SCOD/TCOD ratio in 1 hour at a ultrasonic power of 1,300W with 1/sludge. Solubilization efficiencies in combined treatment using alkaline and ultrasonic were 47-53% higher than single treatment at a sonicated time of 1 hour. Ozone treatment followed by alkaline treatment also represented the enhanced solubilization compared to ozone treatment. Therefore, ultrasonic or ozone treatment assisted by alkaline could achieve the short treatment time as well as high solubilizetion efficiency.

Effect of Soaking Condition on the Physicochemical Properties of Chicken Feet Gelatin (닭발의 침지조건이 닭발 젤라틴에 미치는 영향)

  • Jang, Eun-Gyung;Lim, Ju-Yean;Kim, Kwang-Ok
    • Korean Journal of Food Science and Technology
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    • v.34 no.3
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    • pp.425-430
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    • 2002
  • Physicochemical properties of chicken feet gelatin produced under acidic and alkaline conditions were investigated. Amino acid content of chicken feet gelatin was different from that of commercial gelatin due to the differences in raw materials and production process. Yield and hardness of chicken feet gelatin reached maximum at 24 h under acidic condition and at 1 week under alkaline condition, respectively. As the soaking period increased, viscosity and clarity increased under acidic condition, while decreased under alkaline condition. Color of the acid-treated chicken feet gelatin gel was more desirable than that of the alkali-treated on based upon L, a, b values. From gel permeation chromatography of the chicken feet gelatin, 12 subunits were detected. The amount of high molecular weight subunits, which is related to viscosity and hardness, of the alkali-treated chicken feet gelatin was twice as much as that of the acid-treated one.

Activity of Alkaline Phosphatase from the Mosquito, Culex pipiens pallens (홍모기(Culex pipiens pallens)의 난성숙 과정 중 alkaline phosphase의 활성)

  • 이영수;이승훈;박영민;성기창
    • The Korean Journal of Zoology
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    • v.36 no.3
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    • pp.425-432
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    • 1993
  • Alkaline phosphatase from Culex pipiens pallens was examined to determine the optimal assay condition and to assay the activity during ovarian development. The activity of alkaline phosphatase in a male and a nongravid female continuously were declined after eclosion. But by the stimulus of a blood meal, the enzyme activity was increased dramatically. At 30 hr. after a blood meal, the maximal activity was reached and then declined. And after 48 hr. after a blood meal, the second activity increase was revealed. This second increase was maintained up to oviposition. The first activity increase was revealed in the midgut and the second increase was done in the ovary to assay the organ distribution of alkaline phosphatase. In electrophresis data, it was shown 5 isozyme bands, ALP-1 and ALP-2 in the ovary, ALP-3 in the thorax and the midgut, and ALP-4 and ALP-5 in the thorax, the fatbody and the midgut in crude extract at 30 hr. after a blood meal. One the same ovary pattern were shown at 72 hr. after a blood meal.

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Production and Properties of Alkaline Pretense from Bacillus sp. Strain in Thermophilic and Alkaline Condition (Bacillus속 AP-5 균주의 고온성 알카리 배양에 따른 Alkaline Pretense의 생성 및 성질)

  • 이광배
    • Journal of environmental and Sanitary engineering
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    • v.5 no.2
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    • pp.103-110
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    • 1990
  • For production of thermophilic and alkaline protease, Bacillus sp. strain AP-5 was isolated from a compost. The production of the protease was reached at maximum for 4 days at $55^{\circ}$ in standing culture. Chitin and Cellulose as carbon source, and Skim Milk as nitrogen source were favorable for the production of the enzyme. Optimal temperature and optimal pH of the enzyme was $55^{\circ}$ and 11, respectively. Metal ion didn't effect on the enzyme activity, the protease was very stable at heat treatment of 30 min at $55^{\circ}$.

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Small Punch Test of TRIP Steel Charged with Hydrogen under Different Electrolyte Condition (다른 전해질분위기에서 수소주입시킨 TRIP강의 SP시험)

  • Kim, Kwang-Sig;Yoo, Kwang-Hyun;Park, Jae-Woo;Kang, Kae-Myung
    • Journal of the Korean Institute of Gas
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    • v.19 no.1
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    • pp.64-70
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    • 2015
  • In order to evaluate the degree of hydrogen embrittlement of TRIP steels charged with hydrogen according to varying the current density and the charging time under acid and alkaline electrolyte conditions were tested by small punch test. The results of SP test showed that the degree of hydrogen embrittlement at acid electrolyte condition was more effective factor compared to that of alkaline electrolyte condition. Therefore, all of the charging time and the charging current density were at the condition of acid electrolyte appeared as the main factor of the degree of hydrogen embrittlement in the condition of acid electrolyte. But, it was considered that the charging time compared to the charging current density at the condition of alkaline electrolyte was more effective factor to raise the degree of hydrogen embrittlement.

Comparing Bioavailability of Cadmium and Arsenic in Agricultural Soil Under Varied pH Condition

  • Oh, Se Jin;Kim, Sung Chul;Ok, Yong Sik;Oh, Seung Min;Lee, Bup Yeol;Lee, Sang Hwan;Yang, Jae E.
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.1
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    • pp.57-63
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    • 2015
  • Bioavailability of cadmium (Cd) and arsenic (As) can be different depending on soil pH. For this reason, main purpose of this research was to compare bioavailability of Cd and As in agricultural field under varied soil pH and different extractants. Bioavailable fraction of Cd and As in soil was extracted with $CaCl_2$, $NaNO_3$, DTPA, EDTA, and low molecular weight organic acids (LMWOAs). Soil samples and cultivated crops were collected at the range of soil pH 4.5-8.5 and correlation analysis was conducted between bioavailable fraction of Cd and As in soil and total concentration of Cd and As in crops. Results showed that concentration of Cd and As in acidic soil was ranged $0.002-0.462mg\;kg^{-1}$ and $0.041-4.903mg\;kg^{-1}$ respectively. In alkaline condition, concentration of Cd and As were ranged $0.006-0.351mg\;kg^{-1}$ and $0.039-2.807mg\;kg^{-1}$ respectively. Comparing bioavailable fraction of Cd and As in acidic and alkaline soil condition, higher concentration was measured in acidic condition. Similarly, higher average concentration of Cd and Asin crops was observed in acidic condition (0.398 and $0.751mg\;kg^{-1}$ respectively) than alkaline condition (0.248 and $0.264mg\;kg^{-1}$). Among different extractants, LMWOAs method showed higher correlation ($r^2=0.545$) for Cd in acidic condition indicating that LMWOAs method could be applied for evaluating bioavailability of Cd in acidic soil. However, no high correlation was observed for As in both acidic and alkaline condition. Overall, bioavailable fraction of Cd and As can be higher in acidic condition of soil than alkaline condition resulting higher uptake of Cd and As from soil to crops. Therefore, efficient best management practice (BMPs) for Cd and As in acidic soil should be conducted for minimizing uptake of Cd and As into crops.

The Investigation on Color Change of Dis-azo Acid Dye in Wool Dyeing (양모섬유의 염색시 디스아조계 산성염료의 변색현상 규명)

  • 김미경;김태경;윤석한;임용진
    • Textile Coloration and Finishing
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    • v.15 no.2
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    • pp.86-92
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    • 2003
  • It is already known that the color of wool fabric dyed with disazo acid dyes could be changed in dyeing process and this is accelerated under alkaline condition. Focus was given to figuring out the mechanism of this color change, through the LC-MS analysis. In this study, no color change was seen in wool fabrics dyed with C. I. Acid Blue 113 under weak acidic, neutral and weak alkaline conditions for 1hour. However, the wool fabrics dyed under weak alkaline condition for a long time over 3 hours fumed reddish orange. When the wool fabrics dyed under weak acidic, neutral and weak alkaline conditions were treated with $0.5g/L\;Na_2C0_3$ solution, all of them turned reddish orange. On the other hand, the color of silk fabrics dyed with C. I. Acid Blue 113 were not changed after the same alkaline treatment. Wool contains cystine and cysteine, whereas silk does not. Due to the reversible reduction/oxidation process of cystine and cysteine in wool dyeing, the C. I. Acid Blue 113 of the dis-azo type is decomposed by reduction and consequently turned them into the reddish orange mono-azo types dye.