• Journal of the Korean Chemical Society
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• v.58 no.4
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• pp.351-358
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• 2014

Anionic (sodium lauryl sulphate, NaLS) cationic (cetyl ammonium bromide, CTAB) and non-ionic (Tween-80) surfactants have been found to inhibit the rate of oxiadation L-proline and L-methionine by alkaline $KMnO_4$. A first order dependence of rate of oxidation was observed with respect to $MnO_4{^-}$. The order of reaction in substrate and alkali was found to be fractional nearby 0.65 and 0.55 in Aminoacid and $OH^-$, respectively. An aggregation/association between $MnO_4{^-}$ and surfactant has been confirmed spectrophotometrically. A mechanism, involving kinetically inactive [$MnO_4{^-}$ surfactant] aggregate and consistent with kinetic data, has been proposed. The effect of surfactants has been discussed in terms of hydrophobic and electrostatic interactions.

• Proceedings of the Korea Concrete Institute Conference
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• 1994.04a
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• pp.163-168
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• 1994

If the concrete is exposed below freezing point of the outer temperature before hardened, the quality of the concrete will be lowered after hardened. Anti-freezing agent which doesn't corrode the steel bar and doesn't generate the alkali-aggregate reaction by noncholride recently developed in Japan and Northern Europe. But the effects of these agents are rarely known. Therefore, this study is desigend for analyzing the freezing properties at the condition of solution of solution and cement paste. And this study aims to present the reference data for practical use of the concrete works using anti-freezing agent.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.141-144
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• 2006

In this study, evaluation of physical and chemical properties of crushed sand was performed to establish optimal mix proportion standard for concrete using crushed sand afterward. Most of properties of crushed sand were satisfied with KS F 2527. Especially, chemical stabilities such as alkali-aggregate reaction were fairly good. However, considerable attention would be required in using crushed sand from lime stone judging from the result that weight loss of it was more than 23.8%. There were some differences in the properties with production region, stone type and capacity of facility, therefore it is thought that quality should be controled by optimal regulations for corresponding items.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.265-266
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• 2009

To know the thermal-moisture condition of the concrete is very important to expect the concrete durability such as chloride attack, carbonation, alkali-aggregate reaction, freezing damage. The purpose of this study is to establish the temperature-moisture coupled model which is based on the finite element method and measure temperature and relative humidity under the exposured condition.

• Proceedings of the Korea Concrete Institute Conference
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• 1995.10a
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• pp.134-138
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• 1995

The reinforced concrcte structure were once belicved to have permanent durability. However, it is now spoiled by durability failure caused by the corrosion of embeded steel reingorcement carbonation. alkali-aggregate reaction and salt attack Recently. salt damage has been also spreading. Salt damage is found in concrete structures built using seasands or certain admixtures containing calcium chlorides and in coastal structures frequently caught in seawater spray or blown by seawind It is the aim of this study to investigate the performance and application of new repair system for the exterior wall according to the durability improvement in the RC structures.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10b
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• pp.1215-1220
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• 2000

Blast-Furnace Slag, a by-product of the iron or steel industry, has potential sa a cementitious material. The addition of a Blast-Furnace Slag generally reduces the heat of hydration and can confer significant improvements in resistance to sulfate attack and alkali-aggregate reaction, as well as increases in ultimate strength. But it also reduces early-age strength. In this study, for the purpose of improvement of early-age quality of Blast-Furnace Slag concrete, we choose blaine fineness of $6, 000~8, 000cm^2/g$ of Blast-Furnace Slag, and investigate the various properties of concrete. As a result, workability and early-age strength of Blast-Furnace Slag concrete were improved according to the increase of blaine fineness of Blast-Furnace Slag.

• Journal of the Mineralogical Society of Korea
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• v.3 no.1
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• pp.18-33
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• 1990

각종 콘크리트 구조물의 기초공사에서 생기는 문제점 외에 시멘트와 골재자체의 반응, 즉 알카리-골재반응에 의한 물리, 화학적인 변화가 구조물에 피해를 주는 일차적인 요인으로 작용된 사례가 최근 10년간 외국에서는 잇달아 보고 되고 있다. 국내산 콘크리트 구조물에 대한 본 연구에 의하면 변성작용을 받은 이축성 석영, 자아석류가 시멘트로부터 공급된 알카리용매에 쉽게 반응, 붕괴되며 조립질보다 세립질 골재에 더 큰 영향이 나타난다. 골재와 시멘트 사이의 반응에 의하여 K, Na, Ca 및 Si 성분이 함량이 높은 부분으로부터 낮은 곳으로 상호 치환 이동되는데 그 과정에서 smectite와 illite같은 점토광물이 반응생성물로 정출된다. 이러한 광물은 구조물 내에서 수분의 흡수와 방출에 의하여 부피의 팽축이 거듭됨으로써 콘크리트 구조물에 심각한 손상을 야기시킨다.

• Advances in concrete construction
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• v.3 no.1
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• pp.39-54
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• 2015

Relative humidity and strains within a massive concrete cylinder (${\varphi}450mm{\times}900mm$) in the drying and the re-saturating process were measured for elucidating the process of ASR surface cracking in concrete. The expansion behavior of mortars in dry atmospheres with various R.H. values and the resaturating process was revealed. Non- or less-expansive layers were formed in near-surface regions in the concrete cylinder in the drying process, but ASR expansions actively progressed in inner portions. After resaturating, R.H. values of near-surface regions rapidly increased with time, but expansions in the regions were found to be very small. However, in the middle portions, of which R.H. values were kept 80% ~ 90% R.H. in the drying process, expansion actively progressed, resulting in further development of surface cracks in the re-saturating process.

• Korean Journal of Agricultural Science
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• v.18 no.1
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• pp.33-40
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• 1991

This study was performed to obtain the basic data applied to use of synthetic lightweight aggregate concrete affected by alkali silica reaction. The results obtained were summarized as follows; 1. The compressive strength of type A concrete was increased with increase of curing age. At the curing age 28 days, the highest compressive strength was showed at type Band C concrete, respectively. But, it was gradually decreased with increase of curing age at those concrete. 2. The flexural strength of type A concrete was increased with increase of curing age. At the curing age 14 days, the highest flexural strength was showed at type Band C concrete, respectively. But, it was gradually decreased with increase of curing age at those concrete. 3. The correlation between compressive and flexural strength of the sample was shown highly significant only at type A concrete. 4. It was shown that the water absorptions of the type Band C were 7.0-7.8 times higher than the type A concrete. It was significantly higher at the early stage of immersed time at all sample. 5. The correlation between compressive strength and water absorption of the sample was significant only at the type A concrete.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.3
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• pp.56-64
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• 2019

Various approaches have been attempted to develop recycling technologies related to industrial waste resources containing metals. Among them, glass is not decomposed into microorganisms, so landfill is not suitable, and interest in the recycling of waste glass is increasing. In this paper, by incorporating chelate resin to suppress the elution of heavy metals in waste glass and using waste glass as a fine aggregate and we want to evaluate the strength, drying shrinkage, alkali-silica reaction and heavy metal leaching of shielded filler materials and to provide basic data for utilizing waste glass as an economical and environmentally friendly shielding filler. As a result of the test, it was found that the use of waste glass as a fine aggregate was effective in the development of strength, but the incorporation of chelate resin had an influence on the strength development. In addition, the addition of chelate resin was effective in improving drying shrinkage but it was found to affect the alkali - silica reaction. As a result of the heavy metal leaching test, the KSLP test method satisfies all the criteria for heavy metal leaching. However, in case of lead, the limit of US ANSI 67-2007a was exceeded and further study should be done.