• Title/Summary/Keyword: Alkali silica reaction

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An Experimental Study on the Alkali-Silica Reaction of Crushed Stones (Part4: The Application of the JIS Rapid Test Method to the Several Domestic Reactive Aggregates) (쇄석골재의 알칼리-실리카 반응에 관한 실험적 연구 (제4보: 국내산 반응성 골재에 JIS 신속법 적용가능성))

  • 차태환;조원기;조일호;노재호;이양수;정재동;윤재환
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.447-450
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    • 1994
  • The chemical method and mortar-bar method for identification of the susceptibility to Alkali-Aggregate Reaction (AAR) was established as KS method by referencing the ASTM methods. However, the chemical method requires skilled chemical engineers and aggregates are tested in very severe condition, and on the other hand, the mortar-bar method needs a long time of 3 or 6 months. Judging from this circumstance that the use of crushed stones are increased due to the shortage of natural aggregates, the development and standardization of a new rapid test method is considered essential. The purpose of this paper is to research for the possibility to apply the rapid method, instead of the chemical method and the mortar-bar method with using the several domestic crushed stones.

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Reaction Characteristics of Kaolinite-based Additives and Alkali Salts (Kaolinite 계열의 첨가제와 알칼리염의 반응 특성)

  • Jun, HyunJi;Choi, Yujin;Shun, Dowon;Han, Keun-Hee;Bae, Dal-Hee;Rhee, Young-Woo
    • Clean Technology
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    • v.26 no.3
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    • pp.221-227
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    • 2020
  • When the waste solid fuel (SRF, Bio-SRF) is burnt in a boiler, a problem occurs in the combustion process involving the alkali components (Na, K) contained in large amounts in the fuel. The alkaline component has a low melting point, which usually forms low melting point salt in the temperature of the furnace, with the resulting low melting point salts attaching to the heat pipe to form a clinker. Various additives are used to suppress clinker generation, and the additive based on the kaolinite has alkali-aluminum-silica to inhibit the clinker. In this study, the reactivity of the additives based on the kaolinite was compared. The additives utilized were R-kaolinite, B-kaolinite, and A-kaolinite. Also silica and MgO were sourced as the comparison group. The experimental group was employed as a laboratory-scale batch horizontal reactor. The additive and alkaline salts were reacted at a weight ratio of 1 : 1, and the reaction temperature was performed at 900 ℃ for 10 hours. The first measurement of HCl occurring during the experiment was performed 30 minutes after the detection tube was used, and the process was repeated every hour after the experiment. After the reaction, solid residues were photographed for characterization analysis by means of an optical microscope. The reaction characteristics of the kaolinite were confirmed based on the analysis results.

Elastic modulus of ASR-affected concrete: An evaluation using Artificial Neural Network

  • Nguyen, Thuc Nhu;Yu, Yang;Li, Jianchun;Gowripalan, Nadarajah;Sirivivatnanon, Vute
    • Computers and Concrete
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    • v.24 no.6
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    • pp.541-553
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    • 2019
  • Alkali-silica reaction (ASR) in concrete can induce degradation in its mechanical properties, leading to compromised serviceability and even loss in load capacity of concrete structures. Compared to other properties, ASR often affects the modulus of elasticity more significantly. Several empirical models have thus been established to estimate elastic modulus reduction based on the ASR expansion only for condition assessment and capacity evaluation of the distressed structures. However, it has been observed from experimental studies in the literature that for any given level of ASR expansion, there are significant variations on the measured modulus of elasticity. In fact, many other factors, such as cement content, reactive aggregate type, exposure condition, additional alkali and concrete strength, have been commonly known in contribution to changes of concrete elastic modulus due to ASR. In this study, an artificial intelligent model using artificial neural network (ANN) is proposed for the first time to provide an innovative approach for evaluation of the elastic modulus of ASR-affected concrete, which is able to take into account contribution of several influence factors. By intelligently fusing multiple information, the proposed ANN model can provide an accurate estimation of the modulus of elasticity, which shows a significant improvement from empirical based models used in current practice. The results also indicate that expansion due to ASR is not the only factor contributing to the stiffness change, and various factors have to be included during the evaluation.

Expansion Properties of Mortar Using Waste Glass and Industrial By-Products (폐유리와 산업부산물을 사용한 모르터의 팽창특성)

  • 박승범;이봉춘
    • Journal of the Korea Concrete Institute
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    • v.14 no.3
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    • pp.440-448
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    • 2002
  • Waste glass has been increased with the development of industry. The utilization of waste glass for concrete can cause the concrete to be cracked and to be weakened due to an expansion by alkali-silica reaction(ASR). In this study, ASR expansion and properties of strength were analyzed in terms of waste glass color(amber, emerald-green), industrial by-products(ground granulated blast-furnace slag, fly ash), and the content of industrial by-products for reducing ASR expansion caused by the waste glass. The possibility of using glass ground as pozzolanic properties was also analyzed. From the result of this study, the pessimum size of waste glass was 2.5∼1.2 mm regardless of waste glass color. And the smaller than 2.5∼1.2 mm waste glass is, the more decreasing expansion of ASR is. Also, the combination of waste glass with industrial by-products have an effect on reducing the expansion and strength loss caused by ASR between the alkali in the cement paste and the silica in the waste glass, and the glass ground of less than 0.075 mm is applicable as a pozzolanic material.

Microstructural Study of Mortar Bar on Akali-Silica Reaction by Means of SEM and EPMA Analysis (알칼리-실리카 반응에 의한 모르타르 봉의 SEM과 EPMA 분석을 통한 미세구조 연구)

  • Jun, Ssang-Sun;Lee, Hyo-Min;Jin, Chi-Sub
    • Journal of the Korea Concrete Institute
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    • v.21 no.4
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    • pp.531-537
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    • 2009
  • In this study alkali reactivity of crushed stone was conducted according to the ASTM C 227 that is traditional mortar bar test, and C 1260 that is accelerated mortar bar test method. The morphology and chemical composition of products formed in mortar bar, 3 years after the mortar bar tests had been performed, were examined using scanning electron microscopy (SEM) with secondary electron imaging (SEI) and electron probe microanalysis (EPMA) with backscattered electron imaging (BSEI). The crushed stone used in this study was not identified as being reactive by ASTM C 227. However, mortar bars exceeded the limit for deleterious expansion in accelerated mortar bar test used KOH solution. The result of SEM (SEI) analysis, after the ASTM C 227 mortar bar test, confirmed that there were no reactive products and evidence of reaction between aggregate particles and cement paste. However, mortar bars exposed to alkali solution (KOH) indicated that crystallized products having rosette morphology were observed in the interior wall of pores. EPMA results of mortar bar by ASTM C 227 indicated that white dots were observed on the surface of particles and these products were identified as Al-ASR gels. It can be considered that the mortar bar by ASTM C 227 started to appear sign of alkali-silica reaction in normal condition. EPMA results of the mortar bar by ASTM C 1260 showed the gel accumulated in the pores and diffused in to the cement matrix through cracks, and gel in the pores were found to be richer in calcium compared to gel in cracks within aggregate particles. In this experimental study, damages to mortar bars due to alkali-silica reaction (ASR) were observed. Due to the increasing needs of crushed stones, it is considered that specifications and guidelines to prevent ASR in new concrete should be developed.

Evaluation for Fundamental Properties of Concrete mixed with Pyroclastic Flow Deposit (화쇄류 퇴적물을 혼입한 콘크리트의 기초특성 평가)

  • Choi, Hyeong-Gil;Kim, Gyu-Yong;Noguchi, Takafumi
    • Journal of the Korea Concrete Institute
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    • v.28 no.1
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    • pp.49-57
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    • 2016
  • The aim of this study was to investigate the fundamental properties of pyroclastic flow deposit (PFD), and evaluate the fresh and strength properties of concrete mixed with PFD by indoor tests. The fresh properties, strength properties, shrinkage properties, and durability of the concrete mixed with PFD were also evaluated by outdoor plant tests. the harmful alkali-silica reaction did not occur by mixing concrete with PFD. ages. Moreover, no difficulty was found to be associated with concrete manufacture in the plant because no change in air contents and noticeable slump loss occurred by mixing concrete with PFD. The strength properties, shrinkage properties, and durability of the concrete mixed with PFD were also compared with those of normal concrete. With a suitable temperature control and curing method of concrete, the concrete mixed with PFD is considered to be useful in the construction material field.

A Case Study for Deterioration due to Alkali-Silica Reaction in the Cement Concrete Pavement (알칼리-실리카 반응에 의한 시멘트 콘크리트 포장 파손 사례)

  • Hong, Seung-Ho;Han, Seung-Hwan;Yun, Kyong-Ku
    • Journal of the Korea Concrete Institute
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    • v.18 no.3 s.93
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    • pp.355-360
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    • 2006
  • The Alkali-Silica Reaction(ASR) may cause a serious failure in the concrete pavements and structures. Several researches in some nations have conducted the continuous studies to prevent failure of the concrete structures by the ASR distress as well as the studies to manifest the mechanism. The researches on the ASR have not been performed affluently in Korea because the distress due to ASR has seldom been reported literarily. In this study, we tried to set up the systematic scheme practically for verifying the cause of distress due to ASR by using the visual inspections in field, the chemical method, petrographic analysis, and Electron Dispersive X-ray Spectrometer(EDX) method of Scanning Electron Microscopy(SEM) in laboratory. The chemical method, petrographic method using SEM, and X-ray method were used to verify the cause of pattern crack on the surface and internal crack in the plain concrete pavement. It can be concluded that the distress of a specific site in plain concrete pavement was mainly due to ASR. The chemical method, the petrographic method and EDX method using SEM may be the effective tools for verifying the cause of AAR distresses.

Evaluation of Mechanical Properties and Alkali-Silica Reaction of High Strength Mortar Using Waste Glass Sand (폐유리 잔골재를 치환한 고강도 모르타르의 역학적 특성 및 알칼리-실리카 반응 평가)

  • Eu, Ha-Min;Kim, Gyu-Yong;Choe, Gyeong-Cheol;Son, Min-Jae;Nam, Jeong-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.528-536
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    • 2020
  • In this study, high strength mortar and normal strength mortar using waste glass sand were evaluated. The main parameters studied were mechanical properties, alkali-silica reaction(ASR) and residual mechanical properties after ASR. As a result of this experiment, it was found that the increase in strength of the mortar has a limitation in improving the slip of the waste glass sand(GS), and rather, it causes a larger ASR. However, the possibility of improving the slip of GS was confirmed by the temporary increase of initial residal compressive and flexural strength of the mortar containing GS after the ASR. Therefore, to improve the slip of GS, the additional research is required, such as modification of the surface of GS and the incorporation of a binder which can increase the strength and makes matrix compact.

A Study on the Chemical Properties and Strength Development of Regional Hwangto (지역별 황토의 화학적 특성 및 강도발현에 관한 연구)

  • Hwang, Hey-Zoo;Kim, Jeong-Gyu;Yang, Jun-Hyuk
    • KIEAE Journal
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    • v.6 no.2
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    • pp.11-18
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    • 2006
  • In this research, Conducting an engineering properties experiment, this study examined basic properties of regional Hwangto. The results of experiments are as followings. 1) This study confirmed that a result of examining lime order for Hwangto and comparison of stimulants, this study confirmed that 28 day's strength promotion is found in case of calcium hydroxide(Ca(OH)2) and calcium chloride(CaCl2) stimulant. Finally, it is known the fact that lime highly improves the weak strength of Hwangtoh. 2) As XRD analysis for proving the strength manifestation principle of Hwangto by regions, CSH figure and CASH figure appeared in each regional Hwangto in all the strength areas. This result could be appeared through hydraulicity from reaction of alkali stimulant and water, and pozzolan reaction(CSH figure) and $Str{\ddot{a}}tlingite$ reaction(CASH figure) by silica (SiO2) ingredient and calcium hydroxide (Ca(OH)2) among ingredients of clay, and alumina(Al2O3). 3) In result of strength analysis, It is knowned that the Gyeongsangdo Hwangto is stronger than the Jeollado Hwangto in reactivity.

Equifield line simulation and ion migration prediction for concrete under 2-D electric field

  • Liu, Chih-Chien;Kuo, Wen-Ten;Huang, Chun-Yao
    • Computers and Concrete
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    • v.12 no.4
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    • pp.431-442
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    • 2013
  • This study attempted to find a proper method applicable to simulating practical equifield lines of two-dimensional Accelerate Lithium Migration Technique (ALMT), and evaluate the feasibility of using the theoretical ion migration model of one-dimensional ALMT to predict the ion migration behavior of two-dimensional ALMT. The result showed that the electrolyte or carbon plate can be used as matrix to draw equifield line graph similar to that by using mortar as matrix. Using electrolyte electrode module for simulation has advantages of simple production, easy measurement, rapidness, and economy. The electrolyte module can be used to simulate the equifield line distribution diagram in practical two-dimensional electrode configuration firstly. Then, several equifield line zones were marked, and several subzones under one-dimensional ALMT were separated from various equifield line zones. The theoretical free content distribution of alkali in concrete under two-dimensional electric field effect could be obtained from duration analysis.