• Title/Summary/Keyword: Alkali activator

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TECHNICAL APPLICATION OF READY MIXED CONCRETE SLUDGE WATER TO CEMENT MATRIX

  • Moon, Han-Young;Shin, Hwa-Cheol
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.555-559
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    • 2001
  • A by-product, waste sludge water produced from ready mixed concrete(remicon) factories may affect our environmental contamination if it is discharged without proper waste disposal. In Korea, all waste sludge water has been recycled in the way of mixing water of remicon, but the quality of the concrete then produced can be deteriorated, so it might cause slump loss or irregular compressive strength. In this study, waste sludge water is divided into two parts, remicon sludge and residual water in order to make it's property more stable. Then, the remicon sludge and high-alkaline residual water were used as admixture and alkali activator respectively. In this paper we research about quality of with remicon sludge and residual water and performed the fundamental properties of cement matrix mixed with remicon sludge and residual water.

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A study on optimum mixing derivation of the enviroment-friendly high performance geopolymer paste (친환경 고성능 지오폴리머 페이스트의 적정배합 도출에 관한 연구)

  • Lee, Kang-Pil;Do, Yun-seok;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.107-110
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    • 2009
  • After inquiring into physical characteristics of using fly ash and alkali solution, it was found that higher pH density is favorable to strength development at early age and the higher the age is, the higher the compressive strength gets. Also, it was found that when there is more addition of activator, the compressive strength is higher. I was shown that more than atmospheric curing, steam curing was favorable for development of compressive strength. When the temperature of curing temperature was higher, most of the compressive strengths were higher. Thus, based on this study, it was understood that environmental-friendly chemically combined concrete using fly ash and alkali solution can be utilized without using cement.

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SEM Analysis Property of Non-cement Light-weight Matrix according to Type and Mixing Ratio of Alkali Activator (알칼리자극제 종류 및 혼입율에 따른 무시멘트 경량 경화체의 SEM분석 특성)

  • Shin, Jin-Hyun;Kim, Tae-Hyun;Lee, Dong-Hoon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.161-162
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    • 2017
  • As the use of cement increases with the development of modern society along with the increase of buildings, environmental pollution intensifies and researches on industrial byproducts are continuing. Research on blast furnace slag and fly ash as industrial byproducts is increasing, and research on industrial byproducts such as polysilicon sludge and paper ash used in this study is increasing. Blast furnace slag, which is one of the industrial byproducts, has been widely studied as a material used with cement. However, in this study, we fabricated lightweight matrix of polysilicon sludge and paper ash replaced based on blast furnace slag, and performed SEM analysis.

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Relationship between Compressive Strength of Geo-polymers and Pre-curing Conditions

  • Kim, Hyunjung;Kim, Yooteak
    • Applied Microscopy
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    • v.43 no.4
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    • pp.155-163
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    • 2013
  • Meta-kaolin (MK) and blast furnace slag (BS) were used as raw materials with NaOH and sodium silicate as alkali activators for making geo-polymers. The compressive strength with respect to the various pre-curing conditions was investigated. In order to improve the recycling rate of BS while still obtaining high compressive strength of the geo-polymers, it was necessary to provide additional CaO to the MK by adding BS. The specimens containing greater amounts of BS can be applied to fields that require high initial compressive strength. Alkali activator(s) are inevitably required to make geo-polymers useful. High temperature pre-curing plays an important role in improving compressive strength in geo-polymers at the early stage of curing. On the other hand, long-term curing produced little to no positive effects and may have even worsened the compressive strength of the geo-polymers because of micro-structural defects through volume expansion by high temperature pre-curing. Therefore, a pre-curing process at a medium range temperature of $50^{\circ}C$ is recommended because a continuous increase in compressive strength during the entire curing period as well as good compressive strength at the early stages can be obtained.

Waste Glass as an Activator in Class-C fly Ash/GGBS based Alkali Activated Material

  • Sasui, Sasui;Kim, Gyu Yong;Lee, Sang Kyu;Son, minjae;Hwang, Eui Chul;Nam, Jeong Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.77-78
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    • 2020
  • An alkaline activator was synthesized by dissolving waste glass powder (WGP) in NaOH-4M solution to explore its effects on the Class-C fly ash (FA) and ground granulated blast furnace slag (GGBS) based alkali-activated material (AAM). The compressive strength and porosity were measured, and (SEM-EDX) were used to study the hydration mechanism and microstructure. Results indicated that the composition of alkali solutions was significant in enhancing the properties of the obtained AAM. As the amount of dissolved WGP increased in alkaline solution, the silicon concentration increased, causing the accelerated reactivity of FA/GGBS to develop Ca-based hydrate gel as the main reaction product in the system, thereby increasing the strength. Further increase in WGP dissolution led to strength loss, which were believed to be due to the excessive water demand of FA/GGBS composites to achieve optimum mixing consistency. Increasing the GGBS proportion in a composite also appeared to improve the strength which contributed to develop C-S-H-type hydration.

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A Study on the Alkali Application of Recycled Aggregates as a Solution to Reduced Intial Intensity of Blast Furnace Slags (고로슬래그의 초기강도 저하 해결방안으로써 순환 잔골재의 알칼리 활용가치에 대한 연구)

  • Kwak, Yong-Jin;Zhao, Yang;Jung, sang-woon;Heo, Young-sun;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.05a
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    • pp.85-86
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    • 2013
  • Weakness of fine powder of blast furnace slags includes the decrease of initial intensity and delay of setting time. To solve this problem, there has been research on the alkali activation to induce hardening using alkaline chemical. However, the use of chemicals is dangerous and not cost effective, which can be solved by using recycled aggregates, one of construction wastes. The role of alkali activator can be substituted by alkali of non-hydrated cement included in recycled aggregates. In this study, the alkaline value of recycled aggregates will be evaluated through the comparison of molarity of sodium hydroxide (NaOH).

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Strength Properties of Alkali-Activated Lightweight Composites with Alkali Activators of Different Types and Amounts (알칼리 자극제의 종류 및 첨가율에 따른 무시멘트 경량 경화체의 강도특성)

  • Lee, Sang-Soo;Kim, Yun-Mi;Park, Sun-Gyu
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.4
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    • pp.301-307
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    • 2014
  • In order to reduce the emission of carbon dioxide($CO_2$), this research use blast furnace slag in concrete manufacture, as 100% replacement of cement. The aim of this study is to investigate the density and strength properties of alkali-activated lightweight composites with alkali activators of different types and different amounts. The bubble for achieving the lightweight of alkali-activated lightweight composites was generated in the reaction between the paper ash and the alkali activators instead of using a foaming agent. Lightweight formed concrete was conducted basic experimental for determining replacement ratio of paper ash. Then, the density and strength were measured according to the types and the contents of the alkali accelerator that can react with the paper ash. As results, the optimum replacement ratio of the paper ash was 5%. The alkali activator containing NaOH 12.5% obtained the lowest weight of $1.13g/cm^3$. Also, compressive strength were relatively high. Therefore, this study demonstrated that alkali accelerator with a certain amount of NaOH can achieve relatively high strength and lightweight alkali-activated lightweight composites.

Strength Development of the Concrete Incorporating Blast Furnace Slag and Recycled Aggregate as Alkali Activator (고로슬래그 미분말과 알칼리 자극재로서 순환골재를 사용하는 콘크리트의 강도발현 특성)

  • Kim, Jun-Ho;Han, Min-Cheol;Han, Cheon-Goo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.2
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    • pp.107-114
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    • 2014
  • The objective of this study is to evaluate the strength development of blast furnace slag concrete in response to the use of recycled aggregate as alkali activator. The influence of the amount of recycled aggregate was evaluated depending on different ratios of replacement for each RFA and RCA to NFA and NCA, respectively. The results indicated that as replacement of RFA and RCA increased, their strength exhibited to be increased. This was due to the fact that the latent hydraulic properties of blast furnace slag was activated by the alkali in recycled aggregates. However, in case of 365-days, it showed lower compressive strength than using NA(natural aggregates) which could be explained as the exhaustively use of alkali containing in RA. The specimens using RA showed about 90% of compressive strength comparing with specimens using NA.

Compressive Strength Properties of Geopolymer Using Power Plant Bottom Ash and NaOH Activator (화력발전소 바텀애쉬와 수산화나트륨 활성화제를 이용해 제작한 지오폴리머의 압축강도 특성)

  • An, Eung-Mo;Cho, Sung-Baek;Lee, Su-Jeong;Miyauchi, Hiroyuki;Kim, Gyu-Yong
    • Korean Journal of Materials Research
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    • v.22 no.2
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    • pp.71-77
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    • 2012
  • When a new bonding agent using coal ash is utilized as a substitute for cement, it has the advantages of offering a reduction in the generation of carbon dioxide and securing the initial mechanical strength such that the agent has attracted strong interest from recycling and eco-friendly construction industries. This study aims to establish the production conditions of new hardening materials using clean bottom ash and an alkali activation process to evaluate the characteristics of newly manufactured hardening materials. The alkali activator for the compression process uses a NaOH solution. This study concentrated on strength development according to the concentration of the NaOH solution, the curing temperature, and the curing time. The highest compressive strength of a compressed body appeared at 61.24MPa after curing at $60^{\circ}C$ for 28 days. This result indicates that a higher curing temperature is required to obtain a higher strength body. Also, the degree of geopolymerization was examined using a scanning electron microscope, revealing a micro-structure consisting of a glass-like matrix and crystalized grains. The microstructures generated from the activation reaction of sodium hydroxide were widely distributed in terms of the factors that exercise an effect on the compressive strength of the geopolymer hardening bodies. The Si/Al ratio of the geopolymer having the maximum strength was about 2.41.