• 제목/요약/키워드: Alkali Activated

검색결과 256건 처리시간 0.024초

Performance of one-part alkali activated recycled ceramic tile/fine soil binders

  • Mawlod, Arass Omer
    • Advances in concrete construction
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    • 제10권4호
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    • pp.311-317
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    • 2020
  • Performance of Sustainable materials continues through using of recycled waste construction materials to minimize the utilization of the natural resources. The cement industry is a major source of CO2 in the atmosphere which is the main cause of global warming. Replacement of OPC with other sustainable cementitious materials has been the most interesting area of researches. This investigation focuses on the properties of alkali-activated mortar with the different replacement ratios of ceramic tile powder (CTP) by fine soil powder (FSP) (0 to 100)% and different molarities of sodium hydroxide concentrations. The experimental program was conducted by examining the compressive strength, water absorption, and water sorptivity. The results showed that the compressive strength of the specimens at age of (28, 56, and 90 days) increases with an increase in the amount of fine soil powder content and decreases at the age of 120 days. Also, minimum water absorption at the age of 90 days was found in the mixes containing 100% fine soil powder. However, fine soil powder replacement had a negative effect on the sorptivity and water absorption values at the age of 120 days. On the other hand, the 12M sodium hydroxide concentration was considered the optimum concentration compared to other concentrations.

Bond properties of steel and sand-coated GFRP bars in Alkali activated cement concrete

  • Tekle, Biruk Hailu;Cui, Yifei;Khennane, Amar
    • Structural Engineering and Mechanics
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    • 제75권1호
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    • pp.123-131
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    • 2020
  • The bond performance of glass fibre reinforced polymer (GFRP) bars and that of steel bars embedded in Alkali Activated Cement (AAC) concrete are analysed and compared using pull-out specimens. The bond failure modes, the average bond strength and the free end bond stress-slip curves are used for comparison. Tepfers' concrete ring model is used to further analyse the splitting failure in ribbed steel bar and GFRP bar specimens. The angle the bond forces make with the bar axis was calculated and used for comparing bond behaviour of ribbed steel bar and GFRP bars in AAC concrete. The results showed that bond failure mode plays a significant role in the comparison of the average bond stress of the specimens at failure. In case of pull-out failure mode, specimens with ribbed steel bars showed a higher bond strength while specimens with GFRP bars showed a higher bond stress in case of splitting failure mode. Comparison of the bond stress-slip curves of ribbed steel bars and GFRP bars depicted that the constant bond stress region at the peak is much smaller in case of GFRP bars than ribbed steel bars indicating a basic bond mechanism difference in GFRP and ribbed steel bars.

양생조건에 따른 레드머드 혼입 알칼리활성화 슬래그 시멘트 모르타르의 강도 및 백화특성 (Strength and Efflorescence Characteristics of Alkali-Activated Slag Cement Mortar with Red Mud according to Curing Conditions)

  • 강석표;황병일
    • 한국건축시공학회지
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    • 제18권3호
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    • pp.267-275
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    • 2018
  • 본 논문은 알칼리활성화 슬래그 레드머드 시멘트의 백화저감을 위한 기초연구로서 다양한 온도 및 습도 조건이 레드머드 혼입 알칼리활성화 슬래그 시멘트의 강도 및 백화에 미치는 영향을 보통 포틀랜트 시멘트와 비교하여 검토하였다. 양생조건에 따른 레드머드 혼입 알칼리활성화 슬래그시멘트의 강도 및 백화특성 검토결과 표준수중양생을 실시한 모르타르는 기건양생, 고온양생, 저온양생과 비교하여 28일 압축강도, 휨강도가 가장 높게 나타났으며 흡수율 및 백화발생면적, $Na^+$용출량은 가장 낮게 나타났다. 따라서 향후 레드머드의 대량 활용을 위한 방안으로서 적정한 양생조건은 수중양생으로 사료된다.

Laboratory investigations on the effects of acid attack on concrete containing portland cement partially replaced with ambient-cured alkali-activated binders

  • Ramagiri, Kruthi K.;Patil, Swaraj;Mundra, Harsh;Kar, Arkamitra
    • Advances in concrete construction
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    • 제10권3호
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    • pp.221-236
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    • 2020
  • To reduce the CO2 emissions associated with the manufacture of portland cement (PC), an efficient alternative like an alkali-activated binder (AAB) is the requirement of the industry. To promote the use of AAB in construction activities, a practically implementable mix proportion is required. Owing to the several raw ingredients of AAB concrete and their associated uncertainties, partial replacement of PC by AAB may be adopted instead of complete replacement as per industrial requirements. Hence, the present study aims to determine an optimal proportion for partial replacement of PC with AAB and recommend a technique for it based on site conditions. Three modes of partial replacement are followed: combining all the dry ingredients for AAB and PC followed by the addition of the requisite liquids (PAM); combining the PC and the AAB concrete in two horizontal layers (PAH); and two vertical layers (PAV). 28-day old specimens are exposed to 10% v/v solutions of HCl, H2SO4, and HNO3 to evaluate changes in mechanical, physical, and microstructural characteristics through compressive strength, corrosion depth, and microscopy. Based on deterioration in strength and integrity, PAH or PAV can be adopted in absence of acid attack, whereas PAM is recommended in presence of acid attack.

Alkali-activated GGBS and enzyme on the swelling properties of sulfate bearing soil

  • Thomas, Ansu;Tripathia, R.K.;Yadu, L.K.
    • Geomechanics and Engineering
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    • 제19권1호
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    • pp.21-28
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    • 2019
  • Use of cement in stabilizing the sulfate-bearing clay soils forms ettringite/ thaumasite in the presence of moisture leads to excessive swelling and causes damages to structures built on them. The development and use of non-traditional stabilisers such as alkali activated ground granulated blast-furnace slag (AGGBS) and enzyme for soil stabilisation is recommended because of its lower cost and the non detrimental effects on the environment. The objective of the study is to investigate the effectiveness of AGGBS and enzyme on improving the volume change properties of sulfate bearing soil as compared to ordinary Portland cement (OPC). The soil for present study has been collected from Tilda, Chhattisgarh, India and 5000 ppm of sodium sulfate has been added. Various dosages of the selected stabilizers have been used and the effect on plasticity index, differential swell index and swelling pressure has been evaluated. XRD, SEM and EDX were also done on the untreated and treated soil for identifying the mineralogical and microstructural changes. The tests results show that the AGGBS and enzyme treated soil reduces swelling and plasticity characteristics whereas OPC treated soil shows an increase in swelling behaviour. It is observed that the swell pressure of the OPC-treated sulfate bearing soil became 1.5 times higher than that of the OPC treated non-sulfate soil.

Thermomechanical behavior of alkali-activated slag/fly ash composites with PVA fibers exposed to elevated temperatures

  • Kim, J.S.;Lee, H.K.
    • Advances in concrete construction
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    • 제11권1호
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    • pp.11-18
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    • 2021
  • The present study fabricated polyvinyl alcohol (PVA) fiber-reinforced alkali-activated slag/fly ash (AASF) composites with varying mixture ratios of slag and fly ash. The thermomechanical behaviors of the AASF composites exposed to 200, 400, 600, or 800℃ were evaluated by means of compressive strength test, visual observation, and fire resistance tests. X-ray diffractometry, mercury intrusion porosimetry, and thermogravimetry tests were performed to analyze the microstructure change of the AASF composites upon exposure to high temperatures. Specimens exhibited a gradual strength loss up to 600℃, while also showing a significant decrease in the strength above 600℃. The fire resistance test revealed the occurrence of an inflection point as indicated by an increase in the internal temperature at around 200℃. In addition, specimens showed the dehydration of C-S-H gel, the presence of åkermanite, gehlenite, and anorthite upon exposure to 800℃, which is associated with the formation of macropore population with pores having diameters of 1-3 ㎛ and 20-40 ㎛. Visual observation indicated that the PVA fibers mitigated the cracking and/or spalling of the specimens upon exposure to 800℃.

Use of waste glass as an aggregate in GGBS based alkali activated mortar

  • Sasui, Sasui;Kim, Gyu Yong;Son, Min Jae;Pyeon, Su Jeong;Suh, Dong Kyun;Nam, Jeong Soo
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 가을 학술논문 발표대회
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    • pp.21-22
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    • 2021
  • This study incorporates fine waste glass (GS) as a replacement for natural sand (NS) in ground granulated blast furnace slag (GGBS) based alkali activated mortar (AAm). Tests were conducted on the AAm to determine the mechanical properties, apparent porosity and the durability based on its resistance to Na2SO4 5% and H2SO4 2% concentrated solutions. The study revealed that increasing GS up to 100 wt%, increased strength and decreased porosity. The lower porosity attained with the incorporation of GS, improved the resistance of mortar to Na2SO4 and thus increasing durability. However, the durability of mortar to H2SO4 solution was negatively impacted with the further reduction of porosity observed with increasing GS above 50 wt.% believed to be caused by the stress induced as a result of expansive reaction products created when the mortar reacted with acid.

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Red mud와 제지회를 혼합한 CLSM의 적정 혼합비 산정 (The Estimation of Optimal Mixing Ratio of CLSM Mixed with Red Mud and Paper Sludge Ash)

  • 노성오;김태연;이봉직
    • 한국지반환경공학회 논문집
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    • 제23권4호
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    • pp.21-27
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    • 2022
  • 최근 GGBS 및 Fly ash 등과 같은 산업부산물과 알칼리 자극제를 활용한 알칼리 활성화 시멘트에 대한 연구가 활발히 진행되고 있다. 알칼리 활성화 시멘트는 산업부산물에 알칼리 자극제를 혼합함으로 시멘트를 사용하지 않고 강도를 발휘하는 결합재의 일종으로 대표적인 탄소저감 기술이나, 알칼리 활성화를 위해 사용되는 알칼리 자극제는 고가이며 강알칼리성으로 인한 위험성으로 현장적용에 여러 어려움이 있다. 이에 본 연구에서는 알칼리 자극제의 대체재로 Red mud의 활용방안을 모색하고자 Red mud와 제지회를 결합재로 활용한 CLSM의 유동특성, 강도특성 등의 공학적 특성과 토양오염 발생가능성을 평가하였으며, Red mud와 제지회를 혼합한 CLSM의 적정 혼합비를 제시하였다.

알칼리 활성화제 혼합비가 플라이애시 모르타르에 미치는 영향 (The Effect on the Alkali-Activator Mixture Ratio of fly Ash Mortar)

  • 강현진;강수태;고경택;류금성;박정준;이장화
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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    • pp.395-396
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    • 2009
  • 본 연구는 플라이애시 100% 사용 알칼리 활성 모르타르에 대하여 알칼리 활성화제의 혼합비율이 유동성 및 압축강도에 미치는 영향을 검토하는데 목적이 있다.

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알카리활성 슬래그 콘크리트의 동결융해 저항성 (Resistance to Freezing and Thawing of Alkali-Activated Slag Concrete)

  • 문재성;조아람;심재일;양근혁
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 추계 학술논문 발표대회
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    • pp.105-106
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    • 2011
  • The present tests examined the resistance to freezing and thawing of alkail-activated (AA) slag concrete having compressive strength between 30~56 MPa. To enhance the compressive strength and resistance to freezing and thawing of AA slag concrete, Na ions were used for an activator. Test results revealed that the resistance to freezing and thawing of AA slag concrete is comparable to that of cement concrete when compressive strength is more than 50 MPa.

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