• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 하계학술대회 논문집 C
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• pp.1628-1630
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• 2000

Vertically aligned multiwalled carbon nanotubes are grown on silicon oxide substrate at 950$^{\circ}C$ by thermal chemical vapor deposition using $C_{2}H_2$. Three catalytic metals such as iron(Fe), cobalt (Co), and nickel(Ni) are used as catalyst, we found that the growth rate of carbon nanotubes for three catalyst particles are in an order of Fe > Ni > Co. All carbon nanotubes are revealed to have bamboo structure with no encapsulated catalytic particles, the diameter of carbon nanotubes depend on the catalyst, the tip and the compartment sheets of bamboo structure also depend on the shape of catalytic particles.

• 한국전기전자재료학회논문지
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• 제21권5호
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• pp.402-410
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• 2008

Single-walled carbon nanotubes (SWCNTs) were currently produced together with some contaminants such as a metallic catalyst, amorphous carbon, and graphitic nanoparticles, which should be sometimes purified for their applications. This study aimed to develop efficient, scalable purification processes but less harmful to SWCNTs. We designed three-step purification processes: acidic treatment, surface functionalization and soxhlet extraction, and heat treatment. During the soxhlet extraction using tetrahydrofuran, specifically, carbon impurities could be easily expelled through a glass thimble filter without any significant loss of CNTs. Finally, SWCNTs were left as a bulky paper on the filter through membrane filtration. Vertically aligned SWCNTs on one side of bulky paper were well developed in a speparation from the filter paper, which were formed by being sucked through the filter pores during the pressurized filtration. The bucky paper showed a very high peak current density of field emission up to $200\;mA/cm^2$ and uniform field emission images on phosphor, which seems very promising to be applied to vacuum microelectronics such as microwave power amplifiers and x-ray sources.

• 대한기계학회논문집B
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• 제37권6호
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• pp.615-620
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• 2013

이전 연구에서 우리는 나노구조와 화학연료의 동축 구조를 제작하여 이를 점화시켰을 때, 축방향으로 매우 빠르게 화학 반응이 전파되며, 이와 동시에 높은 비출력을 가지는 화학-전기 에너지를 생성할 수 있음을 증명하였으며, 이러한 현상을 열동력 파도로 명명하였다. 본 연구에서는 열동력 파도와 관련된 여러가지 물리적인 현상을 심도있게 다루려 한다. 나노구조의 다른 배열 상태에 따라 반응 전파속도, 에너지 생성 정도가 어떻게 달라지는지, 그리고 이와 동시에 발생하는 전기 신호와는 어떤 연관 관계가 있는 지를 연구하였다. 또한 이론적으로 온도 변화에 따라 달라지는 나노튜브와 화학연료의 성질, 대류와 복사에 의한 영향을 고려했을 때 열동력 파도의 전파 양상이 어떻게 달라지는 지를 규명하였다.

• E2M - 전기 전자와 첨단 소재
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• 제12권7호
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• pp.7-11
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• 1999

Fully sealed field emission display in size of 4.5 inch has been fabricated using single-wall carbon nanotubes-organic vehicle com-posite. The fabricated display were fully scalable at low temperature below 415$^{\circ}C$ and CNTs were vertically aligned using paste squeeze and surface rubbing techniques. The turn-on fields of 1V/${\mu}{\textrm}{m}$ and field emis-sion current of 1.5mA at 3V/${\mu}{\textrm}{m}$ (J=90${\mu}{\textrm}{m}$/$\textrm{cm}^2$)were observed. Brightness of 1800cd/$m^2$ at 3.7V/${\mu}{\textrm}{m}$ was observed on the entire area of 4.5-inch panel from the green phosphor-ITO glass. The fluctuation of the current was found to be about 7% over a 4.5-inch cath-ode area. This reliable result enables us to produce large area full-color flat panel dis-play in the near future. Carbon nanotubes (CNTs) have attracted much attention because of their unique elec-trical properties and their potential applica-tions [1, 2]. Large aspect ratio of CNTs together with high chemical stability. ther-mal conductivity, and high mechanical strength are advantageous for applications to the field emitter [3]. Several results have been reported on the field emissions from multi-walled nanotubes (MWNTs) and single-walled nanotubes (SWNTs) grown from arc discharge [4, 5]. De Heer et al. have reported the field emission from nan-otubes aligned by the suspension-filtering method. This approach is too difficult to be fully adopted in integration process. Recently, there have been efforts to make applications to field emission devices using nanotubes. Saito et al. demonstrated a car-bon nanotube-based lamp, which was oper-ated at high voltage (10KV) [8]. Aproto-type diode structure was tested by the size of 100mm $\times$ 10mm in vacuum chamber [9]. the difficulties arise from the arrangement of vertically aligned nanotubes after the growth. Recently vertically aligned carbon nanotubes have been synthesized using plasma-enhanced chemical vapor deposition(CVD) [6, 7]. Yet, control of a large area synthesis is still not easily accessible with such approaches. Here we report integra-tion processes of fully sealed 4.5-inch CNT-field emission displays (FEDs). Low turn-on voltage with high brightness, and stabili-ty clearly demonstrate the potential applica-bility of carbon nanotubes to full color dis-plays in near future. For flat panel display in a large area, car-bon nanotubes-based field emitters were fabricated by using nanotubes-organic vehi-cles. The purified SWNTs, which were syn-thesized by dc arc discharge, were dispersed in iso propyl alcohol, and then mixed with on organic binder. The paste of well-dis-persed carbon nanotubes was squeezed onto the metal-patterned sodalime glass throuhg the metal mesh of 20${\mu}{\textrm}{m}$ in size and subse-quently heat-treated in order to remove the organic binder. The insulating spacers in thickness of 200${\mu}{\textrm}{m}$ are inserted between the lower and upper glasses. The Y\ulcornerO\ulcornerS:Eu, ZnS:Cu, Al, and ZnS:Ag, Cl, phosphors are electrically deposited on the upper glass for red, green, and blue colors, respectively. The typical sizes of each phosphor are 2~3 micron. The assembled structure was sealed in an atmosphere of highly purified Ar gas by means of a glass frit. The display plate was evacuated down to the pressure level of 1$\times$10\ulcorner Torr. Three non-evaporable getters of Ti-Zr-V-Fe were activated during the final heat-exhausting procedure. Finally, the active area of 4.5-inch panel with fully sealed carbon nanotubes was pro-duced. Emission currents were character-ized by the DC-mode and pulse-modulating mode at the voltage up to 800 volts. The brightness of field emission was measured by the Luminance calorimeter (BM-7, Topcon).

• Computers and Concrete
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• 제26권3호
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• pp.213-226
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• 2020

The present study covenants with the static and free vibration behavior of nanocomposite sandwich plates reinforced by carbon nanotubes resting on Pasternak elastic foundation. Uniformly distributed (UD-CNT) and functionally graded (FG-CNT) distributions of aligned carbon nanotube are considered for two types of sandwich plates such as, the face sheet reinforced and homogeneous core and the homogeneous face sheet and reinforced core. Based on the first shear deformation theory (FSDT), the Hamilton's principle is employed to derive the mathematical models. The obtained solutions are numerically validated by comparison with some available cases in the literature. The elastic foundation model is assumed as one parameter Winkler - Pasternak foundation. A parametric study is conducted to study the effects of aspect ratios, foundation parameters, carbon nanotube volume fraction, types of reinforcement, core-to-face sheet thickness ratio and types of loads acting on the bending and free vibration analyses. It is explicitly shown that the (FG-CNT) face sheet reinforced sandwich plate has a high resistance against deflections compared to other types of reinforcement. It is also revealed that the reduction in the dimensionless natural frequency is most pronounced in core reinforced sandwich plate.

• Computers and Concrete
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• 제32권1호
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• pp.75-85
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• 2023

This work utilizes simplified higher-order shear deformation beam theory (HSDBT) to investigate the vibration response for functionally graded carbon nanotube-reinforced composite (CNTRC) beam. Novel to this work, single-walled carbon nanotubes (SWCNTs) are distributed and aligned in a matrix of polymer throughout the beam, resting on a viscoelastic foundation. Four un-similar patterns of reinforcement distribution functions are investigated for the CNTRC beam. Porosity is another consideration taken into account due to its significant effect on functionally graded materials (FGMs) properties. Three types of uneven porosity distributions are studied in this study. The damping coefficient and Winkler's and Pasternak's parameters are considered in investigating the viscosity effect on the foundation. Moreover, the impact of different parameters on the vibration of the CNTRC beam supported by a viscoelastic foundation is discussed. A comparison to other works is made to validate numerical results in addition to analytical discussions. The findings indicate that incorporating a damping coefficient can improve the vibration performance, especially when the spring constant factors are raised. Additionally, it has been noted that the fundamental frequency of a beam increases as the porosity coefficient increases, indicating that porosity may have a significant impact on the vibrational characteristics of beams.

• 대한기계학회논문집A
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• 제37권2호
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• pp.153-160
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• 2013

고무 혼합물의 가류특성 및 전자석 장치를 이용하여 범용고무를 기지로 하는 이방성 자기유동 고무 복합재료(MRRC)의 제조가 가능하였다. 철 입자(IP) 함유량의 증가에 따라 MRRC의 자기 투과율은 증가하였으며, 불규칙 배향에 비해 2 tesla로 배향시킨 경우가 1.8~2배 높게 나타났다. 2 tesla로 배향한 CNT만 강화한 MRRC의 자기 투과율은 3.7%로 자기장의 영향이 뚜렷이 확인되었다. IP 90 + CNT 5 & 2 tesla 배향의 MRRC는 압축시험 시 0.49 tesla의 자기장 하에서 압축응력이 기지에 비해 2.1배 증가하였다. IP 함유량 증가에 따라 자기유동(MR) 효과는 증가하였으며, IP 90 & 2 tesla 배향의 경우 20.4%의 MR 효과를 보였다. 시험편 제조 시 및 압축시험 시 부여한 자기력 세기가 MRRC의 압축특성에 미치는 영향이 크다고 판단된다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 하계학술대회 논문집
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• pp.418-418
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• 2009

Vertically aligned arrays of multi-walled carbon nanotube (MWCNT) on layered Si substrates have been synthesized by water-assisted thermal chemical vapor deposition (CVD). We studied changes in growth by parameters of growth temperature, growth time, rates of gas and annealing time of catalyst. Also, We grew CNTs by adding a little amount of water vapor to enhance the growth of CNTs. $H_2$, Ar, and $C_2H_2$ were used as carrier gas and feedstock, respectively. Before growth, Fe served as catalyst, underneath which AI were coated as an underlayer and a diffusion barrier, respectively, on the Si substrate. The water vapor had a greater effect on the growth of CNTs on a smaller thickness of catalyst. When the water vapor was introduced, the growth of CNTs was enhanced than without water. CNTs grew 1.29 mm for 10 min long by adding the water vapor, while CNTs were 0.73 mm long without water vapor for the same period of time. CNTs grew up to 1.97 mm for 30 min prior to growth termination under adding water vapor. As-grown CNTs were characterized by using scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), and Raman spectroscopy.

• 한국전기전자재료학회논문지
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• 제15권4호
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• pp.367-372
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• 2002

The vertically well-aligned carbon nanotubes(CNTs) were successfully grown on Ni coated silicon wafer substrate by DC bias-assisted PECVD(Plasma Enhanced Chemical Vapor Deposition). As a catalyst, Ni thin film of thickness ranging from 15~30nm was prepared by electron beam evaporator method. In order to find the optimum growth condition, the type of gas mixture such as $C_2H_2-NH_3$ was systematically investigated by adjusting the gas mixing ratio at $570^{\circ}C$ under 0.4Torr. The diameter of the grown CNTs was 40~200nm and the diameter of the CNTs increased with increasing the Ni particles size. TEM images clearly showed carbon nanotubes to be multiwalled. The measured turn-on field was $3.9V/\mu\textrm{m}$ and an emission current of $1.4{\times}10^4A/\textrm{cm}^2$ was $7V/\mu\textrm{m}$. The CNTs grown by bias-assisted PECVD was able to demonstrate high quality in terms of vertical alignment, crystallization of graphite and the processing technique at low temperature of $570^{\circ}C$ and this can be applied for the emitter tip of FEDs.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.313-313
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• 2016

Transparent conductive oxide (TCO) films have many disadvantages, such as rarity, possible exhaustion, process temperature limitations, and brittleness on a flexible substrate. In particular, as display technology moves toward flexible displays, TCO will become completely unsuitable due to its brittleness. To address theses issue, many researchers have been studying TCO substitutes. In recent efforts, metal nanowires, conducting polymers, carbon nanotube networks, graphene films, hybrid thin films, and metal meshes/grids have been evaluated as candidates to replace TCO electrodes. In this study, we fabricated the TCO film with Ag meshes shape using polystyrene (PS) beads monolayer on the substrate. The PS beads were used as a template to create the mesh pattern. We fabricated the monolayer on the flexible substrate (PES) with the well-aligned PS beads. Electrodes with Ag mesh shape were formed using this patterned monolayer. We could fabricated the Ag mesh electrode with the sheet resistance with $8ohm{\Omega}/{\Box}$.