• Title/Summary/Keyword: Al-species

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Changes in the Removal Efficiency of Total Phosphorus by the Basicity of Al(III) Coagulant (Al(III) 응집제의 염기도에 따른 총인 제거효율의 변화)

  • Han, Seung-Woo;Lee, Chul-Hee;Lee, Jae-Kwan;Kang, Lim-Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.2
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    • pp.229-236
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    • 2012
  • The analysis of Al (III) hydrolysis species with PACls prepared by different basicity showed that mononmeric Al species were reduced while precipitate Al species were increased with an increase in basicity for PACls. In the case of the PACl with 13.6% basicity, monomeric Al species were 81%, polymeric Al (III) species 19%, precipitate Al (III) species was 0%, as showing the dominant monomeric Al species. The PACl with 13.6% basicity showed above 80% of turbidity removal efficiency without any restabilization. In addition, the PACl with 13.6% basicity showed higher organic removal expressed by $UV_{254}$ which was caused by lower coagulation pH. The PACl containing the higher amount of monomeric Al species was the most beneficial for T-P and $PO_{4}-P$ removal.

Removal Mechanism of Phosphorus in Wastewater Effluent using Coagulation Process (응집공정을 이용한 하수처리수 중의 인 제거 Mechanism)

  • Han, Seung-Woo;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.8
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    • pp.774-779
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    • 2010
  • The experimental results for the analysis of aluminum hydrolysis species with PACls (polyaluminum chloride) prepared by different basicity (r value) showed that monomeric Al species were reduced while polymeric Al species were increased with an increase in basicity for PACls. The PACl with 2.2 of r value contained the highest amount of polymeric Al species. According to the experimental results for the phosphorus removal, the alum and PACl (r=0), which consisted of mainly monomeric Al species, were the most effective for phosphorus removal. Therefore, it was concluded that the Al coagulant containing higher amount of monomeric or lower molecular Al species would be more beneficial for phosphorus removal.

Comparison of the characteristics of Al(III) hydrolyzed species by improved ferron assay test (개선된 Ferron 분석 비교를 통한 Al(III) 가수분해종 특성 연구)

  • Yoon, Mihyoung;Kang, Limseok
    • Journal of Korean Society of Water and Wastewater
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    • v.36 no.3
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    • pp.177-186
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    • 2022
  • In this study, newly improved Ferron assay test haved on timed spectrometry was used for the determination of hyolrolytic Al species presented in PACl coagulant. The color development reagent ferron was prepared by using conventional method and two newly developed methods. Then the ferron assay test was used to compare and analyze the distribution of Al(III) hydrolyzed species presented in the prepared PACl and alum. The preparing method of reagent A required an aging period of 7 days by adding a hydroxylamine hydroxide and a 1,10-phenanthroline monohydrate reagent, whereas the preparing method of reagent B was used as a coloring agent immediately without aging time. The regression analysis between UV absorbance and Al concentrations of conventional method and newly developed method of ferron reagents in low-concentration aluminum solutions and high-concentration aluminum solutions, showed the correlation coefficients of 0.999 or higher, as showing high correlations of conventional method and newly developed method. Applying Ferron assay test, Al species in the PACls and alum were classified as Ala(monomeric Al), Alb (polymeric Al), and Alc (colloidal and precipitated Al). Distribution of Al(III) hydrolyzed species according to the preparation of ferron colorimetric reagents was similar.

Four newly recorded species of the genus Exochus (Hymenoptera: Ichneumonidae: Metopiinae) from South Korea

  • Choi, Jin-Kyung;Lee, Jong-Wook
    • Journal of Species Research
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    • v.10 no.4
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    • pp.412-418
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    • 2021
  • Four species of the genus Exochus belonging to the subfamily Metopiinae, family Ichneumonidae, are reported in South Korea for the first time. The subfamily Metopiinae was recorded by Förster in 1869 based on genus Metopius and more than 870 described species have been reported worldwide. Among the genera of Metopiinae, genus Exochus is the largest, which is cosmopolitan and comprises more than 290 described species worldwide (Choi et al., 2016; Yu et al., 2016). A taxonomic study of South Korean Exochus was initiated by Choi et al. (2014), who reported four species. Until now, 10 species have been described as new species and 25 species were recorded as new records of this genus from South Korea (Choi et al., 2014, 2016). In the present study, the following four species are reported in South Korea: Exochus latiareolus Tolkanitz, 2003, E. ornatus Momoi & Kusigemati, 1970, E. pictus Holmgren, 1858, and E. yasumatsui Momoi, Kusigemati & Nakanishi, 1968. In addition, we provide the diagnoses of these four species along with diagnostic photographs.

Electron Spin Resonance Study of Manganese Ion Species Incorporated into Novel Aluminosilicate Nanospheres with Solid Core/Mesoporous Shell Structure

  • Back, Gern-Ho;Kim, Ki-Yub;Kim, Yun-Kyung;Yu, Jong-Sung
    • Journal of the Korean Magnetic Resonance Society
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    • v.14 no.2
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    • pp.55-75
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    • 2010
  • An ion-exchanged reaction of $MnCl_2$ with Al-incorporated solid core/mesoporous shell silica (AlSCMS) followed by calcinations generated manganese species, where average oxidation state of manganese ion is 3+, in the mesoporous materials. Dehydration results in the formation of $Mn^{2+}$ ion species, which can be characterized by electron spin resonance (ESR). The chemical environments of the manganese centers in Mn-AlSCMS were investigated by diffuse reflectance, UV-VIS and ESR spectroscopic methods. Upon drying at 323 K, part of manganese is oxidized to higher oxidation state ($Mn^{3+}$ and $Mn^{4+}$) and further increase in (average) oxidation state takes place upon calcinations at 823 K. It was found that the manganese species on the wall of the Mn-AlSCMS were transformed to tetrahedral $Mn^{3+}$ or $Mn^{4+}$ and further changed to square pyramid by additional coordination to water molecules upon hydration. The oxidized $Mn^{3+}$ or $Mn^{4+}$ species on the surfaces were reversibly reduced to $Mn^{2+}$ or $Mn^{3+}$ species or lower valances by thermal process. Mn(II) species I with a well resolved sextet was observed in calcined, hydrated Mn-AlSCMS, while Mn (II) species II with g = 5.1 and 3.2 observed in dehydrated Mn-AlSCMS. Both species I and II are considered to be non-framework Mn(II).

Characteristic of Al(III) Hydrosis Species at Rapid Mixing Condition (급속흔화조건에서 AI(III) 가수분해종의 분포특성)

  • Jung, Chul-Woo;Son, Jung-Gi;Shon, In-Shik;Kang, Lim-Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.2
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    • pp.128-136
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    • 2004
  • The overall objective of this research was to find out the role of rapid mixing conditions in the species of hydrolyzed Al(III) formed by different Al(III) coagulants. When an Al(III) salt is added to water, monomers, polymers, or solid precipitates may form. Different Al(III) coagulants (alum and PACl) show to have different Al species distribution over a rapid mixing condition. During the rapid mixing period, for alum, formation of dissolved Al(III) (monomer and polymer) increases, but for PACl, precipitates of $Al(OH)_{3(s)}$. increases rapidly. Also, for alum, higher mixing speed favoured Al(III) polymers formation over precipitates of $Al(OH)_{3(s)}$ but for PACl, higher mixing speed formed more precipitates of $Al(OH)_{3(s)}$. At A/D and sweep condition, both $Al(OH)_{3(s)}$ and dissolved Al(III) (monomer and polymer) exist, concurrent reactions by both mechanism appear to cause simultaneous precipitation.

Taxonomical Review of the Korean Labroidei (Teleostei: Perciformes) (한국산 놀래기과 어류의 분류학적 검토)

  • Kim, Byung-Jik
    • Korean Journal of Ichthyology
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    • v.21 no.sup1
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    • pp.74-74
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    • 2009
  • The perciform suborder Labroidei comprising six families (Cichlidae, Embiotocidae, Pomacentridae, Labridae, Odacidae, and Scaridae) are characterized by having the specialized pharyngeal jaws for food processing, i.e., united fifth ceratobranchials and upper pharyngeal jaw articulating with the basicranium via diarthroses (Stiassny and Jensen, 1987). They usually inhabit in the most tropical and subtropical seas and comprise about 235 genera and roughly 2,274 species worldwide (Nelson, 2006). Concerning the Korean labroid fishes, Mori (1952) had listed 18 genera and 26 species belong to four families in his check list of Korean fishes since Jordan and Metz (1913) firstly reported six genera and seven species in only two families (Embiotocidae and Labridae). Chyung (1977) added two species, Tilapia mossambica and Cirrhilabrus temmincki, to Mori’s list and also classified them into three suborders, i.e., Embiotocina (containing only Embiotocidae), Pomacentrina (Cichlidae and Pomacentridae), and Labrina (Labridae and Scaridae). Subsequently, Lee and Kim (1996) reviewed the Korean labroidfishes taxonomically resulting in 22 genera and 32 species in five families with some taxonomical modifications including a new Korean record. It is remarkable to be added many new Korean recordsto the pomacentrids or the labrids for recent 10 years (Koh et al., 1995; Yoo et al., 1995; Koh et al., 1997; Myoung, 1997; Choi and Kim, 2000; Choi et al., 2002; Kim and Go, 2003). Recently, Kim et al. (2005) briefly described all members of the Korean Labroidei with a color photograph or a figure, recognizing 27 genera and 42 species in five families. In the present study, the current taxonomical status of the Korean labroid fishes including distributional features is summarized based both on specimens collected from the Korean waters and on literature survey to provide bio-information of the Korean native fish species. As a result, the Korean labroid fishes totally consist of 27 genera and 44 species in five families, that is, Cichlidae (1 species), Embiotocidae (3), Pomacentridae (15), Labridae (22), and Scaridae (2). They distributed mainly in the coastal waters of the South Sea, Korea, however, most pomacentrids or labrids occur in the coastal waters of Jeju Island only, although some species were observed in their larval or juvenile stages only from coastal waters of the island. Interestingly, several species are expanding their distribution north to Ulreung and Dok islands in the East Sea, Korea lately.

Taxonomy of four scuticociliates(Protozoa: Ciliophora) from coastal waters of South Korea

  • Jung, Jae-Ho
    • Journal of Species Research
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    • v.10 no.2
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    • pp.184-190
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    • 2021
  • The diversity of scuticociliates (subclass Scuticociliatia Small, 1967) had previously been superficially investigated in Korea and only 10 species were reported according to the National Species List of Korea published in 2019. Here, we identify four scuticociliates, collected from three coastal water samples, by observing protargol-impregnated specimens. As a result, the present species belong to the order Pleuronematida Fauré-Fremiet in Corliss, 1956 and their lower taxonomic classifications are as follows: family Eurystomatellidae Miao et al., 2010 - Eurystomatella sinica Miao et al., 2010; family Pleuronematidae Kent, 1881 - Pleuronema grolierei Wang et al., 2008, P. setigerum Calkins, 1902, and Schizocalyptra aeschtae Long et al., 2007. The family Eurystomatellidae and the genus Schizocalyptra Dragesco, 1968 are reported for the first time in Korea. Considering that the scuticociliates are a species-rich group and very common in most habitats(including freshwater and terrestrial habitats), our findings indicate that we are far from understanding the complete diversity of Korean scuticociliates.

Comparison of Al(III) and Fe(III) Coagulants for Improving Coagulation Effectiveness in Water Treatment (정수처리 응집효율 개선을 위한 Al(III)염과 Fe(III)염 응집제의 비교)

  • Han, Seung woo;Kang, Lim seok
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.6
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    • pp.325-331
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    • 2015
  • The experimental results of the characteristics of aluminum based and ferric based coagulants for the Nakdong River water showed that the main hydrolysis species contained in alum and $FeCl_3$ are monomeric species of 98% and 93.3%, respectively. The PACl of r=1.2 produced by the addition of base contained 31.2% of polymeric Al species and the PACl of r=2.2 contained 85.0% of polymeric Al species, as showing more polymeric Al species with increasing r value. Coagulation tests using Al(III) and Fe(III) salts coagulants for the Nakdong River water showed that the coagulation effectiveness of turbidity and organic matter was high in the order of $FeCl_3$ > PACl (r=2.2) > PACl (r=1.2) > alum. $FeCl_3$ has showed better flocculation efficiency than Al(III) salts coagulants. In addition, in case of Al(III) coagulants, the Al(III) coagulants of higher basicity, which contained more polymeric Al species, resulted in better coagulation efficiency for both turbidity and organic matter removed. The optimum pH range for all of the coagulants investigated was around pH 7.0 under the experimental pH range of 4.0~9.5. Especially, the highest basicity PACl (r=2.2) and $FeCl_3$ were considered as more appropriate coagulants for the removal of turbidity in the case of raw water exhibiting higher pH.

Description of a new species of the genus Venturia Schrottky (Hymenoptera: Ichneumonidae: Campopleginae) from South Korea

  • Choi, Jin-Kyung
    • Journal of Species Research
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    • v.11 no.2
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    • pp.128-131
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    • 2022
  • A new species, Venturia tenuiabdominalis Choi sp. nov., belonging to the subfamily Campopleginae, family Ichneumonidae, is described in South Korea. The subfamily Campopleginae was recorded by Forster in 1869 based on genus Campoplex and more than 2,100 described species into 66 genera have been reported worldwide. Among the 66 genera of Campopleginae, the genus Venturia is one of the large groups, which is more than 140 species worldwide (Yu et al., 2016; Vas, 2019a; 2019b; Vas, 2020; Vas and Di Giovanni, 2020; Han et al., 2021). A taxonomic study of South Korean Venturia was initiated by Choi et al. (2012), who reported Venturia longipropodeum (Uchida, 1942). A key to species of South Korean Venturia, description of new species and diagnostic illustrations are provided.