• Title/Summary/Keyword: Al-Si

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Thermoelectric Properties of AlN-doped SiC Ceramics (AlN 첨가 SiC 세라믹스의 열전변환특성)

  • Pai, Chul-Hoon
    • Korean Journal of Metals and Materials
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    • v.50 no.11
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    • pp.839-845
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    • 2012
  • The effect of an AlN additive on the thermoelectric properties of SiC ceramics was studied. Porous SiC ceramics with 48-54% relative density were fabricated by sintering the pressed ${\alpha}-SiC$ powder compacts with AlN at $2100-2200^{\circ}C$ for 3 h in an Ar atmosphere. In the undoped specimens, the Seebeck coefficients were positive (p-type semiconducting) possibly due to a dominant effect of the acceptor impurities (Al, Fe) contained in the starting powder. With AlN addition, the reverse phase transformation of 6H-SiC to 4H-SiC was observed during the sintering process. The electrical conductivity of the AlN doped specimen was larger than that of the undoped specimen under the same conditions, which might be due to a reverse phase trans-formation. The Seebeck coefficient of the AlN doped specimen was also larger than that of the undoped specimen. The density of specimen and the amount of addition had significant effects on the thermoelectric properties.

Synthesis and properties of $Al_2O_3-SiC$ Composites from Alkoxides III. Effect of Composite Powder Type on the Sintering Characteristics and Properties of $Al_2O_3-SiC$ Comopsites (알콕사이드로부터 $Al_2O_3-SiC$ 복합재료의 제조 및 특성 III. 복합분말의 형태에 따른 $Al_2O_3-SiC$ 복합재료의 소결 특성 및 물성)

  • 이홍림;김규영
    • Journal of the Korean Ceramic Society
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    • v.30 no.4
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    • pp.316-324
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    • 1993
  • Three types of dispersed, coated and mechanically mixed SiC reinforced Al2O3 composite powders were used to investigate the effect of composite powder type on sintering characteristics and properties of Al2O3-SiC composites. Sinterability of coated type composite powders was superior to that of other composite powders when they were pressureless sintered at 1500~1$700^{\circ}C$ for 2h in Ar atmosphere. However, sinterabilities (>98% TD) of each type of composite powders were similar when they were hot pressed at 180$0^{\circ}C$ for 1h under 30MPa in N2 atmosphere. SiC powders were randomly distributed in the specimen prepared from dispersed type composite powders, whereas homogeneously distributed for coated type specimens. It was found that SiC powders inhibited the grain growth of Al2O3, and fracture toughness was increased by the increment of crack growth resistance due to residual stress by secondary SiC particles within Al2O3 grains.

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Effects of Mn, Cr, and Sr Additions on the Microstructure and Tensile Properties of Al-7Si-0.4Mg-1Fe Casting Alloy (Al-7Si-0.4Mg-1Fe 주조합금의 미세조직과 인장성질에 미치는 Mn, Cr 및 Sr 첨가의 영향)

  • Kim, Jeong-Min;Park, Joon-Sik;Kim, Ha-Young;Cho, Jae-Ik;Jung, Chang-Yeol
    • Journal of Korea Foundry Society
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    • v.29 no.1
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    • pp.27-32
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    • 2009
  • The microstructure of Al-7Si-0.4Mg-1Fe alloy mainly consists of aluminum dendrites, Al-Si eutectics, and $Al_5FeSi$ needles. When Mn was added to the alloy, the substantial amount of $Al_5FeSi$ phase was changed into Al(Mn,Fe)Si, however the needle-like morphology was almost unchanged. Combined additions of Cr or Sr with Mn to the base alloy resulted in rod-like Al(Mn, Fe,Si)Si phase. The tensile properties of as-cast alloys were enhanced by the Mn addition, especially when it was added with Sr. The tensile properties after T6 heat treatment was a little improved with 0.7%Mn addition, but Cr or Sr additions with Mn didn't show any positive effect on the properties of heat-treated alloys.

Reflectance Characteristics of Al-Si based Alloys according to Powder Size and Composition (Al-Si계 합금의 분말 크기 및 조성에 따른 반사율 변화 특성)

  • Choi, Gwang Mook;Chae, Hong Jun
    • Journal of Powder Materials
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    • v.26 no.1
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    • pp.22-27
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    • 2019
  • In this study, the effects of powder size and composition on the reflectance of Al-Si based alloys are presented. First, the reflectance of Al-Si bulk and powder are analyzed to confirm the effect of powder size. Results show that the bulk has a higher reflectance than that of powder because the bulk has lower surface defects. In addition, the larger the particle size, the higher is the reflectance because the interparticle space decreases. Second, the effect of composition on the reflectance by the changing composition of Al-Si-Mg is confirmed. Consequently, the reflectance of the alloy decreases with the addition of Si and Mg because dendrite Si and $Mg_2Si$ are formed, and these have lower reflectance than pure Al. Finally, the reflectance of the alloy is due to the scattering of free electrons, which is closely related to electrical conductivity. Measurements of the electrical conductivity based on the composition of the Al-Si-Mg alloy confirm the same tendency as the reflectance.

Wear properties of Al-Pb alloys produced by a forced stirring method (강제교반법으로 제조된 Al-Pb계 베어링 합금의 마모특성)

  • 임화영;허무영;임대순
    • Tribology and Lubricants
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    • v.8 no.1
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    • pp.70-77
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    • 1992
  • Al-Pb-Si bearing alloys were produced by a forced stirring method and a rapid solidification process to study wear properties of bearing alloys. A homogeneous distribution of Pb particles in Al matrix could be obtained by means of the forced stirring and the rapid cooling during the casting. The wear properties of bearing alloys were tested by a pin-on-disc wear tester. The change in microstructure according to the alloy manufacturing variables was observed by the backscattered electron images. Al-Pb and Al-Si binary alloys showed a transition from mild to severe wear. The transition was not found in Al-Pb-Si ternary alloys. It could be concluded that the lubricatioin effect of Pb and the strengthening effect of Si in the ternary alloys enhanced the bearing properties. A Al-25%Pb-13%Si alloy showed the lowest coefficient of friction in this experiment. It indicated that the optimum concentration of alloy was 25% Pb and 13% Si when the forced stirring of melt and water-cooled-copper-mold solidification were adopted.

Load Relaxation and Creep Transition Behavior of a Spray Cast Hypereutectic Al-Si Based Alloy (분무 주조 과공정 Al-Si계 합금의 응력이완 및 Creep 천이 거동)

  • Kim M. S.;Bang W.;Park W. J.;Chang Y. W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.176-179
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    • 2005
  • Spray casting of hypereutectic Al-Si based alloy has been reported to provide distinct advantages over ingot metallurgy (IM) or rapid solidification/powder metallurgy (RS/PM) process in terms of microstructure refinement. Hypereutectic Al-Si based alloys have been regarded attractive for automotive and aerospace application, due to high specific strength, good wear resistance, low coefficient of thermal expansion, high thermal stability, and good creep resistance. In this study, hypereutectic Al-25Si-2.0Cu-1.0Mg alloy was prepared by OSPREY spray casting process. High temperature deformation behavior of the hypereutectic Al-Si based alloy has been investigated by applying the internal variable theory proposed by Chang et al. The change of strain rate sensitivity and Creep transition were analyzed by using the load relaxation test and constant creep test.

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A Study for the Increased Reliability of Al-1%Si Thin Film Metallizations (Al-1%Si 박막 금속화의 신뢰도 향상을 위한 연구)

  • 최재승;김진영
    • Journal of the Korean Vacuum Society
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    • v.1 no.3
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    • pp.382-388
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    • 1992
  • Electromigration은 인가된 전계하에서 발생하는 전자풍력에 의한 금속 이온의 현 상이며, 반도체 디바이스의 주요 결함 원인으로 보고되어 왔다. 선폭 1$mu extrm{m}$의 Al-1%Si 금속 박막전도체에 대한 electromigration 수명 실험을 위해 인가된 d.c. 전류밀도는 10MA/cm2 이었고, electromigration에 대한 활성화 에너지 측정을 위한 분위기 온도는 $80^{\circ}C$, 10$0^{\circ}C$ 그리고 $120^{\circ}C$이었다. 평균수명 및 신뢰성에 대한 보호 절연막 효과를 위해 두께 3000 $\AA$의 SiO2 산화막을 sputtering 진공증착기를 사용하여 Al-1%Si 금속 박막 전도체 위에 증착하였 다. 주요 연구 결과는 다음과 같다. Al-1%Si 금속 박막 전도체의 electromigration에 대한 활성화 에너지값은 0.75eV이었고 온도가 증가함에 따라 Al-1%Si의 수명은 감소하였고 신 뢰성은 향상되었다. SiO2 보호막은 electromigration에 대한 저항성을 크게 함으로써 평균수 명을 향상시켰으며, electromigration failure는 lognormal failure distribution은 갖는 것으로 나타났다.

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A Study on the Squeeze Casting of Al-7.0Si-0.4Mg Alloy for Fuel System Parts (Al-7.0Si-0.4Mg 합금 자동차 연료계 부품의 스퀴즈 캐스팅에 관한 연구)

  • 김순호
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.12
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    • pp.48-54
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    • 2003
  • Alumium alloys casting are gaining increased acceptance in the automotive and electronic industeries and squeeze casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Al-7.0Si-0.4Mg (AC4C) alloy fabricated by squeeze casting process for development of Fuel system Parts (Fuel rail). The microstructure of squeeze casted specimen were composed of eutectic structure Alumimim solid solution and $Mg_2$Si precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg ahoy revealed 298.5MPa. It was found that Al-7.0Si-0.4Mg alloy have good corrosion resistance in electrochemical polarization test.

Difference in Solidification Process between Al-Mg Alloy and Al-Si Alloy in Die-Casting (Al-Mg계 합금과 Al-Si계 합금의 다이캐스팅 응고과정의 차이)

  • Choi, Se-Weon;Kim, Young-Chan;Cho, Jae-Ik;Kang, Chang-Seog;Hong, Sung-Kil
    • Korean Journal of Materials Research
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    • v.22 no.2
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    • pp.82-85
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    • 2012
  • The effect of the alloy systems Al-Mg alloy and Al-Si alloy in this study on the characteristics of die-casting were investigated using solidification simulation software (MAGMAsoft). Generally, it is well known that the casting characteristics of Al-Mg based alloys, such as the fluidity, feedability and die soldering behaviors, are inferior to those of Al-Si based alloys. However, the simulation results of this study showed that the filling pattern behaviors of both the Al-Mg and Al-Si alloys were found to be very similar, whereas the Al-Mg alloy had higher residual stress and greater distortion as generated due to solidification with a larger amount of volumetric shrinkage compared to the Al-Si alloy. The Al-Mg alloy exhibited very high relative numbers of stress-concentrated regions, especially near the rib areas. Owing to the residual stress and distortion, defects were evident in the Al-Mg alloy in the areas predicted by the simulation. However, there were no visible defects observed in the Al-Si alloy. This suggests that an adequate die temperature and casting process optimization are necessary to control and minimize defects when die casting the Al-Mg alloy. A Tatur test was conducted to observe the shrinkage characteristics of the aluminum alloys. The result showed that hot tearing or hot cracking occurred during the solidification of the Al-Mg alloy due to the large amount of shrinkage.

Effects of Cr, B, Ti and Si on Rolling Characteristics in Fe-30at.%A1 Alloy (Fe-30at.%A1 합금의 압연성에 미치는 Cr, B, Ti 및 Si 첨가효과)

  • Choi, Dap-Chun;Lee, Ji-Sung
    • Journal of Korea Foundry Society
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    • v.23 no.2
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    • pp.77-85
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    • 2003
  • Some alloying elements such as Cr, B, Ti and Si were added individually or as a mixture to Fe-30 at.%Al alloys. The alloys were melted using an arc furnace and then heat-treated for homogenization at 1000$^{\circ}C$ for 7 days and followed by rolling at 1000$^{\circ}C$. The alloying elements on rolling characteristics were investigated by the microstructures and fracture mode before and after rolling. The microstructures before rolling showed that all of the alloys had equiaxed grains. On the other hand, the microstructures of rolling plane as well as its perpendicular plane became elongated after rolling. The alloys such as Fe-30Al, Fe-30Al-3Ti, Fe-30Al-0.5B, Fe-30Al-5Cr and Fe-30Al-3Ti-0.5B revealed better rolling behaviour from the point that intergranular and cleavage fractures were not fundamentally occurred. But the addition of 5Ti or 3Si to Fe-Al alloys had detrimental effects. The Ti-added alloy system such as Fe-30Al-5Ti, Fe-30Al-5Ti-5Cr, Fe-30Al-3Ti-5Cr and Fe-30Al-5Ti-0.5B were cracked through grain and showed cleavage fracture. The Si-added alloy system such as Fe-30Al-5Si, Fe-27Al-3Si and Fe-27Al-5Cr-3Si were cracked along the grain boundary and showed intergranular fracture. $DO_3{\leftrightarrow}B_2$ transition temperature of Fe-30at.%Al alloy was 520$^{\circ}C$, whereas the addition of 3Ti and 3Ti+0.5B comparably increased the temperature to 797 and 773$^{\circ}C$, respectively.