• 제목/요약/키워드: Al substitution

검색결과 172건 처리시간 0.026초

저전력 가정용 식품건조기 개발에 관한 실험적 연구 (Experimental Study on the Development of Food Drying Machine for Home Use Using Low Electricity)

  • 김순호;김기완;김훈
    • 동력기계공학회지
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    • 제19권4호
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    • pp.43-49
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    • 2015
  • This study has been analyzed and investigated the possibility for the substitution of a heat source with the application of PTC(Positive Temperature Coefficient Heater) in a food drying machine. And this experiment was conducted to measure temperatures at the upper part of the vessel and the heat sink. And the structure has the many holes plane connected with the external air in the upper part of similar volumetric vessel, and attached to the PTC heater (3sets) of total consumption electricity of 120[W] in Al radiant heat structure and the small fan (2sets) in the suitable space of the lower part. Consequently, it was found that at the most conditions of food drying test with the seven holes(5mm) under the control temperature $62^{\circ}C$, the optimum drying condition formatted and the optimum time range especially appeared from 6,500 second to 7,000 second in case of drying test on banana sample.

MgO의 첨가량에 따른 $(Ba_{0.5}Sr_{0.5}){TiO_3}$ 후막의 유전 특성 (Dielectirc Properties of $(Ba_{0.5}Sr_{0.5}){TiO_3}$ Thick Films Doped with MgO)

  • 강원석;남송민;고중혁;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.5-6
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    • 2006
  • Using the $(Ba_{0.5}Sr_{0.5}){TiO_3}$(BST) powders prepared by the Sol-Gel method, the EST thick films were fabricated on the ${Al_2}{O_3}$ substrates coated with Pt by the screen printing method. Compared with pure EST thick films, the structural and dielectric properties of the EST thick films doped with 1${\sim}$10 wt % MgO were investigated. It was observed that the Mg substitution into EST causes a shift in the cubic-tetragonal EST phase transition peak to a lower temperature. The microstructure of the EST substituted with Mg was homogeneous and dense. Mg substitution into EST had a significant effect on the grain size reduction. Dielectric constant was decreased with increasing the MgO content and temperature. In the case of EST thick films doped with 1 wt% MgO, the relative permittivity and dielectric loss were 158] and 1.4 % at 1 MHz.

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Study of Substitution Effect of Anthraquinone by SERS Spectroscopy

  • Lee, Chul-Jae;Kang, Jae-Soo;Park, Yong-Tae;Rezaul, Karim Mohammad;Lee, Mu-Sang
    • Bulletin of the Korean Chemical Society
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    • 제25권12호
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    • pp.1779-1783
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    • 2004
  • In the present study, we carried out comparative research on the anthraquinones Raman spectrum and on the anthraquinones derivative 1,4-diamino-anthraquinone focusing on change in its intermediate in terms of pH and change in the substituent. WE use the SERS method and employ a silver sol prepared by Creighton et al.'s method. From the analysis of the UV spectrum of the mixture solution of 1,4-diamino-anthraquinone and silver sol, we could see that the 1,4-diamino-anthraquinone physically adsorbs silver sol. In terms of the adsorbing orientation, the adsorption of the nitrogen atom in the amino group is perpendicular to the surface of silver sol according to the surface selection rule. From the structure of the 1,4-diamino-anthraquinone intermediate according to the change of pH, we could see that the C=O bond is strengthened in the acidic state and weakened in the neutral and the alkaline state because of the resonance effect of the amines.

Ni-Doped Hibonite 파란색 안료의 합성과 발색기구 (Synthesis and Mechanism of Ni-Doped Hibonite Blue Pigments)

  • 김금선;이병하
    • 한국재료학회지
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    • 제24권1호
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    • pp.43-47
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    • 2014
  • NiO-doped hibonite pigments were synthesized by the solid state method to get stabilized blue color pigment in both oxidation and reduction atmospheres. Optimum substitution condition with NiO for hibonite blue pigment was investigated. Experimental results were comparable to those of previous cobalt-minimization studies performed with other phosphate- or oxide-based cobalt-containing ceramic pigments (having olivine ($Co_2SiO_4$), spinel ($CoAl_2O_4$), or with co-doped willemite ($(Co,Zn)_2SiO_4$) structures). Composition was designed varying the NiO molar ratio increasing with $SnO_2$. The optimum substitution content is 0.93 mole NiO with 0.75mole $SnO_2$. The characteristics of the synthesized pigment were analyzed by XRD, Raman spectroscopy, SEM, and UV-vis. Synthesized pigment was applied to a lime-barium glaze with 10 wt% each and fired at an oxidation atmosphere of $1250^{\circ}C/1h$ and a reducing atmosphere $1240^{\circ}C/1h$. Blue color was obtained with $L^*a^*b^*$ values at 43.39, -6.78, -18.20 under a reducing atmosphere and 41.66, -6.36, -14.7 under and oxidation atmosphere, respectively.

MgO가 첨가된 $Ba_{0.5}Sr_{0.5}TiO_3$ 후막의 구조 및 유전 특성 (Structural and Dielectirc Properties of $Ba_{0.5}Sr_{0.5}TiO_3$ Thick Films Doped with MgO)

  • 강원석;남성필;고중혁;이성갑;이영희
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제55권12호
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    • pp.555-559
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    • 2006
  • Using the $Ba_{0.5}Sr_{0.5}TiO_3$(BST) powders prepared by the Sol-Gel method, the BST thick films were fabricated on the $Al_2O_3 $substrates coated with Pt by the screen printing method. Compared with pure BST thick films, the structural and dielectric properties of the BST thick films doped with $1{\sim}10$ wt % MgO were investigated. It was observed that the Mg substitution into BST causes a shift in the cubic-tetragonal BST phase transition peak to a lower temperature. The microstructure of the BST substituted with Mg was homogeneous and dense. Mg substitution into BST had a significant effect on the grain size reduction. Dielectric constant was decreased with increasing the MgO content and temperature. In the case of BST thick films doped with 1 wt% MgO, the relative permittivity and dielectric loss were 1581 and 1.4 % at 1 MHz.

석탄회-점토계 소지의 제조 및 물성 (Manufacture and Properties of Coal Fly Ash-Clay Body)

  • 송종택;윤성대;류동우;한경섭
    • 한국세라믹학회지
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    • 제33권7호
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    • pp.771-778
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    • 1996
  • Utilization of fly ash by-produced from coal fired power plants and classified as general waste became very important problem to solve in the environmental protection and recycling of waste materials. The possibility of large scale substitution of fly ash as a raw material for bricks and wet tiles was highly expected because the chemical compositions of fly ash were mostly Al2O3 and SiO2 and the properties of it were very similar with clay. Accordingly in order to investigate the substitutional limit these specimens were substituted from 0 to 100 wt% fly ash by 20wt% increment for clay. Fly ash-clay bodies were fired at 1200, 1250 and 130$0^{\circ}C$ and then their properties were measured, It was found that these specimens sintered at 125$0^{\circ}C$ had a good bending strength. Especially when these sintered bodies were added to 20, 40 and 60 wt% fly ash the bending strength of those were 201 , 205 and 191kg.cm2 respectively with the water absorption below 1%, This showed that fly ash could be substituted ab 60 wt% in this experiment.

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아민기 치환 시 용매 사용량 절감을 위한 기계 장치 설계 및 NH2-HNT 제조 (Mechanical Device Design for Solvent Usage Reduction for Amine Group Substitution and Production of NH2-HNT)

  • 김문일
    • 한국환경과학회지
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    • 제32권6호
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    • pp.477-482
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    • 2023
  • Halloysite nanotube (HNT) has a nanotube structure with the chemical formula of Al2Si2O5(OH)4 · nH2O and is a natural sediment of aluminosilicate. A lot of research has been conducted to improve the mechanical properties of epoxy composites by generating interactions between HNTs and polymers through surface treatment of HNTs, such as exchange of amine group as a terminal functional group. However, most of the surface modification methods are performed under wet conditions, which require a relatively large amount of time, manpower and solvent. In order to save time and simplify complicated procedures, a dry coating machine was designed and used for amine group exchange. Comparing the XPS results, it was found that the results of NH2-HNT prepared using a dry coating machine and the substitution through the wet method were not significantly different, and it has been confirmed that the amount of solvent used and the time savings can be made.

PREPERATION OF AMPHOTERIC STARCHS AND STUDY ON WET END CHEMISTRY IN PAPERMAKING

  • Shan, Chen-Fu;Su, Xie-Lai;Yi, Wang-Hai;Quan, Long-Yan
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 1999년도 Pre-symposium of the 10th ISWPC Recent Advances in Paper Science and Technology
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    • pp.386-389
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    • 1999
  • Amphoteric polymers have brought to papermakers' attention gradually. In this paper, a series of amphoteric starches with different cationic and anionic degree of substitution (DS) are prepared. Better product has been selected and used under different condition. As retention and drainage aids, amphoteric starches were used in shorter fiber length, weak strength and poor drainage bleached AQ-Soda wheat straw pulp. In neutral and alkaline papermaking system, when amphoteric starches contain 0.024-0.026 anionic degree of substitution (DS), it is shown that the higher the cationic degree of substitution (DS) in amphoteric starches, the better the filler retention. The filler retention is improved 12.5%, 30.3%, and 35.1% and 32.5% respectively by adding 1% amphoteric starch LS-L2 -1 (0.034), LS-L2-2 (0.040), LS-L2-3 (0.047) and LS-L2-4 (0.052). But the strength of handsheets if affected a little. By adding 2% Al2 (SO4)3 and 1.5% LS-L2-3 at pH 7.5, filler retention can be improved from 38% to 80%, and breaking length of sheet only decreases 3.2%. As dry strengthening aids, amphoteric starches were used in eucalyptus APMP. Amphoteric starches are used in eucalyptus APMP. The amphoteric starch LS-L2-2 is better dry strength aid. Adding 1% LS-L2-2 can improve breaking length 24.5%, burst index 42.9%, tear index 38.8%, folding endurance and density of the handsheets.

A comprehensive evaluation of Mg-Ni based alloys radiation shielding features for nuclear protection applications

  • M.I. Sayyed;K.A. Mahmoud;Faras Q. Mohammed;Kawa M. Kaky
    • Nuclear Engineering and Technology
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    • 제56권5호
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    • pp.1830-1835
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    • 2024
  • The current study aims to study the impacts of the substitution of magnesium with nickel concentrations on physical and γ-ray shielding capacity of magnesium alloys. The density of the magnesium alloys under study is varied from 3.677 g/cm3 to 5.652 g/cm3, with raising the nickel content from 26.7 wt% to 54.8 wt% and reducing the magnesium concentration from 72.6 wt% to 44.2 wt%, respectively. Additionally, the examination of the γ-ray shielding capacity using the Monte Carlo simulation code shows that the substitution of magnesium by nickel content in the magnesium alloys was associated with an enhancement in the γ-ray shielding capacity, where the linear attenuation coefficient for the studied alloys was enhanced by 53.22 %, 52.45 %, and 52.52 % at γ-ray energies of 0.662 MeV, 1.252 MeV, and 1.408 MeV, respectively, with raising the nickel concentration from 26.7 wt% to 54.8 wt%. Simultaneously, the half-value thickness for magnesium alloys was reduced from 2.47 cm to 1.62 cm (at gamma ray energy of 0.662 MeV), from 3.39 cm to 2.22 cm (at gamma ray energy of 1.252 MeV), and from 3.60 cm to 2.36 cm (at gamma ray energy of 1.408 MeV), raising the nickel concentration from 26.7 wt % to 54.8 wt%, respectively. The study shows that the substitution of magnesium for nickel greatly enhanced the radiation shielding capacity of the magnesium alloys.

분무열분해 공정을 이용하여 스트론튬 알루미네이트 녹색 형광체의 합성 및 발광 특성 개선 (Synthesis and Luminescence Enhancement of Strontium Aluminate Green Phosphor via Spray Pyrolysis)

  • 김미나;정경열
    • Korean Chemical Engineering Research
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    • 제49권5호
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    • pp.594-599
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    • 2011
  • 분무열분해 공정을 이용하여 $SrAl_2O_4:Eu$ 녹색 형광체를 제조함에 있어 붕소의 치환, 유기첨가제 및 건조 조절제의 사용에 따른 발광 특성을 조사하였다. Al 자리에 붕소를 치환시켜 줌으로써 결정상은 순수해지고 발광강도는 크게 향상됨을 확인하였다. 휘도 측면에서 붕소의 함량은 약 1 at%로 하는 것이 가장 바람직하였다. 유기첨가제의 함량 변화에 따른 $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ 형광체의 휘도 변화를 조사한 결과 0.2M을 사용했을 때 가장 높은 휘도를 얻었다. 유기첨가제와 함께 건조 조절제로 DMF 0.5M을 함께 사용함으로써 $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ 형광체의 휘도는 약 172% 향상되었다. XRD 분석 결과에 의하면 사용한 유기첨가제와 DMF의 사용은 $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ 형광체의 결정상 변화 없이 결정성을 크게 향상시켰다. 유기 첨가제만을 사용할 경우 형광체의 표면적은 커졌지만 DMF를 함께 사용함으로써 현저히 줄어들었다. 따라서 유기첨가제와 DMF를 동시에 사용하여 합성한 형광체의 휘도가 크게 향상된 것은 결정성 증가와 표면적 감소에 기인한 것이라고 결론지었다.