• 한국주조공학회지
• /
• 제18권4호
• /
• pp.357-363
• /
• 1998

Microstructure of A356 aluminium alloys cast in a permanent mold was investigated by optical microscope and image analyzer, with particular respect to the shape and size distribution of iron intermetallics known as ${\beta}-phase$ ($Al_5FeSi$). Morphologies of the ${\beta}-phase$ was found to change gradually with the Be:Fe ratio like these. In Be-free alloys, ${\beta}-phase$ with needlelike morphology was well developed, but script phase was appeared when the Be:Fe ratio is above 0.2:1. With the Be:Fe ratios of 0.4:1-1:1, script phase as well as Be-rich phase was also observed. In case of higher Be addition, above 1:1, Be-rich phase was observed on all regions of the specimens, and increasing of the Be:Fe ratios gradually make the Be-rich phase coarse. It was also observed that the ${\beta}-phase$ with needlelike morphology was coarsened with increase of the Fe content in Be-free alloys. However, in Be-added alloys, length and number of these ${\beta}-phases$ were considerably decreased with the increased Be:Fe ratio. It was concluded that Fe impurity element to be crystallized into needlelike intermetallics was tied up by Be addition element, and new phases were crystallized into script or Be-rich intermetallics.

• Journal of Welding and Joining
• /
• 제20권6호
• /
• pp.762-768
• /
• 2002

In this study, the low temperature toughness was evaluated by using the instrumented Charpy impact testing procedures for A15083-O aluminum alloy used in the LNG carrying and storage tank. The specimens were GMA(Gas Metal Arc) welded with four different mixing shield gas ratios (Ar100%+He0%, Ar67%+He33%, Ar50%, and Ar33%+He67%), and tested at four different temperatures(+25, -30, -85, and $-196^{\circ}C$) in order to investigate the influence of the mixing shielding gas ratio and the low temperature. The specimens were divided into base metal, weld metal, fusion line, and HAZ specimen according to the notch position. From experiment the maximum load and displacement were shown the highest and He lowest at $-196^{\circ}C$ than the other test temperatures. The absorption energy of weld metal notched specimens was not nearly depends on test temperature and mixing shield gas ratio because the casting structure was formed in weld metal zone by melting welding wire. On the other hand, the others specimens was shown that the lower temperature, the higher absorption energy slightly up to $-85^{\circ}C$ but the energy was decreased so mush at $-196^{\circ}C$.

• 한국표면공학회지
• /
• 제54권2호
• /
• pp.43-52
• /
• 2021

The Ni-based superalloy, Inconel 740, was corroded between 800 and 1100℃ for up to 100 hr in air and Ar-0.2%SO₂ gas in order to study its corrosion behavior in air and sulfur/oxygen environment. It displayed relatively good corrosion resistance in both environment, because its corrosion was primarily dominated by not sulfidation but oxidation especially in Ar-0.2%SO₂ gas. Such was attributed to the thermodynamic stability of oxides of alloying elements when compared to corresponding sulfides. The scales consisted primarily of Cr₂O₃, together with some NiAl₂O₄, MnCr₂O₄, NiCrMnO₄, and rutile-TiO₂. Sulfur from SO₂ gas made scales prone to spallation, and thicker. It also widened the internal corrosion zone when compared to air. The corrosion resistance of IN740 was mainly indebted to the formation of protective Cr₂O₃-rich oxides, and suppression of the sulfide formation.

• 한국주조공학회지
• /
• 제18권5호
• /
• pp.431-438
• /
• 1998

Microstructure of A356 aluminum alloys cast in the permanent mold was investigated by optical microscope and image analyzer, with particular respect to the shape and size distribution of iron intermetallics known as ${\beta}-phase$ ($Al_5FeSi$). Morphologies of the ${\beta}-phase$ was found to change gradually with the Be:Fe ratio like these. In Be-free alloys, ${\beta}-phase$ with needlelike morphology was well developed, but script phase was appeared when the Be:Fe ratio is above 0.2:1. With the Be:Fe ratios of 0.4:1-1:1, script phase as well as Be-rich phase was also observed. In case of higher Be addition, above 1:1, Be-rich phase was observed on all regions of the specimens, and increasing of the Be:Fe ratios gradually make the Be-rich phase coarse. It was also observed that the ${\beta}-phase$ with needlelike morphology was coarsened with increase of the Fe content in Be-free alloys. However, in Be-added alloys, length and number of these ${\beta}-phases$ were considerably decreased with the increased Be:Fe ratio. Beryllium addition improved tensile properties and impact toughness of the A356 aluminium alloy, due to the formation of a script phase or a Be-rich phase instead of a needlelike ${\beta}-phase$. The DSC tests indicated that the presence of Be could increase the amount of Mg which is available for $Mg_2Si$ precipitate hardening, and enhance the precipitation kinetics by lowering the ternary eutectic temperature.

• 한국해양공학회:학술대회논문집
• /
• 한국해양공학회 2002년도 추계학술대회 논문집
• /
• pp.373-378
• /
• 2002

Metal matrix composites have a great interest in recent years because high specific strength, high specific stiffness characteristics, and application ranges of the composites are extend to variety industry. In this paper, an investigation was performed on the plane strain fracture toughness and slinding wear properties of AC4CH alloy(Al-Si-Mg line) reinforced with 20wt% aluminum borate whisker expect one, which contained a inorganic binder($TiO_2$). the binder led to the formation of strengthen the whisker each other. The test of fracture toughness was using CT(half size) specimen of thickness 12.5mm, width 25mm. and test of slinding wear of using tribo a pin-on-disk machine and lubricant is used without paraffine 8.2CST at room temperature. As results, Fracture toughness $K_{IC}$ is $8.7MPa-m^{05}$ for ABOw/AC4CH, $9.28MPa-m^{05}$ for ABOw/AC4CH added $TiO_2$. but AC4CH alloy was violated the critical stipulated by ASTM standard for valid measurement of $K_{IC}$. In case of, it was performed $J_{IC}$ test instead of $K_{IC}$ based on ASTM E 1820.

• 한국항공우주학회지
• /
• 제31권3호
• /
• pp.15-22
• /
• 2003

피로균열성장모델을 유도하고 지연모델을 제안하였다. 피로균열성장모델은 피로균열선단의 소성변형으로 인하여 균열표면에 발생하는 잔류소성스트레치를 고려하고 있다. 균열 성장률은 균열선단 재료요소의 소성변형에너지와 누적피로손상으로부터 계산된다. 유도한 균열성장모델로부터 계산한 균열성장률은 AL6061-T651과 17-4PH 주강의 시험결과와 잘 일치하고 있다. 피로균열성장지연모델은 인장과대하중으로부터 생성된 잔류소성스트레치를 근거로 하고 있으며, 인장과대하중은 다음 하중 사이클의 소성변형률을 감소시킨다. Strip-yield모델을 이용하여 균열선단의 소성역을 계산하였다. 새로 제안된 지연모델은 인장과대하중하의 피로균열선장특성 및 지체지연 현상을 잘 기술하고 있다.

• 한국주조공학회지
• /
• 제22권1호
• /
• pp.42-48
• /
• 2002

Effects of coating treatment of metallic Cu, Ni-P film on $SiC_p$, for $SiC_p$/iron aluminide composites were studied. Porous hybrid preforms were fabricated by reactive sintering after mixing the coated $SiC_p$, Fe and Al powders. Then the final composites were manufactured by squeeze casting after pouring AC4C Al alloy melts in preforms. The change of reactive temperature, density, microstructure of the preforms and microstructure of the composites were investigated. The exprimental results were summarized as follows. The thickness of Cu and Ni-P metallic layer formed on $SiC_p$ by electroless plating method were about $0.5{\mu}m$ and coated uniformly. There was no remakable change in the ignition temperature with variation of the mixing ratio of Fe and Al powder while in the case of coated $SiC_p$ it was lower about $20^{\circ}C$ than in the non-coated $SiC_p$. The maximum reaction temperature increased with increasing Al contents, but decreased with increasing $SiC_p$ contents. Expansion ratio of preform after reactive sintering increased with amount of Cu coated $SiC_p$. In the case of Fe-70at.%Al, the expansion ratio was about 7% up to 8wt.% of $SiC_p$, addition but further addition of $SiC_p$, increased the ratio significantly. And in the case of Fe-50 and 60at.%Al, it was about 20% up to 16wt.% of $SiC_p$ addition and about 28% in 24wt.% of $SiC_p$, addition. The microstructures of compounds showed that the grains became finer as amount of $SiC_p$, and mixing ratio of iron powder increased and the shape of compounds was changed gradually from irregular to spheroidal.

• Composites Research
• /
• 제12권1호
• /
• pp.68-75
• /
• 1999

본 연구에서는 저속 충격에서 충격 속도에 따른 금속복합재료의 동적 거동을 연구하였다. 시험에 사용된 재료는 모재로 AC8A와 보강재로 알루미나($Al_2O_3$)와 탄소를 사용하였으며 용탕 주조법을 이용하여 금속복합재료를 제조하였다. 금속복합재료에는 15%의 부피분율을 가진 알루미나 예비성형체와 알루미나와 탄소를 각각 12%와 3% 사용한 혼합 에비성형체가 사용되었다. 제조된 금속복합재료는 인장 시험과 진동 시험을 통해 인장 강도와 탄성계수를 구하였으며, 저주파 여파기(low pass filter)와 계장화 충격 시험기를 이용하여 충격 속도에 따른 금속복합재료의 충격 거동을 연구하였다. 저주파 여파기를 이용함으로써 충격 속도에 관계없이 안정적인 실험치를 확보할 수 있었다. 충격 속도의 증가에 따라 모재와 금속복합재료의 충격에너지는 증가하였으나, 동적인성치는 일정한 값을 보였다. 충격 속도가 증가할수록 충격에너지 중 균열전파에너지의 향상이 두드러졌으며, 재료의 변형량이 증가하였다. 충격에너지 중 균열개시에너지와 동적파괴인성치의 관계를 설명하기 위하여 변형율 에너지와 노치에서의 응력 분포를 이용하여 간단한 모델을 제시하였으며, 이로부터 균열개시에너지는 동적 파괴 인성치의 자승에 비례하고 탄성계수에 반비례하는 것을 보였다.

• 소성∙가공
• /
• 제19권5호
• /
• pp.311-319
• /
• 2010

Rare earth metal Ce has a relatively low melting point and high specific gravity. Because of its significantly high affinity to oxygen, nitrogen and sulfur, it is highly usable as a steel refining agent. However, because Ce compound has relatively high specific gravity, it is difficult to be separated from molten steel through floatation, and it degrades the purity of molten steel, or may clog the nozzle in continuous casting. Such problem may be solved by using an appropriate deoxidation agent together with Ce and settling molten steel sufficiently after refining. Thus a fundamental study in the formation behavior of non-metallic inclusion in Ce added Hyper Duplex STS melts was investigated. The addition amount of Ce, melt temperature were considered as experimental variables. A main non-metallic inclusion in mother alloy is 51(wt%MnO) - 27.6(wt%SiO$_2$)- 10.9(wt%$Cr_2O_3$). Non-metallic inclusion was dramatically decreased and the particle size was fined as the amount of Ce increased. Moreover (%MnO) and (%SiO$_2$) of non-metallic inclusion were decreased. But (%$Al_2O_3$)were relatively increased. The number of non-metallic inclusion were decreased and the large particle size were increased by increasing the temperature of molten steel.

• 대한치과보철학회지
• /
• 제45권2호
• /
• pp.203-215
• /
• 2007

Statement of problem: Titanium and its alloy, with their excellent bio-compatibility and above average resistance to corrosion, have been widely used in the field of dentistry. However, the excessive oxidization of titanium which occurs during the process of firing on porcelain makes the bonding of titanium and porcelain more difficult than that of the conventional metal-porcelain bonding. To solve this problem related to titanium-porcelain bonding, several methods which modify the surfaces, coat the surfaces of titanium with various pure metals and ceramics, to enable the porcelain adhesive by limiting the diffusion of oxygen and forming the adhesive oxides surfaces, have been investigated. Purpose: The purpose of this study was to know whether the titanium-porcelain bonding strength could be enhanced by treating the titanium surface with gold and TiN followed by fabrication of clinically applicable porcelain-fused-to-titanium crown Material and method: The porcelain-fused-to-titanium crown was fabricated after sandblasting the surface of the casting titanium coping with $Al_2O_3$ and treating the surface with gold and TiN coating followed by condensation and firing of ultra-low fusing porcelain. To compare with porcelain-fused-to-titanium crowns, porcelain-fused-to-gold crowns were fabricated and used as control groups. The bonding strengths of porcelain-fused-to-gold crowns and porcelain-fused-totitanium crowns were set for comparison when the porcelain was fractured on purpose to get the experimental value of fracture strength. Then, the surface were examined by SEM and each fracturing pattern were compared with each other Result:Those results are as follows. 1. The highest value of fracture strength of porcelain-fused-to-titanium crowns was in the order of group with gold coating, group with TiN coating, group with $Al_2O_3$ sandblasting. No statistically significant difference was found among the three (P>.05). 2. The porcelain-fused-to-gold crowns showed the highest value in bonding strength. The bonding strength of crowns porcelain-fused-to-titanium crowns of rest groups showed bonding strength reaching only 85%-94% of that of PFG, though simple comparision seemed unacceptable due to the difference in materials used. 3. The fracturing patterns between metal and porcelain showed mixed type of failure behavior including cohesive failure and adhesive failure as a similar patterns by examination with the naked eye and SEM. But porcelain-fused-to-gold crowns showed high incidence of adhesive failure and porcelain-fused-to-titanium crowns showed high incidence of cohesive failure. Conclusion: Above results proved that when fabricating porcelain-fused-to-titanium crowns, treating casting titanium surface with gold or TiN was able to enhance the bonding strength between titanium and porcelain. Mean value of masticatory force was found to showed clinically acceptable values in porcelain bonding strength in all three groups. However, more experimental studies and evaluations should be done in order to get better porcelain bonding strength and various surface coating methods that can be applied on titanium surface with ease.