• 제목/요약/키워드: Al(OH)$_3$

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鹽基性炭酸알루미늄 알칼리金屬 化合物의 合成 (Synthesis of Basic Alkali Metal Aluminium Carbonates)

  • 김병호
    • 대한화학회지
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    • 제21권1호
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    • pp.53-59
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    • 1977
  • 알루민산나트륨과 알루민산칼륨 용액에 $CO_2$가스 吹入法에 의해 $NaAlCO_3(OH)_2\;(Dawsonite)와\;KAlCO_3(OH)_2$를 合成하였다. 이 反應은 80 ∼ $90^{\circ}C$에서 $Na_2O/Al_2O_3,\;K_2O/Al_2O_3$의 몰比가 各 各 6∼8, 8∼10인 알루민산알칼리 용액중에 $CO_2$가스를 吹?하여 達成되었다. 알루민산알칼리 용액중에 $HCO_3^-$이 多量 存在하며 알루미나가 平衡固相으로서 Boehmite로 存在할 때 高純度의 Dawsonate와 $KAlCO_3(OH)_2$가 生成된다는 것을 알았다. 이런 條件下에서 合成된 Dawsonite와 $KAlCO_3(OH)_2$의 示性式은 赤外線吸收스펙트럼 分析結果 各各 $NaAlO(OH)HCO_3와\;KAlO(OH)HCO_3$로 나타내는 것이 妥當하다고 생각된다. 또 電子顯微鏡觀察로부터 Dawsonite는 纖維狀結晶, $KAlCO_3(OH)_2$는 針狀結晶으로 되어 있다는 것을 알았다.

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Sendust-Al(OH)3를 이용한 전파 흡수체 특성 분석 (Analysis on the Characteristics of the EM Wave Absorber Using Sendust-Al(OH)3)

  • 이대희;김동일;최창묵;송영만
    • 한국전자파학회논문지
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    • 제18권10호
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    • pp.1136-1141
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    • 2007
  • 본 논문에서 는 Sendust와 $Al(OH)_3$를 이용하여 전파 흡수체를 제작하였으며, 지지재로는 CPE(Chlorinated Polyethylene)를 이용하였다. 주 재료인 Sendust에 $Al(OH)_3$를 0 wt.%, 3 wt.%, 5 wt.%, 7 wt.%만큼 혼합하여 그 특성을 파악하였다. 그 결과 $Al(OH)_3$의 양이 5 wt.%일 때 전파 흡수 특성이 가장 향상되는 것을 알 수 있었다. 그리고 이 특성을 이용하여 적층형 전파 흡수체를 만들었으며, 두께 2 mm인 전파 흡수체가 무선 LAN사용 주파수인 2.4 GHz에서 전파 흡수능 18.5 dB의 특성을 보였다.

Al(OH)3를 PVC로 고정화한 PVC-Al(OH)3 비드의 제조와 수중의 불소 이온의 흡착 특성 (Preparation of PVC-Al(OH)3 Beads Immobilized Al(OH)3 with PVC and their Adsorption Characteristics for Fluoride Ions from Aqueous Solution)

  • 유해나;감상규;이민규
    • 한국환경과학회지
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    • 제23권5호
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    • pp.887-893
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    • 2014
  • In order to remove fluoride ions from aqueous solution, PVC-$Al(OH)_3$ beads were prepared by immobilizing $Al(OH)_3$ with polyvinyl chloride (PVC). The prepared PVC-$Al(OH)_3$ bead was characterized by using SEM, EDS and Zeta potential. Dependences of pH, contact time and initial fluoride concentration on the adsorption of fluoride ions were studied. The optimal pH was in the range of 4~10. The adsorption was rapid during the initial 12 hr, and equilibrium was attained within 72 hr. The adsorption rate of fluoride ions by PVC-$Al(OH)_3$ beads obeyed the pseudo-second-order kinetic model. The maximum adsorption capacity obtained from Langmuir isotherm model was found to be 62.68 mg/g.

EPDM계 내열재의 Al(OH)3와 Sb2O3 함량에 따른 난연 효과 연구 (Studies on Incombustibility Improvement of EPDM-based Insulation with Al(OH)3 and Sb2O3)

  • 김진용;임대현;이원복
    • 항공우주시스템공학회지
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    • 제7권4호
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    • pp.36-41
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    • 2013
  • In order to improve incombustibility of EPDM(Ethylene propylene diene monomer)-based rubber, inorganic materials as $Al(OH)_3$ and $Sb_2O_3$ were added. The mechanical and thermal properties have been measured for vulcanized rubber loaded with different concentrations of $Al(OH)_3$ and $Sb_2O_3$. As inorganic material contents increases from 5phr to 30phr, the specific gravity and hardness increase while elongation at break decreases. This study performed incombustibility test and thermal analysis through TGA(Thermogravimetric Analyzer). As a results, incombustible and thermal properties of EPDM-based rubber were improved as $Al(OH)_3$ and $Sb_2O_3$ contents increase.

$Al(OH)_3$$Sb_2O_3$의 첨가에 따른 EPDM계 고무의 난연성 향상 연구 (Studies on Incombustibility Improvement of EPDM Rubber with $Al(OH)_3$ and $Sb_2O_3$)

  • 김진용;이원복;임대현;서혁;이영우
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2009년도 제33회 추계학술대회논문집
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    • pp.449-452
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    • 2009
  • EPDM(Ethylene-propylene diene monomer)계 고무의 난연성 향상을 위하여 무기계 난연재료인 $Al(OH)_3$$Sb_2O_3$를 첨가하여 물성 및 열적 특성을 조사하였다. 각 시편의 물성은 큰 차이를 보이지 않았으나, 난연재료의 함량이 증가할 수 록 비중과 경도는 높아지는 반면에 신율은 낮아지는 경향이 있었다. 본 연구에서는 열분석과 난연성 시험을 실시하였고, 결과적으로 난연재료의 함량이 10phr 이상에서는 난연 효과가 확연히 나타나는 것으로 판단되었다.

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실험 계획법을 이용한 $Al(OH)_3$ 첨가량에 따른 고무의 난연 특성 연구 (The Study on the Flame Retardancy of Rubber according to $Al(OH)_3$ Addition Using Experimental Design Method)

  • 민영초;강윤진;김기영;강경식
    • 대한안전경영과학회지
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    • 제10권4호
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    • pp.121-126
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    • 2008
  • The effect of $Al(OH)_3$ on physical, thermal, and retardant property of rubber was studied. It was analyzed by statistical experimental design method with one way array to confirm the effect of factors. Physical characteristics, thermal pyrolysis temperature, and combustion time were considered as the properties. The amount of $Al(OH)_3$ addition was chosen as significant parameter. As the result of ANOVA analysis, thermal pyrolysis temperature increased and combustion time decreased with increasing of $Al(OH)_3$.

Al 분말의 수화 반응과 스파크 플라즈마 열처리법으로 제조된 알루미나 성형체 연구 (Study of Hydrolysis of Al Powder and Compaction of Nano Alumina by Spark Plasma Sintering(SPS))

  • 엄영랑;이민구;이창규
    • 한국분말재료학회지
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    • 제12권6호
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    • pp.422-427
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    • 2005
  • The $Al_2O_3$ with various phases were prepared by simple ex-situ hydrolysis and spark plasma sintering (SPS) process of Al powder. The nano bayerite $(\beta-Al(OH)_3)$ phase was derived by hydrolysis of commercial powder of Al with micrometer size, whereas the bohemite (AlO(OH)) phase was obtained by hydrolysis of nano Al powder synthesized by pulsed wire evaporation (PWE) method. Compaction as well as dehydration of both nano bayerite and bohemite was carried out simultaneously by SPS method, which is used to fabricate dense powder compacts with a rapid heating rate of $100^{\circ}C$ per min. under the pressure of 50MPa. After compaction treatment in the temperature ranges from $100^{\circ}C\;to\; 1100^{\circ}C$, the bayerite and bohemite phases change into various alumina phases depending on the compaction temperatures. The bayerite shows phase transition of $Al(OH)_3{\to}{\eta}-Al_2O_3{\to}{\theta}-Al_2O_3{\to}\alpha-Al_2O_3$ sequences. On the other hand, the bohemite experiences the phase transition from AlO(OH) to ${\gamma}-Al_2O_3\;at\;350^{\circ}C.$ It shows AlO(OH) ${\gamma}-Al_2O_3{\to}{\delta}-Al_2O_3{\to}{\alpha}-Al_2O_3$ sequences. The ${\gamma}-Al_2O_3$ compacted at $550^{\circ}C$ shows a high surface area $(138m^2/g)$.

$Al_{l3}$ 거대 양이온으로부터 알루미나-계면활성제 중간상의 합성 (Synthesis of Alumina-Surfactant Mesophase with $Al_{l3}$-Keggin Cation)

  • 김윤섭;고형신
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2000년도 추계종합학술대회
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    • pp.653-655
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    • 2000
  • Alumina-surfactant mesostructures have been synthesized with the $Al_{13}$-Keggin cation prepared by Al(N $O_3$)$_3$.9$H_2O$ solution with NaOH solution in the presence of a non-ionic surfactant at room temperature. The synthesized samples had the hexagonal structure similar to MCM-41 type materials. These samples have been characterized by X-ray diffraction and thermal analysis(TG). The samples prepared from OH/Al ratio 1.5 and 2.0 were well-crystalline mesostructures, but the sample from OH/Al ratio 2.5 was not. Also, The d$_{100}$ value decreased slightly from 38 to 36 according to the OH/Al mole ratio. These results could be explained that Keggin ion depended on the OH/Al molar ratio and pHpH

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Al-isopropoxide로부터 합성한 AlN 세라믹스의 기계적 성질 (Mechanical Properties of AlN Ceramics Prepaerd from Al-isopropoxide)

  • 박세민;이홍림;조덕호
    • 한국세라믹학회지
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    • 제26권4호
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    • pp.453-458
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    • 1989
  • Aluminum nitride powder prepared from the hydroxides, AlOOH and Al(OH)3 which were obtained by hydrolysis of Al-isopropoxide, was densified at 1750 and 180$0^{\circ}C$ for 60 min by hot-pressing under the pressure of 25kg/$\textrm{cm}^2$. Theoretical density could be obtained at 175$0^{\circ}C$. Their flexural strengths were 450MPa and 395MPa for the specimens obtained from Al(OH)3 and AlOOH, respectively. There was no remarkable change in flexural strength up to 100$0^{\circ}C$. Fracture toughness values were 3.50MN/m3/2 for Al(OH)3 and 3.11MN/m3/2 for AlOOH. It is assumed that these differences in mechanical properties are due to the abnormal grain growth for the AlN ceramics obtained from AlOOH.

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메카노케미컬 공정에 의한 $La_{2}O_{3}-Al_{2}O_{3}$$La_{2}O_{3}-Al(OH)_{3}$의 비교연구 (Comparative studies of the mechanochemically treatment of $La_{2}O_{3}-Al(OH)_{3}$)

  • 조정호;최상수;김강언;정수태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.701-704
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    • 2001
  • The dielectric and sintering properties of LaAlO$_3$ceramics synthesised with La$_2$O$_3$-Al$_2$O$_3$(LAO) and La$_2$O$_3$-Al(OH)$_3$(LAH) were investigated. In case of LAH samples, a single phase of LaAlO$_3$powders was formed at 100$0^{\circ}C$, density of the ceramics sintered at 140$0^{\circ}C$ was 6.41g/㎤, and the dielectric constant and loss were 22.4 and 0.003, respectively. In case of LAO samples, a single phase of LaAlO$_3$powders was formed at 130$0^{\circ}C$, density of the ceramics sintered at 150$0^{\circ}C$ was 6.35g/㎤, and the dielectric constant and loss were 22.16 and 0.009, respectively.

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