• 한국대기환경학회지
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• 제29권4호
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• pp.447-458
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• 2013

The present operating system for the atmospheric monitoring network in the city of Seoul, Korea, has been established since the late 90s by the Korean Ministry of Environment (KMOE). In this research, it was evaluated by the multi-statistical approaches through combinations of time series analysis, correlation matrix, and multiple cluster analysis. Finally, road traffic including resuspended materials can be one of the main sources of particulate matter in the atmosphere. Based on its importance, it will be significant challenges in quantitative evaluation of its contribution to airborne concentrations. The future directions for their amendments such as a new management plan for the source of road dust (including car emissions) were devised and proposed based on the statistical judgements derived in this research.

• 환경생물
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• 제20권4호
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• pp.294-299
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• 2002

PM (Particulate Matter) samples contained fungal spores were collected in the ambient air of Seosan, west Korea, in springtime of 2000 and 2001. PM concentrations were $199.8\mu{g}\;m^{-3}$ in the 1st Asian Dust Storm period (March, 23 ~ 24) and $249.4\mu{g}\;m^{-3}$ in the 2nd period (April, 7~9), 2000. Compared with the concentrations in 2000, relatively low PM concentration ($157.3\mu{g}\;m^{-3}$ ) was measured in the Asian Dust Storm period (April, 24 ~ 20) of 2001. Although there were somewhat differences for the total PM concentrations among the three periods, majorities of the PM were composed of coarse particles sized about 5 ~ 6 $\mu{m}$ over the periods of the two years. Diverse molds grown from fungal aerosols were observed in the PM samples and identified at the genus level. All the genera, Fusarium, Aspergillus, Penicillium, Basipetospora, Epicoccum and Monotospora are hyphomycetes in the division Fungi imperfecti (Deuteromycota). Especially, morphologically more diversified mycelia of hyphomycetes were grown on the fine PM sample (1.1 ~ 2.1 $\mu{m}$) than coarse PM samples in the periods of 2000. Furthermore, some molds were grown on even the background PM sample less than 0.43 $\mu{m}$ in the period of 2001. It was thought that some kinds of ultra fine sized fungal spores were transported by the Asian Dust Storm and suspended in the ambient air of study area during the events.

• 한국산업보건학회지
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• 제25권3호
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• pp.380-391
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• 2015

Objectives: The objective of this study is to assess airborne particulate matter pollution and its effect on health of residents living near Ansim Briquette Fuel Complex and its vicinities. Also, this study measured and analyzed the concentration of TSP, $PM_{10}$, $PM_{2.5}$, and heavy metals which influences on the environmental and respiratory disease in Ansim Briquette Fuel Complex, Daegu, Korea. Methods: In this study, we analyzed various environmental pollutants such as particulate matter and heavy metals from Ansim Briquette Fuel Complex that adversely affected local residents's health. In particular, we verified the concentration distribution and characteristics of exposure for TSP, $PM_{10}$, and $PM_{2.5}$ among particulate matters, and heavy metals(Cd, Cr, Cu, Mn, Ni, Pb, Fe, Zn, and Mg). In that regard, the official test method on air pollution in Korea for analysis of particulate matter and heavy metal in atmosphere were conducted. The large capacity air sampling method by the official test method on air pollution in Korea were applied for sampling of heavy metals in atmosphere. In addition, we evaluated the concentration of seasonal environmental pollutants for each point of residence in Ansim Briquette Fuel Complex and surrounding area. The sampling measured periods for air pollutants were from August 11, 2013 to February 21, 2014. Furthermore, we measured and analyzed the seasonal concentrations(summer, autumn and winter). Results: The average concentration for TSP, $PM_{10}$, and $PM_{2.5}$ by direct influence area at Ansim Briquette Fuel Complex were 1.7, 1.4 and 1.9 times higher than reference region. In analysis results of seasonal concentrations for particulate matter in four direct influence and reference area, concentration levels for winter were generally somewhat higher than concentrations for summer and autumn. The average concentrations for Cd, Cr, Mn, Ni, Pb, Fe, and Zn in direct influence area at Ansim Briquette Fuel Complex were $0.0008{\pm}0.0004{\mu}g/Sm^3$, $0.0141{\pm}0.0163{\mu}g/Sm^3$, $0.0248{\pm}0.0059{\mu}g/Sm^3$, $0.0026{\pm}0.0011{\mu}g/Sm^3$, $0.0272{\pm}0.0084{\mu}g/Sm^3$, $0.4855{\pm}0.1862{\mu}g/Sm^3$, and $0.3068{\pm}0.0631{\mu}g/Sm^3$, respectively. In particularly, the average concentrations for Cd, Cr, Mn, Ni, Pb, Fe, and Zn in direct influence area at Ansim Briquette Fuel Complex were 1.9, 3.6, 2.1, 1.9, 1.4, 2.6, and 1.2 times higher than reference area, respectively. The continuous monitoring and management were required for some heavy metals such as Cr and Ni. Moreover, the average concentration in winter for particulate matter in direct influence area at Ansim Briquette Fuel Complex were generally higher than concentrations in summer and autumn. Also, average concentrations for TSP, $PM_{10}$, and $PM_{2.5}$ were from 1.5 to 2.0 times, 1.2 to 1.8 times, and 1.1 to 2.3 times higher than reference area, respectively. In results for seasonal atmospheric environment, TSP, $PM_{10}$, $PM_{2.5}$, and heavy metal concentrations in direct influence area were higher than reference area. Especially, the concentrations in C station were a high level in comparison with other area. Conclusions: In the results, some particulate matters and heavy metals were relatively high concentration, in order to understand the environmental pollution level and health effect in surrounding area at Ansim Briquette Fuel Complex. The concentration of some heavy metals emitted from direct influence area at Ansim Briquette Fuel Complex were relatively higher than reference area. In particular, average concentration for heavy metals in this study were higher than average concentrations in air quality monitoring station for heavy metal for 7 years in Deagu metropolitan region. Especially, the residents near Ansim Briquette Fuel Complex may be exposed to the pollutants(TSP, $PM_{10}$, $PM_{2.5}$, and heavy metals, etc) emitted from the factories in Ansim Briquette Fuel Complex.

• 한국환경보건학회지
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• 제45권6호
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• pp.630-637
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• 2019

Objectives: This study was performed to evaluate the secular changes in indoor airborne dust or endotoxin levels in the dust from swine confinement buildings. Indoor levels were compared with the level at the exhaust outlet in order to examine the contribution potential of indoor dust to nearby ambient air dust. Methods: Comparisons were made on inhalable and respirable dust levels reported in 2002, 2012, and 2017 from 14, 10, and 36 swine fattening confinement buildings in Korea, respectively. This data was produced by the same research group. Levels of endotoxin adsorbed into inhalable or respirable dust were also compared. Samples of inhalable or respirable dust were collected indoors and at exhaust outlets from 17 swine fattening confinement buildings in 2019, and dust levels were compared between the indoor and the outlet. Results: The outlet inhalable dust level (0.111 mg/㎥) was approximately 19% of that from indoors, and the respirable dust level (0.033 mg/㎥) was approximately 74% of that from indoors. The outlet respirable dust levels were lower than the airborne fine dust levels in the towns where those farms are located. No significant difference was observed in the inhalable dust levels among the years examined, but the respirable dust level in 2017 (0.143 mg/㎥) was significantly lower than in 2002 (0.328 mg/㎥). The level of endotoxin in inhalable dust was significantly higher in 2017 (722 EU/㎥) than in both 2002 (75 EU/㎥) and 2012 (171 EU/㎥). Conclusion: Even though no apparent contribution from swine farm indoor dust to nearby ambient air dust was observed in terms of amount, a certain control strategy to reduce the production of airborne dust and endotoxin from swine farms is merited.

• 한국산업보건학회지
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• 제28권4호
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• pp.382-392
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• 2018

Objective: Allergic diseases such as asthma due to fungal exposure in houses have increased, and proper management is urgent. Mold can grow in the air, floor, walls, and other areas according to environmental conditions, and there are many limitations to the conventional methodology for examining fungal exposure. For this reason, the degree of fungal contamination is being evaluated by ERMI (Environmental Relative Moldiness Index), a quantitative analysis method proposed by the EPA. In this study, we compared ERMI values between water-damaged dwellings and non-damaged ones to evaluate the effectiveness of Korean ERMI values. We also explored the association of ERMI values with the level of airborne mold and characteristics of dwellings. Methods: Floor dust was collected after installing a Dustream collector on the suction port of a vacuum cleaner. The collected samples were filtered to remove only 5 mg of dust, and DNA was extracted using the FastDNA SPIN KIT protocol. Results: The ERMI values were found to be 19.6 (-6.9-58.8) for flooded houses, 7.5 (-29.2-48.3) for leaks/condensation, and 0.8 (-29.2-37.9) for non-damaged dwellings. The airborne concentration of mold for flooded, leakage or condensed, and non-damaged houses were $684CFU/m^3$, $566CFU/m^3$, and $378CFU/m^3$, respectively. The correlation between ERMI values and the levels of airborne mold was low (R = 0.038), but a weakly significant association of the ERMI values with the concentration of particulate matter ($PM_{10}$) was observed as well(R=0.231,P<0.05). Conclusions: Our findings show that the reference value using ERMI can be used to distinguish water-damaged and non-damaged dwellings. It is believed that ERMI values could be a promising tool for assessing long-term fungal exposure in dwellings.

• 대한화장품학회지
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• 제45권1호
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• pp.57-67
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• 2019

직경 $10{\mu}m$ 미만의 대기 미립자 물질(particulate matter, PM10)은 다양한 신체기관에서 산화 스트레스와 염증반응을 유발한다. 본 연구의 목적은 인간 표피 각질형성세포(HEK)에서 PM10에 의해 유도되는 반응성 산소종(ROS) 생성의 메커니즘을 알아보는 것이다. 배양된 HEK를 PM10에 노출시켰을 때 ROS가 증가하였으며, 이는 항산화제 apocynin에 의해 저해되었다. PM10에 의해 유도되는 ROS 생성에서 NADPH oxidase(NOX) family의 역할을 규명하기 위하여 이들의 mRNA 발현을 분석하였다. PM10은 NOX1, NOX2, dual oxidase (DUOX)1 및 DUOX2의 mRNA 발현을 증가시켰다. 다른 NOX들에 비교하여 DUOX1 및 DUOX2의 발현 수준이 높았으며, 이들 효소의 maturation factors, 즉 DUOXA1와 DUOXA2의 mRNA 발현도 PM10에 의하여 증가하였다. 칼슘 의존성 효소인 DUOX1과 DUOX2가 PM10에 의해 유도되는 ROS의 생성을 매개하는지 조사하였다. 선택적인 세포내 칼슘 킬레이터인 BAPTA-AM은 PM10 및 칼슘 ionophore A23187에 유도된 ROS 생성을 감소시켰다. 작은 간섭 RNA (siRNA)에 의한 DUOX2의 하향 조절은 PM10에 의해 유도된 ROS의 생성을 감소시켰고 DUOX1 siRNA는 영향이 없었다. PM10은 interleukin $(IL)-1{\beta}$, IL-6, IL-8 및 interferon $(IFN)-{\gamma}$ 등 사이토카인의 발현을 증가시켰다. siRNA에 의한 DUOX2의 하향 조절은 $IFN-{\gamma}$의 발현을 저해하였지만 다른 사이토카인의 발현은 저해하지 않았다. 본 연구는 PM10에 노출된 HEK의 ROS 생성 및 염증 반응에서 DUOX2가 중요한 역할을 함을 시사한다.

• 약학회지
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• 제34권1호
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• pp.1-10
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• 1990

Total suspended particulate (TSP) in the atmosphere was collected and size-fractionated by Andersen high volume air sampler for the past two years (Mar. 1987-Feb. 1989) in Seoul. The concentrations of several polycyclic aromatic hydrocarbons and heavy metals were determined to investigate the atmospheric concentrations, seasonal variations and its relationship with the size distribution of suspended particulate matter. The arithmetic mean concentration of total suspended particulate was $229.48\;{\mu}g/m^3$. The concentrations of heavy metals were $2971.94\;ng/m^3$ for Fe, $767.75\;ng/m^3$ for Zn, $765.80\;ng/m^3$ for Pb, $218.40\;ng/m^3$ for Cu, $129.91\;ng/m^3$ for Mn, respectively. And the concentration of PAHs were $3.23\;ng/m^3$ for benzo(a)pyrene, $2.71\;ng/m^3$ for benzo(k)fluoranthene, $4.53\;ng/m^3$ for benzo(ghi)perylene, respectively. The mass-size distribution of TSP was lowest in the particle size range $1.1-3.3\;{\mu}m$ increased as the particle size increased or decreased. But PAHs, Pb and Zn abounded in particles below $2.0\;{\mu}m$, while Fe and Mn abouned in particles above $2.0\;{\mu}m$. TSP and its chemical compositions showed the seasonal variations. The concentrations of anthrophogenic origin like TSP, PAH and heavy metals in the fine particles were highest in winter and lowest in summer. PAH and Ph analyzed showed significant correlations with each other and with TSP concentration in fine particles, indicating that the particles in which they are contained have a similar behavior in the atmosphere.

• 한국항만경제학회지
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• 제37권1호
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• pp.143-157
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• 2021

세계보건기구(World Health Organization, WHO), 경제개발협력기구(Organization for Economic Cooperation and Development, OECD)등 국제기구 및 주요 선진국에서는 대기오염의 심각성을 인지하고 있다. 또한 국제해사기구(International Maritime Organization, IMO) 등의 국제기구에서도 선박에서 발생하는 대기오염을 감소시키 위해 다양한 규제를 시행하고 있다. 이러한 국제적인 흐름에 따라 국내에서도 「항만지역등 대기질 개선에 관한 특별법」(이하 특별법)을 제정하며, 항만에서 기인하는 대기오염을 감소시키려는 노력을 보이고 있다. 특별법의 목적은 항만지역 등의 대기질을 개선하기 위하여 종합적인 시책을 추진하는 것이다. 본 연구는 이러한 정책적 움직임에 맞추어 항만에서 기인하는 대기오염물질 배출원별 배출량을 파악하여 정책의 우선순위 설정에 기초자료를 마련하고자 하였다. 이를 위해 선박, 차량, 하역장비, 하역/야적재비산먼지, 도로재비산먼지, 철도 6개 부문으로 분류하여 분석을 시행하였으며, 유럽환경청(European Environment Agency, EEA)과 미국환경보호국(United States Environmental Protection Agency, EPA)에서 제시하는 방법론을 이용하였다. 분석대상 오염물질은 일산화탄소(CO), 질소산화물(NOX), 황산화물(SOX), 총부유물질(TSP), 미세먼지 및 초미세먼지(PM10, PM2.5), 암모니아(NH3)를 대상으로 분석하였다. 분석결과 총 7,122톤의 배출량이 발생한 것으로 나타났다. 물질별로는 NOX가 5,084톤으로 가장많은 비중을 차지하는 것으로 나타났으며, 다음으로 CO(984톤), SOx(530톤), TSP(335톤)의 순으로 나타났다. 배출원 별로는 선박이 4,107톤으로써 가장 많은 비중을 차지하며 다음으로 차량이 2,622톤으로써 높은 배출량을 보였다. 이는 각각 전체 배출량의 57.6%와 36.8%로써 항만 대기오염을 유발하는 주요원인으로 판명되어 이들 배출원에 대한 대책이 필요함을 시사하였다.

• Asian Journal of Atmospheric Environment
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• 제5권3호
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• pp.146-151
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• 2011

1-Nitropyrene (1-NP), 2-NP and 2-nitrofluoranthene (2-NFR) are useful markers for studying the atmospheric behaviors of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs). However, present methods for measuring trace levels of these compounds are lesssensitive and laborious. Here we describe several improvements to a previously reported high-performance liquid chromatography-chemiluminescence detection system that allows it to determine trace levels of 1-, 2-NPs and 2-NFR. The proposed system was equipped with a reducer column packed with Pt/Rh instead of zinc whose life-time was limited. The combination of Cosmosil MS-II (monomeric ODS) and AR-II (polymeric ODS) columns was used instead of polymeric ODS columns as the separator column to improve the separation. An ethanol mixture with acetate buffer (pH 5.5) was used in place of an acetonitrile mixture with the same buffer to activate the reducer column. The same ethanol mixture was used as the mobile phase for the clean-up column. The switching time of the column switching valve was optimized to concentrate the amino-derivatives of above NPAHs quantitatively on the concentrator column. The concentrations of bis(2,4,6-trichlorophenly) oxalate and hydrogen peroxide in the chemiluminescence reagent solution were optimized to 0.4 mM and 30 mM, respectively, to increase the sensitivity. Under the above conditions, the detection limits (S/N=3) of 1-, 2-NPs and 2-NFR were 1 fmol (0.25 pg), 10 fmol (2.5 pg) and 4 fmol (1 pg), respectively. The proposed system was effectively used to determine trace levels of 1-, 2-NPs and 2-NFR in airborne particulates collected at Noto Peninsula. The atmospheric concentrations of 1-, 2-NPs and 2-NFR were not more than sub pg $m^{-3}$ levels. They were higher in winter (January) than in summer (July). In both seasons, the concentrations were in decreasing order, [2-NFR]>[1-NP]>[2-NP].

• Journal of Animal Science and Technology
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• 제64권3호
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• pp.539-563
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• 2022

Nine pig farms were evaluated for the welfare quality in Korea using animal- and environment-based parameters (particularly air quality parameters) during the winter of 2013. The Welfare Quality^® (WQ^®) protocol consists of 12 criteria within four principles. The WQ^® protocol classifies farms into four categories ranging from 'excellent' to 'not classified'. Each of these criteria has specific measures for calculating scores. Calculations for the welfare scores were conducted online using the calculation model in the WQ^® protocol. Environment-based parameters like microclimate (i.e., temperature, relative humidity, air speed, and particulate matter), bacteria (total airborne bacteria, airborne total coliform, and airborne total Escherichia coli), concentration of gases (carbon dioxide, ammonia, and hydrogen sulfide) were measured to investigate the relationship between animal- and environment-based parameters. Correlations between the results of animal- and environment-based parameters were estimated using spearman correlation coefficient. The overall assessments found that five out of nine farms were 'acceptable', and four farms were 'enhanced'; no farm was 'not classified'. The average score for the four principles across the nine farms, in decreasing order, were 'good feeding' (63.13 points) > 'good housing' (59.26 points) > 'good health' (33.47 points) > 'appropriate behaviors' (25.48 points). In the result of the environment aspect, the relative humidity of farms 2 (93.4%), 3 (100%), and 9 (98%) was much higher than the recommended maximum relative humidity of 80%, and four out of the nine farms had ammonia concentrations greater than 40 ppm. Ammonia had negative correlations with 'positive social behaviors' and positive emotional states: content, enjoying, sociable, playful, lively, happy and it had positive correlations with negative emotional states: aimless, distressed. The concentration of carbon dioxide had negative correlations with positive emotional states; calm, sociable, playful, happy and it had a positive correlation with negative emotional state; aimless. Our results indicate that the control of the environment for growing pigs can help improve their welfare, particularly via good air quality (carbon dioxide, ammonia, hydrogen sulfide).