• Title/Summary/Keyword: Air volume fraction

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Gas-particle Partitioning of Organochlorine Pesticides in Atmosphere (대기 중 유기염소계 살충제의 가스-입자 분배)

  • Choi, Min-Kyu;Chun, Man-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.4
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    • pp.457-465
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    • 2007
  • This study was performed to estimate the gas-particle partitioning of organochlorine pesticides (OCPs) in atmosphere, the samples were collected by PUF high volume air sampler for two years from June, 2000 to June, 2002. The gas phase fraction of ${\alpha/\gamma}-HCH$, heptachlor epoxide, ${\alpha/\gamma}-chlordane$ and trans-nonachlor was over 90%. But the gas phase fraction of ${\beta}-HCH$, p,p'-DDE, endosulfan sulfate, p,p'-DDD and p,p'-DDT was range of 20% through 80%, which means the gas phase fraction of OCPs components described above is sensitive to temperature. The correlation between the gas phase fraction and molecular weight of each OCPs component was not found in this research. The slope of regression line between gas-particle partitioning coefficient(${\log}K_p$) and subcooled liquid vapor(${\log}{P^o}_L$), gal-particle partitioning coefficient(${\log}K_p$) and octanol-air partitioning coefficient(${\log}K_{oa}$) which show -0.54 and 0.43 was not steep. So the equilibrium state between gas and particle was not reached and in this state the particulate fraction was low.

Air horizontal jets into quiescent water

  • Weichao Li ;Zhaoming Meng;Jianchuang Sun;Weihua Cai ;Yandong Hou
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2011-2017
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    • 2023
  • Gas submerged jet is an outstanding thermohydraulic phenomenon in pool scrubbing of fission products during a severe nuclear accident. Experiments were performed on the hydraulic characteristics in the ranges of air mass flux 0.1-1400 kg/m2s and nozzle diameter 10-80 mm. The results showed that the dependence of inlet pressure on the mass flux follows a power law in subsonic jets and a linear law in sonic jets. The effect of nozzle submerged depth was negligible. The isolated bubbling regime, continuous bubbling regime, transition regime, and jetting regime were observed in turn, as the mass flux increased. In the bubbling regime and jetting regime, the air volume fraction distribution was approximately symmetric in space. Themelis model could capture the jet trajectory well. In the transition regime, the air volume fraction distribution loses symmetry due to the bifurcated secondary plume. The Li correlation and Themelis model showed sufficient accuracy for the prediction of jet penetration length.

Microstructure and Mechanical Properties of 600 MPa-Grade Seismic Resistant Reinforced Steel Bars Fabricated by a Pilot Plant (Pilot Plant를 이용한 600 MPa급 내진용 철근들의 제조, 미세조직과 기계적 특성 비교)

  • Hong, Tae-Woon;Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.29 no.6
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    • pp.349-355
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    • 2019
  • This study deals with the microstructure and tensile properties of 600 MPa-grade seismic reinforced steel bars fabricated by a pilot plant. The steel bar specimens are composed of a fully ferrite-pearlite structure because they were air-cooled after hot-rolling. The volume fraction and interlamellar spacing of the pearlite and the ferrite grain size decrease from the center region to the surface region because the surface region is more rapidly cooled than the center region. The A steel bar specimenwith a relatively high carbon content generally has a higher pearlite volume fraction and interlamellar spacing of pearlite and a finer ferrite grain size because increasing the carbon content promotes the formation of pearlite. As a result, the A steel bar specimen has a higher hardness than the B steel bar in all the regions. The hardness shows a tendency to decrease from the center region to the surface region due to the decreased pearlite volume fraction. On the other hand, the tensile-to-yield strength ratio and the tensile strength of the A steel bar specimen are higher than those of the B steel bar with a relatively low carbon content because a higher pearlite volume fraction enhances work hardening. In addition, the B steel bar specimen has higher uniform and total elongations because a lower pearlite volume fraction facilitates plastic deformation caused by dislocation slip.

Effect of Diluents and Oxygen-Enrichness on the Stability of Nonpremixed Flame (산소부화와 희석제에 따른 비예혼합 화염의 안정성)

  • 배정락;이병준
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.10
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    • pp.1458-1464
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    • 2002
  • $CO_2$ is well known greenhouse gas which is the major source of global warming. Reducing $CO_2$ emission in combustion process can be achieved by increasing combustion efficiency, oxygen enriched combustion and recirculation of the emitted $CO_2$ gas. Stability of non-premixed flame in oxygen enriched environment will be affected by the amount of oxygen, kind of diluents and fuel exit velocity. The effects of these parameters on flame liftoff and blowout are studied experimentally oxidizer coflowing burner. Experiments were divided into three cases according as where $CO_2$gas was supplied. - 1) to coflowing air, 2) to fuel with 0$_2$-$N_2$ coflow, 3) to coflowing oxygen. Flame in air coflowing case was lifted in turbulent region. Flame lift and blowout in laminar region with the increase in $CO_2$ volume fraction in $CO_2$-Air mixture makes flame lift and blowout in laminar region. Increase in oxygen volume fraction makes flame stable-i.e. flame liftoff and blowout occur at higher fuel flowrates. Liftoff height was non-linear function of nozzle exit velocity and affected by the $O_2$ volume fraction. It was found that the flame in $O_2$-$N_2$ coflow case was more stable than $O_2$-$CO_2$ case, Liftoff heights vs (nozzle exit velocity/laminar burning velocity)$^{3.8}$ has a good correlation in $O_2$-$CO_2$ oxidizer case.

Combustion Characteristics and Soot Formation in a Jet Diffusion Flame (제트 확산화염의 연소특성과 매연생성에 관한 연구)

  • 이교우;백승욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.10
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    • pp.2712-2723
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    • 1994
  • Numerical simulation of an axisymmetric ethylene-air jet diffusion flame has been carried out in order to investigate flame dynamics and soot formation. The model solves the time-dependent Navier-Stokes equations and includes models for soot formation, chemical reaction, molecular diffusion, thermal conduction, and radiation. Numerically FCT(Flux Corrected Transport) and DOM(Discrete Ordinate Method) methos are used for convection and radiation trasport respectively. Simulation was conducted for a 5 cm/sec fuel jet flowing into a coflowing air stream. The maximum flame temperature was found to be approximately 2100 K, and was located at an axial position of approximately 5 cm from the base of the flame. The maximum soot volume fraction was about $7{\times}10^{-7}$, and was located within the high temperature region where the fuel mole fraction ranges from 0.01 to 0.1. The buoyancy-driven low-frequency(12~13 Hz) structures convected along the outer region of the flame were captured. In case without radiation trasport, the maximum temperature was higher by 150 K than in case with radiation. Also the maximum soot volume fraction reached about $8{\times}10^{-6}$. As the the hydrocarbon fuel forms many soot particles, the radiation transport becomes to play a more important role.

Study on the Asymmetric Regional Deposition of Airborne Pollutant Particles in the Human Respiratory Tract (대기오염 입자의 인체 호흡기내 비대칭 국부침전 특성에 관한 연구)

  • 구재학;김종숭
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.5
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    • pp.551-560
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    • 2003
  • Particle deposition in human lungs was investigated theoretically by using asymmetric five-lobe lung model. The volumes of each of the five lobes were different, thereby forming an asymmetric lung structure. The tidal volume and flow rate of each lobe were scaled according to lobar volume. The total and regional deposition with various breathing patterns were calculated by means of tracking volume segments and accounting for particle loss during inhalation and exhalation. The deposition fractions were obtained for each airway generation and lung lobe, and dominant deposition mechanisms were investigated for different size particles. Results show that the tidal volume and flow rate have a characteristic influence on particle deposition. The total deposition fraction increases with an increase in tidal volume for all particle sizes. However, flow rate has dichotomous effects: a higher flow rate results in a sharp increase in deposition for large size particles, but decreases deposition for small size particles. Deposition distribution within the lung shifts proximally with higher flow rate whereas deposition peak shifts to the deeper lung region with larger tidal volume. Deposition fraction in each lobe was proportional to its volume. Among the three main deposition mechanisms, diffusion was dominant for particles < 0.5 ${\mu}{\textrm}{m}$ whereas sedimentation and impaction were most influential for larger size particles. Impaction was particularly dominant for particles> 8 ${\mu}{\textrm}{m}$. The results may prove to be useful for estimating deposition dose of inhaled pollutant particles at various breathing conditions.

LASER-INDUCED SOOT VAPORIZATION CHARACTERISTICS IN THE LAMINAE DIFFUSION FLAMES

  • Park, J.K.;Lee, S.Y.;Santor, R.
    • International Journal of Automotive Technology
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    • v.3 no.3
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    • pp.95-99
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    • 2002
  • The characteristics of soot vaporization induced by a high-energy Pulsed laser were studied in an ethylene-air laminar flame. A system consisting of two pulsed lasers was used for the experiments. The pulse from the first laser was used to vaporize the soot particles, and the delayed pulse from the second laser was used to measure the residual soot volume fraction. Laser-induced soot vaporization was characterized according to the initial particle size distribution. The results indicated that soot particles could not be completely vaporized simply by introducing a high intensity laser pulse. Residual soot volume fractions present after vaporization appeared to be insensitive to the initial soot particle size distribution. Since the soot vaporization effect is more pronounced in the region of high soot concentrations, this laser-induced soot vaporization technique may be a very useful tool for measuring major species in highly sooting flame.

An Experimental Study of the Effect of Flow on Flame Propagation in a Constant-Volume Combustion Chamber (정적연소기내 유동형태가 화염전파에 미치는 영향 연구)

  • Jeong, D.S.;Oh, S.M.;Suh, S.W.;Chang, Y.J.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.2
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    • pp.136-145
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    • 1995
  • The aim of this study is to gain a better understanding of the effect of a flow motion on the flame development by means of an optically-accessible constant-volume combustion chamber and the visualization technique of a combustion flame. At first, the characteristics of a flame propagation are investigated in the combustion field of the two kinds of flow conditions such as a quiescent and a flowing condition, and methane-air mixture is used as fuel. Then the same investigation is performed in two flow configurations : bulk flow motion type and turbulence generating type. In this study, the combustion phenomena are analyzed by measuring the combustion pressure, flame propagation speed, mean velocity, turbulent intensity, and mass fraction burned.

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Calculation of Two-Phase Turbulent Jet with a Two-Equation Model (2-方程式 모델 에 의한 二相亂流 제트流動 의 數値解析)

  • 양선규;최영돈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.6
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    • pp.714-724
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    • 1985
  • Two-phase(air-solid, air-liquid droplet) turbulent round jet has been analyzed numerically using two equation turbulence model. The mean motion of suspending particles in air has been treated as the secondary fluid with virtual density and eddy viscosity. In this paper, the local mean velocity of secondary fluid is not assumed to be the same as that of the primary one. Dissipation rate of turbulent kinetic energy which arises because the particles can not catch up with the turbulent fluctuations of the primary fluid has been modelled by using the concept of Kolmogorov's spectral energy transfer. Numerical computations were performed for flows with different volume fraction of the dispersed phase and the diameter of particle. Results show that the total rate of turbulent energy dissipation, turbulent intensities and spreading rate of jets are reduced by the increase of volume fraction of dispersed phase. However it does not show consistent tendency with increasing the particle diameter. This investigation also shows that presence of particles in the fluid modifies the structure of the primary fluid flow significantly. Predicted velocity profiles and turbulence properties qualitatively agree with available data.

Determining Potassium Bromate in the Inhalable Aerosol Fraction in Workplace Air with Ion Chromatography

  • Kowalska, Joanna;Lis, Monika;Biesaga, Magdalena
    • Safety and Health at Work
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    • v.12 no.2
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    • pp.209-216
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    • 2021
  • Background: The article presents the results of studies performed in order to develop a new method of airborne potassium bromate(V) determination at workplaces. Methods: The method is based on a collection of the inhalable fraction of potassium bromate(V) using the IOM Sampler, then extraction of bromates with deionized water and chromatographic analysis of the obtained solution. The analysis was performed using ion chromatography with conductometric detection. The tests were performed on a Dionex IonPac®AS22 analytic column (250 × 4 mm, 6 ㎛) with AG22 precolumn (50 × 4 mm 11 ㎛). Results: The method provides for potassium bromate(V) determination within the concentration range of 0.043 ÷ 0.88 mg/m3 for an air sample of 0.72 m3 in volume, i.e., 0.1-2 times the exposure limit value as proposed in Poland. The method was validated in accordance with PN-EN 482. The obtained validation data are as follows: measuring range: 3.1-63.4 ㎍/mL, limit of detection (LOD) = 0.018 ㎍/mL and limit of quantification (LOQ) = 0.053 ㎍/mL. The developed method has been tested in the work environment, on laboratory employees having contact with potassium bromate(V). Conclusion: The analytical method allowed the determination of the inhalable fraction of airborne potassium bromate(V) at workplaces and can be used to assess occupational exposure.