• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.291-300
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• 2008

Catalytic cracking of n-octane was carried out over H-ZSM-5 zeolite catalysts after calcination with air and steaming with 100% steam in the temperature range of $550-750^{\circ}C$ for 24 h and compared with the results of thermal cracking. The increase of calcination and steaming temperature resulted in the decrease of surface area, pore volume, and strong acid sites, which was mainly caused by the dealumination of H-ZSM-5 framework. It was found by $^{27}Al$ and $^{29}Si$ MAS NMR that the dealumination was proceeded through the transformation process of tetrahedral framework Al${\rightarrow}$penta-cordinated Al ${\rightarrow}$ octahedral framework Al and the phenomena was much more severe in steaming conditions than that of calcination. In the catalytic cracking of n-octane, as the temperatures of calcination and steaming were increased, the conversion of n-octane, the selectivity of light olefins and ethylene to propylene ratio were decreased due to the dealumination of framework aluminum resulting the loss of acidic strengths. The conversion, selectivity of light olefins and ethylene to propylene ratio reached almost to the level of thermal cracking after steaming at $750^{\circ}C$ for 24 h.

• Journal of the Korea Institute of Building Construction
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• v.14 no.6
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• pp.639-645
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• 2014

For the construction materials, concrete, as the most widely used material, is focused on its improvement of performance. Although concrete has many advantages of easiness of handling, economical benefits, and high compressive strength, low tensile strength, brittleness and drying shrinkage are reported as the drawbacks of concrete. Hence, to solve these drawbacks of concrete, many research has conducted especially using fiber-reinforced concrete technology. Especially, HPFRCC which has high volume of fiber reinforcement was suggested as a solution of these drawbacks of normal concrete with increased ductility while it has the possibility of workability loss with fiber clumping which can cause low performance of concrete. Therefore, in this paper, optimized fiber combination with either or both metal and organic fibers is suggested to provide better performance of HPFRCC in tensile strength and ductility. As the results of experiment, better workability was achieved with 1 % of single fiber rather than multiple fibers combinations, espeically, short steel fiber showed the best workability result. Furthermore, in the case of organic fibers which showed higher air content than steel fibers, higher compressive strength was achieved while lower tensile and flexural strength were shown.

• Journal of the Korean Society of Food Science and Nutrition
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• v.38 no.12
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• pp.1760-1766
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• 2009

Physical properties of Yukwa base extruded with glutinous rice flour, rice flour, defatted soy flour, and salt using an twin-screw extruder were investigated. The ingredients were extruded at various moisture contents (16-18%), screw speeds (300 & 400 rpm) at 43.4 kg/hr feed rate. Length and specific volume of Yukwa base increased with decreasing moisture contents. Hunter's color L* values of Yukwa base was higher whereas $a^*\;and\;b^*$ values were lower with increasing moisture content. Water absorption index of Yukwa base increased with increasing moisture contents. X-ray diffraction of Yukwa base showed B type moisture content of 16% and 17% while it showed A type moisture content of 18%. Degree of crystallinity and breaking strength of Yukwa base were the lowest in the moisture content of 16% while the lowest value for hardness was found in the moisture content of 16% and of 17% with screw speed 400 rpm for all samples. In the microstructure of cross section of Yukwa base, air cell size was larger and cell wall was thicker as moisture content increased. The sensory evaluation of the Yukwa base showed that color and flavor were not significantly different among samples, while taste, appearance, mouth feel, and overall preference were higher as moisture contents decreased.

• Journal of Bio-Environment Control
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• v.9 no.1
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• pp.20-26
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• 2000

This study aims at analyzing physical and chemical properties of perlite substrate. Particles of substrate were divided into five categories In size: gravel, very-coarse, coarse, medium and fine grade. Particles of very-coarse and greater grades in perlite substrate occupied 98.5％ of total particles. The air phase of total particles was distributed between 76.8％ and 87.7％ with especially showing that of very-coarse grade was lower than that of coarse or smaller one. However, the liquid and solid phases were vice versa. The cation exchange capacity (CEC) measured was highest in the fine grade. In drainage experiments, the water being drained from the substrate increased with the ratio of drain area, and the 65~70％ of total water reduced within five minutes after irrigation. The drained volume was proportional to the depth of the substrate, which contained about 2mL.cm$^2$：by depth (cm). Due to quick reduction of the water in the substrate, the pF value increased in four minutes after irrigation and showed the highest negative correlation ($R^2$＝0.997) with the moisture content of the substrate. The physical and chemical properties including drainage characteristics analyzed in this study can be, therefore, utilized to control the moisture content of perlite substrate, efficiently.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.3 no.3
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• pp.1-7
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• 1983

In spite of extensive knowledge of the surface chemistry and the transport mechanism in filtration systems, there is still insufficient understanding of the physical characteristics of suspensions and the system components. Because of this, no filtration mechanisms are mathematically generalized to the full extent. The purpose of this paper is to propose experimental equations for the filtration process. using the tracer study in filter layer. Some of results are as follows. (1) The Volume of the specific deposit (${\sigma}$) in filtration was directly measurable using the tracer study without interrupting the filtration. (2) It was also confirmed that the head loss in filtration was greatly in fluenced by the micro-air babbles. (3) The correction coefficient(f) was introduced into the Kozeny-Carman equation in order to apply it for the clogging filter media. The coefficient(f) was experimentally obtained. The total head loss of the filter media is given by next equation. $${\frac{h}{h_0}}={\frac{1}{L}}{\int}^{z=L}_{z=0}f({\sigma})g({\varepsilon}_0,{\sigma})dz$$ $$f=aexp(-b{\sigma})$$ The above equation was applicable without regard to the variation of the suspension concentration, the filter medium diameter, the filter depth, the filtration velocity, and the amount of aluminum in all continuous filtration experiments. (4) The total head loss was graphically generalized assuming mathematical filtration models I II (see fig. 7,8) (5) The total head loss was obtained from the filtration model in the field filtration conditions. (see fig. 9,10)

• Applied Chemistry for Engineering
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• v.24 no.5
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• pp.544-550
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• 2013

This work investigated the environmental application of an underwater dielectric barrier discharge plasma reactor consisting of a porous hydrophobic ceramic tube to the decolorization of an azo dyeing wastewater. The reactive species generated by the plasma are mostly short-lived, which also need to be transferred to the wastewater right after the formation. Moreover, the gas-liquid interfacial area should be as large as possible to increase the decolorization rate. The arrangement of the present wastewater treatment system capable of immediately dispersing the plasmatic gas as tiny bubbles makes it possible to effectively decolorize the dyeing wastewater alongside consuming less amount of electrical energy. The effect of discharge power, gas flow rate, dissolved anion and initial dye concentration on the decolorization was examined with dry air for the creation of plasma and amaranth as an azo dye. At a gas flow rate of $1.5Lmin^{-1}$, the good contact between the plasmatic gas and the wastewater was achieved, resulting in rapid decolorization. For an initial dye concentration of $40.2{\mu}molL^{-1}$ (volume : 0.8 L; discharge power : 3.37 W), it took about 25 min to attain a decolorization efficiency of above 99%. Besides, the decolorization rate increased with decreasing the initial dye concentration or increasing the discharge power. The presence of chlorine anion appeared to slightly enhance the decolorization rate, whereas the effect of dissolved nitrate anion was negligible.

• Proceedings of KOSOMES biannual meeting
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• 2007.11a
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• pp.97-102
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• 2007

The piggery wastewater is the major source of the water pollution problem in the rural area. The treatment alternatives for piggery wastewater are limited by the characteristics of both high organic and nitrogen(N) content. In order to investigate an efficient N removal system, the thermophilic aerobic digestion process was examined. The experiment was investigated organic and nitrogen removal efficiency at various HRTs and air supply volume. The results of semi-continuous experiment indicated that a higher removal of the soluble portion of COD was achieved with the longer HRTs. However, the inert portion of COD in piggery wastewater was not much changed by thermophilic aerobic digestion. In addition, with the higher HRT of 3 days, up to 79% of NH4-N removal efficiency was achieved. Lower the HRTs, a decrease of NH4-N removal was founds. The gas samples from the lab reactor were analyzed along with the N content in influent and effluent. The N2O formation in our system indicates a novel aerobic deammonification process occurred during the thermophilic aerobic digestion. Both N02 and N03 were not presented in the effluent of thermophilic aerobic digester. With the HRT of 3 days, 36.4% of influent N(or 57.5% removal N) was aerobically converted to N2O gas. The ammonium conversion to N2O gas significantly decrease to 4.5% at low HRT of .05 day..

• Journal of the Korean Chemical Society
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• v.37 no.11
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• pp.923-928
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• 1993

The series of solid solutions in the $Sr_{1+x}Ho_{1-x}FeO_{4-y}$ (x = 0.00, 0.25, 0.50, 0.75 and 1.00) systems with $K_2NiF_4$ type structure have been prepared at 1550$^{\circ}$C under an atmospheric air pressure. The X-ray powder diffraction spectra of these samples assign that the crystallographic phases are tetragonal system over the whole x range. The lattice volume was increased with increasing the substitution amount of the $Sr^{2+}$ ion. The mole ratio of the $Fe^{4+}$ ion to total iron ions or ${\tau}$ value has been determined by Mohr salt titration of the sample and then the y value was calculated from x and ${\tau}$ values. The ${\tau}$ and y values have been increased with x values. The nonstoichiometric chemical formula are formulated from the general formula of $Sr_{1+x}Ho_{1-x}Fe^3_{1-}\;^+_{\tau}Fe_{\tau}^{4+}O_{4-y}$ replaced by x,${\tau}$ and y values. Mossbauer spectra show the mixed valence state and coordination state of $Fe^{3+}\;and\;Fe^{4+}$ ions. It is found out that the magnetic property of the samples is paramagnetic at room temperature. Electrical conductivity varied within the semiconductivity range of 1.0 to 1 ${\times}\;10^{-9}{\Omega}^{-1}cm^{-1}$. Activation energy of the electrical conductivity was decreased with the $\tau$ value. The conduction mechanism should be explained by the hopping model of the conduction electrons between the valence states of $Fe^{3+}\;and\;Fe^{4+}$ ions.

• Korean Journal of Agricultural Science
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• v.40 no.4
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• pp.317-323
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• 2013

This research was conducted to obtain the basic information for establishment of standard guidelines in the design and installation of roof ventilation system in single-span plastic greenhouse. To achieve this, the greenhouse structure & characteristics, cultivation status, and ventilation system were investigated for single-span greenhouse with roof ventilation system cultivating the Cucurbitaceae vegetables, watermelon, cucumber, and oriental melon. Most of single-span watermelon greenhouse in Haman and Buyeo area were a hoop-style and the ventilation system in those greenhouses mostly consisted of two different types of 'roof vent (circular or chimney type) + side vent (hole) + fan' and 'roof vent (circular type) + side vent (hole or roll-up type)'. The diameter of circular and chimney-type vent was mostly 60cm and the average number of vents was 10.5 per a bay with vent spacing of average 6.75m. The ratio of roof vent area to floor area and side vent area in the single-span watermelon greenhouse with ventilation fan were 0.46% and 7.6%, respectively. The single-span cucumber greenhouse in Haman and Changnyeong area were a gable roof type, such as even span, half span, three quarter and the 70.6% of total investigated single-span greenhouses was equipped with a roof ventilation fan while 58.8% had a circulation fan inside the greenhouse. The ratios of roof vent area to floor area in the single-span cucumber greenhouse ranged from 0.61 to 0.96% and in the case of the square roof vent, were higher than that of the circular type vent. On average, the roof ventilation fan in single-span cucumber greenhouse was equipped with the power input of 210W and maximum air volume of $85.0m^3/min$, and the number of fans was 9.75 per a bay. The number of roof vent of single-span oriental melon greenhouse with only roll-up type side vent ranged from 8 to 21 (average 14.8), which was higher than that of other Cucurbitaceae vegetables while the vent number of the greenhouse with a roof ventilation fan was average 7 per a bay.

• Journal of Korea Soil Environment Society
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• v.1 no.1
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• pp.89-102
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• 1996

An integrated model is presented to describe underground flow and mass transport, using a multicomponent multiphase approach. The comprehensive governing equation is derived considering mass and force balances of chemical species over four phases(water, oil, air, and soil) in a schematic elementary volume. Compact and systemati notations of relevant variables and equations are introduced to facilitate the inclusion of complex migration and transformation processes, and variable spatial dimensions. The resulting nonlinear system is solved by a multidimensional finite element code. The developed code with dynamic array allocation, is sufficiently flexible to work across a wide spectrum of computers, including an IBM ES 9000/900 vector facility, SP2 cluster machine, Unix workstations and PCs, for one-, two and three-dimensional problems. To reduce the computation time and storage requirements, the system equations are decoupled and solved using a banded global matrix solver, with the vector and parallel processing on the IBM 9000. To avoide the numerical oscillations of the nonlinear problems in the case of convective dominant transport, the techniques of upstream weighting, mass lumping, and elementary-wise parameter evaluation are applied. The instability and convergence criteria of the nonlinear problems are studied for the one-dimensional analogue of FEM and FDM. Modeling capacity is presented in the simulation of three dimensional composite multiphase TCE migration. Comprehesive simulation feature of the code is presented in a companion paper of this issue for the specific groundwater or flow and contamination problems.