• 환경영향평가
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• 제24권1호
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• pp.66-77
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• 2015

본 연구는 2001년 1월부터 2011년 12월까지 국가산단인 여수시 인구집단을 대상으로 일일 사망자료와 환경측정자료 및 기상자료를 이용하여 대기오염 물질 중 미세먼지($PM_{10}$)와 이산화황($SO_2$)이 일별 총 사망과 심혈관계 사망에 미치는 영향을 추정하였다. 대기오염과의 상관성분석은 S-Plus 프로그램을 이용한 generalized additive models(GAM)을 적용하여 시계열(Time-Series) 분석법을 실시하였다. 총 사망의 위해도는 65세 이상에서 $SO_2$의 농도가 11.67ppb(IQR) 증가함에 따라 5.0% 증가하였고, 심혈관계 사망의 위해도는 전체연령에서 8.6% 증가하는 것으로 나타났다. 지연효과는 총 사망과 심혈관계 사망의 모든 연령 그룹에서 사망 당일부터 7일 전 $SO_2$농도와 가장 관련성이 높은 것으로 분석되었다.

• 한국대기환경학회지
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• 제27권1호
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• pp.73-86
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• 2011

Haze phenomena were analyzed to assess the impact of long range transport process on the air quality of Seoul and Busan. We statistically classified haze days observed in both Seoul and Busan into two types of haze cases: stagnant case and long-range transport case, and analyzed the air pollutant levels comparatively for each of the two cases for the period of 2000~2007. The results showed that the long-range transport haze case occurs less frequently with the occurrence frequency of 35.5% than stagnant case with the occurrence frequency of 64.5%. During the observed all haze days, all pollutants have high concentration in comparison with those under other meteorological conditions (Rain, Mist, Dust, Clear, Rain+Mist) except for only $PM_{10}$ of Dust case where its level shows highest among total 6 categorized conditions. The long range transport haze case shows similar levels of $PM_{10}$ and $NO_2$, but higher $SO_2$ and lower $O_3$ compared with stagnant haze cases, suggesting the importance of sulfur chemistry for long range transport haze case and local photochemistry for stagnant haze case. In addition, by employing the NOAA/HYSPLIT-4 backward trajectory model, we subdivided the long range transport haze cases into two different sources: urban anthropogenic high emission areas of central China, and natural emission sources over north China and/or Mongolia. The former long range transport haze case shows higher occurrence (with Seoul 70% and Busan 85%) than the latter haze case (with Seoul 30% and Busan <10%). This is also implying that the long haze phenomena occurred over Korea have been influenced by not only the anthropogenic emissions but also the natural dust emissions. These both emission sources can be good contributors in calculating the source-receptor relationship over Korean atmospheric environment.

• 한국학교보건학회지
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• 제16권1호
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• pp.81-90
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• 2003

This study was conducted to contribute to the basic data for decisions on environment policy improvement in health promotion for students in elementary, middle and high schools. This study was carried out to investigate the extent of indoor air pollution in elementary, middle and high schools in residential, traffic congestional and industrial areas. The concentrations of major indoor air pollutants(carbon monoxide, carbon dioxide, respiratory particulate, radon) and thermocircumstance (temperature, relative humidity, intensity of illumination) indices were observed from June to August 2000. As results of the survey, the mean values of thermocircumstance in school were $26.94{\pm}1.15^{\circ}C$ of temperature, $68.88{\pm}5.31%$ of humidity and $268.26{\pm}164.60$ Lux of intensity of illumination. The mean concentrations of carbon monoxide, carbon dioxide, respiratory particulate were $8.36{\pm}0.29\;ppm$, $547.66{\pm}175.58\;ppm$, $36.23{\pm}48.39\;{\mu}g/m3$, respectively. These values were lower than those of the indoor environmental standard on the first clause of Article 45 of public utilization service notified public hygiene of the Ministry of Health and Social Affairs. The mean concentration of radon was $20.07{\pm}17.95\;Bq/m3$. Which was below the U.S. EPA radon action level.

• 한국안전학회지
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• 제35권6호
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• pp.85-92
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• 2020

Wet Scrubber reacts the incoming pollutant gas with cleaning water (water + absorbent) to absorb pollutants and release the clean air to the atmosphere. Wet scrubbers and packed tower scrubbers using this principle are widely used in businesses that emit acid gases. In particular, in the etching process using hydrochloric acid (HCl), alkaline washing water (NaOH) having a pH of about 8 to 11 is used to absorb a large amount of acid gas. However, These salts are attached to the injection nozzle (nozzle), filling material (packing), and the demister (Demister), causing air pollution, human damage, and inoperability due to clogging and acid gas discharge. Therefore, In this study, an improvement plan was proposed to manage the washing water with pH 3~4 acidic washing water. The test method takes samples from the Wet Scrubber flue measurement laboratory twice a month for 1 year. Hydrogen chloride (HCl) concentration (ppm) was measured, and nozzle clogging and scale conditions were measured, compared, and analyzed through a differential pressure gauge and a pressure gauge. As a result of the check, it was visually confirmed that the scale was reduced to 50% or less in the spray nozzle, filler, and demister. In addition, the emission limit of hydrogen chloride in accordance with the Enforcement Regulation of the Air Quality Conservation Act [Annex 8] met 3 ppm or less. Therefore, even if the washing water is operated in an acidic pH range of 3 to 4, it is expected to reduce air pollution and human damage due to clogging of internal parts, and it is expected to reduce maintenance costs such as regular cleaning or replacement of parts.

• Communications for Statistical Applications and Methods
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• 제30권2호
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• pp.119-133
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• 2023

With the rapid growth of the economy and fossil fuel consumption, the concentration of air pollutants has increased significantly and the air pollution problem is no longer limited to small areas. We conduct statistical analysis with the actual data related to air quality that covers the entire of South Korea using R and Python. Some factors such as SO₂, CO, O₃, NO₂, PM₁₀, precipitation, wind speed, wind direction, vapor pressure, local pressure, sea level pressure, temperature, humidity, and others are used as covariates. The main goal of this paper is to predict air quality index (AQI) spatio-temporal data. The observations of spatio-temporal big datasets like AQI data are correlated both spatially and temporally, and computation of the prediction or forecasting with dependence structure is often infeasible. As such, the likelihood function based on the spatio-temporal model may be complicated and some special modelings are useful for statistically reliable predictions. In this paper, we propose several methods for this big spatio-temporal AQI data. First, random effects with spatio-temporal basis functions model, a classical statistical analysis, is proposed. Next, neural networks model, a deep learning method based on artificial neural networks, is applied. Finally, random forest model, a machine learning method that is closer to computational science, will be introduced. Then we compare the forecasting performance of each other in terms of predictive diagnostics. As a result of the analysis, all three methods predicted the normal level of PM_2.5 well, but the performance seems to be poor at the extreme value.

• Asian Journal of Atmospheric Environment
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• 제10권4호
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• pp.208-216
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• 2016

This paper reports the results of a field evaluation which used sampling and analytical methods to determine the levels of airborne hexavalent chromium Cr(VI) in major industrial complexes in Korea over a seven year period (2007-2013). Cr(VI) concentrations were determined using cellulose filter sampling and ion chromatography analysis. In order to validate the analytical performance of these methods, studies were also carried out to investigate data quality control (QC) parameters, such as the method detection limit (MDL), repeatability, and recovery efficiencies. The average concentrations of Cr(VI) for the nine industrial complexes in Korea were in the range of 0.09 to $1.40ng/m^3$, which is similar to of the concentrations in other industrial areas around the world. The impacts of Cr(VI) emissions from industrial areas on Cr(VI) concentrations in neighboring-residential areas were considerably low, and the dispersion of Cr(VI) from industrial areas to residential areas was estimated to be 'not-significant'. Cr(VI) levels were not affected by seasonal variation, which suggests that chromium was emitted continuously from the industrial sources throughout the year. The concentration of Cr(VI) measured accounted for 0.7 to 9.4 percent of the total chromium level, which is a low percentage compared to those in other urban areas around the world. This is the first report in an international journal of a field study conducted in Korea to determine the concentration of Cr(VI) in the ambient air of industrial and residential areas.

• 한국환경보건학회지
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• 제41권1호
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• pp.49-60
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• 2015

Objectives: Pine needles were used as a passive air sampler (PAS) of atmospheric persistent organic pollutants (POPs). This study was performed to investigate concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) deposited on pine needles near a waste incinerator and PCDD/Fs source contributions using principal component analysis (PCA). Methods: Two-year-old pine needles were sampled at 11 points with respect to distance and wind direction from the incinerator. PCDD/Fs deposited on pine needles were analyzed with HRGC/HRMS. The source contribution of PCA was calculated with SPSS. Results: The average concentration of PCDD/Fs deposited on pine needle was 0.79 (0.27-1.76) pg TEQ/g dry, PCDDs with 0.24 (0.01-0.95) pg TEQ/g dry and PCDFs with 0.56 (0.27-0.82) pg TEQ/g dry, respectively. The average concentration fraction of PCDDs was 29.7%, that of PCDFs was 70.3%, and PCDFs were more prevalent than PCDDs. The contributions of PCDD/Fs sources were estimated as incineration at 58.3% and automobiles at 28.4%. However, a relation and regulation between PCDD/Fs concentrations deposited on pine needles and distance from incinerator or wind direction was not shown. Conclusion: It was concluded that atmospheric PCDD/Fs concentrations near an industrial complex with a waste incinerator were affected by multiple sources. However, PCDD/Fs concentrations were lower than in other inland cities with the exception of background area.

• 한국환경과학회지
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• 제21권11호
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• pp.1321-1331
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• 2012

To date, carbon and nitrogen co-doped photocatalysts (CN-$TiO_2$) for environmental application focused mainly on the aqueous phase to investigate the decomposition of water pollutants. Accordingly, the present study explored the photocatalytic performance of CN-$TiO_2$ photocatalysts for the purification of indoor-level gas-phase aromatic species under different operational conditions. The characteristics of prepared photocatalysts were investigated using X-ray diffraction, scanning emission microscope, diffuse reflectance UV-VIS-NIR analysis, and Fourier transform infrared (FTIR) analysis. In most cases, the decomposition efficiency for the target compounds exhibited a decreasing trend as input concentration (IC) increased. Specifically, the average decomposition efficiencies for benzene, toluene, ethyl benzene, and xylene (BTEX) over a 3-h process decreased from 29% to close to zero, 80 to 5%, 95 to 19%, and 99 to 32%, respectively, as the IC increased from 0.1 to 2.0 ppm. The decomposition efficiencies obtained from the CN-$TiO_2$ photocatalytic system were higher than those of the $TiO_2$ system. As relative humidity (RH) increased from 20 to 95%, the decomposition efficiencies for BTEX decreased from 39 to 5%, 97 to 59%, 100 to 87%, and 100 to 92%, respectively. In addition, as the stream flow rates (SFRs) decreased from 3.0 to 1.0 L $min^{-1}$, the average efficiencies for BTEX increased from 0 to 58%, 63 to 100%, 69 to 100%, and 68 to 100%, respectively. Taken together, these findings suggest that three (IC, RH, and SFR) should be considered for better BTEX decomposition efficiencies when applying CN-$TiO_2$ photocatalytic technology to purification of indoor air BTEX.

• 환경위생공학
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• 제21권3호
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• pp.15-26
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• 2006

As traffic in city-centre around the world continues to increase, so levels of atmospheric pollutants continue to rise. High concentrations of NOx can have negative effects on human health, and we must find new ways to reduce their levels in the air we breathe. Nitrogen oxide gas (NOx), consisting of nitrogen monoxide (NO) and nitrogen dioxide $(NO_2)$ produced using $O_3$ oxidation, at a low concentration corresponding to that on roads as a result of exhaust from automobiles, was carried out to evaluate the removal characteristics of NOx through a laboratory-scale biofilter packed with soil as a packing material. A mixture media (yellow soil (30%): soil (40%): compost (10%): a used briquet (20%)) was applied. After about 1day of operation, the removal efficiency for $NO_2$ in all experiments with a constant condition ($25^{\circ}C$ and water humidity (60%)) was over 98%. The retention times of the section between phase I and phase II for formation and reduction of $NO_3$ NO and $NO_2$ on the initial $NO_3$ concentration was 50min $(O_3:195\;ppb),\;55min\;(O_3:925\;ppb),\;65min\;(O_3:1743\;ppb),\;70min\;(O_3:2616\;ppb),\;75min\;(O_3:3500\;ppb)$, respectively The soil biofilter system is a unique technology that purifies urban air by utilizing the natural processes that take place in the soil. Although some of the processes are quite complex, they can broadly be summarized as adsorption onto soil particles, dissolution into soil pore water, and biochemical.

• Environmental Engineering Research
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• 제17권4호
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• pp.179-184
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• 2012

The light absorbance of photocatalysts and reaction kinetics of environmental pollutants at the liquid-solid and gas-solid interfaces differ from each other. Nevertheless, many previous photocatalytic studies have applied the science to aqueopus applications without due consideration of the environment. As such, this work reports the surface and morphological characteristics and photocatalytic activities of carbon-embedded (C-$TiO_2$) photocatalysts for control of gas-phase methyl tertiary-butyl ether (MTBE) under a range of different operational conditions. The C-$TiO_2$ photocatalysts were prepared by oxidizing titanium carbide powders at $350^{\circ}C$. The characteristics of the C-$TiO_2$ photocatalysts, along with pure TiC and the reference pure $TiO_2$, were then determined by X-ray diffraction, scanning emission microscope, diffuse reflectance ultraviolet-visible-near infrared (UV-VIS-NIR), and Fourier transform infrared spectroscopy. The C-$TiO_2$ powders showed a clear shift in the absorbance spectrum towards the visible region, which indicated that the C-$TiO_2$ photocatalyst could be activated effectively by visible-light irradiation. The MTBE decomposition efficiency depended on operational parameters, including the air flow rate (AFR), input concentration (IC), and relative humidity (RH). As the AFRs decreased from 1.5 to 0.1 L/min, the average efficiencies for MTBE increased from 11% to 77%. The average decomposition efficiencies for the ICs of 0.1, 0.5, 1.0, and 2.0 ppm were 77%, 77%, 54%, and 38%, respectively. In addition, the decomposition efficiencies for RHs of 20%, 45%, 70%, and 95% were 92%, 76%, 50%, and 32%, respectively. These findings indicate that the prepared photocatalysts could be effectively applied to control airborne MTBE if their operational conditions were optimized.