• Bulletin of the Korean Chemical Society
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• v.17 no.8
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• pp.700-706
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• 1996

We present the results of molecular dynamics simulations of monolayers of long-chain alkyl thiol [S(CH2)15CH3] molecules on an air-solid interface using the extended collapsed atom model for the chain-molecule and a gold surface for the solid surface. Several molecular dynamics simulations have been performed on monolayers with areas per molecule ranging from 18.30 to 32.10 Å2/molecule. It is found that there exist three possible transitions: a continuous transition characterized by a change in molecular configuration without change in lattice structure, a sudden transition characterized by the distinct lattice defects and perfect islands, and a third transition characterized by the appearance of a random, liquid-like state. The analysis of probability distributions of the segments shows that the structure of the chain-molecules at the air-solid interface is completely different from that at the air-water interface in the view of the degree of overlap of the probability distributions of the neighbor segments. The calculated diffusion coefficients of the chain-molecules on the monolayers seem to be not directly related to any one of the three transitions. However, the large diffusion of the molecules enhanced by the increment of the area per molecule may induce the second transition.

• Journal of ILASS-Korea
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• v.3 no.4
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• pp.43-49
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• 1998

In order to clarify the effect of equivalence ratio and kinds of fule in flame structure, a numerical simulation of triple flame developed in a co-flowing methane-air and air stream was carried out by the elementary chemical reaction mechanism. The following conclusions were obtained. Equivalence ratio at which the apparent burning velocity is maximum is a little larger than that of the one-dimensional premixed flame. Apparent burning velocities are two times higher than that of the one-dimensional premixed flame for the methane-air. The flame thrusts out forward in the downstream of the boundary between mixture and air stream, and a part of the flow is bent and forks out in this protruding flame so that a triple flame is originated; this triple flame is composed of fuel rich and lean premixed flame branches and a diffusion flame branch. Near the equivalence ratio at which the burning velocity of rule-dimensional premixed flame is the largest the effect of one-dimensional premixed flame becomes large and the fuel rich premixed flame advances and becomes vertical to the flow direction.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.11
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• pp.739-745
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• 2008

This paper presents the measurement of ground thermal conductivity and the characteristics of ground thermal diffusion by a ground heat exchanger(GHE). A borehole is installed to a depth of 175 m with a diameter of 150 mm. To analyze the thermal diffusion property of the GHE, thermocouples are installed under the ground near the GHE. The outdoor temperature, the ground temperature, and the water temperature of the GHE are monitored for evaluating the characteristics of ground thermal diffusion. The ground thermal conductivity is evaluated by the in-situ thermal response tester and the line source model. It is found to be 3.08 W/$m^{\circ}C$ in this study. The ground temperature is greatly dependent on the outdoor temperature from the ground surface to 2.5 m in depth and is stable below 10 m in depth. The surface temperature of the GHE varies as a function of the temperature of circulating water. But the ground temperature at 1.5 m far from the GHE is not changed in accordance with the temperature of circulating water.

• Journal of Radiation Protection and Research
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• v.39 no.2
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• pp.70-80
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• 2014

The interpretation on the diffusion of radiation contaminants in air is usually to apply a Gaussian plume equation that obtains normal distributions in stable air flow conditions to draw a conservative conclusion. In this study, a numerical study using computational fluid dynamics methods was performed to interpret the air flow pattern and the diffusion of the radiation contaminants at the Wolseong nuclear power plants, and a more detailed solution can be obtained than the Gaussian plume equation, which is difficult to use to simulate complex terrains. The results show that a significant fluctuation of air flow in the terrain appears in the case of a northwester and southeaster because of the mountain located in the northwest and the sea located in the south-east. The northwesterly air flow shows the most unstable flow in the vertical direction when it passes over the terrain of mountain. The stable southeasterly air flow enters into the nuclear power plant from the sea, but it becomes unstable rapidly because of the interference by the building and the terrain. On the other hand, in the case of a northeaster and southwester, a small interruption of air flow is caused by the terrain and wake behind the buildings of nuclear power plants.

• Journal of Korean Society for Atmospheric Environment
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• v.7 no.3
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• pp.189-196
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• 1991

In recent years spectral methods have been found to be a powerful tool for the numerical solution of hynamic differential equations. The main attraction of spectral method is accuracy even though it is generally difficult to implement and solve the complex problems using spectral method. We introduced diffusion equations describing the state of air pollution and solved by pseutospectral method in dimensionless form. The results were compared with both those of other numerical methods and analytical solutions. Comparing with finite difference method and finite element method, spectral method shows the highest accuracy for one dimension problem in this study. Also, the results of two dimensional diffusion problems show good agreement with analytical solutions.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.1
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• pp.29-41
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• 1996

The two-stage numerical model was used to study the relation between three-dimensional local wind model, advection/diffusion model of random walk method and second moment method on Pusan coastal area. The first stage is three dimensional time-dependent local wind model which gives the wind field and vertical dirrusion coefficient. The second stage is advection/diffusion model which uses the results of the first stage as input data. First, wind fields on Pusan coastal area for none synoptic scale wind showed typical land and sea breeze circulation, and convergence zone occured at 1200LST in northern of domain, in succession, moved northward of domain. Emissions from Sinpyeong industrial district were trasnported toward the inland by sea breeze during daytime, and reached the end part of domain about 1800LST. During nighttime, emissions return to sea by land breeze and vertical diffusion also contributes to upward transport. In order to use this model for forecast of air pollution concentration on the Pusan coastal area, it is necessary that computed value must be compared with measured value and wind fields model must also be dealt in detail.

• Journal of the Korean Society of Safety
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• v.31 no.4
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• pp.75-81
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• 2016

This study presents the effect of urea and sulfur admixture on compressive strength, chloride diffusion coefficient, and internal void distribution of concrete. Compressive strength of concretes with urea admixture by 5% increased by 5% relative to Control. However, that of concretes with urea admixture over 10% decreased. Chloride diffusion coefficient of concrete with urea and sulfur admixture decreased by 40% relative to Control. Additionally, the volume of internal void of concrete with urea and sulfur admixture decreased by 20% relative to Control. Therefore, it can be mentioned from test results that the use of adequate urea and sulfur admixture improves the mechanical properties and durability of concrete.

• Journal of the Korean Society of Combustion
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• v.1 no.1
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• pp.11-18
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• 1996

The stabilization characteristics of diffusion flame formed behind a bluff body with fuel injection slits was experimentally investigated by varying main fuel injection angles and auxiliary fuel injection conditions. The flame stability limits, temperature and length of recirculation zone, direct and schlieren photographs of flames were measured in order to study the stabilization mechanism of the diffusion flame. The results of this investigation are as follows. The stability limits can be improved by the condition of the kind and quanity of the injected auxiliary fuel. The length and temperature decrease with injection of auxiliary fuel, and these phenomena are remarkable when LPG is injected into the recirculation zone. When the LPG is injected into the recirculation zone, flame remains sooty. Fluctuation of fuel and main stream is generated actively by air injection.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2006.05a
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• pp.1194-1197
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• 2006

Recently, international standard for measurement of sound absorption in a reverberation room has been amended. In the revised version, temperature, humidity and air pressure conditions are strictly restricted and also the concrete procedures are presented to reduce the differences in test results by adding inspection of diffusion, measurement uncertainty etc. In this paper, the systematic tests are conducted based on the inspection guide of diffusion defined by ISO 354 and the effects of diffusers on the measurement of sound absorption ratio are considered. As a result, we perceived that the averaged sound absorption ratio in mid and high frequency range is expected to measure around $0.05{\sim}0.1$ higher in high sound absorption material. Therefore, as for the reverberation room for measurement of sound absorption, we need to take into consideration not only the spatial standard deviation of sound pressure mandated by ISO 3741, but also, inspection regulation of diffusion showed by ISO 354.

• Journal of Ginseng Research
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• v.9 no.2
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• pp.248-255
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• 1985

In order to investigate the optimal drying condition of white ginseng by using bulk air drier(130 x 62 x 65cm), drying curves, diffusion coefficient at various drying temperature, the energy of activation, variation of color intensity and chemical components during drying of white ginseng were studied. Fick's second low of diffusion for diffusion out of spheres was successfully applied to describe the drying of white ginseng. It was found that the diffusion coefficient of water was 2.2x107, 9.0x107 cm2/sec at drying temperature 4$0^{\circ}C$, 55$^{\circ}C$, respectively. An Arrhenius type temperature dependency of moisture diffusivity was found, the energy of activation being 18.8 Kcal/g mol. Color intensity of white ginseng dried at various drying temperature was increased with an increase in drying temperature. The contents of crude protein, reducing sugar and crude saponin during drying of white ginseng were gradually decreased as increasing of drying time. And with the sensory evaluation by multiple comparison difference analysis, the optimal drying temperature of white ginseng was between 45$^{\circ}C$ and 5$0^{\circ}C$.