• Title/Summary/Keyword: Air Sample

검색결과 960건 처리시간 0.037초

Impact of Dust Transported from China on Air Quality in Korea -Characteristics of PM2.5 Concentrations and Metallic Elements in Asan and Seoul, Korea

  • Yang, Won-Ho;Son, Bu-Soon;Breysse, Patrick;Chung, Tae-Woong
    • 한국환경보건학회지
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    • 제33권6호
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    • pp.479-487
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    • 2007
  • [ $PM_{2.5}$ ], particulate matter less than 2.5 um in a diameter, can penetrate deeply into the lungs. Exposure to $PM_{2.5}$ has been associated with increased hospital visits for respiratory aliments as well as increase mortality. $PM_{2.5}$ is a byproduct of combustion processes and as such has a complex composition including a variety of metallic elements, inorganic and organic compounds as well as biogenic materials (microorganisms, proteins, etc). In this study, the average concentrations of fine particulates $PM_{2.5}$ have been measured simultaneously in Asan and Seoul, Korea, by using particulate matter portable sampler from September 2001 to August 2002. Sample collection filters were analyzed by ICP-OES to determine the concentrations of metallic elements (As, Ni, Fe, Cr, Cd, Cu, Pb, Zn, Si). Annual mean $PM_{2.5}$ concentrations in Asan and Seoul were 37.70 and $45.83\;{\mu}g/m^3$, respectively. The highest concentrations of $PM_{2.5}$ were found in spring season in both cities and the concentrations of measured metallic elements except As in Asan were higher than those in Seoul, suggesting that yellow dust in spring could affect $PM_{2.5}$ concentrations in Asan rather than Seoul. The correlation coefficients of Pb and Zn were 0.343 for Asan and 0.813 for Seoul during non-yellow dust condition, suggesting that Pb and Zn were influenced with the same sources. The correlation coefficients between Si and Fe in the fine particulate mode were 0.999 (Asan) and 0.998 (Seoul) during yellow dust condition. It was suggested that these two elements were impacted by soil-related transport from China during the yellow dust storm condition.

연소해석을 이용한 충돌형 제트분사기의 연소 안정성 평가에 관한 수치적 연구 (A Numerical Study on Combustion-Stability Rating of Impinging-Jet Injectors Using Hot-Fire Simulation)

  • 최효현;손채훈
    • 한국추진공학회지
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    • 제14권5호
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    • pp.24-31
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    • 2010
  • 충돌형 분사기가 장착된 모델 연소실에서 연소장 수치 해석을 이용하여 연소 안정성을 평가하였다. 충돌형 분사기로는 F(fuel)-O(oxidizer)-O-F형 분사기를 채택하였다. 본 연구에서는 연료와 산화제의 제트 혼합과정이 지배적이라는 가정하에 순간 화학 반응 모델을 채택하여 수치해석을 수행하였다. 선행 연구를 통해 제안된 방법론을 토대로 모델 연소실 형상이 설계되고 연소실 작동 조건이 결정되었다. 본 연구에서 제시한 방법을 토대로 얻은 연소 안정성 경계는 공기 분사 음향 실험과 연소 실험결과와 정성적으로 잘 일치하였다. 연료와 산화제의 분사와 혼합이 연소 불안정 유발에 지배적인 경우, 본 연구에서 제안된 수치해석 기법을 이용하여 효과적으로 분사기의 연소 안정성을 평가할 수 있다.

Magneto-transport Properties of La0.7Sr0.3Mn1+dO3-Manganese Oxide Composites Prepared by Liquid Phase Sintering

  • Kim, Hyo-Jin;You, Jae-Hyoung;Choi, Soon-Mi;Yoo, Sang-Im
    • Journal of Magnetics
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    • 제19권3호
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    • pp.221-226
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    • 2014
  • Significantly enhanced low-field magnetoresistance (LFMR) and maximum dMR/dH {$(dMR/dH)_{max}$} values were successfully achieved from $La_{0.7}Sr_{0.3}MnO_3$(LSMO)-manganese oxide composite samples prepared by liquid phase sintering, compared with those of the same composites prepared by solid state reaction. For this study, pure LSMO and LSMO-manganese oxide composites with various nominal compositions of (1-x)LSMO-$xMn_2O_3$ (x = 0.1, 0.2, 0.3, 0.4, and 0.8) were sintered at $1450^{\circ}C$, above the eutectic temperature of $1430^{\circ}C$, for 1 h in air. The highest LFMR value of 1.28% with the highest $(dMR/dH)_{max}$ value of 21.1% $kOe^{-1}$ was obtained from the composite sample with x = 0.3 at 290 K in 500 Oe. This enhancement of LFMR and $(dMR/dH)_{max}$ values is ascribed to efficient suppression of magnetic disorder at the LSMO grain boundary, by forming a characteristic LSMO-manganese eutectic structure.

Discharge Capacity Fading of LiCoyMn2-yO4 with Cycling

  • Kwon, Ik-Hyun;Song, Myoung-Youp
    • 한국세라믹학회지
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    • 제40권7호
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    • pp.620-624
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    • 2003
  • LiCo$_{y}$Mn$_{2-y}$O$_4$ samples were synthesized by calcining a mixture of LiOH.$H_2O$, MnO$_2$ (CMD) and CoCO$_3$ calcining at 40$0^{\circ}C$ for 10 h and then calcining twice at 75$0^{\circ}C$ for 24 h in air with intermediate grinding. All the synthesized samples exhibited XRD patterns for the cubic spinel phase with a space group Fd(equation omitted)m. The electrochemical cells were charged and discharged for 30 cycles at a current density 600 $mutextrm{A}$/$\textrm{cm}^2$ between 3.5 and 4.3 V. As the value of y increases, the size of particles becomes more homogeneous. The first discharge capacity decreases as the value of y increases, its value for y=0.00 being 92.8 mAh/g. The LiMn$_2$O$_4$ exhibits much better cycling performance than that reported earlier. The cycling performance increases as the value of y increases. The efficiency of discharge capacity is 98.9% for y=0.30. The larger lattice parameter for the smaller value of y is related to the larger discharge capacity. The more quantity of the intercalated and the deintercalated Li in the sample with the larger discharge capacity brings about the larger capacity fading rate.ate.

EPDM 가스켓의 장시간 운전에 따른 기계적 성능변화 (Mechanical Properties of EPDM Gasket after Long-Term Operations)

  • ;김선학;천승호;김진수;현덕수;김병헌;이성근;정재훈;지덕진;오병수
    • 한국수소및신에너지학회논문집
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    • 제22권4호
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    • pp.488-494
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    • 2011
  • Gasket plays an important role on sealing of the polymer electrolyte membrane fuel cell (PEMFC) stack. Stack requires gaskets in each cell to keep the hydrogen and air/oxygen within their respective regions. The failure of the gasket creates the problems of fuel leakage, mixing, damage on parts and can be a direct reason for the degrading the efficiency of fuel cell. The purpose of this paper researches on how mechanical properties of EPDM gasket in PEMFC are changed after long-term operations. The EPDM (ethylenepropylene-diene monomer) gaskets are obtained from the stack after long-term operations. DMA (dynamic mechanical analysis) is conducted to access the change of mechanical properties of the EPDM gasket. SEM/EDS (scanning electron microscope/energy dispersive spectroscopy) was used to show the surface topography and chemical characterization on the sample surface.

Predictors Affecting Breast Self-Examination Practice among Turkish Women

  • Doganer, Yusuf C.;Aydogan, Umit;Kilbas, Zafer;Rohrer, James E.;Sari, Oktay;Usterme, Necibe;Yuksel, Servet;Akbulut, Halil;Balkan, Salih M.;Saglam, Kenan;Tufan, Turgut
    • Asian Pacific Journal of Cancer Prevention
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    • 제15권20호
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    • pp.9021-9025
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    • 2014
  • Background: Breast cancer (BC) is the most common cancer among females in Turkey. Predictors affecting the breast self-examination (BSE) performance vary in developing countries. Objective: To determine the frequency of BSE performance and predictors of self-reported BSEs among women in the capital city of Turkey. Materials and Methods: This cross-sectional study was conducted on 376 Turkish women using a self-administered questionnaire covering socio-demographic variables and BSE-related features. Results: Of the participants, 78.7% (N=296) reported practicing BSE, whereas 9.5% (N=28) were implementing BSE regularly on a monthly basis, and only 5.7% (N=17) were performing BSE regularly within a week after each menstrual cycle. Multivariate logistic regression modeling revealed that BSE performance was more likely in younger age groups [20-39 years] (p=0.018, OR=3.215) and [40-49 years] (p=0.009, OR=3.162), women having a family history of breast disease (p=0.038, OR=2.028), and housewives (p=0.013, OR=0.353). Conclusions: Although it appears that the rates of BSE performers are high, the number of women conducting appropriate BSE on a regular time interval basis is lower than expected. Younger age groups, family history of breast diseases and not being employed were identified as significant predictors of practicing BSE appropriately. Older age and employment were risk factors for not performing BSE in this sample.

Development of Photo-Fenton Method for Gaseous Peroxides Determination and Field Observations in Gwangju, South Korea

  • Chang, Won-Il;Shim, Jae-Bum;Hong, Sang-Bum;Lee, Jai H.
    • Journal of Korean Society for Atmospheric Environment
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    • 제23권E1호
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    • pp.16-28
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    • 2007
  • An improved method was developed to determine gas-phase hydrogen peroxide($H_2O_2$) and organic hydro-peroxides (ROOH) in real-time, The analytical system for $H_2O_2$ is based on formation of hydroxybenzoic acid (OHBA), a strong fluorescent compound. OHBA is formed by a sequence of reactions, photoreduction of Fe(III)-EDTA to Fe(II)-EDTA, the Fenton reaction of Fe(II)-EDTA with $H_2O_2$, and hydroxylation of benzoic acid. By use of this analytical method rather than a previous similar method, Fenton reaction time was reduced from 2 min. to 30s. Air samples were collected by a surfaceless inlet to prevent inlet line losses. With a special arrangement of the sampling apparatus, sample delivery time was drastically reduced from ${\sim}5\;min\;to\;{\sim}20\;s$. The automated system was found to be sensitive, capable of continuous monitoring, and affordable to operate. A comparison of this method with a well-established one showed an excellent linear correlation, validating applicability of this technique to $H_2O_2$ determination. The system was applied to field measurements conducted during summertime of 2004 in Gwangju, South Korea. $H_2O_2$ was found to be a predominant species of peroxides. The diurnal variation of $H_2O_2$ displayed the maximum in early afternoon and the broad minimum throughout night. $H_2O_2$ was correlated positively with ozone, photochemical age, and temperature, however, negatively with $NO_x$ and relative humidity.

WO3-TiH2 혼합분말의 동결건조 및 수소환원에 의한 W-Ti 다공체 제조 (Fabrication of Porous W-Ti by Freeze-Drying and Hydrogen Reduction of WO3-TiH2 Powder Mixtures)

  • 강현지;박성현;오승탁
    • 한국분말재료학회지
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    • 제24권6호
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    • pp.472-476
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    • 2017
  • Porous W-10 wt% Ti alloys are prepared by freeze-drying a $WO_3-TiH_2$/camphene slurry, using a sintering process. X-ray diffraction analysis of the heat-treated powder in an argon atmosphere shows the $WO_3$ peak of the starting powder and reaction-phase peaks such as $WO_{2.9}$, $WO_2$, and $TiO_2$ peaks. In contrast, a powder mixture heated in a hydrogen atmosphere is composed of the W and TiW phases. The formation of reaction phases that are dependent on the atmosphere is explained by a thermodynamic consideration of the reduction behavior of $WO_3$ and the dehydrogenation reaction of $TiH_2$. To fabricate a porous W-Ti alloy, the camphene slurry is frozen at $-30^{\circ}C$, and pores are generated in the frozen specimens by the sublimation of camphene while drying in air. The green body is hydrogen-reduced and sintered at $1000^{\circ}C$ for 1 h. The sintered sample prepared by freeze-drying the camphene slurry shows large and aligned parallel pores in the camphene growth direction, and small pores in the internal walls of the large pores. The strut between large pores consists of very fine particles with partial necking between them.

대구 건제품의 핵산관련물질 및 유리아미노산 함량 (Contents of Free Amino Acids, and Nucleotides and Their Related Compounds of Dried Cod)

  • 이영경;성낙주;정승용
    • 한국수산과학회지
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    • 제18권4호
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    • pp.333-338
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    • 1985
  • 저렴한 동물성 단백질의 급원인 냉동대구의 식품학적 기초자료를 얻기 위해 북양산 냉동대구육을 천일건조 및 열풍 건조시켜 1개월간 저장하면서 유리아미노산 및 핵산관련물질의 변화를 실험하여 다음과 같은 결과를 얻었다. 생시료에는 proline, histidine, lysine및 alanine의 함량이 가장 많았고, 천일건조시료, 천일건조 저장시료, 열풍건조시료 및 열풍건조 저장시료에는 glycine, histidine, lysine, proline 및 alanine의 함량이 가장 많았으며, 총유리아미노산의 함량은 저장중 현저히 증가하였다. 핵산관련물질의 함량은 생시료와 건조시료 및 저장시료 모두 inosine의 함량이 가장 많았으며, 다음으로 IMP의 함량이 많았다. 이상의 결과들로 미루어 볼 때 glycine, histidine, lysine, proline 및 alanine등의 유리아미노산과 핵산관련물질로서는 IMP등이 냉동대구를 원료로 한 대구 건제품의 맛에 중요할 구실을 할 것으로 추정된다.

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Pythium Population 의 생태적 특성 고찰을 위한 Soil Dilution Planting Method의 개발 (Development of Soil Dilution Planting Method for Ecological Studies of Pythium Populations)

  • 이윤수
    • 한국환경농학회지
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    • 제13권1호
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    • pp.83-89
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    • 1994
  • 토양중 Pythium속 사상균의 취락조사시 희석평판을 위한 희석배수가 균수에 미치는 영향을 조사한 결과 다음과 같은 결과를 얻었다. 1. 희석배수 1:50은 1:100보다 기대했던 것 보다 Pythium속 취락수가 감소했으며 높은 희석배수에서도 뚜렷한 상관관계를 보이지 않음. 2. 토양시료를 이용한 희석배수실험에서도 유사한 결과를 보였으나 1:50의 회석반복실험결과는 상관관계가 관찰되었음. 그러나 토양을 풍건시켰을 경우 취락의 감소경향을 발견하였음. 3. 본 시험에 사용한 두개의 사탕수수포장에서 채취한 토양에서 Pythium번식체가 균일하게 존재하지 않는 것을 확인할 수 있었으며 희석배수 1:50일때 상관관계를 보인 것은 토양중 균사파편 혹은 분주과정에서 균사위조현상에 기인된 것으로 생각됨.

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