• Title/Summary/Keyword: Air Quality.

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Morphology control of glassy carbon coating layer to additive ethylene glycol and phenolic resin (페놀수지 및 에틸렌 글리콜을 첨가한 유리질 카본 코팅층의 물성 제어)

  • Joo, Sang Hyun;Joo, Young Jun;Lee, Hyuk Jun;Sim, Young Jin;Park, Dong Jin;Cho, Kwang Youn
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.3
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    • pp.89-95
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    • 2022
  • In this study, glassy carbon coating was performed on the graphite using a phenolic resin and a curing agent was mixed with ethylene glycol as an additive to form the uniform surface. The phenolic resin was dried and cured under the environments of hot air, then converted into a glassy carbon layer by pyrolysis at 500~1,500℃. FTIR, XRD, SEM analysis, and density/porosity/contact angle measurement were performed for characterization of glassy carbon. The pyrolysis temperature for high-quality glassy carbon was optimized to be about 1,000℃. As the content of the additive increased, the effect of reducing surface defects on the coated surface, reduction of porosity, increase of contact angle, and increase of density were investigated in this study. The method of forming a glassy carbon coating layer through an additive is expected to be applicable to graphite coating and other fields.

A Study on the Exposure Factors Used in the Assessment of Inhalation Exposure to Household Chemicals (생활화학제품의 흡입노출평가에 사용되는 노출계수에 대한 고찰)

  • Yoon, Chungsik;Kwon, Taehong;Oh, Gitaek;Kim, Minjung;Kim, Boowook;Shin, CheolWoong;Lee, Kiyoung;Zoh, Kyungduk
    • Journal of Environmental Health Sciences
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    • v.48 no.4
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    • pp.195-205
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    • 2022
  • Background: The biggest concern when using household chemical products is the health risk from inhalation exposure. Objectives: The purpose of this paper was to provide information necessary for estimating inhalation exposure factors in several countries/organizations and to present some examples. Methods: We attempted to use PRISMA-ScR for a systematic review, but no major reports were found. We used the Google search function instead to find 'exposure factor handbook'. As for the results, inhalation exposure factors from South Korea, the United States, Canada, the EU, Australia, Japan, and China were compared. Results: The basic concept and origin of exposure factors was the US Environmental Protection Agency's Exposure Factor Handbook. Its latest version is 2011, but several chapters have been updated in 2017, 2018, and 2019. South Korea's Exposure Factor Handbook was updated in 2019, more recently than those of other countries, and was systematically investigated. In South Korea, the average daily respiratory rate is 14.62 m3/day for adults and 12.73 m3/day for children. It is difficult to compare breathing rate by country because each country divides age groups differently and uses different methods to estimate it. Information on household chemical products, space used, and ventilation rate are in the exposure factor handbook in some countries and not in others. It is not in the handbook in South Korea, but in the notice from the NIER (National Institute of Environmental Research), a sub-regulation of the Chemical Product Safety Act. Conclusions: The exposure factors registered in South Korea's exposure factor handbook have been systematically studied and reflect the most recent data. When using data not in the relevant handbook, data from other countries might be applied, but it should be determined whether the nature and quality of the original data have been managed.

Spatial Gap-filling of GK-2A/AMI Hourly AOD Products Using Meteorological Data and Machine Learning (기상모델자료와 기계학습을 이용한 GK-2A/AMI Hourly AOD 산출물의 결측화소 복원)

  • Youn, Youjeong;Kang, Jonggu;Kim, Geunah;Park, Ganghyun;Choi, Soyeon;Lee, Yangwon
    • Korean Journal of Remote Sensing
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    • v.38 no.5_3
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    • pp.953-966
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    • 2022
  • Since aerosols adversely affect human health, such as deteriorating air quality, quantitative observation of the distribution and characteristics of aerosols is essential. Recently, satellite-based Aerosol Optical Depth (AOD) data is used in various studies as periodic and quantitative information acquisition means on the global scale, but optical sensor-based satellite AOD images are missing in some areas with cloud conditions. In this study, we produced gap-free GeoKompsat 2A (GK-2A) Advanced Meteorological Imager (AMI) AOD hourly images after generating a Random Forest based gap-filling model using grid meteorological and geographic elements as input variables. The accuracy of the model is Mean Bias Error (MBE) of -0.002 and Root Mean Square Error (RMSE) of 0.145, which is higher than the target accuracy of the original data and considering that the target object is an atmospheric variable with Correlation Coefficient (CC) of 0.714, it is a model with sufficient explanatory power. The high temporal resolution of geostationary satellites is suitable for diurnal variation observation and is an important model for other research such as input for atmospheric correction, estimation of ground PM, analysis of small fires or pollutants.

Detection of Wildfire Smoke Plumes Using GEMS Images and Machine Learning (GEMS 영상과 기계학습을 이용한 산불 연기 탐지)

  • Jeong, Yemin;Kim, Seoyeon;Kim, Seung-Yeon;Yu, Jeong-Ah;Lee, Dong-Won;Lee, Yangwon
    • Korean Journal of Remote Sensing
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    • v.38 no.5_3
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    • pp.967-977
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    • 2022
  • The occurrence and intensity of wildfires are increasing with climate change. Emissions from forest fire smoke are recognized as one of the major causes affecting air quality and the greenhouse effect. The use of satellite product and machine learning is essential for detection of forest fire smoke. Until now, research on forest fire smoke detection has had difficulties due to difficulties in cloud identification and vague standards of boundaries. The purpose of this study is to detect forest fire smoke using Level 1 and Level 2 data of Geostationary Environment Monitoring Spectrometer (GEMS), a Korean environmental satellite sensor, and machine learning. In March 2022, the forest fire in Gangwon-do was selected as a case. Smoke pixel classification modeling was performed by producing wildfire smoke label images and inputting GEMS Level 1 and Level 2 data to the random forest model. In the trained model, the importance of input variables is Aerosol Optical Depth (AOD), 380 nm and 340 nm radiance difference, Ultra-Violet Aerosol Index (UVAI), Visible Aerosol Index (VisAI), Single Scattering Albedo (SSA), formaldehyde (HCHO), nitrogen dioxide (NO2), 380 nm radiance, and 340 nm radiance were shown in that order. In addition, in the estimation of the forest fire smoke probability (0 ≤ p ≤ 1) for 2,704 pixels, Mean Bias Error (MBE) is -0.002, Mean Absolute Error (MAE) is 0.026, Root Mean Square Error (RMSE) is 0.087, and Correlation Coefficient (CC) showed an accuracy of 0.981.

Effect of Removal of Power Plant Emissions on the characteristics of Ozone Concentration Changes in Summer (화력발전소 배출량 제거에 따른 여름철 O3 농도의 변화 특성)

  • Kim, Dongjin;Jeon, Wonbae;Park, Jaehyeong;Mun, Jeonghyeok
    • Journal of the Korean earth science society
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    • v.42 no.2
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    • pp.149-163
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    • 2021
  • In this study, the changes in ozone (O3) concentrations due to the removal of power plant emissions were analyzed using a community multi-scale air quality (CMAQ) model. Two different CMAQ model simulations, one considering the emissions from the Hadong power plant and one without considering the emissions, were conducted to investigate the effect of the emissions on the changes in the O3 concentrations in the surrounding areas. Subsequently, the CMAQ simulations exhibited an increase in the O3 concentration (25.24%) despite a decrease in the NOx (-18.87%) and volatile organic carbon (VOC, -11.27%) concentrations, which are major O3 precursors. The changes in the NO and O3 concentrations due to the removal of power plant emissions presented a strong negative correlation (r= -0.72). This indicated that the increase in the O3 concentration was mainly attributed to the significantly decreased NO concentration, thus, mitigating the O3 titration reaction (NO+O3→NO2+O2). Additionally, due to the VOC-limited (i.e., NOx-saturated) conditions in the study region, NO affected the O3 concentration, indicating that the O3 concentrations in a particular region are not only proportional to the increase or decrease in emissions. Therefore, an in-depth understanding of the chemical O3 production and loss in a particular region is necessary to accurately evaluate the effect of emission control on the changes in the O3 concentration.

A Study on the Design of Planterior to Reduce and Purify Indoor Particle Matters (PM) (실내 미세먼지 저감을 위한 플랜테리어 디자인 연구)

  • Ahn, SeungWon;Jeong, Jun Hyun
    • Journal of the Korean Society of Floral Art and Design
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    • no.44
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    • pp.3-31
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    • 2021
  • To verify the types of effects that plants have in our general living conditions, I examined an air quality in living rooms of the three, 129.78m2 size, apartments that were with and without plants. and the findings of the study were as addressed below. 1) Experiments showed no statistically significant differences in Case A. However, in Case B and Case C, the standard deviation of PM10, PM2.5 and PM 1.0 verified that each had statistically significant (p<.01) differences. 2) It is believed that the effect of reducing particle matters due to the installation of plants in the indoor space is to vary significantly depending on the indoor environmental conditions, the cleanliness of the room, and the amount of furniture and may also differ depending on the daily dietary cooking method. In addition, it is believed that the planterior will not only reduce indoor fine dust, but also reduce the psychological comfort and eye fatigue of the residents. Nevertheless, supplementary research is needed. 3) In the planterior design for reducing indoor particle matters, various measures were examined. Among them, the vertical wall design method was tested and suggested through empirical experiments. In addition, maintenance methods were proposed depending on the type of indoor plant.

Reduction of ammonia conversion from urea by adding acetohydroxamic acid (Acetohydroxamic acid 이용한 Urea로부터 암모니아 발생 저감 연구)

  • Yun, Gwang Su;Oh, Ha Eun;Jung, Min Woong;Hwang, Okhwa;Yun, Yeo-Myeong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.4
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    • pp.5-13
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    • 2021
  • Ammonia, primarily originating from urinary urea of the livestock manure, is known to play as a major precursor of fine particulate matter (PM2.5) generation which leads to a decrease in air quality and to harmful effects on public health. The objective of this study was to evaluate the effect of acetohydroxamic acid (AHA) addition on inhibition of ammonia conversion from urea. The experiment was performed at different urea concentration (500-4,000 mg Urea-N/L), AHA concentration (0-4,000 mg AHA/L), pHs (pH 6-10), and temperature (10-35℃). The result showed that the urease inhibition efficiency increased at higher concentration of AHA. However, the specific urease inhibition activity decreased at higher pH, showing 867.1±6.7 Unit/g AHA at pH 6 and 1,167.9±17.4 Unit/g AHA at pH 10, respectively. Decreased urease inhibition efficiency at both AHA and control was observed at higher temperature. This finding indicates that AHA can be used as the urease inhibitor for reducing ammonia emission in the management of livestock manure.

Evaluation of Performance and Maintenance Cost for Roadside's Particulate Matter Reduction Devices Using Smart Green Infrastructure Technology (스마트 그린인프라 기술을 활용한 도로변 미세먼지 저감장치의 성능 및 유지·관리 비용 평가)

  • Song, Kyu-Sung;Seok, Young-Sun;Yim, Hyo-Sook;Chon, Jin-Hyung
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.25 no.4
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    • pp.15-31
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    • 2022
  • The Green Purification Unit System (GPUS) is a green infrastructure facility applicable to the roadside to reduce particulate matter from road traffic. This study introduces two types of GPUS (type1 and type2) and assesses the performance and maintenance costs of each of them. The GPUS's performance analysis used the data collected in November 2021 after the installation of the GPUS type1 and type2 at the study site in Suwon. The changes in the particulate matter concentration near the GPUS were measured. The maintenance cost of GPUS type1 and type2 was assessed by calculating the initial installation cost and the management and repair cost after installation. The results of the performance analysis showed that the GPUS type1, which was manufactured by combining plants and electric dust collectors, had a superior particulate matter reduction performance. In particular, type1 produced a greater effect of particulate matter reduction in the time with a high concentration (50㎍/m3 or higher) of particulate matter due to the operation of electric dust collectors. GPUS type2, which was designed in the form of a plant wall without applying an electric dust collector, showed lower reduction performance than type1 but showed sufficiently improved performance compared to the existing band green area. Meanwhile, the GPUS type1 had three times higher costs for the initial installation than GPUS type2. In terms of costs for managing and repairing, it was evaluated that type1 would be slightly more costly than type2. Finally, this study discussed the applicability of two types of GPUS based on the result of the analysis of their particulate matter performance and maintenance cost at the same time. Since GPUS type2 has a cheaper cost than type1, it could be more economical. However, in the area suffering a high concentration of particulate matter, GPUS type1 would be more effective than type2. Therefore, the choice of GPUS types should rely on the status of particulate matter concentration in the area where GPUS is being installed.

The Effect of Oocyte Activation on Development of Porcine Cloned Embryos

  • Kim, Y.S.;Lee, S. L.;Park, G. J.;S. Y. Choe
    • Proceedings of the Korean Society of Developmental Biology Conference
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    • 2003.10a
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    • pp.124-124
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    • 2003
  • The successful development of embryos cloned by nuclear transfer (NT)have been dependent on a wide range of known factors including cell cycle of donor and recipient ooplast, oocyte quality, NT procedure and oocyte activation. The present study compared the development of cloned porcine embryos following different activation treatments. Cumulus-oocyte complexes (COCs) were aspirated from 26 mm follicles of slaughterhouse ovaries and cultured for 22 h in NCSU #23 medium supplemented with 10% porcine follicular fluid, 0.57 mM cysteine, 0.5 g/mL LH, 0.5 g/mL FSH and 10 ng/mL EGF. The COCs were further cultured for an additional 22 h in the same medium at $39{\cird}C$ in an atmosphere of 5% $CO_2$ in air, without hormonal supplements. Primary cultures of fibroblasts isolated from a female fetus on day 40 of gestation were established in DMEM + 15% FCS. For nuclear donation, cells at the 5th-6th passage were cultured in DMEM +0.5% FCS for 5 days in order to arrest the cells in G0/Gl. After enucleation, oocytes were reconstructed by transfer of donor cells and fusion with three DC pulses (1.4 KV/cm, 30 sec) in 0.28 M mannitol containing 0.01 mM $CaCl_2$ and 0.01 mM $MgCl_2$. Eggs were then divided into three treatment groups, control (without further treatment, Group 1), eggs cultured in 10 g/ml cycloheximide (CHX) for 5 h (Group 2), and eggs cultured in 1.9 mM 6-dimethylaminopurine (6-DMAP) for 5 h (Group 3). The eggs were then cultured in sets of 30 in 60 I drops of NCSU#23 supplemented with 4mg/ml BSA (essentially fatty acid free) until day 7 at $39{\circ}C$ in a humidified atmosphere of 5% $CO_2$. On day 4 the culture were fed by adding 20 I NCSU #23 supplemented with 10% FBS. Development rates into blastocysts were significantly higher (P<0.05) in Group 3 embryos compared to Group 1 controls ($27.6 \mu 2.7% vs. 20.1 \mu 4.1%$, respectively), but rates did not differ in Group 2 compared to control ($23.8 \mu 5.7%$). Total cell number in Group 3 blastocysts was however significantly higher (P<0.05) than in Groups 1 and 2 ($44.6 \mu 2.4 vs. 19.9 \mu 1.9 and 21.9 \mu 2.1$, respectively). These results suggest that 6-DMAP is more efficient than cycloheximide in the activation of electrically fused NT oocytes during in vitro production of cloned porcine embryos.

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Nutritional and Agronomic Characteristics of Super-Giant Embryo Mutant in Rice (벼 초거대배 돌연변이계통의 영양 및 작물학적 특성)

  • Koh, Hee-Jong;Park, Sun-Zik;Won, Yong-Jae;Heu, Mun-Hue
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.38 no.6
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    • pp.537-544
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    • 1993
  • Super-giant-embryo mutant line (Hwacheong-ge$^s$) with high nutritional quality was developed from Hwacheongbyeo, a Korean Japonica cultivar. Grain weight of brown rice of Hwacheong-ge$^s$ line was lighter than of Hwacheongbyeo. However, embryo dry weight of the line was 3.22 times heavier than that of Hwacheongbyeo on the single grain base. Hwacheong-ge$^s$ line showed higher protein(8.99%) than the original variety(7.39%), without changes in storage protein. In amino acid composition, lysine content was greatly increased in the mutant, while the contents of methionine, serine and tyrosine were slightly decreased as compared with the original one. Lipid content of Hwacheong-ge$^s$ line was 1.5 times higher compared with that of Hwacheongbyeo. The contents of Vitamin Bl, B2, and E(${\alpha}$-tocopherol) were also greatly increased in Hwacheong-ge$^s$line. The grain yields of the mutant lines ranged from 69.2% to 78.8% compared with that of Hwacheongbyeo, 556kg /10a. Most of the mutant lines of M4 generation were homogeneous for growth characters, and some of them seemed to be readily applicable for farmer's field.

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