• Journal of the Korea institute for structural maintenance and inspection
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• v.13 no.6 s.58
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• pp.135-147
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• 2009

In order to develop the ultra high strength concrete over 400Mpa at 28 day, Low-heat portland cement, ferro-silicon, silica-fume and steel fiber were mixed and tested under the special autoclave curing conditions. Considering the influence of Ultra high strength concrete. normal concrete is used as a comparison with low water-cement ratio possible Low-heat portland cement. Additionally, as a substitution of aggregates, we analyzed the compressive strength of Ferro Silicon by making the states of mixed and curing conditions differently. In addition, SEM films testified the development of C-S-H hydrates of Type III & Type IV, and tobermolite, zonolite due to the high temperature, high pressure of autoclave curing. Fineness of aggregate, filler and reactive materials in concrete caused 420Mpa compressive strength at 28day successfully.

• Carbon letters
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• v.28
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• pp.47-54
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• 2018

High surface carbon aerogels with hierarchical and tunable pore structure were prepared using ionic liquid as carbon precursor via a simple salt templating method. The as-prepared carbon aerogels were characterized by nitrogen sorption measurement and scanning electron microscopy. Through instant visual observation experiments, it was found that salt eutectics not only serve as solvents, porogens, and templates, but also play an important role of foaming agents in the preparation of carbon aerogels. When the pyrolyzing temperature rises from 800 to $1000^{\circ}C$, the higher temperature deepens the carbonization reaction further to form a nanoporous interconnected fractal structure and increase the contribution of super-micropores and small mesopores and improve the specific surface area and pore volume, while having few effects on the macropores. As the mass ratio of ionic liquid to salt eutectics drops from 55% to 15%, that is, the content of salt eutectics increases, the salt eutectics gradually aggregate from ion pairs, to clusters with minimal free energy, and finally to a continuous salt phase, leading to the formation of micropores, uniform mesopores, and macropores, respectively; these processes cause BET specific surface area initially to increase but subsequently to decrease. With the mass ratio of ionic liquids to salts at 35% and carbonization temperature at $900^{\circ}C$, the specific surface area of the resultant carbon aerogels reached $2309m^2g^{-1}$. By controlling the carbonization temperature and mass ratio of the raw materials, the hierarchically porous architecture of carbon aerogels can be tuned; this advantage will promote their use in the fields of electrodes and adsorption.

• Journal of the Korea Concrete Institute
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• v.17 no.2 s.86
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• pp.293-302
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• 2005

This study describes data from determination of the optimum mix proportion and site application of the mass concrete placed in bottom slab and side wall having a large depth and section as main structures of LNG in-ground tank. This concrete requires low heat hydration, excellent balance between workability and consistency because concreting work of LNG in-ground tank is usually classified by under-pumping, adaptation of longer vertical and horizontal pumping line than ordinary pumping condition. For this purpose, low heat Portland cement and lime stone powder as cementitious materials are selected and design factors including unit cement and water content, water-binder ratio, fine aggregate ratio and adiabatic temperature rising are tested in the laboratory and batch plant. As experimental results, the optimum unit cement and water content are selected under $270kg/m^3$ and $l55{\~}l60 kg/m^3$ separately to control adiabatic temperature rising below $30^{\circ}C$ and to improve properties of the fresh and hardened concrete. Also, considering test results of the confined water ratio($\beta$p) and deformable coefficient(Ep), $30\%$ of lime stone powder by cement weight is selected as the optimum replacement ratio. After mix proportions of 5cases are tested and compared the adiabatic temperature rising($Q^{\infty}$, r), tensile and compressive strength, modulus of elasticity, teases satisfied with the required performances are chosen as the optimum mix design proportions of the side wall and bottom slab concrete. $Q^{\infty}$ and r are proved smaller than those of another project. Before application in the site, properties of the fresh concrete and actual mixing time by its ampere load are checked in the batch plant. Based on the results of this study, the optimum mix proportions of the massive concrete are applied successfully to the bottom slab and side wall in LNG in-ground tank.

• Proceedings of the Korea Concrete Institute Conference
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• 1994.04a
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• pp.163-168
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• 1994

If the concrete is exposed below freezing point of the outer temperature before hardened, the quality of the concrete will be lowered after hardened. Anti-freezing agent which doesn't corrode the steel bar and doesn't generate the alkali-aggregate reaction by noncholride recently developed in Japan and Northern Europe. But the effects of these agents are rarely known. Therefore, this study is desigend for analyzing the freezing properties at the condition of solution of solution and cement paste. And this study aims to present the reference data for practical use of the concrete works using anti-freezing agent.

• Textile Coloration and Finishing
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• v.10 no.5
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• pp.56-62
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• 1998

In the prior study, the dyeing behaviors of Milling Cyanine 5R on silk fiber in aqueous dyeing liquor including small amount of organic compounds were investigated. The most effective compound was acetophenone which increased dye uptake as well as dyeing rate. In this study, the role of the acetophenone in dyeing of silk with Milling Cyanine 5R was studied. By addition of acetophenone into the dye solution, the molar absorptivity of Milling Cyanine 5R increased, and the wavelength of maximum absorption was shifted to longer wavelength, namely bathochromic shifted. This shows that the acetophenone prevents the dye to aggregate, and increases the number of monomeric dye molecule relative to the dye solution without acetophenone. This fact was also confirmed by the increase of the permeation rate of the dye through cellulose semipermeable membrane from the dye solution including the acetophenone. From these results, the acetophenone acts as a prohibitor of dye aggregation, increases the number of monomeric dye molecules even at relatively low temperature, and makes the dyes penetrate into the fiber easier.

• Advances in concrete construction
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• v.5 no.3
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• pp.183-199
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• 2017

This paper reports an experimental study into the rheological behaviour of Smart Dynamic Concrete (SDC). The investigation is aimed at quantifying the effect of the varying amount of mineral admixtures on the rheology, setting time and compressive strength of SDC containing natural sand and crushed sand. Ordinary Portland cement (OPC) in conjunction with the mineral admixtures was used in different replacement ratio keeping the mix paste volume (35%) and water binder ratio (0.4) constant at controlled laboratory atmospheric temperature ($33^{\circ}C$ to $35^{\circ}C$). The results show that the properties and amount of fine aggregate have a strong influence on the admixture demand for similar initial workability, i.e., flow. The large amounts of fines and lower value of fineness modulus (FM) of natural sand primarily increases the yield stress of the SDC. The mineral admixtures at various replacement ratios strongly contribute to the yield stress and plastic viscosity of SDC due to inter particle friction and cohesion.

• Magazine of the Korean Society of Agricultural Engineers
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• v.45 no.6
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• pp.136-143
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• 2003

This study is performed to evaluate performance of the developed pipe when using for underground drainage in fm land, the efficiency of the pipe is examined such as quantity of drainage, water temperature and other field performance in all weather condition. Results of this study, the higher permeability through wall of the pipe is achieved by making various size pores using open-graded aggregate. And in all weather conditions, permeable polymer concrete pipe perform much better than conventional perforated pipes. During rice farming period, quantity of drainage the permeable polymer concrete pipe is 1.25 time greater than conventional perforated pipes. Therefore, use of the permeable polymer concrete pipe is greater advantages when considering collecting and draining capacity compared with conventional perforated pipes.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.297-297
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• 2006

Recently columnar liquid crystals have been studied due to their possible application to organic conducting materials. Supramolecular columnar liquid crystals consist of mesogenic unit which can aggregate into discs that will make up the columns which associate to form a two-dimensional network. In this study, we prepared supramolecular columnar liquid crystals containing hydrogen bonding between carboxylic acid and, pyridine moieties. Thermal and structural properties of prepared complexe were investigated, and it exhibited hexagonal columnar structure ($Col_{h}$) at room temperature.

• Nuclear Engineering and Technology
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• v.42 no.2
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• pp.175-182
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• 2010

As part of a fundamental study on the volume reduction of contaminated concrete wastes, the separation characteristics of the aggregates and the distribution of the radioactivity in the aggregates were investigated. Radioisotope $^{60}Co$ was artificially used as a model contaminant for non-radioactive crushed concrete waste. Volume reduction for radioactively contaminated dismantled concrete wastes was carried out using activated heavy weight concrete taken from the Korea Research Reactor 2 (KRR-2) and light weight concrete from the Uranium Conversion Plant (UCP). The results showed that most of the $^{60}Co$ nuclide was easily separated from the contaminated dismantled concrete waste and was concentrated mainly in the porous fine cement paste. The heating temperature was found to be one of the effective parameters in the removal of the radionuclide from concrete waste. The volume reduction rate achieved was above 80% for the KRR-2 concrete wastes and above 75% for the UCP concrete wastes by thermal and mechanical treatment.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.557-560
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• 2006

In the existed study, a fire outbreak in a reinforced concrete structure looses the organism by the different contraction and expansion of hardened cement pastes and aggregate, and causes cracks by thermal stress, leading to the deterioration of the durability. So accurate diagnosis of deterioration is needed based on mechanism of fire deterioration in general concrete structures. Fundamental information and data on the properties of concrete exposed to high temperature are necessary for accurate diagnosis of deterioration. Therefore, this study is willing to propose fundamental data for accurate diagnosis of deteriorated concrete structure by fire damage with experiment according to the curing conditions.