• Title/Summary/Keyword: Agglomeration

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Rheological characteristics of non-spherical graphite suspensions

  • Mustafa, Hiromoto Usui;Ishizuki, Masanari;Shinge, Ibuki;Suzuki, Hiroshi
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.19-25
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    • 2003
  • Since the microstructure of functional thin films depends on the dispersion characteristics of dense slurry, it is important to control the agglomerative nature of slurries under processing. The present authors have been discussing the model prediction of agglomerative nature and local rate of agglomeration in dense suspensions. The experiments have been peformed under shear flow using the nearly spherical and oblate type graphite particles. In this study, the experiment has been conducted using water and glycerol as dispersion media. Stress control type rheometer was used to measure the slurry rheology. Local agglomeration of graphite particles has been predicted by using Usui's model. The experimental results show that both the shape and slurry processing method affect on the local dispersion condition. The agglomeration formed by oblate type graphite particles seems to be more difficult to break up than that of spherical particles.

Diameter Control of Carbon Nanotubes Using Surface Modified Fe Nano-Particle Catalysts with APS (APS로 표면 처리한 Fe 나노 입자 촉매를 이용한 CNT의 직경제어)

  • Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.6
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    • pp.478-481
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    • 2013
  • Diameter controlled carbon nanotubes (CNTs) were grown using surface modified iron nano-particle catalysts with aminpropyltriethoxysilane (APS). Iron nano-particles were synthesized by thermal decomposition of iron pentacarbonyl-oleic acid complex. Subsequently, APS modification was done using the iron nano-particles synthesized. Agglomeration of the iron nano-particles during the CNT growth process was effectively prevented by the surface modification of nano-particles with the APS. APS plays as a linker material between Fe nano-particles and $SiO_2$ substrate resulting in blocking the migration of nano-particles. APS also formed siliceous material covering the iron nano-particles that prevented the agglomeration of iron nano-particles at the early stages of the CNT growth. Therefore we could obtain the diameter controlled CNTs by blocking agglomeration of the iron nano-particles.

Vibration analysis of silica nanoparticles-reinforced concrete beams considering agglomeration effects

  • Shokravi, Maryam
    • Computers and Concrete
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    • v.19 no.3
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    • pp.333-338
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    • 2017
  • In this paper, nonlinear vibration of embedded nanocomposite concrete is investigated based on Timoshenko beam model. The beam is reinforced by with agglomerated silicon dioxide (SiO2) nanoparticles. Mori-Tanaka model is used for considering agglomeration effects and calculating the equivalent characteristics of the structure. The surrounding foundation is simulated with Pasternak medium. Energy method and Hamilton's principal are used for deriving the motion equations. Differential quadrature method (DQM) is applied in order to obtain the frequency of structure. The effects of different parameters such as volume percent of SiO2 nanoparticles, nanoparticles agglomeration, elastic medium, boundary conditions and geometrical parameters of beam are shown on the frequency of system. Numerical results indicate that with increasing the SiO2 nanoparticles, the frequency of structure increases. In addition, considering agglomeration effects leads to decrease in frequency of system.

The effect of Fe2O3 nanoparticles instead cement on the stability of fluid-conveying concrete pipes based on exact solution

  • Nouri, Alireza Zamani
    • Computers and Concrete
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    • v.21 no.1
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    • pp.31-37
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    • 2018
  • This paper deals with the stability analysis of concrete pipes mixed with nanoparticles conveying fluid. Instead of cement, the $Fe_2O_3$ nanoparticles are used in construction of the concrete pipe. The Navier-Stokes equations are used for obtaining the radial force of the fluid. Mori-Tanaka model is used for calculating the effective material properties of the concrete $pipe-Fe_2O_3$ nanoparticles considering the agglomeration of the nanoparticles. The first order shear deformation theory (FSDT) is used for mathematical modeling of the structure. The motion equations are derived based on energy method and Hamilton's principal. An exact solution is used for stability analysis of the structure. The effects of fluid, volume percent and agglomeration of $Fe_2O_3$ nanoparticles, magnetic field and geometrical parameters of pipe are shown on the stability behaviour of system. Results show that considering the agglomeration of $Fe_2O_3$ nanoparticles, the critical fluid velocity of the concrete pipe is decreased.

Vibration analysis of sandwich beam with nanocomposite facesheets considering structural damping effects

  • Cheraghbak, Ali;Dehkordi, M. Botshekanan;Golestanian, H.
    • Steel and Composite Structures
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    • v.32 no.6
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    • pp.795-806
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    • 2019
  • In this paper, free vibration of sandwich beam with flexible core resting on orthotropic Pasternak is investigated. The top and bottom layers are reinforced by carbon nanotubes (CNTs). This sandwich structural is modeled by Euler and Frostig theories. The effect of agglomeration using Mori-Tanaka model is considered. The Eringen's theory is applied for size effect. The structural damping is investigated by Kelvin-voigt model. The motion equations are calculated by Hamilton's principle and energy method. Using analytical method, the frequency of the structure is obtained. The effect of agglomeration and CNTs volume percent for different parameter such as damping of structure, thickens and spring constant of elastic medium are presented on the frequency of the composite structure. Results show that with increasing CNTs agglomeration, frequency is decreased.

Effects of a naturally derived surfactant on hydrate anti-agglomeration using micromechanical force measurement

  • Li, Mingzhong;Dong, Sanbao;Li, Bofeng;Liu, Chenwei
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.140-147
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    • 2018
  • The performance of a hydrate anti-agglomerant (AA) on cyclopentane (CyC5) hydrate anti-agglomeration at various concentrations (0-1 wt%, based on the oil phase) using MMF apparatus has been investigated. At low AA concentrations up to 0.01 wt%, the AA reduces the cohesion force (capillary force) by reducing the CyC5-water interfacial tension. At concentrations higher than 0.1 wt%, hydrate hydrophobicity alternation and AA's thermodynamic inhibition effects are the main part of AA's mechanism. Additionally, a "temporary agglomeration" phenomenon caused by surface melting of the hydrate particles is also observed, which may indicate the AA's weak ability to produce stable water-CyC5 interface.

Application of computer algorithms for modelling and numerical solution of dynamic bending

  • Jianzhong, Qiu;Naichang, Dai;Akbar Shafiei, Alavijeh
    • Steel and Composite Structures
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    • v.46 no.1
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    • pp.143-152
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    • 2023
  • In this paper, static and dynamic bending of nanocomposite micro beam armed with CNTs considering agglomeration effect is studied. The structural damping is considered by Kelvin-Voigt model. The agglomeration effects are assumed using Mori-Tanaka model. The micro beam is modeled by third order shear deformation theory (TSDT). The motion equations are derived by principle of Hamilton's and energy method assuming size effects on the basis of Eringen theory. Using differential quadrature method (DQM) and Newmark method, the static and dynamic deflections of the structure are obtained. The effects of agglomeration and CNTs volume percent, damping of structure, nonlocal parameter, length and thickness of micro-beam are presented on the static and dynamic deflections of the nanocomposite structure. Results show that with increasing CNTs volume percent, the static and dynamic deflections are decreased. In addition, enhancing the nonlocal parameter yields to higher static and dynamic deflections.

An Analysis of the Agglomeration Characteristics and Innovative Milieu of the Shoemaking Industry in Seoul (서울시 제화산업의 집적 특성 및 혁신환경 분석)

  • Park, Rae-Hyeon
    • Journal of the Korean Geographical Society
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    • v.40 no.6 s.111
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    • pp.653-670
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    • 2005
  • The purpose of this study is to explore a spatial agglomeration characteristics and innovative milieu of the shoemaking industry in Seoul. In order to explain it, currently discussed dynamic agglomeration economies approach is applied and as an example, shoemaking industry in Seoul has been analyzed. The result of this research can be boardly summarized into two points. Frist, agglomeration economy is changing from urbanization economy to localization economy in this newly rising core of shoemaking industry which is Sung-Su dong area. Also, cooperative effects based on collective efficiency between companies and people are being generated within the area. This is largely affected by networking infrastructure between companies and people within the area, non-trade dependency and social capital acclamation. Secondly, the lack of institutional agglomeration formation in this area is considered to be the obstacle for the long-term development and innovation spin-off. This means recognition switch-over and institutional concern and support is needed in the future from the public sector.

Preparation of Spherical Energetic Composites by Crystallization/Agglomeration and their Thermal Decomposition Characteristics (결정화/응집 기법에 의한 구형 에너지 복합체 제조 및 그 열분해 특성)

  • Lee, Eun-Ae;Shim, Hong-Min;Kim, Jae-Kyeong;Kim, Hyoun-Soo;Koo, Kee-Kahb
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.158-164
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    • 2016
  • Spherical DADNE/AP (1,1-diamino-2,2-dinitroethylen/ammonium perchlorate) energetic composites were produced by drowning-out/agglomeration (D/A). The agglomeration of DADNE with AP particles was found to be affected by the amount of the bridging liquid, stirring velocity and residence time. The composites appeared to grow dramatically with the amount of bridging liquid which triggers agglomeration. As the stirring velocity and the residence time increased, the size of composites increased and then tended to decrease. Thermal gravimetric analysis showed that the addition of DADNE activates the low temperature decomposition (LTD) of AP. For the neat AP, the only about 30 wt% of AP was found to decompose at the LTD. On the other hand, it was found that 70 wt% of AP decomposed when DADNE was added by physical mixing and 90 wt% of AP decomposed when the DADNE/AP composites were prepared by the D/A method.

Analysis of Impact of Agglomeration Externalities in Manufacturing on Regional Productivity: Focused on the Moderating Effects of Industrial Complex (제조업 집적의 외부효과가 지역경제 생산성에 미치는 영향 분석: 산업단지 조절효과를 중심으로)

  • Woo, Hansoun
    • Journal of the Economic Geographical Society of Korea
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    • v.25 no.1
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    • pp.41-59
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    • 2022
  • Does the industrial complex of Korea leading the growth in manufacturing industry play the role of intensifying agglomeration effects? To answer this question, this study empirically analyzes the moderating effects of industrial complex on the relation between agglomeration externalities and regional productivity, which has not been covered by previous researches. To do so, analysis of panel data has been conducted using the regional level data for the period of 2010 to 2019. Empirical results are provided at different levels including the whole country, capital region and non-capital region. As a result, it was found that in non-capital region, environments to strengthen positive agglomeration externalities stemming from specialization and diversity in manufacturing through industrial complex whithin the region are built up. However, moderating effects of industrial complex is quite limited in capital region. This implies that the role of industrial complex needs to be importantly reconsidered in the perspective of maximization of agglomeration effects in manufacturing, revitalization of non-capital area and manufacturing innovation.