• Title/Summary/Keyword: Aerosol surface area

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이어도 해양종합과학기지에서의 3차원 바람성분에 따른 에어로솔 수 농도 변동 특성 (The Variation of Aerosol Number Concentrations in Relation with 3D Wind Components in the Ieodo Ocean Research Station)

  • 박성화;장상민;이동인;정운선;정종훈;정성아;정창훈;김경식;김경익
    • 대기
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    • 제22권1호
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    • pp.97-107
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    • 2012
  • To investigate variation of aerosol number concentration at each different size with three-dimensional (3D) wind components in ocean area, aerosol particles and 3D wind components were measured in the Ieodo Ocean Research Station, which is located to 419 km southwest from Marado, the southernmost island of Korea, from 25 June to 8 July 2010. The Laser Particle Counter (LPC) and ultrasonic anemometer were used to measure the size of aerosol particles and 3D wind components (zonal (u), meridional (v), and vertical (w) wind) respectively. Surface weather chart, NCEP/NCAR reanalysis data and sounding data were used to analyze the synoptic condition. The distribution of aerosol number concentration had a large variation from bigger particles more than 1.0 ${\mu}m$ in diameter by wind direction during precipitation. In the number concentration of aerosol particles with respect to the weather conditions, particles larger than 1.0 ${\mu}m$ in size were decreased and sustained to the similar concentration at smaller particles during precipitation. The increase in aerosol number concentration was due to the sea-salt particles which was suspended by southwesterly and upward winds. In addition, the aerosol number concentration with vertical wind flow could be related with the occurrence and increasing mechanism of aerosol in marine boundary layer.

에너제틱 금속입자 제조 및 안정화 기술 (Preparation of Energetic Metal Particles and Their Stabilization)

  • 이혜문;김경태;양상선;유지훈;김용진
    • 한국입자에어로졸학회지
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    • 제9권3호
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    • pp.173-185
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    • 2013
  • Oxidations of metal generate large quantity of thermal and light energies but no toxic pollutants, so that metals with high calorific values, such as beryllium, boron, aluminum, magnesium, and lithium, are possible to be used as clean fuels instead of fossil fuels. However, they are so explosive due to very high oxidation rates that they should be stabilized by their surface passivation with oxides, organics and inorganics. For reasonable use of energetic metal particles as solid fuel, therefore, some detail information, such as thermal properties, preparation and passivation methods, and application area, of the energetic metals is introduced in this manuscript.

다분산 에어로졸에 대한 전기집진 효율의 해석해 (Analytic Solution of Electrostatic Precipitator′s Collection Efficiency for Polydisperse Aerosol)

  • 정창훈;박현설;이규원
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2002년도 춘계학술대회 논문집
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    • pp.297-298
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    • 2002
  • 전기집진기(ESP)는 보일러, 소각로등 많은 산업 공정에서 발생되는 입자상 물질을 제거하는데 일반적으로 사용되어 왔다. 가장 널리 쓰이는 ESP의 집진효율을 예측하기 위한 수식으로는 Deutsch-Anderson식으로 다음과 같다.(equation omitted) 여기서 η는 포집효율, Ac는 집진판의 표면적(surface area), Ve는 전기집진기 내 입자의 유효 이동속도(effective migration velocity), 그리고 Q는 단위면적을 통과하는 가스의 부피 유량이다. (중략)

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에어로졸공정에 의한 다공성 TiO2분말의 제조 및 공극특성 (Fabrication and Characterization of Porous TiO2 Powder by Aerosol Process)

  • 장한권;장희동;박진호;조국;길대섭
    • Korean Chemical Engineering Research
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    • 제46권3호
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    • pp.479-485
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    • 2008
  • Aerosol templating 법을 이용하여 두 종류의 출발물질 용액($TiO_2$ 나노분말/PS 콜로이드 혼합용액 및 TTIP/PS 혼합용액)으로부터 mesopore 및 macropore를 동시에 가지는 다공성 $TiO_2$ 나노구조체 분말을 제조하였다. $TiO_2$에 대한 PS 분말의 혼합비 및 반응기 온도가 다공성 나노구조체 분말의 특성에 미치는 영향을 조사하였다. $TiO_2$ 나노분말을 출발 물질로 사용한 경우, $PS/TiO_2$ 무게 혼합비를 0.79에서 1.31로 증가시킴에 따라 macropore의 증가가 SEM을 통하여 관찰되었으며 비표면적과 mesopore volume은 각각 $31.6m^2/g$에서 $39.1m^2/g$으로, $0.068cm^3/g$에서 $0.89cm^3/g$으로 증가하였다. TTIP 전구체를 사용한 경우, 동일조건에서 제조한 분말의 비표면적 및 mesopore volume이 각각 67% 및 75% 감소하였다.

해색 센서 SeaWiFS 관측을 이용한 황사 판독 (Identifying Yellow Sand from the Ocean Color Sensor SeaWIFS Measurements)

  • 손병주;황석규
    • 대한원격탐사학회지
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    • 제14권4호
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    • pp.366-375
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    • 1998
  • 해색 센서인 SeaWIFS의 자료를 이용하여 황사의 광학적 성질과 황사가 해색 원격탐사에 미치는 영향에 대해 연구하였다. 황사가 해색에 미치는 영향을 살펴보기 위해 황사현상이 나타났던 1998년 4월 18일과 맑은 날인 4월 25일의 자료를 선택하였다. NASA 표준 대기 보정 알고리즘은 황사의 영역을 복사휘도가 너무 크거나 또는 구름의 영역으로 간주하여 황사 지역에 대한 해색 정보를 생산하지 않고 있다. 4월 18일 동아시아 해양에 도착한 황사는 에어로졸의 광학적 두께의 관점에서 상대적으로 균질한 두 부류로 구성되어 있음을 보여주었다. 즉, 에어로졸 광학적 두께가 0.8 부근에 최대의값을 갖는 강한 황사와 0.4 부근의 값을 갖는 약한 황사가 존재하였다. 즉 에어로졸 광학적 두께가 0.8 부근에 최대의 값을 갖는 강항 황사와 0.4 부근의 값을 갖는 약한 황사가 존재하였으며, 이 값들은 지상의 관측 결과와 잘 일치하였다. 지상 일기도의 분석과 경로 역추적을 통해 얻은 황사의 이동은 약한 황사 영역이 먼지 폭풍의 가장자리로부터 기원하고 있음을 암시한다. 또한, 황사와 관련된 에어로졸 광학적 두께가 큰 영역은 dir 0.2 정도의 광학적 두께를 갖는 배경 에어로졸과 매우 다름을 알 수 있다. 이러한 에어로졸의 광학적 특성은 대기 보정 변수의 도입과 더불어 황사의 영역을 정량적으로 결정할 수있음을 가능케 하고 있다. 본 논문의 결과는 대기 보정 변수와 광학적 두께의 분산 그래프에 나타나는 특징을 황사 영역을 결정할 수 있음을 보여준다.

대향류 확산 화염 중에서 비구형 입자 성장에 관한 해석 (Simulation of the Growth of Non-Spherical Particles in a Counterflow Diffusion Flame)

  • 정재인;황준영;이방원;최만수;정석호
    • 대한기계학회논문집B
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    • 제23권8호
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    • pp.997-1009
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    • 1999
  • Silica particle formation and growth process including chemical reaction, coagulation and sintering was studied in a counterflow diffusion flame burner. The counterflow geometry provides a one dimensional flow field, along the stagnation point streamline, which greatly simplifies interpretation of the particle growth characteristics. $SiCl_4$ has been used as the source of silicon in hydrogen/oxygen/argon flames. The temperature profiles obtained by calculation showed a good agreement with experiment data. Using one and two dimensional sectional method, aerosol dynamics equation in a flame was solved, and these two results were compared. The two dimensional section method can consider sintering effect and growth of primary particle during synthesis, thus it showed evolution of morphology of non-spherical particles (aggregates) using surface fractal dimension. The effects of flame temperature and chemical loading on particle dynamics were studied. Geometric mean diameter based on surface area and total number concentration followed the trend of experiment results, especially, the change of diameters showed the sintering effect in high temperature environment.

비구형 입자의 형상에 따른 단극 확산 하전 특성 (Effects of Particle Shapes on Unipolar Diffusion Charging of Non-Spherical Particles)

  • 오현철;박형호;김상수
    • 대한기계학회논문집B
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    • 제28권5호
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    • pp.501-509
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    • 2004
  • Unipolar diffusion charging of non-spherical particles was investigated for various particle shapes. We researched with TiO$_2$agglomerates produced by the thermal decomposition of titanium tetraisopropoxide (TTIP) vapor. TTIP was converted into TiO$_2$, in the furnace reactor and was subsequently introduced into the sintering furnace. Increasing the temperature in the sintering furnace, aggregates were restructured into higher fractal dimensions. The aggregates were classified according to their mobility using a differential mobility analyzer. The projection area and the mass fractal dimension of particles were measured with an image processing technique performed by using transmission electron microscope (TEM) photograph. The selected aggregates were charged by the indirect photoelectric-charger and the average number of charges per particle was measured by an aerosol electrometer and a condensation particle counter. For the particles of same mobility diameter, our results showed that the particle charge quantity decreases as the sintering temperature increases. This result is understandable because particles with lower fractal dimension have larger capacitance and geometric surface area.

융합형여과집진장치에서의 먼지입자와 원소수은의 제거 성능 특성 (Simultaneous Removal Characteristics of Particulate and Elemental Mercury in Convergence Particulate Collector)

  • 박영옥;정주영
    • 한국입자에어로졸학회지
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    • 제6권4호
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    • pp.173-183
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    • 2010
  • The high temperature pleated filter bags which were used during this study were made of pleated nonwoven fabric of heat and acid resistant polysulfonate fibers which can withstand the heat up to $300^{\circ}C$ and have a filtration area which is 3 to 5 times larger than the conventional round filter bags. Cartridge module packed with 3 kind of the sulfur impregnated activated-carbon based sorbents were inserted in the inner of the pleated filter bag. This type of pleated filter bag was designed to remove not only the particulate matter but also the gaseous elemental mercury. The electrostatic precipitator part can enhance the particulate removal efficiency and reduce the pressure drop of the pleated filter bag by agglomerated particles to form a more porous dust layer on the surface of the pleated bag which is increased the filter bag cleaning efficiency. In addition, the most of particles are separated from the flue gas stream through the cyclone and the electrostatic precipitator part which were installed at the lower part and main body part of the convergence particulate collector, respectively. Thus reduce particulate loading of the high temperature pleated filter bags were applied in this study to analyze the removal characteristics of particulate matter and gaseous elemental mercury.

Polymerization of fibrous and high molecular weight polyethylene using MgCl2/SBA-16/TiCl4

  • Panpoom, Salinla;Klinsrisuk, Sujitra;Martwiset, Surangkhana;Poonsawat, Choosak
    • 한국입자에어로졸학회지
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    • 제11권4호
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    • pp.107-113
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    • 2015
  • SBA-16 (Santa Barbara Amorphous) was synthesized over supported $TiCl_4/MgCl_2$. Due to its high surface area and excellent morphological performance, it was expected to form the bi-supported catalytic system and be used for ethylene polymerization. Polymerization of ethylene was carried out at atmospheric pressure using hexane as solvent and triethylaluminium as cocatalyst. ICP, FTIR, DSC, TG-DTA were used to characterize polyethylene and catalyst product. Optimum conditions for ethylene polymerization were found to be 100 mL hexane, Al/Ti molar ratio of 160 and 1 h polymerization at $60^{\circ}C$. The activity of 396.76 kg PE/mol Ti.h.atm was achieved. Melting point of the obtained polymer was in the range of $132-135^{\circ}C$ and the highest degree of crystallization was 46%.