• Journal of Korean Society for Atmospheric Environment
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• v.20 no.5
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• pp.685-695
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• 2004

Size-segregated measurements of aerosol composition are used to estimate the transport of natural and anthropogenic aerosols at Gosan site during May 2002. The results of measurement show that not only soil dust but also anthropogenic aerosols, including sulfur and enriched trace metals such as Pb, Zn, Cu, are transported to Gosan. This study combines the size- and time-resolved aerosol composition measurements with factor analysis in order to identify some source materials. As a result, coarse particles (2.5${\mu}m$~12${\mu}m$) are influenced by soil, sea-salt, coal, coal combustion, and nonferrous sources. But fine particles have different sources. The fine particles, which the diameter is from 0.56${\mu}m$ to 2.5${\mu}m$, are more affected by road dust, oil combustion, industry. municipal incineration, and ferrous metal sources. The very fine particles, from 0.09${\mu}m$ to 0.56${\mu}m$, mainly supplied by biomass burning, oil combustion, nonferrous and ferrous metal sources.

• Environmental Engineering Research
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• v.24 no.4
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• pp.690-698
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• 2019

Air pollution has attracted ever-increasing attention because of its substantial influence on air quality and human health. To better understand the characteristics of long-range transported pollution, the single particle chemical composition and size were investigated by the single particle aerosol mass spectrometry in Fuzhou, China from 17th to 22nd January, 2016. The results showed that the haze was mainly caused by the transport of cold air mass under higher wind speed (10 m·s^-1) from the Yangtze River Delta region to Fuzhou. The number concentration elevated from 1,000 to 4,500 #·h^-1, and the composition of mobile source and secondary aerosol increased from 24.3% to 30.9% and from 16.0% to 22.5%, respectively. Then, the haze was eliminated by the clean air mass from the sea as indicated by a sharp decrease of particle number concentration from 4,500 to 1,000 #·h^-1. The composition of secondary aerosol and mobile sources decreased from 29.3% to 23.5% and from 30.9% to 23.1%, respectively. The particles with the size ranging from 0.5 to 1.5 ㎛ were mainly in the accumulation mode. The stationary source, mobile source, and secondary aerosol contributed to over 70% of the potential sources. These results will help to understand the physical and chemical characteristics of long- range transported pollutants.

• Proceedings of the KSRS Conference
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• 2002.10a
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• pp.367-372
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• 2002

Asian dust aerosol layer of 4-6 km altitude accompanied by low clouds was observed by LIDAR and sky-radiometer in Tokyo urban area on April 10, 2001. To synthesize the top of atmosphere (TOA) reflectance, radiative transfer simulation conducted assuming aerosol/cloud vertical structure and aerosol size distribution that were modeled after the ground observations. The refractive index of Asian dust is derived from a laboratory measurement of sampled Chinese soil particles. The synthesized TOA reflectance is compared to the SeaWiFS-derived one sampled at the low cloud pixels whose airmass is the same as the one passed at the observation site. While the two TOA reflectances compare generally well with few percent difference in reflectance, possible sources of the discrepancy are discussed.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.5
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• pp.515-528
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• 2003

The characteristics of one year observation aerosol data in Seoul, 200 I was studied using an OPC (Optical Particle Counter). The size resolved aerosol number concentrations of 0.3 ∼ 25 11m were measured. The results were compared with PM$_{10}$ mass concentration data under various meteorological conditions including dust and precipitation events. For fine particles whose diameter is less than 2.23 ${\mu}{\textrm}{m}$, the number concentration increases in the early morning which is considered due to transportation. while the coarse mode particles increase during daytime. This increase can be explained as local sources and human activities near sampling site. Hourly averaged data show that there exists diurnal variation. Generally, PM$_{10}$ data showed a similar tendency with OPC data. The size resolved OPC data showed that the particles of 0.5 ∼ 3.67 ${\mu}{\textrm}{m}$ are positively correlated with PM$_{10}$ data. The accumulated volume fraction of size resolved aerosol concentration in 0.5 ∼ 10 ${\mu}{\textrm}{m}$ showed that 0.5 ∼ 2.23 ${\mu}{\textrm}{m}$ particles occupied 59.2% of total aerosol volume of 0.5 ∼ 10 ${\mu}{\textrm}{m}$./TEX>.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.10
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• pp.1489-1497
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• 2003

Aerosol charge neutralizers with various radioactive sources have been used to apply an equilibrium charge distribution to aerosols of unknown charge distribution. However, the performance of aerosol charge neutralizers is not well known, especially for highly charged particles. Measurements of highly charged particles are needed in air cleaning devices, e.g. electrostatic precipitator, bag filter with a pre-charger, and electrical cyclone. In this study, the particle charging characteristics of two different aerosol charge neutralizers were experimentally investigated for singly charged monodisperse particles and highly charged polydisperse particles. One has radioactive source of $^{85}$ Kr (beta source, 2 mCi) and the other has $^{210}$ Po (alpha source, 0,5 mCi). The air flow rate passing through each aerosol charge neutralizer was changed from 0.2 to 2.5 L/min. The results show that the charge distribution of singly charged monodisperse particles passing through the $^{85}$ Kr aerosol charge neutralizer is well agreed with the Boltzmann equilibrium charge distribution at an air flow rate of 0.3 L/min, However, it deviates from the equilibrium charge distribution when the air flow rates are 0.6, 1,0, and 1,5 L/min, On the other hands, the effect of air flow rate is insignificant for the $^{210}$ Po aerosol charge neutralizer. The non-equilibrium character in charge distribution of highly charged polydisperse particles passing through the $^{85}$ Kr aerosol charge neutralizer greatly depends on the air flow rate, however it is insensitive to the air flow rate for the $^{210}$ Po aerosol charge neutralizer.

• Journal of Korean Society for Atmospheric Environment
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• v.9 no.1
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• pp.44-50
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• 1993

The suspended particulate matters had been collected by a cascade impactor having 9 size fragnated stages for 2 years (Dec. 1989 to Nov. 1991) in Kyung Hee University-Suwon Campus. The particulate matters were then collected on each stage by membrane filters. The weight concentration on each stage was estimated by a microbalance and further chemical element concentrations were determined by an XRF system. The study focused on developing of a receptor model using the TTFA (target transformation factor analysis) to apportion aerosol mass with the 30 ambient data sets. Each data set consists of the 8 size-ranged subdata sets characterized by 13 element variables. Even though a couple of sources could not be identified, three to five sources were extracted from each aerosol size-range, and then 9 statistical source profiles were generated. Finally, source contribution of particulate matters on each size-range could be estimated in Suwon area.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.5
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• pp.523-528
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• 1996

Aerosol Particles were collected in a heaby traffic region in pusan. Samples were collected in two size fractions with a two-stage sampler during the day and the night. Elemental concentrations of these aerosol particles were determined by a PIXE(Proton Induced X-ray Emission) analysis method. The results suggest that the elements originating mainly from natural sources such as Si, Ca, Fe, Cl, and K are dominent in the coarse fraction, but the elements such as S, Pb, Br, and Zn are dominent in the fine fraction. Br/Pb ratio are evaluated in both coarse and fine size fraction, and which are mainly emitted automobile sources. The study further also discussed other Br/Pb ratio related works described elsewhere. Sulfur in the fine fraction was continuously increased during the sampling period without time variation.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.6
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• pp.629-640
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• 2008

This study investigates long-term trends and characteristics of aerosol optical depth ($\tau_a$) and Angstrom exponent (${\AA}$) around Korea in order to understand aerosol effects on the regional climate change. The analysis period is mainly from 1999 to 2006, and the analysis sites are Anmyun and Gosan, the background monitoring sites in Korea, and two other sites of Xianghe in China and Shirahama in Japan. The annual variations of $\tau_a$ at Anmyun and Gosan have slightly systematic increasing and decreasing trends, respectively. $\tau_a$ at Anmyun shows more substantial variation, probably because of it's being closer and vulnerable to anthropogenic influence from China and/or domestic sources than Gosan. Both values at Gosan and Anmyun are approximately 1.5 times greater than those at Shirahama. The monthly variation of $\tau_a$ exhibits the highest values at late Spring and the lowest at late-Summer, which are thought to be associated with the accumulation of fine aerosol formed through the photochemical reaction before the Jangma period and the scavenging effect after the Jangma period, respectively. Meanwhile, the episode-average $\tau_a$ for the Yellow dust period increases 2 times greater than that for the non-Yellow dust period. A significant decrease in ${\AA}$ for the Yellow dust period is attributable to an increase in the loading of especially the coarse particles. Also we found no weekly periodicity of $\tau_a$'s, but distinct weekly cycle of $PM_{10}$ concentrations, such as an increase on weekdays and a decrease on weekends at Anmyun and Gosan. We expect these findings would help to initiate a study on aerosol-cloud interactions through the combination of surface aerosol and satellite remote sensing (MODIS, Calipso and CloudSat) in East Asia.

• Journal of Korean Society for Atmospheric Environment
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• v.11 no.2
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• pp.191-198
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• 1995

In order to evaluate the distribution and behaviour of atmospheric particulate metals in high-altitude area, we collected 22 aerosol samples using a high volume air sampler at Soback Mt. Meteorological Observation Station from Jan. to Nov. 1993 and analysed for metals (Al, Fe, Mg, Na, Ca, Mn, Co, Ni, Cu, Zn, Cd, and Pb) with ICP/AES and ICP/MS. Although sampling site is located in high-altitude and far from local sources of atmospheric pollutants, enrichments of metals are 2 times higher than those of western coastal reural area. This fact may imply that of metallic pollutants in the coastal rural site were came from further western side (e.g. China), atmospheric metals in this study area contain the signal of metropolitan cities located in the main wind direction (NNW). Sea salts are negligible in the aerosol particle population because reference elements of sea salts (Na, Mg) are all originated from soil particles. The contents of soil particles in aerosols are highest in spring and lowest in winter. Atmospheric enriched elements (Ni, Cu, Zn, Cd and Pb) are diluted with soil particles, especially during the yellow sand period. The results of factor analysis suggest possibility of interpreting their chemical significance in terms of sources (soil, pollutants) and gas-particle conversion processes (formation of ammonium sulfates, ammonium nitrates and/or their mixtures).

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.1
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• pp.39-51
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• 2012

Aerosol slurry samples were collected in 60-min interval using Korean Semi-continuous Elements in Aerosol Sampler (KSEAS) between May 19 and June 6, 2010 at an urban site of Gwangju. The $PM_{2.5}$ samples were collected with a flow rate of 16.7 L/min and particles are grown by condensation of water vapor in a condenser maintained at ${\sim}5^{\circ}C$ after saturation by direct injection of steam. The resulting droplets are collected in a liquid slurry with a airdroplet separator. Concentrations of 16 elements (Al, Fe, Mn, Ca, K, Cu, Zn, Pb, Cd, Cr, Ti, V, Ni, Co, As, Se) in the collected slurry samples were determined off-line by ICP-MS. KSEAS sample analysis encompassed the sampling periods for which 24-hr average elemental species concentrations were calculated for comparison with those derived from 24-hr integrated filter samples. Relationship between elemental species measured by two methods indicated high correlation coefficients (r), mostly greater than r of 0.80. However, we note that concentrations of Al, K, Ca, Mn, and Fe, which are often associated with crustal elemental particles, in the KSEAS samples, were substantially lower (1.4~11 times) than those found in the typical filter-based samples. This discrepancy is probably due to difficulties in transferring insoluble dust particles to the collection vials in the KSEAS. Temporal profiles of elemental concentrations indicate that some transient events in their concentrations are observed over the sampling periods. For the elemental species studied, atmospheric concentrations during the transient events increased by factors of 4 in Mn~80 in Zn, compared to their background levels. Principle component analyses were applied to the hourly KSEAS data sets to identify sources affecting the concentrations of the metal constituents observed. In this study, we conclude that hourly measurements for particle-bound elemental constituents were extremely useful for revealing the short-term variability in their concentrations and developing insights into their sources.