• Tribology and Lubricants
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• v.39 no.5
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• pp.190-196
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• 2023

Anti-adhesion coatings are very important in the processing of adhesive materials such as optical clear adhesive (OCA) films. Choosing the appropriate release coating material for dies and tools can be quite challenging. Hydrophobic surface treatment is usually performed, and its performance is often estimated by the static water contact angle (CA). However, the relationship between the release performance and the CA is not well understood. In this study, the water CAs of surfaces coated with anti-adhesion materials and the peel strengths of the acrylic-based adhesive films are evaluated. STC5 and SUS304 are selected as the base materials. Base materials with different surface roughnesses are produced by hairline finishing, mirror-polishing, and end milling. Four fluoropolymer compounds, including a self-assembled monolayer, are selected to make the base surface hydrophobic. Static, advancing, and receding CAs are mostly increased due to the coating, but the CA hysteresis is found to increase or decrease depending on the coating material. The peel strengths all decreased after coating and are largely dependent on the coating material, with significantly lower values observed for fluorosilane and perfluoropolyether silane coatings. The peel strength is observed to correlate better with the static CA and advancing CA than with the receding CA or hysteresis. However, it is not possible to accurately predict the anti-adhesion performance based on water CA alone, as the peel strengths are not fully proportional to the CAs.

• Applied Chemistry for Engineering
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• v.10 no.1
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• pp.93-97
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• 1999

In order to lower the surface energy of unsaturated polyester(UPE) resin, small amount of siloxane-ester copolymers were incorporated. The copolymers were synthesized by a condensation polymerization using ethylene glycol and hydroxy termintated polydimethylsiloxane as diols and maleic anhydride and phthalic anhydride as dibasic acids. The modified UPE resin surface was characterized by dynamic contact angle (DCA), peel strength measurements of pressure sensitive adhesives and X-ray photoelectron spectroscopy(ESCA). As the copolymer content in the blend and PDMS content in the copolymer are increased, both advancing and receding contact angles against water are increased. The strength required to peel-off the pressure sensitive adhesive tape from the modified UPE resin decreased dramatically with the addition of the copolymer. ESCA results indicated that polydimethylsiloxane segments are predominated at the outer surface of the modified UPE resin.

• The Journal of Korean Academy of Prosthodontics
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• v.30 no.2
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• pp.233-245
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• 1992

The purpose of this study was to evaluate the demensioal stability and wettability of several rubber impression materials. Impressions were made from a metal master die machined to stimulate five full veneer crown preparations symmetrically placed in an arch form. Cast from impressions were measured about ; 1) intrapreparation distance 2) lower base diameter 3) length. For comparing materials were formed against a smooth surface. The advancing contact angle of a saturated aqueous solution of $CaSO_4$ on the impression materials was measured after 1 minute. Mean contact angle were calculated and results were analyzed. Results were as follows : 1. As the intrapreparation distance, hydrophilic addition-cured silicone had the smallest change and condensation-cured silicone had the largest one. 2. As the lower base diameter, traditional addition-cured silicone had the smallest change and polyether had the largest one. 3. As the height, traditional addition-cured silicone had the smallest change and polyether had the largest one. 4. As the contact angle, polyether had the smallest change and condensation-cured silicone had the largest one.

• Journal of computational fluids engineering
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• v.12 no.3
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• pp.41-46
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• 2007

Dynamic behavior of immiscible gas bubble attached to the wall in channel flow plays very important role in many engineering applications. Special attention has been paid to micro direct methanol fuel cell(${\mu}$DMFC) where surface tension becomes dominant factor with minor gravitational effect due to its reduced size. Therefore, displacement of $CO_2$ bubble generating on a cathode side in ${\mu}$DMFC can be very difficult and efficient removal of $CO_2$ bubbles will affect the overall machine performance considerably. We have focused our efforts on studying the dynamic behavior of immiscible bubble attached to the one side of the wall on 2D rectangular channel subject to external shear flow. We used Level Contour Reconstruction Method(LCRM) which is the simplified version of front tracking method to track the bubble interface motion. Effects of Reynolds number, Weber number, advancing/receding contact angle and property ratio on bubble detachment characteristic has been numerically identified.

• Geomechanics and Engineering
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• v.21 no.1
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• pp.23-33
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• 2020

An advancing cutting roof for gob-side entry retaining with no-pillar mining under specific geological conditions is more conducive to the safe and efficient production in a coalmine. This method is being promoted for use in a large number of coalmines because it has many advantages compared to the retaining method with an artificial filling wall as the gateway side filling body. In order to observe the inner structure of the gateway cutting roof and understand its stability mechanism, an equivalent material simulation experiment for a coalmine with complex geological conditions was carried out in this study. The results show that a "self-stabilization bearing structure" equilibrium model was found after the cutting roof caving when the cut line deviation angle was unequal to zero and the cut height was greater than the mining height, and the caving roof rock was hard without damage. The model showed that its stability was mainly controlled by two key blocks. Furthermore, in order to determine the optimal parameters of the cut height and the cut line deviation angle for the cutting roof of the retaining gateway, an in-depth analysis with theoretical mechanics and mine rock mechanics of the model was performed, and the relationship between the roof balance control force and the cut height and cut line deviation angle was solved. It was found that the selection of the values of the cut height and the cut line deviation angle had to conform to a certain principle that it should not only utilize the support force provided by the coal wall and the contact surface of the two key blocks but also prevent the failure of the coal wall and the contact surface.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.32 no.2
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• pp.143-147
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• 2008

Super-hydrophobic surfaces showed that contact angle of water was higher than 140 degrees. That surface could be made several methods such as Carbon nano tubes grown vertically, PDMS asperities arrays, hydrophobic fractal surfaces, and self assembled monolayers coated by CVD and so on. However, we fabricated super-hydrophobic surfaces with plasma treatments which were very cost efficient processes. Their surfaces were characterized by static contact angles, advancing, receding, and stability against UV irradiation. Optimal surfaces showed static contact angles were higher than 150 degrees. Super-hydrophobic property was remained after UV irradiation for one week.

• Membrane and Water Treatment
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• v.1 no.1
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• pp.83-92
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• 2010

To improve the antifouling characteristics of polypropylene hollow fiber microporous membranes in a submerged membrane-bioreactor for wastewater treatment, the surface-modification was conducted by Ar plasma treatment. Surface hydrophilicity was assessed by water contact angle measurements. The advancing and receding water contact angles reduced after the surface modification, and hysteresis between the advancing and receding water contact angles was enlarged after Ar plasma treatment due to the increased surface roughness after surface plasma treatment. After continuous operation in a submerged membrane-bioreactor for about 55 h, the flux recovery after water cleaning and the flux ratio after fouling were improved by 20.0 and 143.0%, while the reduction of flux was reduced by 28.6% for the surface modified membrane after 1 min Ar plasma treatment, compared to those of the unmodified membrane. Morphological observations showed that the mean membrane pore size after Ar plasma treatment reduced as a result of the deposition of the etched species; after it was used in the submerged membrane-bioreactor, the further decline of the mean membrane pore size was caused by the deposition of foulants. X-ray photoelectron spectroscopy and infrared spectroscopy confirmed that proteins and polysaccharide-like substances were the main foulants in the precipitate.

• Journal of the Korean Society of Visualization
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• v.12 no.2
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• pp.23-29
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• 2014

Although many studies have been done on an open-end capillary, the invasion into a closed end capillary is still novel in its investigation. In this research we have explored the fluid invasion in closed-end capillaries where the shape of the meniscus and the height of invasion were accompanied by gas compression inside the capillary. Theoretically, the one dimensional momentum balance equation shows the fluid oscillation. In the experiments, we have found the different phenomena, either the fluid oscillation with low frequency or no oscillation. This discrepancy is mostly caused by two factors. First, a continuous decrease of the advancing contact angle due to decreasing invasion velocity as increasing pressure inside the closed-end capillary reduces the invasion velocities. Second, the high shear stress within the entrance length region was generated by the plug like velocity profile.

• Composites Research
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• v.25 no.3
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• pp.76-81
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• 2012

Atmospheric pressure plasma treatment on carbon nanotube (CNT) surfaces was performed to modify reinforcement effect and interfacial adhesion of carbon fiber reinforced CNT-phenolic composites. The surface changes occurring on CNT treated with plasma were analyzed by using Fourier transform infrared spectroscope (FT-IR). The significant improvement of wettability on CNT was confirmed by static contact angle test after plasma treatment. Such plasma treatment resulted in a decrease in the advancing contact angle from $118^{\circ}$ to $60^{\circ}$. The interfacial adhesion between carbon fiber and CNT-phenolic composites increased by plasma treatment based on apparent modulus test results during quasi-static tensile strength. Furthermore, the proposed database offers valuable knowledge for evaluating interfacial shear strength (IFSS).

• Journal of Mechanical Science and Technology
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• v.20 no.11
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• pp.1980-1992
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• 2006

Nucleate pool boiling experiments were performed using pure R11 for various surface angles under constant heat flux conditions during saturated pool boiling. A 1-mm-diameter circular heater with an artificial cavity in the center that was fabricated using a MEMS technique and a high-speed controller were used to maintain the constant heat flux. Bubble growth images were taken at 5000 frames per second using a high-speed CCD camera. The bubble geometry was obtained from the captured bubble images. The effects of the surface angle on the bubble growth behavior were analyzed for the initial and thermal growth regions using dimensional scales. The parameters that affected the bubble growth behavior were the bubble radius, bubble growth rate, sliding velocity, bubble shape, and advancing and receding contact angles. These phenomena require further analysis for various surface angles and the obtained constant heat flux data provide a good foundation for such future work.