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Mechanochemical Synthesis of ZnMn2O4 and its Electrochemical Properties as an Anode Material for Lithium-ion Batteries

  • Park, Yoon-Soo;Oh, Hoon;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3333-3337
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    • 2011
  • $ZnMn_2O_4$ has been prepared by a mechanochemical process using a mixture of $Mn_2O_3$ and ZnO as starting materials, and investigated as a possible anode material for lithium-ion batteries. The phase evolution and morphologies of the ball-milled and annealed powders are characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy dispersive microanalysis (EDX), respectively. The solid-state reaction for the formation of $ZnMn_2O_4$, under the given experimental conditions, is achieved in a short time (30 min), and the prepared samples exhibit excellent electrochemical performances including an enhanced initial coulombic efficiency, high reversible capacity, and stable capacity retention with cycling.

Preparation and Luminescence Properties of PDP Green Phosphors using Polymer Matrix Technique

  • Jun, Sang-Bae;Lee, Dong-Kyu;Kim, Soo-Jong;Masaki, Takaki;Han, Chung-Hwa
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.3
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    • pp.121-124
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    • 2007
  • The $Zn_2SiO_4:Mn$ phosphors were prepared using polymer matrix technique in order to improve the performance of green emitting phosphors for plasma display panel(PDP). $Zn_2SiO_4:Mn$ phosphor exhibits a strong green emission around 520-530 nm. The emission intensity and particle size of powders were controlled by sintering temperature and raw material composition. The zinc silicate $Zn_2SiO_4:Mn$ single phase were obtained at lower temperature than prepared by solid-state reaction method. PL luminance of $Zn_2SiO_4:Mn$ phosphor was similar to the commercial material.

Application of silk composite to decorative laminate

  • Kimura, Teruo;Aoki, Shinpei
    • Advanced Composite Materials
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    • v.16 no.4
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    • pp.349-360
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    • 2007
  • Recently, natural fiber reinforced composite is attracting attention and considered as an environmentally friendly material. Usually cellulosic fibers are used to reinforce the composites, but some protein fibers such as silk and wool serve the same purpose. In this paper, we proposed a method of producing artistic composite from artistic fabric by using silk fiber reinforced biodegradable plastic, which is designated as 'silk composite', for reinforcement. In order to expand applications of the silk composite, we performed the compression molding of decorative laminates with woody material, which was selected as a core material, and examined the properties of molded decorative laminates with various content of the silk composite. Since plywood and medium-density fiberboard (MDF) are widely used for decorative laminates, we selected them as core materials. As a result, flexible decorative laminates with high flexural strength were obtained by compounding the silk composite with wood materials.

Hardness and Distortion Characteristics of SCM415 Steel by Carburizing (진공침탄과 가스침탄에 의한 SCM415강의 경도 및 변형특성)

  • Park, S.J.;Rhee, K.S.;Kim, K.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.6
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    • pp.269-271
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    • 2002
  • For the investigation of the hardness profiles and distortion characteristics of SCM415 steel, test pieces of SCM415 steel were gas and vacuum carburizing treated. The hardness profiles and distortion characteristics of vacuum and gas carburized SCM415 steel show different results. Vacuum carburizing can offer more improved hardness profiles than alternate methods of carburizing. Compared to alternate methods of carburizing, vacuum carburizing can offer improved mechanical properties and reduced cycle times of the process.

Dual Domain Effect on a Rubbing Mura in a Fringe-Field Switching (FFS) Liquid Crystal Display

  • Oh, S.M.;Jeon, Y.M.;Lee, S.H.;Eom, T.Y.;KIM, H.Y.;LIM, Y.J.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.426-429
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    • 2005
  • The fringe-field switching (FFS) mode associated with a transition from a homogenously aligned to twist deformation require rubbing process. In this devices, $1^o$ of misalignment in an azimuthal direction could cause voltage-dependent transmittance (V-T) to be different from that in a normal area and consequently results in a rubbing mura. According to our studies, the single domain FFS cells are much more sensitive to the rubbing mura than the dual domain FFS cell. Moreover, the FFS cells with negative LC are much more sensitive to the rubbing mura than the FFS cells with positive LC.

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Fringe-Field Switching Transflective Displays

  • Lim, Y.J.;Choi, M.O.;Lee, S.H.;Song, J.H.;Jeong, Y.H.;Kim, H.Y.;Kim, S.Y.;Lim, Y.J.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.419-422
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    • 2005
  • We have studied transflective liquid crystal displays (LCDs) associated with fringe-field switching (FFS) mode to achieve high image quality. In the past, several cell structures were used to fabricate transflective FFS liquid crystal display s. Their structures and characteristics are carefully examined to find their merits and cons. Further, optimization of cell parameters to achieve a single driving circuit is performed.

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Zn$_2SiO_4$ : Mn Phosphor Particles Prepared by Spray Pyrolysis Process

  • Kang, Yun-Chan;Park, Hee-Dong;Lim, Mi-Ae
    • Journal of Information Display
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    • v.2 no.4
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    • pp.57-62
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    • 2001
  • Green-emitting $Zn_2SiO_4$:Mn phosphor particles having a spherical shape and high luminescence intensities under VUV were prepared by spray pyrolysis process under severe preparation conditions. The type of precursor solutions affected the morphology and luminescence characteristics of the prepared particles. The particles prepared from the clear solution by laboratory-scale process had spherical shape and dense morphology, while the particles prepared from the severe preparation conditions had rough surface and collapsed structure. However, the particles prepared from the colloidal solution utilizing fumed silica were spherical in shape and filled morphology at the severe preparation conditions of high flow rate of carrier gas, high concentration of solution, and large reactor size. The prepared $Zn_2SiO_4$:Mn phosphor particles with complete spherical shape had higher photoluminescence intensity than that of the commercial product prepared by solid state reaction.

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Principle, current status and developing trend of FRAM

  • Chung, Il-Sub;Yi, In-Sook;Lee, Jung-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.82-82
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    • 1999
  • Ferroelectric materials are characterized by the existence of a spontaneous remnant polarization that can be switched between two stable states by an applied field. This phenomenon is known as ferroelectricity. The ferroelectricity can be utilized for nonvolatile memory application. Up to now 256K FRAM was successfully fabricated and sold in the memory market. This paper will briefly review the current statue of ferroelectric random access memory (FRAM) focusing on recent developments. In addition, the future prospects of FRAM will be addressed.

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Fabrication of Low Density Sintered Stainless Steel Filter

  • Seok, Se-Hoon;Park, Dong-Kyu;Jung, Kwang-Chul
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.611-612
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    • 2006
  • In a manufacturing technique of the sintered filter, pressureless sintering method has good permeability, it is not need the binder and lubricant used on compacting process, so it has little contamination and it is easy to control the pore size and shape but the mechanical strength is low relatively and it is difficult that parts of complicate form are manufactured. In the case of manufacturing the filter by press and sintering method, in order to be satisfactory characteristic of un-pressed filter, in this study sintered metal filter fabricated by using 30-40mesh stainless steel 316L powder and additive agents. Porosity and structure of pores, permeability and mechanical strength of the sintered filter were investigated with the variation sintering conditions. Porosity was nearly constant about $60{\sim}70%$, density, permeability and mechanical strength were changed markedly with quantity of additive materials and sintering conditions.

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Preparation of Nanocapsules Containing Phase Change Materials by Miniemulsion Polymerization

  • Oh, Keun Jin;Kim, Dae-Su;Lee, Jae Heung;Choi, Kil-Yeong;Lee, Changjin
    • Journal of Adhesion and Interface
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    • v.4 no.1
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    • pp.35-42
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    • 2003
  • Polystyrene nanocapsules containing octadecane as a core material were prepared by miniemulsion polymerization. The morphology and size of the nanocapsules were measured with varying the surfactant concentration, content of initiator, core/shell ratio and content of comonomer. The morphologies of the prepared nanoparticles were examined by a scanning electron microscope, a transmission electron microscope and the core material was confirmed by a differential scanning calorimeter. The particles below 70 nm in diameter were formed at a high surfactant concentration. The size of the nanoparticles was not significantly affected by the initiator content. With increasing the core/shell ratio and polar comonomer content, the particle size and its distribution were increased.

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