• 한국환경과학회지
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• 제11권3호
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• pp.227-234
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• 2002

Laboratory experiments were conducted to examine the behavior of metalaxyl in environment which was used as pesticide in green soil of golf course and as functions of the characteristics of adsorption, desorption and degradation in soil texture and organic matter contents. Acid water containing metalaxyl was conducted to evaluate the effects on adsorption, desorption and degradation. The adsorption of metalaxyl played more significant role in organic contents than clay contents, and pH Increases more pH 2.5 than pH 5.6. The desorption of metalaxyl from contaminants soil decreased higher organic contents LS-soil than S-soil, but the desorption amount of metalaxyl increased more pH 5.6 than pH 2.5. The rate of degradation of metalaxyl in green soil environmental increased higher organic contents LS-soil than S-soil and decreased more pH 2.5 than pH 5.6. These results indicated that the behavior of metalaxyl of the green soil was affected the soil texture of the golf course. Increasing of organic contents, the adsorption amount of metalaxyl on soil increased. Moreover the decrease of the pH of solution increased adsorption amounts and decreased desorption amounts. As the results, the transportation of metalaxyl in soil decreased the acidic rates. The acidification of soil by the acid rain increased the adsorption amount of metalaxyl, but the degradation of metalaxyl decreased. Therefore, it is possible to sustain contamination in run-off the stream and ground water by residuals in soil.

• 한국자동차공학회논문집
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• 제13권5호
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• pp.181-187
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• 2005

The behavior of fox adsorption and desorption of the NOx storage catalyst supported on Ba additive were studied by the TPA/TPD experiments and reactivity tests. Applying the transient responses and NOx TPA/TPD test by CLD were effective methods to analyze the characteristics of the NOx storage catalyst. NOx variation of the NOx storage catalyst in the lean air/fuel conditions according to temperature was dominated by NOx adsorption and desorption rather than catalytic reduction. The presence of reductants in the lean mixture promoted the NOx desorption at the $500^{\circ}C$ higher temperature. The temperatures for maximum NOx conversion with CH4 and $C_3H_6$ as a rich spike reductant appear around $500^{\circ}C\;and\; 400^{\circ}C$ respectively.

• 한국안전학회지
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• 제12권3호
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• pp.97-105
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• 1997

Mo-99(Molybdenum) is the only source of Tc-99m(Technetium) which is most frequently used in nuclear medical diagnostics and the demand is on the increase recently. Separation and refining of Mo-99 was investigated by adsorption and desorption on alumina. At pH=0.63, adsorption isotherm of Mo was fitted by Redlich ＆ Peterson equation using the adsorption experimental data. It was found that the pore diffusion model ($D_p=1.4{\times}10^{-6}cm^2/s, K_f/=0.4 cm/s$) agreed well with batch adsorption experimental data. RTDs(Residence Time Distributions ) were measured and axial dispersion coefficients were obtained in the fixed bed absorber according to the changes of the flow rate using 0.05% -NaCl. From the adsorption experimental data, it was shown that the behavior of breakthroughs depended on flow rate. Mo recovery yield was increased as adsorption flow rate was increased and desorption flow rate was decreased.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.268-268
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• 2012

Adsorption and desorption of toluene from bare and $TiO_2$-coated silica with a mean pore size of 15 nm was studied using breakthrough curves and temperature programmed desorption. Thicknesses of $TiO_2$ films prepared by atomic layer deposition on silica were < 2 nm, and ~ 5 nm, respectively. For toluene adsorption, both dry and humid conditions were used. $TiO_2$-thin film significantly improved toluene adsorption capacity of silica under dry condition, whereas desorption of toluene from the surface as a consequence of displacement by water vapor was more pronounced for $TiO_2$-coated samples with respect to the result of bare ones. In the TPD experiments, silica with a thinner $TiO_2$ film (thickness < 2 nm) showed the highest reactivity for toluene oxidation to $CO_2$ in the absence and presence of water. We show that the toluene adsorption and oxidation reactivity of silica can be controlled by varying thickness of $TiO_2$ thin films.

• Journal of Electrochemical Science and Technology
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• 제7권3호
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• pp.185-189
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• 2016

The coupled channel method via the Local Reflection (LORE) matrix is employed to investigate the quantum mechanical behavior of the sticking or adsorption and desorption of hydrogen (H) atom on bilayer graphene via the armchair edge. The sticking and desorption probabilities of H are calculated and are plotted against the initial translational energy of H. The sticking probability plot shows a barrierless reaction indicating that hydrogen is easily adsorbed on the armchair edge of graphene. The desorption probability plot, however, shows that desorption of H from the graphene sheets is an activated process with a barrier height of 4.19 eV suggesting that a strong bond exists between the adsorbed H atom and the edge carbon atom. Thus, temperatures higher than the operating temperatures (300 - 1500 K) of conventional fuel cells are necessary to release the adsorbed H atom from the armchair edge of graphene.

• Advances in environmental research
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• 제4권2호
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• pp.135-142
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• 2015

In this study, we evaluated the adsorption/desorption of uranium (U) in pure soil environment using continuous column reactor. We additionally investigated the adsorption/desorption mechanism of U on vivianite surface in molecular scale using quantum calculation. We observed that below $0.1{\mu}M$ of U was detected after 20 d from U injection ($1{\mu}M$) in adsorption test. However, all of absorbed U was detached from vivianite surface in 24 h by injection of CARB solution ($1.44{\times}10^{-2}M\;NaHCO_3$ and $2.8{\times}10^{-3}M\;Na_2CO_3$). Based on exchange energy calculation, we found that $UO_2(CO_3)_2{^{2-}}$ and $UO_2(CO_3)_3{^{4-}}$ species have higher repulsive energy than $UO_2(OH)_2$ species. The results obtained from this study could be applied to predict the behavior of uranium in contaminated and remediation sites.

• 자원리싸이클링
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• 제31권6호
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• pp.25-35
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• 2022

본 연구는 겔 타입의 음이온교환 수지를 이용하여 바나듐과 텅스텐 이온의 흡·탈착 거동과 분리조건을 규명하였다. 용액의 초기산도에 따른 흡착실험에서 바나듐은 강산성 및 강염기성에서 흡착률이 현저히 낮아지며, 텅스텐은 강염기성에서 흡착률이 낮게 나타났다. 반응온도의 상승은 흡착반응속도 및 최대흡착량의 증가에 영향을 주었으며, 텅스텐은 최대흡착량에 미치는 영향이 미미하였다. 이온교환 수지에 대한 바나듐과 텅스텐의 흡착등온실험은 두 이온 모두 Langmuir 흡착등온식에 적합하였으며, 텅스텐의 경우 폴리옥소메탈레이트화 되어 이온 간의 결합이 이루어져 다분자층 흡착의 형태가 나타나 Freundlich 흡착등온식에도 적합한 것으로 나타났다. 두 이온교환 수지 모두 유사 2차 반응속도모델에서 잘 모사되었으며, 탈착용액의 종류에 따른 바나듐과 텅스텐의 탈착특성에서 바나듐은 HCl 수용액 및 NaOH 수용액 모두 탈착이 이루어 졌으며, 텅스텐은 HCl 수용액에서 탈착이 전혀 이루어지지 않아 탈착공정을 통한 두 이온의 분리가 가능하였다. 탈착반응은 반응 개시 후 30분 이내에 평형에 도달하였으며, 90% 이상 회수가 가능하였다.

• 한국대기환경학회지
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• 제22권2호
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• pp.249-257
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• 2006

In this work, the adsorptive and desorptive behavior of reduced sulfur compounds (RSC) was investigated using the combination of the Peltier cooling (PC)/thermal desorption (TD) unit with the gas chromatographic (GC) detection technique. To examine the adsorptive characteristics of RSC on clothing materials, a total of nine experiments were conducted in a stepwise manner. Once small towel pieces are exposed to significant quantities of RSC standards with high concentrations (10 ppm), the desoprtion stage was then induced by deloading RSC with ultrapure $N_2$ at three different flow rates (FR) of 20, 40, and 60 mL/min. At each FR, the total deloading volume of 400, 800, and 1,600 mL were maintained. These results were then compared in terms of odoring efficiency by dividing the total amount of desorption with the total amount used for exposition or RSC loading. The results indicated that desorption reaction of certain compounds ($CH_3SH$ and DMS) can be influenced significantly with the reducing FR, while they are not affected directly by the total deloading volume. In addition, when the extent of adsorption was compared for most S compounds by the odoring efficiency term, the extent of absorption generally occurred at approximately 1/1000 level of original exposition.

• 한국산학기술학회논문지
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• 제12권5호
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• pp.2439-2444
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• 2011

기존에 주로 사용되었던 활성탄을 대체할 수 있는 활성탄소섬유를 이용하여 휘발성 유기화합물질의 흡 탈착 특성을 연구하였으며, 고정층을 이용하여 흡착 및 파과특성을 조사하였다. 활성탄소섬유중 ACFJ의 경우가 활성탄에 비하여 약1.15배 높은 흡착량을 보였으며, 흡착층의 온도가 증가함에 따라 파과시간 및 흡착량은 감소하였다. 또한 활성탄의 경우 약 99%까지 탈착하는데 20분이 소요되었으며, 활성탄소섬유의 경우 약 99% 탈착되기까지 5분이 걸려 활성탄소섬유가 약 4배 빠르게 탈착됨을 알 수 있었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.219-219
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• 2012

The formation and thermal desorption behaviors of octanethiol (OT) SAMs on single crystalline Au (111) and polycrystalline Au, Ag, and Cu substrates were examined by X-ray photoelectron microscopy (XPS), thermal desorption spectroscopy (TDS), and contact angle (CA) measurements. XPS and CA measurements revealed that the adsorption of octanethiol (OT) molecules on these metals led to the formation of chemisorbed self-assembled monolayers (SAMs). Three main desorption fragments for dioctyl disulfide (C8SSC8+, dimer), octanethiolate (C8S+), and octanethiol (C8SH+) were monitored using TDS to understand the effects of surface morphology and the nature of metal substrates on the thermal desorption behavior of alkanethiols. TDS measurements showed that a sharp dimer peak with a very strong intensity on single crystalline Au (111) surface was dominantly observed at 370 K, whereas a broad peak on the polycrystalline Au surface was observed at 405 K. On the other hand, desorption behaviors of octanethiolates and octanethiols were quite similar. We concluded that substrate morphology strongly affects the dimerization process of alkanethiolates on Au surfaces. We also found that desorption intensity of the dimer is in the order of Au＞＞Ag＞Cu, suggesting that the dimerization process occurs efficiently when the sulfur-metal bond has a more covalent character (Au) rather than an ionic character (Ag and Cu).