• 한국세라믹학회지
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• 제39권7호
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• pp.663-668
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• 2002

폐기물 함유 세라믹 재료의 성형과정에서 일차적인 중금속의 안정화를 알아보기 위하여 중금속(Cd, Cr, Cu, Fe, Pb, Zn) 표준용액의 농도를 각각 5, 10, 15, 20ppm으로 조절하여 점토, 백토와 제올라이트에 대해 회분식 흡착실험을 행하였다. 중금속 표준용액의 농도가 증가할수록 모든 시료에서 중금속 흡착률은 감소하는 경향을 보였다. 점토와 백토는 Cr을 제외한 모든 중금속에서 평균 80% 이상의 흡착률을 보였고, Fe와 Pb에서는 99% 이상의 우수한 흡착률을 보였다 점토와 백토를 혼합한 경우, Cr에 대한 흡착률이 점토와 백토에 비해 우수하였으나 Zn에 대한 흡착률은 상대적으로 작았다. Cr, Zn은 다른 중금속에 비해 낮은 중금속 흡착률을 보이는데, 이것은 낮은 pH에서 용액 내 수소이온과 이온교환경쟁을 벌이기 때문인 것으로 사료된다.

• 한국물환경학회지
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• 제24권3호
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• pp.311-316
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• 2008

This study aimed to obtain equilibrium concentration on adsorption removal of ammonia nitrogen by activated carbon, to express the adsorption characteristics following Freundlich isotherm and also, based on the value obtained, to investigate the relationship between physical characteristics of activated carbon and dynamics of ammonia nitrogen removal by obtaining rate constant and effective pore diffusivity. The results summarized from this study are as follows. It was noted that powdered activated carbon showed better adsorption ability than granular activated carbon. The value of constant (f) of Freundlich isotherm of powered activated carbon was $4.6{\times}10^{-8}$ which is bigger than that of granular activated carbon. The adsorption rate constant on ammonia nitrogen of powered activated carbon with high porosity and low effective diameter was highest as 0.416 hr-1 and the effective pore diffusivity ($D_e$) was lowest as $1.17{\times}10^{-6}cm^2/hr$, and the value of ammonia nitrogen adsorption rate constant of granular activated carbon was $0.149{\sim}0.195hr^{-1}$. It was revealed that, with the same amount of dosage, the adsorptive power of activated carbon with lower effective diameter and bigger porosity was better and its rate constant was also high. With a little adsorbent dosage of 2 g, there was no difference removal ability of ammonia nitrogen as change of adsorption properties.

• 공업화학
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• 제9권5호
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• pp.689-697
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• 1998

가교도와 희석제량을 변화시켜 제조한 인산기를 갖는 MR형 양이온 교환수지(RGP)에 대하여 우라늄의 흡착평형, 흡착속도 및 흡착 율속 단계를 고찰하였다. RGP 수지에 대한 우라늄의 흡착 평형은 가교도, 희석제량 및 흡착온도 변화 모두 Freundlich 등온식과 Langmuir 등온식으로 잘 나타났다. RGP수지에 대한 우라늄의 흡착량과 흡착속도는 흡착 온도가 증가함에 따라 증가하였으며 이때 흡착열은 ${\Delta}H=11kcal/mol$ 이었다. RGP 수지에 대한우라늄의 흡착속도는 가교도의 영향인 경우 RGP-10(50)>RGP-1(50)>RGP-2(50)>RGP-5(50)RGP-0(50)>이며, 희석제량의 영향인 경우 RGP-2(75)>RGP-2(100)>RGP-2(50)>RGP-2(30)>RGP-2(0) 순으로 증가하였다. RGP수지에 대한 우라늄의 확산저항은 분자확산<세공확산<표면확산 순이었으며, 수지내의 우라늄의 확산 율속은 세공 확산보다 표면 확산이 율속이었다.

• 한국환경과학회지
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• 제28권1호
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• pp.55-64
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• 2019

The adsorption properties of $Cs^+$ and $Cu^{2+}$ ions were evaluated by using a polysulfone scoria zeolite (PSf-SZ) composite with synthetic zeolite synthesized from Jeju volcanic rocks (scoria). In order to investigate the adsorption properties, various parameters, such as pH, contact time, reaction rate, concentration, and temperature in aqueous solutions, were evaluated by tests carried out in batch experiments. The adsorption capacities of $Cs^+$ and $Cu^{2+}$ ions increased between pH 2 but achieved equilibrium at pH 4 and above. The adsorption rate increased rapidly up to the initial 24 h, after which it plateaued ; the adsorption rate then sustained at equilibrium from 48 h. The adsorption kinetics of $Cs^+$ and $Cu^{2+}$ ions were described better by the pseudo-second-order kinetic model than the pseudo-first-order kinetic model. The Langmuir model fitted the adsorption isotherm data better than the Freundlich model. The maximum adsorption capacities of $Cs^+$ and $Cu^{2+}$ ions obtained from the Langmuir model were 53.8 mg/g and 84.7 mg/g, respectively. The calculated thermodynamic parameters showed that the adsorption of $Cs^+$ and $Cu^{2+}$ ions on PSf-SZ was feasible, spontaneous and endothermic reaction.

• 한국전기전자재료학회논문지
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• 제24권11호
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• pp.929-934
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• 2011

The adsorption kinetic study of ruthenium complex, N3, onto nanoporous titanium dioxide ($TiO_2$) photoanodes has been carried out by measuring dye uptake in-situ. Three simplified kinetic models including a pseudo first-order equation, pseudo second-order equation and intraparticle diffusion equation were chosen to follow the adsorption process. Kinetic parameters, rate constant, equilibrium adsorption capacities and related coefficient coefficients for each kinetic model were calculated and discussed. It was shown that the adsorption kinetics of N3 dye molecules onto porous $TiO_2$ obeys pseudo second-order kinetics with chemisorption being the rate determining step. Additionally the heterogeneous surface and the pore size distribution of porous $TiO_2$ adsorbents were also discussed.

• KSBB Journal
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• 제10권4호
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• pp.358-369
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• 1995

A mathematical model using local thermodynamic equilibrium isotherms for adsorption in encapsulated adsorbent is proposed in order to optimize the design parameters in situ bioproduct separation process. The model accurately follows the experimental data on the adsorption of berberine, secondary metabolite produced in Thaictrum rugosum plant cell culture. The adsorption rate on encapsulated adsorbent is compared with that on alginate-entrapped adsorbent. The result shows that the higher loading capacity in encapsulated adsorbent is mainly due to the increase in the maximum solid phase concentration. Based on the adsorption rate and loading capacity, the encapsulated adsorbent would be more useful than the entrapped adsorbent when used in situ bioproduct separation process. Design parameters in situ bioproduct separation process, such as the size of the capsule, membrane thickness, the ratio of capsule volume to bulk volume, the ratio of single capsule volume to total capsule volume and the adsorbent content in the capsule, are evaluated by using the model. The ratio of single capsule volume to total capsule volume is the most effective parameter for adsorption of berberine on encapsulated adsorbent.

• 대한기계학회논문집B
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• 제31권2호
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• pp.116-124
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• 2007

An adsorption chiller is expected to have high energy-efficiency in utilizing the waste heat exhausted from a process. The objective of this paper is to investigate the performance of silica gel-water adsorption chiller from the cycle simulation and to provide a guideline for design of the adsorption chiller. The effect of cycle time, inlet temperature and water flow rate on the cooling capacity and COP is quantified during the cycle operation. It is found that the performance of adsorption chiller is more sensitive to the change of inlet water temperature rather than the water flow rate. It is concluded that the COP is 0.57 in the standard conditions(hot water $80^{\circ}C$, cooling water $30^{\circ}C$, chilled water inlet temperatures $14^{\circ}C$ and cycle time 420sec).

• 대한환경공학회지
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• 제22권2호
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• pp.217-229
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• 2000

입상 및 분말 활성탄에 대한 페놀의 흡착평형실험을 $25{\pm}1^{\circ}C$에서 행하였으며 그 결과를 Freundlich isotherm으로 나타내었다. 흡착속도 실험은 회분식 흡착법으로 입자외부 물질이동저항이 무시되는 조건하에서 행하였으며, 실험결과는 LDF 흡착속도상수를 구하기 위하여 Miller의 방법으로 해석하였다. 고정층 흡착칼럼에서 페놀-활성탄계의 흡착실험을 행하였다. 흡착칼럼실험은 온도를 $25{\pm}1^{\circ}C$로 일정하게 유지하면서, 흡착대의 길이는 추산한 흡착대 길이보다 크게 하여 정형농도분포가 이루어지도록 하였다. 그리고 각기 다른 두 가지 공탑유속의 경우에 대해 실험하였다. LDF 모델식의 흡착속도계수는 흡착율에 따라 변화되며, 이 가변성 흡착속도계수를 사용하여 정형 농도변화곡선을 추정한 결과 일정 평균치를 사용한 경우보다 실험결과와 더 일치하였다.

• 한국환경과학회지
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• 제23권1호
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• pp.53-60
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• 2014

Adsorption of phenol on activated carbon in a fixed bed was studied. The effects of fixed-bed length, superficial velocity (flow rate) and particle size of adsorbent on fixed-bed performance were investigated. Some characteristic parameters such as the breakthrough time ($t_{0.05}$), saturation time ($t_{0.95}$), length of mass transfer zone ($L_{MTZ}$), adsorptive capacity (W), and adsorption rate constant ($K_a$) were derived from the breakthrough curves. Adsorbent particle sizes significantly affected the shape of the breakthrough curve. Larger particle sizes resulted in an earlier breakthrough, a longer $L_{MTZ}$ and a lower adsorption rate. Superficial velocity was a critical factor for the external mass transfer during fixed-bed adsorption process. The external mass transfer resistance was dominant as increasing superficial velocity.

• Environmental Engineering Research
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• 제21권1호
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• pp.99-107
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• 2016

The adsorption of inorganic mercury, Hg (II), in aqueous solution has been investigated to evaluate the effectiveness of synthesized gold (Au) nanoparticle-coated silica as sorbent in comparison with activated carbon and Au-coated sand. The synthesis of the Au-coated silica was confirmed by x-ray diffraction (Bragg reflections at $38.2^{\circ}$, $44.4^{\circ}$, $64.6^{\circ}$, and $77.5^{\circ}$) and the Au loading on silica surface was $6.91{\pm}1.14mg/g$. The synthesized Au-coated silica performed an average Hg adsorption efficiency of ~96 (${\pm}2.61$) % with KD value of 9.96 (${\pm}0.32$) L/g. The adsorption kinetics of Hg(II) on to Au-coated silica closely follows a pseudo-second order reaction where it is found out to have an initial adsorption rate of $4.73g/{\mu}g/min/$ and overall rate constant of $4.73{\times}10^{-4}g/{\mu}g/min/$. Au-coated silica particles are effective in removing Hg (II) in aqueous solutions due to their relatively high KD values, rapid adsorption rate, and high overall efficiency that can even decrease mercury levels below the recommended concentrations in drinking water.